High Тemp v2

Photoreactive Resin for Form 2

SAFETY DATA SHEET

Prepared: 09/20/2018
FLHTAM02

GHS-Labelling
Hazard pictograms:

Signal word: Danger

GHS FORMAT
1. Chemical Рroduct and Сompany identification
Product Identification: Photoreactive Resin
Product Class: Mixture of acrylic and methacrylic acid esters and photoinitiators
Product Use: For use in Formlabs printer Form 2
Company: Formlabs, Inc.
35 Medford Street, Suite #201
Somerville, MA
Date of Preparation: 09/20/2018
For Emergencies: North America call +1 800 255 3924
Worldwide Intl. call +01 813 248 0585
Reference Contract Number MIS4707563

2. Hazards Identification
EMERGENCY OVERVIEW
COLOR: CLEAR SLIGHTLY YELLOW
PHYSICAL STATE: LIQUID
ODOR: LIGHT ACRYLIC

*Classification of the substance or mixture:

Skin irritation, Category 2
Skin sensitization, Category 1
Eye damage, Category 1
Target Organ Systemic Toxicity: Single Exposure Respiratory Irritation Category 3
Chronic aquatic toxicity, Category 2
GHS-LABELLING
Hazard pictograms:

SIGNAL WORD: DANGER

HAZARD STATEMENTS
H315 Causes skin irritation
H318 Causes serious eye damage
H317 May cause an allergic skin reaction
H335 May cause respiratory irritation
H411 Toxic to aquatic life with long lasting effects
PRECAUTIONARY STATEMENT(S)
Prevention:
P261 Avoid breathing gas/mist/vapors/spray
P264 Wash skin thoroughly after handling
P272 Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection:

FORMLABS MSDS — HIGH TEMP V2 Photoreactive Resin for Form 2 2

Response:
P302 + P352: IF ON SKIN (or hair) : Wash with plenty of soap and water
P305 + P351 + P338: IF IN EYES : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P310: IF SWALLOWED : Immediately call a POISON CENTER or doctor/physician
P333 + P313 : If skin irritation or rash occurs: Get medical advice/attention
P362 : Take off contaminated clothing and wash before reuse
P391 : Collect spillage

SUPPLEMENTAL HEALTH INFORMATION

Potential Health Effects:
Effects due to processing releases:
irritating to eyes, respiratory system and skin. Prolonged or repeated exposure may cause: headache, drowsiness, nausea,
weakness (severity of effects depends on extent of exposure).
Other:
This product may release fume and/or vapor of variable composition depending on processing time and temperature. Possible
cross sensitization with other acrylates and methacrylates.

3. Composition/information on ingredients
Components Approximate C.A.S. No. & Hazard Statements
% by weight EINECS No.

A. Vethacrylated oligomers Proprietary Proprietary H315, H319, H335

B. Acrylated monomers Proprietary Proprietary H315, H317, H318, H411

C. Photoinitiator(s) Proprietary Proprietary H317, H411

4. First-Аid Measures
Emergency Overview: This product is a light yellow colored liquid with a characteristic odor. This product may cause skin and
eye irritation. The inhalation of high vapor concentration may cause a headache and nausea.
Inhalation: In case of exposure to a high concentration of vapor or mist, remove person to fresh air. If breathing has stopped,
administer artificial respiration and seek medical attention.
Eye Contact: Immediately flush with plenty of clean water (under eye lids) for at least 20 minutes. Hold eyelids apart to ensure
flushing. Washing within one minute of contact is essential to achieve maximum effectiveness. Seek medical attention immediately.
Do not apply oil or oily ointments unless ordered by a physician.
Skin Contact: Remove contaminated clothing and rinse contact area thoroughly with soap and water. Particular attention should
be paid to hair, nose, and ears, and other areas not easily cleaned. Wash clothing before reuse. If irritation develops, consult a
physician.
Ingestion: If ingested, dilute with water by giving glasses of water or milk to the victim. Do not give anything by mouth if the
victim is rapidly losing consciousness, is unconscious, or convulsing. Do not induce vomiting If vomiting occurs naturally, keep
airways clear. Get medical attention. Provide anestimate of the time at which the material was ingested and the amount of the
substance that was swallowed.

FORMLABS MSDS — HIGH TEMP V2 Photoreactive Resin for Form 2 3

5. Fire-Fighting Measures
Flash Point: > 93.5°C / 200°F
Method: Closed Cup
Ignition Temperature: n.d
Lower Explosion Limit: n.d
Upper Explosion Limit: n.d
Extinguishing Media: Use carbon dioxide or dry chemical for small fires; aqueous foam or water spray for large fires.
Special Firefighting Procedures: Firefighters should wear full protection clothing and self-contained breathing apparatus
(SCBA). Thoroughly decontaminate firefighting equipment including all firefighting apparel after the incident.
Unusual Fire & Explosion: Emits irritating vapors. High temperatures, accidental impurities, or exposure to radiation
or oxidizers may cause spontaneous polymerization generating heat/pressure and rupture/explosion of closed containers.
Exposure Hazard(s): Material -- Irritant

6. Accidental Release Measures

Procedures of Personal Precautions: Wear adequate personal protective clothing and equipment, as outlined in Section 8.
Environmental Precautions: Contain spill to prevent spread into drains, sewers, water supplies, or soil. Avoid release into the
environment. Dispose of in accordance with all applicable federal, state and local regulations.
Methods of Cleaning Up: In the event of a spill, immediately remove all sources of ignition. Cover the liquid with inert absorbent.
Using appropriate personal protective equipment and non-sparking tools, contain spilled material.
Waste Disposal Method: Do not dispose of in sewers, lakes, rivers or streams. Scoop all contaminated material into compatible
bottles or drums for proper disposal. Dispose of in accordance with all applicable federal, state and local regulations. National
or regional provisions may also be in force

7. Handling and Storage

Handling Precautions: User Exposure -- This product should be used in well-ventilated areas. Product may cause irritation.
Avoid contact with eyes. Avoid prolonged or repeated contact with skin. Wash hands with soap and water before eating, drinking,
smoking, applying cosmetics, or using toilet facilities. Launder contaminated clothing before reuse. Contaminated leather articles,
including shoes, cannot be decontaminated and should be destroyed to prevent reuse. Solvents should never be used to clean
hands or skin because they increase the penetration of the material into skin.
Storage Precautions: Suitable -- Store in a cool, dry place out of direct sun light, in opaque or amber containers. Store the containers
at 10-35°C (50-95°F). Do not exceed 60°C (140°F) when in storage. Keep containers closed. Avoid ignition sources.
Special Requirements: Do not heat containers with steam or electrical equipment. Heating this product above 150°C (300°F) in
the presence of air may cause slow oxidative decomposition; above 260°C (500°F) polymerization may occur. Fumes and vapors
from this thermal decomposition may be dangerous (nitrous vapors, carbon monoxide, carbon dioxide). Do not breathe fumes.

FORMLABS MSDS — HIGH TEMP V2 Photoreactive Resin for Form 2 4

8. Exposure Controls & Personal Protection
EXPOSURE LIMITS:
Component HSIS Australia IOELVs (UK) ACGIH TLV OSHA PEL WEEL
1. Methacrylated oligomerы None None None None None
2. Acrylated monomers None None None None None
3. Photoinitiator(s) None None None None None

No occupational exposure limit values exist for the materials contained in this product.

NOTATIONS:
IOELVs — Indicative Occupational Exposure Limit Values
TWA — Time Weighted Average
OEL — Occupational Exposure Limits
PEL — Permissible Exposure Limit
TLV — Threshold Limit Value
STEL — Short Term Exposure Limit
WEEL — Workplace Environmental Exposure Level by the American Industrial Hygiene Association

EXPOSURE CONTROLS:
Ventilation Controls: Ensure adequate ventilation.
Respiratory Protection: Respirators are generally not needed under normal conditions of use. If this material is handled at
elevated temperature, under mist forming conditions or in case of accidental release of large quantities of product use a full-
face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering
controls. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US)
or CEN (EU).
Protective Gloves: Wear impervious gloves (nitrile or neoprene) for routine handling.
Eye and Face Protection: Chemical splash goggles or a face shield is recommended during operations where splashing could occur.
Skin Protection: Avoid all skin contact. Depending on the conditions of use, cover as much of the exposed skin area as possible
by wearing gloves, aprons, long pants, and long sleeved shirts.
Other Controls: For operations where contact can occur a safety shower and eye wash facility should be available. Always use
good personal hygiene and housekeeping practices. Wash hands thoroughly after handling.
Environmental Exposure Controls: Keep product from waterways and watersheds. This substance is not readily biodegradable
and is dangerous for the environment. Avoid release into the environment.

9. Physical & Chemical Properties

Appearance: Liquid, slight yellow color
Odor: Light/Characteristic/Acrylate
Value Unit Method
Specific Gravity: 1.09 –1.12 g/cm³
Boiling Point: > 100 °C
Flash Point: > 93.5 °C
Ignition Temperature: n.d.
Lower Explosion Limit: n.d.
Upper Explosion Limit: n.d.
Viscosity: ~2,550 cps @ 25°C (77°F)

FORMLABS MSDS — HIGH TEMP V2 Photoreactive Resin for Form 2 5

Vapour Pressure: Not established
Solubility in Water: Only very slightly soluble
Solubility in Organic Solvents: Soluble in organic solvents
Volatile Characteristics: Negligible
Electrostatic Discharge: Safe
Electric Conductivity: Dielectric

10. Stability and Reactivity

Stability: Stable when stored in original container designed for use with light sensitive materials under 35°C (95°F) in dark,
cool place.
Product may crystallize in prolonged storage at < 10oC
Conditions to Avoid: Storage >100°F, exposure to light, loss of dissolved air, and contamination with incompatible materials.
Incompatible Materials to Avoid: Polymerization initiators, including peroxides, strong oxidizing agents, alcohols, copper, copper
alloys, carbon steel, iron, rust, and strong bases.
Hazardous Decomposition Products: Hazardous decomposition products may include oxides of carbon, nitrogen, phosphorus
and varioushydrocarbon fragments.8
Hazardous Polymerization: Hazardous polymerization may occur. Uncontrolled polymerization may cause rapid evolution of
heat and increase in pressure that could result in violent rupture of sealed storage vessels or containers.

11. Toxicological information

A. Methacrylated oligomers No data available. Not tested on animals to obtain numerical data.
B. Acrylated monomer Virtually nontoxic
Acute Oral toxicity (rat) LD50 > 2000 mg/kg body weight (vendor literature)
Acute Dermal toxicity (rabbit) LD50 > 5000 mg/kg body weight (vendor literature)
C. Photoinitiator(s) Acute toxicity
Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Virtually nontoxic
after a single skin contact
Acute Dermal Toxicity LD50 > 2000 mg/kg body weight (vendor literature)

Individual components of this product are not reported to produce mutagenic effects in humans. None of the components of
this material are listed by IARC, NTP, OSHA or ACGIH as carcinogens.

12. Ecological information

Some components are toxic to various aquatic species. Keep product from waterways and watersheds. This substance is not
readily biodegradable. Dispose of in accordance with all applicable federal, state and local regulations.
A. Methacrylated oligomers No data available
B. Acrylated monomer Some components are toxic to various species of fish,
algae and water microorganisms
C. Photoinitiator(s) Some components are toxic to various species of fish, algae and water microorganisms

13. Disposal Considerations

Dispose of in accordance with governmental regulations (community, national or regional). Contact a licensed professional
waste disposal service to dispose of this mixture. As with all foreign substances, do not allow to enter storm or sewer drainage
systems. Avoid release into the environment.
Contaminated Packaging: Dispose of as unused product. Expose the open emptied container to light, then dispose.

FORMLABS MSDS — HIGH TEMP V2 Photoreactive Resin for Form 2 6

14. Transport Information
US Department of Transportation (DOT)

UN Number: 3082
Proper shipping name: Environmentally hazardous substance, liquid, n.o.s.
Technical name: (contains Tricyclodecane Dimethanol Diacrylate)
Class: 9
Packaging group: III
Marine pollutant: yes

International Maritime Dangerous Goods Code (IMDG)

UN Number: 3082
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Technical name: (contains TRICYCLODECANE DIMETHANOL DIACRYLATE)
Class: 9
Packaging group: III
Marine pollutant: yes

International Air Transportation Association (IATA)

UN Number: 3082
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Technical name: (contains TRICYCLODECANE DIMETHANOL DIACRYLATE)
Class: 9
Packaging group: III
Marine pollutant: yes

This product is not regulated as a dangerous good when a single unit is transported in container sizes of ≤5 L or ≤5 kg,
provided the packaging meet the general provisions of 5.0.2.4.1, 5.0.2.6.1. 1 and 5.0.2.8. Quantity of single units packaged in
less than 5L containers does not impact regulation.

15. Regulatory Information

The following provides a summary of the legal requirements.

EUROPEAN ECONOMIC COMMUNITY (EEC) CANADA REGS

Ingredient EPA* CA EINECS European Listed as dangerous EC1272/2008 DSL NDSL
TSCA Prop Community chemicals per ESIS
65 Standards

A. Methacrylated H315, H319,

Yes No Yes None No Yes Yes
oligomers H335

B. Acrylated H315, H317,

Yes No Yes No No Yes Yes
monomer H318, H411

C. Photoinitiator(s) Yes No Yes No No H317, H411 Yes No

All the components present in this product at concentrations equal to or greater than 0.1% are listed, or excluded from listing,
on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory.

SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
Pursuant to Title III of the Superfund Amendments and Reauthorization Act of 1986, (SARA) and 40 CFR 372 Part 372, this product
does not contain chemicals subject to the reporting requirements under Section 313.
California Proposition 65: This product does not contain chemicals which are known to the state of California to cause cancer.

FORMLABS MSDS — HIGH TEMP V2 Photoreactive Resin for Form 2 7

16. Other information

REFERENCES:
1. 2011 Threshold Limit Values and Biological Exposure Indices. American Conference of Governmental Industrial Hygienists.

2. MSDS + Cheminfo CD-ROM, Canadian Centre for Occupational Health and Safety
3. SAX’S Dangerous Properties of Industrial Materials, Tenth Edition
4. TSCA & SARA Title III, U.S. Environmental Protection Agency and the National Technical Information Services
5. Raw Material Manufacturers Material Safety Data Sheets
6. US National Institute of Medicines Toxnet current edition
7. ESIS: European Chemical Substance Information System, http://ecb.jrc.it/esis
8. NOHSC Hazardous Information Substances Information System, Department of Employment and Workplace Relations,
Australian Government, 2005
To the best of our knowledge the information contained herein is accurate. However, Formlabs, Inc. makes no warranty, expressed
or implied, regarding the accuracy of these results to be obtained from the use thereof. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist. Formlabs, Inc. assumes no responsibility for injury from the
use of the product described herein.

FORMLABS MSDS — HIGH TEMP V2 Photoreactive Resin for Form 2 8