MATERIAL SAFETY DATA SHEET NAGR 2015 1.

IDENTIFICATION OF THE SUBSTANCE OR PREPARATION AND THE COMPANY : CRACKDOWN 15 EC : AEF03264000EC02A1 : Hoechst Schering AgrEvo S.A. Saint Aubin Les Algorithmes, Immeuble THALES GIF sur YVETTE CEDEX 91197 FRANCE Toxicology Logistic 2. Tel:(33)4.91.24.45.83 Tel:(33)4.91.24.45.45 Fax:(33)4.91.24.46.84 Fax:(33)4.91.24.46.46 Tel:(33)4.91.35.96.96 Fax:(33)4.91.24.46.46

Trade name Product code Supplier

Medical emergency phone number 24H/24H 2-1. Composition/Information on ingredients Synonyms Chemical family Kind of use CAS 052918-63-5 064742-95-6 3.

COMPOSITION/INFORMATION ON INGREDIENTS :Deltamethrin: 15g/I EC :Pyrethroids :Insecticide. Emulsifiable concentrate. EINECS 258-256-6 265-199-0 Wording Deltamethrin Petroleum Concentration 15g/I 800g/I Symbol T,N Xn,N Risks Phrases 20-25-50/53 10-37-51/53-56

2-2. Hazardous constituents

HAZARDS IDENTIFICATION EC:Not classified

Symbols and labelling

Main hazards Specifics risks Main accute symptoms

: Flammable : Dangerous to aquatic organisms. : *The following symptoms may occur: *Local: skin and eyes paraesthesiae which may be severe. Usually transient with resolution within 24 hours. *Systemic: dizziness, headache, listlessness, nausea and vomiting, epigastric pain, muscular fasciculation of limbs, unconsciousness, convulsions and coma (very high doses)

4.

FIRST-AID MESURES IN CASE OF EXPOSURE :*Symptomatic treatment after decontamination. *Local contamination: *Skin: apply vitamin E cream or simple toilet milks. *Eye: instillation of local anaesthetic drops e.g. 1% amethocaine hydrochloride eye drops.

Instructions for physicain

*Give analgesics as necessary. *Can cause severe pain. *Systemic poisoning. *Monitor fonction: respiratory, cardiac. *Observe specific parameters: electrocardiograph, check for pulmonary oedema in event inhalation. *Gastric lavage. Charcoal administration. *Endotracheal intubation. Artifcial respiration as necessary. *Elimination by: dialysis, haemo-perfusion. *Anticonvulsions therapy: diazepam i.v. *Contraindications: 1.Adrenergic compounds. 2 Areopine. *Recovery: spontaneous. *Must not be confused with organophosphorous compounds. Inhalation :Remove to fresh air. *Keep at rest. If required, seek medical advice immediately. Skin contact :*Carefully remove contaminated clothing. *Wash affected area with soap and water. In case of persistent irritation, seek medical advice. Eyes Contact Ingestion :*Rinse immediately with clean water for at least 15 minutes and obtain Medical aid. :*Wash out mouth with water. *Do not induce vomiting. *Give water to drink. *Keep patient at rest. *Obtain medical advice immediately. 5. FIRE-FIGHTING MEASURES : Water spray jet, CO2, foam, dry chemical. : Jet of water from a fire hose. : In case of hire, the product emits toxic and irritating fumes. : Wear suitable protective clothing. Wear a self-contained breathing apparatus. Other recommendations : Avoid rejection of extinguishing water in the environment. Cool with water the containers against excessive heat. Keep away fromm heat and flame if possible. Do not breathe fumes. Suitable extinguishing media Unsuitable extinguishing Media Fire and explosion hazards Special protective equipment

6.

ACCIDENTAL RELEASE MEASURES : *Before intervention wear protective equipment (cf 8-2). Avoid contact with chemical or contaminated surfaces.

Personal protection

Environment precautions

: Absorb with liquid binding material (sand, cement, line). Sweep and store the material collected into a suitable container. Keep safe for disposal according to regulations. Prevent entry into drains, sewers and watercourses.

Clean-up procedures

: Rinse the contaminated area with a large quantity of water and cleaning agent.

7.

HANDLING AND STORAGE : Use local exhaust ventilation at the source of the contamination. Emergency shower and eye-wash system should be available.

7-1. HANDLING Technical measures

Special protection measures : Do not spray facing the wind. Special precautions 7-2. STORAGE Sensitivity to damp Sensitivity to light Sensitivity to oxidation Storage temperature Low temperature to be avoided Special storage requirement : Keep away from food, drink and animal feeding stuffs. Storage facilities Recommended packaging material Supplier packaging Packaging material to be avoided Other recommendations : Keep only in the original container. Do not re-use empty containers. Respect the height of advice piling. 8. EXPOSURE CONTROLS/PERSONNAL PROTECTION : Wear mask with organic vapour cartridge (A) : Wear solvent-proof gloves. : P.E.T., Steel drum. : PEHD. : *Store in a well ventilated place. : *Aluminium, tinplate, PET, iron. : Not observed. : *Keep protected from direct sunlight. : Not observed. : Keep at ambient temperature. : *Protect from frost (Crystal formation reversible). : Wash hands and exposed part of the body with soap after any handling.

8-1. CONTROL OF EXPOSURE Respiratory protection Hands protection

Eyes protection Skin and body protection Specific hygiene measures 9. PH Characteristic temperatures Flash point Auto-Inflammability Inflammability limits

: *Wear goggles. : Wear suitable protective clothing. : Use only in well-ventilated area.

PHYSICAL AND CHEMICAL PROPERTIES : Light yellow liquid, aromatic odor. : 5 to 7 at 1% in water. : Freezing point: less than-10. : 42 (Closed cup). : 450 (solvent). : Lower: 0.8% m/m (solvent). Upper: 7% m/m (solvent).

Appearance

Inflammability Density Solubility Partition coefficient Octanol/Water

: Flammable. : 0.88 to 0.90 at 20 : Emulsifiable in water : *Deltamethrin: Log Pow =5.43

10. STABILITY AND REACTIVITY Products of decomposition Avoided conditions :*No decomposition under normal conditions. :*Keep away from heat and source of ignition.

11. TOXICOLOGICAL INFORMATION Acute toxicity :Toxicological assesment made on a similar composition (25 g/l). LD 50 oral route/rat: (male+female): 431 mg/kg. LD 50 cutaneous route/rabbit:>2000mg/kg. Irritant potential : Toxicological assesment made on a similar composition (25 g/l). Ocular irritation (rabbit): very irritating. Cutaneous irritation (rabbit): slightly irritation/ Sensitization : Toxicological assesment made on a similar composition (25g/l). Not sensitizing (guinea-pig) : (Buehler). Due to the presence of solvents in the preparation dermatosis may occur by repeated and prolonged contact with skin. Chronic toxicity : *Deltamethrin. Not mutagenic. Not teratogenic Not carcinogenic.

*Deltamethrin : NOEL = 1 mg/kg.bw/day. Comments/symptoms : Somer cutaneous sensations may occur, such as burning, stinging Sensations on the face and mucosa, without lesions and transient some hours, maximum 24 h. *Due to the presence of solvens in the preparation, may cause lung damage if swallowed. 12. ECOLOGICAL INFORMATION Environment protection Mobility Ecotoxicity :Prevent entry into drains, sewers and watercourses :Deltamethrin: fixed in most soils. :*Deltamethrin: LC50 (96h) fish: 0.001-0.01 mg/l. EC 50 (48) daphnia: 0.0035 mg/l. IC 50 (72) algae:>1000 mg/l. 13. DISPOSAL CONSIDERATIONS Waste and residue :Incineration in accordance with the local waste regulation authority. *Do not discharge washing waters in public sewers and water sources (ponds, streams) Destruction soiled packaging :Empty and tripe rinse. Make the container unsuable. Disposal must be traited according to official regulation. 14. TRANSPORT INFORMATION NUN 14-1.BY ROAD Transport assimilation Class Item number Label Hazards Code 14-2. O.A.C.I. (By Air) Transport assimilation Class Group Label Passengers Cargo :Flammable liquid, n.o.s. (Petroleum distillates) :3 :III :3 :309 (60L) :310 (220L) :Flammable liquid, n.o.s. (Petroleum distillates) :3 :31) :3 :30 :1993 Persistence and degradability :Deltamethrin: DT 50 in most soils from 4 to 9 days.

14-3. I.M.D.G. (By Sea) Transport assimilation Class Group Label Mark :Flammable liquid, n.o.s. (Petroleum distillates) :3.3 :III, page 3345 :3 :Marine pollutant (Deltamethrin)

15. REGULATORY INFORMATION 15-2. LOCAL REGULATIONS OF COUNTRY Listed facilities Professional diseases Biomonitoring Symbols and labelling EC: Not classified SPECIAL RISKS (R) 10 SAFETY ADVICE (S) 2 13 20/21 36/37/39 45 :Keep out of the reach of children. :Keep away from food, drink and animal feedingstuffs. :When using do not eat, drink or smoke. :Wear suitable protective clothing, gloves and eyes/face protection. :In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). 16. OTHER INFORMATION Further indications :Refer also to technical instructions for use. MSDS: AGR 1182 The inforamtion given in this data sheet has been introduced in accordance with the guidelines established by article 10 of EEC directive, dated March 5,1991. This data sheet complements the userss instructions, but does not replace them. The information it contains is based on the knowledge available about the product conerned at the time it was compiled. Users are further reminded of the possible a product for purposes other then those for which it was intended. The required information complies with current EEC legislation. Addressees are requested to apply any additional national requirements. Document on reference :In-house data. :Flammable. :1155-253B (France). :Concerned, board 4bis and 84 (France). :Blood test (France).