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Corona Treater

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C

S Corona Supplies Ltd


for all your corona needs

26 Foresters, Bicester Road, Oakley, Bucks. HP18 9PY. UK.


Telephone: +44 (0) 1844 237580 ~ Fax: +44 (0) 1844 237649 ~ E-mail: sales@coronasupplies co.uk

GX 10 / 20
GENERATORS

INCLUDING
GENERATOR & ELECTRODE
MAINTENANCE
2

CONTENTS

1. Introduction

2. Specification

3. Description & Installation

3.1 Description of Equipment


3.2 Installation & Connection

3.2.1 PL1 Mains Input


3.2.2 SK2 Underspeed Probe
3.2.3 Output to HT Transformer
3.2.4 Remote Control & Skip/Treat
Functions
3.2.5 HT Transformer

4. Operating the Equipment

5. Routine Maintenance

6. Description

6.1.1 Circuit Overview


6.1.2 Power Supplies & Interlocks
6.1.3 Inverter Operation
6.1.4 Inverter Control Card

7. Trouble Shooting

8. Matching Generator to Electrode

9. Parts List

10. Machinery Safety

11. Ozone : Health Hazards and Precautionary Measures

GX10 / 20 240V - English


3

SHERMAN SOLID STATE TREATER GENERATOR

GX10 / 20

This handbook has been produced to give you every possible


assistance in the installation and maintenance of your HIGH
FREQUENCY SOLID STATE TREATER GENERATORS.

GX10 / 20 240V - English


4

SHERMAN TREATERS GX20 TRANSISTORISED HIGH


FREQUENCY GENERATOR

GX10 / 20 SPECIFICATION

Input Voltage 240 Volts +/- 10%

Input Current 8 / 15 Amps R.M.S. max

Input Frequency 50/60 Hz

Generator Operating Frequency 20 kHz +/- 5%

Treatment Power 1kW / 2kW

Inverter KVA Rating 2 / 4 KVA

Maximum Output Voltage 600 Volts R.M.S.

Maximum Output Current 10 / 15 Amps R.M.S.

Cabinet Dimensions 475 (h) x 375 (w) x 225 (d)

Weight 22 kg

TRANSFORMER

HT3 20 kg

Check rating plate for operating voltage

Drawing No’s.

A2.851002.01 GX10 (240V) Circuit Diagram

A2.851002.03 GX20 (240V) Circuit Diagram

GX10 / 20 240V - English


5

SECTION 3

3.1 Description of the Equipment

The corona treatment equipment consists of three main parts

(a) The Generator


(b) The High Voltage Transformer
(c) The Electrode Box

(a) The Generator/Inverter converts power from the mains


supply to a suitable high frequency ac for production of the
corona.

The mains input to the unit is rectified to give about 300


volts dc. This is then converted to high frequency ac by
the inverter and applied via an inductor and decoupling
capacitor to the inverter output terminals.

(b) The High Voltage Transformer converts the inverter output


voltage to a sufficiently high voltage to produce the
necessary corona discharge at the electrode. It is tapped
in order to obtain optimum matching of the inverter to the
electrode system.

(c) The Electrode unit consists essentially of one earthed


plane, an air gap, an insulating dielectric, such as silicone
or ceramic, and a high voltage plane. The corona is
formed across the air gap through which the material to be
treated is passed.

3.2 Installation and Connection of Equipment

The Electrode Box must be mounted so that its rollers are exactly
in line with the machine rollers. It should be free to open and be
easily accessible for adjustment and maintenance. The H.T.
Transformer must have all round air supply for cooling purposes
and be mounted in the upright positions. (Identification label
uppermost).
Idler rolls, usually mounted on top of the unit for transit purposes,
should be positioned so as to guide the web through the Electrode
Box without obstruction.

GX10 / 20 240V - English


6

N.B. It is important that the electrode gap is checked prior to


the electrode unit being switched on.
All electrode units have the discharge air gap set before they
are despatched, however the gap may move out of alignment
during transit or installation.
Do not switch the generator power on before rechecking that
the air gap is correct (see Section 4).
Failure to follow these instructions could result in damage to
the roll covering or the electrode and could invalidate the
warranty on these items.

Pneumatically operated units should be connected to a filtered and


lubricated air supply of at least 60 p.s.i. (4.0 bars).

Ozone, which is produced by corona discharge, must be removed


from the area by connecting a suitable extraction fan to the ports
provided on the electrode Box.

Air purged Electrode Boxes must be connected to a suitable fresh


air blower by way of the inlet port provided, so that a positive
pressure of 0.5mm water gauge is maintained within the unit when
an ozone extraction fan is fitted and working. A pressure switch is
provided, which is normally connected into the generator safety
interlock system. Please refer to the circuit diagram at the rear of
the manual.

All Sherman Electrode units are fitted with safety switches at all
access points. All hoods, windows, etc must be closed before the
generator can operate.

3.2.1 PL1 Connection to the Mains Supply

The generator requires a 220-240 Volt, single phase, 50/60 Hz


supply as specified on the rating plate. The cable supplied should
be connected BROWN-LIVE PIN A, BLUE-NEUTRAL PIN B,
GREEN/YELLOW EARTH PIN C. The input fusing should be
suitable for the protection of the cable between the supply and the
inverter unit.

GX10 / 20 240V - English


7

3.2.2 SK2 Underspeed Probe

Socket SK2 is for a 3 core cable from a speed rotation sensor.


The rotation sensor consists of a rod-like device encapsulating a
reed switch activated by four magnets. The four magnets, two red,
two blue, must be fitted alternately (red, blue, red, blue) around the
end of the roll to be monitored. These should be attached using
non-ferrous fixings. The sensor must be fitted so that the magnets
pass within 5mm of its flat end face.

3.2.3 SK3 Output to H.T. Transformer

The cable supplied with the equipment should be used for


generator connection to the H.T. Transformer and should NOT be
lengthened without reference to Sherman Treaters. The current
flowing in the cable will be up to 15 Amps R.M.S. maximum and
the voltage will not exceed 600 Volts ac R.M.S.

Due to the high operating frequency of the inverter this cable


MUST NOT be run in steel conduit or clipped to steel trays as the
eddy current losses in the steel will cause heating, reducing the
effective inverter treatment power.

3.2.4 SK4 Remote Control and Skip/Treat Functions

(a) Skip/Treat. In order to treat only limited segments of


material it is possible to fit a volt free contact between pins
A and B of this plug. When this contact is closed treatment
will take place. If option is not used A and B should be
linked.

(b) Where no rotation sensor is fitted Pins A and B will/may be


connected to a customer's volt free contact in order to put
the generator into standby when the customer's line stops.

(c) Remote Control. To switch the generator off remotely a


contact can be fitted across pins E & F of PL4 (The link
between pins E & F being removed first).

GX10 / 20 240V - English


8

3.2.5 H.T. Transformer

Ensure that the cable from the generator is correctly connected to


the transformer. Check that the transformer case is firmly
connected to the electrode case (which is earthed) and that the
high voltage connection is made from the transformer to the
electrode. An adaptor is supplied in order that an H.T. probe with
a 3mm thread may be used to make the high voltage connection of
Sherman units. This may be discarded when the transformer is
used with other electrode systems. The breather screw should be
fitted before use.

N.B. The transformer should only be operated in an upright


position as indicated on the label.

GX10 / 20 240V - English


9

SECTION 4

Operating the Equipment

In order to obtain optimum treatment from the system it is


necessary to correctly match the generator to the electrode
system. This is done by the selection of the correct tap on the H.T.
Transformer and the correct setting of the choke in the inverter for
the electrode type (Section 4).

(a) Setting up Electrodes

For single sided treatment, the flexible link that connects the H.T.
Transformer to the unused discharge bar should be removed at
the H.T. end and securely stowed. The length of the electrode
(bar) may then be adjusted so that corona only occurs coincident
with the area of the film to be treated. 'U' section electrodes may
be adjusted by loosening the wing nuts on each adjustable section
and sliding the sections to the required position. Segmented
electrodes may be adjusted to give strip treatment. Segments in
use should be turned fully down and those not in use fully up.

Sherman standard electrode units are fitted with calibrated dials


which indicate directly and the gap setting. Some special units do
not have this facility and the gap must be set using a suitable
feeler gauge. Gap setting mechanisms must be locked after use
to prevent inadvertent maladjustment. Careful setting of the gap is
essential if even and effective treatment is to be obtained.

N.B. It is important that the electrode gap is checked prior to


the electrode unit being switched on.
All electrode units have the discharge air gap set before they
are despatched, however the gap may move out of alignment
during transit or installation.
Do not switch the generator power on before rechecking that
the air gap is correct (see Section 4).
Failure to follow these instructions could result in damage to
the roll covering or the electrode and could invalidate the
warranty on these items.

GX10 / 20 240V - English


10

(b) Initial Switch On

It is assumed that all connections have been made as described


previously. Ensure the Output Power Control Potentiometer is
turned fully anticlockwise (minimum).

Turn the circuit breaker on the front panel to the on position. The
'Mains On' lamp, 'Up to Speed' lamp and 'Interlocks Closed' lamps
should light.

If the 'Up to Speed' lamp fails to light then check:

i. that a probe is fitted


ii. that the electrode rolls are turning
iii. that the circuit has been correctly adjusted
iv. that the circuit is switched out (SW1) if not required on the
control circuit card, ie, SW1 is in the down position.

If the 'Interlocks Closed' lamps fails to light then check electrode


safety switches by removing PL4 and checking continuity between
pins F and G on PL4. Check also that this interlock light
extinguishes if the interlock circuit is broken.

Press the Start/Stop switch and after a brief delay the 'Treat On'
lamp should light when corona discharge takes place.

Increase the treatment power by turning the Power Control


potentiometer slowly clockwise. The Treatment power is indicated
by the meter on the front panel and is adjustable between 0 and
1kW / 2kW. If the full power range is not available, then it is
probable that the electrode is incorrectly matched to the generator
(Section 8).

If, as the power increased the red 'Trip' light comes on it is possible
that
i. there is a matching problem (Section 8)
ii. there is fault on the dielectric sleeve on the electrode roll
iii. the high voltage connections have flashed over

GX10 / 20 240V - English


11

(c) Normal Operation After Initial Checks

i. Turn on Mains Circuit Breaker


ii. Depress Start Button
iii. Set Power Demand Potentiometer to required level
iv. Press Stop button to stop treatment

N.B. ALWAYS use Start and Stop buttons for all normal Starting
and Stopping. Use mains on switch only as an isolator for
prolonged shutdown.

GX10 / 20 240V - English


12

SECTION 5

Routine Maintenance

All maintenance should be carried out with the mains supply


disconnected from the system.

(a) Generator - Clean air filter periodically. Change any defective


lamps. Clean inside of generator.

(b) Electrode System

Examine electrode box or roller unit periodically and remove


accumulations of dust and dirt. Clean dielectric sleeves using a
suitable cleaner. Replace any high voltage insulators which show
signs of severe discoloration, or damage. Regrease all adjusting
mechanisms with silicone grease. Confirm that all safety interlocks
are working correctly and that the ozone extraction system is
effective.

Pinholes that may occur in silicone rubber sleeves may be


repaired using silicone rubber compound. The area around the
pinhole must first be removed using a 1mm punch. Allow sufficient
time for compound to harden after application.

If sleeves are badly worn, or damaged they must be replaced.


Silicone rubber sleeves may be removed by inserting the nozzle of
a compressed air line between the sleeve and the metal roller.
The roller should be cleaned and about 50mm of the new sleeve
pulled over it. The air line nozzle should then be reinserted and
the sleeve pulled along the roller. The sleeve should overlap the
roller by 50mm at each end.

GX10 / 20 240V - English


13

SECTION 6

Description of Circuit Operation

6.1.1 Circuit Overview

6.1.2 Power Supply and Interlock Circuit

6.1.3 Inverter Operation

6.1.4 Inverter Control Card

6.1.1 Circuit Overview

Referring to circuit diagram A2.851002.01 / 03 the input power is


fed in through CB1 and mains filter MF1. On closure of CB1
power is fed to the inverter power supply card and the fan via FS1
and FS2. The mains is rectified by BR1, filtered by C1 and fed via
fuse FS3 to the inverter bridge assembly. The inverter assembly,
controlled by the inverter control card produces high frequency ac
which is fed via L1 and decoupling capacitor C2 to the inverter
output. Monitoring and control is provided by CT1 (metering), CT2
(power control), CT3 (inverter current control) and T1 (inverter
voltage limiting).

6.1.2 Power Supply and Interlocks

The power supply is fed from one torroidal transformer to give two
independent supplies, one for the electronics (E) and one for the
auxiliaries (A). Each supply is floating (i) with respect to each
other and (ii) with respect to the mains input and inverter output.

The electronics supply is used solely for feeding the electronics


control card for the inverter.

The auxiliaries supply is used for feeding the metering, indication


and items external to the unit such as the speed rotation sensor
and the interlock circuit.

GX10 / 20 240V - English


14

Each supply is independently fused on the power supply card.


The Interlock CCT runs from the +24V (A) supply to pin F on SK4.
From pin E on PL4 through any microswitches on the electrode
unit, back to pin G on PL4. PL4 pin E being linked to pin F to
complete the CCT. Indication of circuit continuity is given by LP5
the interlock closed lamp.

SK4 Pins A and B are linked. When skip treatment is required the
link should be removed.

6.1.3 Inverter Operation

The Inverter consists essentially of eight transistors (GX20) (Q1 -


Q8) connected in bridge configuration with various auxiliary
components to aid satisfactory power circuit operation. (Diagram
A2/200002.02).

Regarding these transistor (Q1/5, Q2/6, Q3/7, Q4/8) purely as


switches, Q1/5 and Q2/6 switch in opposition - ie, Q1/5 is on the
Q2/6 is off and vice-versa. The same is true for the switching of
Q3/7 and Q4/8.

If Q1/5 is switched on at the same time as Q3/7 (and therefore


Q2/6 at the same time as Q4/8) then the overall voltage at the
inverter output O1 and O2 will be zero. If Q2/6 is switched on at
the same time as Q3/7 (and therefore Q1/5 at the same time as
Q4/8) then the overall voltage at the inverter output will be a
square wave with a peak to peak value of twice the dc voltage
applied to the inverter.

By altering the switching of Q1/5 and Q2/6 relative to the switching


of Q3/7 and Q4/8 (ie, the phase) it is possible to vary the effective
inverter output voltage between the two points defined in the
paragraph above.
This voltage is applied via choke L1 and decoupling capacitor C2
the H.T. Transformer (Drawing A3.200001.04). The secondary of
the H.T. Transformer supplies the electrode.

The capacitance of the electrode will form a resonant circuit with


the inductance L1 in the inverter and dependent upon where the
inverter frequency (fixed) lies relative to the resonant frequency of
this circuit determines the KVA the inverter has to provide to give
the required treatment power (kW).

GX10 / 20 240V - English


15

The KVA rating of the inverter is twice the rated treatment power
(kW). If the full KVA rating of the inverter is exceeded, the trip light
LP3 will come on. To overcome this problem it will be necessary
to change the tapping on the transformer, or in extreme cases the
value of L1, in order to obtain full treatment power.

N.B. The trip light will also operate if there is a fault on the
electrode system, or with the H.T. Transformer itself.

6.1.4 Inverter Control Card

The main printed circuit card contains all the functions for the
control and protection of the inverter (Drawing A1/100007.05). All
interfacing with the card ensures that the card is electrically
independent from other supplies and signals within and outside the
inverter.

The basic inverter control is performed by IC1, IC4, IC7 and IC5.
The master oscillator is within IC1, which produces the drive
pulses (TP9 and TP20) for output transistors Q1/5 and Q2/6, via
T1 and T2. IC7 produces the drive pulses (TP15 and TP18) for
Q3/7 and Q4/8. The main control amplifier is within IC4 and the
width of the pulse on TP11 determines, via the logic in the IC5 the
phase shift between the switching of Q1/5 and Q2/6 and Q3/7 and
Q4/8. This determines the output voltage from the inverter.

The heart of the control lies on IC4 and the following parameters
are used to achieve it.

i. Power Demand derived by IC11 from the treatment power


demand potentiometer and the real current feedback from CT2
via D20-D23.

ii. Inverter Voltage feedback from T1 via D2-D5.

iii. Inverter Current feedback from CT3 via D6-D9.

iv. Clamping due to the various alarm and control functions


(described later).

GX10 / 20 240V - English


16

The Power Demand is fed in via R67 to pin 2 of IC4. This is offset
by the inverter current feedback through R82 and R83. Under
normal operating conditions the amplifier in IC4 will now control so
that the power demand is met.

Should the inverter output voltage exceed 600 volts ac then the
voltage feedback signal will overcome the zener voltage of ZD1
and feed via R9 into pin 2 of IC4 to limit this voltage thus restricting
the power demand.

The board contains various alarm and control circuits as follows:

i. Up to Speed. This is sensed externally as described in


section 1.2 (SK2). The signal (TP3) is fed into a
monostable (IC6) and into level comparator (IC8). This
signal is fed into the trip circuit logic (IC9). External
indication is given via RL2.

ii. Start/Stop. The signal (TP4, 0 volts = Start) is fed directly


into the trip circuit logic (IC9).

iii. Overtemperature, sensed by a thermostat on the inverter


heatsink (TP5, 1 = Overtemperature), feeds directly into
the trip circuit logic (IC9).

iv. Skip/Treat. This signal (TP6, 0 = Treat) is fed directly into


the trip circuit logic (IC9).

v. Instantaneous Current Trip (IC2). The inverter current


feedback signal is compared with a threshold level set on
RV2. Should the comparator toggle on an overcurrent this
triggers a monostable (IC6), the output of which feeds into
the trip circuitry (IC9).

The pulse from the monostable will inhibit the inverter


output for 1.5 seconds, after which the inverter will restart.
CONTINUAL OVERCURRENT WILL PRODUCE A
REPEATED TRIP SIGNAL AND THE TRIP LAMP WILL
NOT BE SEEN TO EXTINGUISH. External indication is
given via RL3.

GX10 / 20 240V - English


17

vi. Power Supply Prime is achieved with C15 and R47.

All of the above six functions inhibit the output of the inverter via
logic contained in IC9 and IC10, by clamping the amplifier on IC4
with TR1. In addition the contactor will open (controlled by RL1) if:

i. Start button not depressed.


ii. Power supply prime not present.
iii. Unit overtemperature.
iv. Interlocks open - This function is hard wired into the
contactor circuit.

IC3 detects a low level of inverter current which gives indication of


'Treat On' via RL4.

NOTE: With the exception of RV5 all the potentiometers on the


card are factory set and sealed. They MUST NOT be
tampered with.

GX10 / 20 240V - English


18

SECTION 7

Trouble Shooting

In the event of a problem, follow carefully the procedures listed


below. Bear in mind that high voltages exist within the inverter
cubicle and any checks within the cubicle must be carried out with
the MAINS SUPPLY ISOLATED. 30 SECONDS SHOULD BE
ALLOWED AFTER ISOLATION OF SUPPLY FOR THE
DISCHARGE OF CAPACITORS WITHIN THE UNIT.

SYMPTOM

Inverter gives no treatment, but 'Mains On' lamp lit.

CHECKS

i. Check 'Up to Speed' and 'Interlocks Closed' lamps are lit. If


not, investigate cause.

ii. Check that Skip/Treat contact is closed if fitted, or that pins


A and B of PL4 are linked.

iii. ISOLATE INVERTER. Check electrode system for visible


signs of trouble and for continuity of connections.

iv. With inverter isolated, open the inverter cubicle and with a
suitable measuring instrument check continuity of inverter
fuse FS3 (Drawing A2.851002.01 / 03). If open circuit,
consult Sherman Treaters, as there is probably a fault on
the inverter stack. Check both fuses on the Power Supply
card. Replace if blown and investigate cause.

v. Remove RL1 and check resistance of coil (350 ohms).

GX10 / 20 240V - English


19

SYMPTOM

Inverter gives no treatment, no lamps lit.

CHECKS

i. Check that mains supply is present to the unit and that


CB1 is
closed.

ii. Isolate mains supply. Check the two fuses on the power
supply card and the fuse feeding the power supply FS2.

SYMPTOM

Inverter 'Trip' light comes on.

CHECKS

This will be due to a fault on the electrode system, or on the H.T.


Transformer, assuming that the system has been correctly
matched.

Examine the electrode system and the dielectric sleeve for signs of
burning, or other damage.

SYMPTOM

Mains Input Circuit Breaker trips

CHECKS

This will be due to either a faulty bridge rectifier BR1, or a problem


with the capacitor precharge circuit A3/100005.05.

GX10 / 20 240V - English


20

SYMPTOM

Inverter Overtemperature

CHECKS

i. The fan is operating and all air inlets and outlets are clear.
If the fan has failed, check fuse FS1 on Drawing
A2.851002.01 / 02

ii. The generator is not being exposed to excessive heat.

If the problem persists, consult Sherman Treaters Service


Department for advice.

GX10 / 20 240V - English


21

SECTION 8

Matching the Generator to the Electrode

The choke L1 contained within the inverter cubicle is adjustable to


suit various electrode systems, but will have been factory set to
best suit your electrode system.

It should be possible to obtain satisfactory matching of the


generator to the load simply by selecting the correct tap on the
H.T. Transformer.

The generator has been designed to operate within certain


parameters, covering inverter voltage, current and frequency. The
inverter will operate within these and, if the matching is incorrect,
limit the treatment to the load.

No adjustments are required, or should be made to, the inverter


itself.

With this generator the highest tap where full treatment power can
still be obtained from the generator should be selected (ie, start off
with the generator connected to the highest tap and reduce the tap
setting until full treatment can be obtained). It is possible that if the
electrode gap, or configuration is altered the tap setting on the
transformer will also have to be changed.

GX10 / 20 240V - English


22

Link o200 o100 0o

o200 o400 800o

Reconnected Wire

NOTE

The inductance must be selected on Choke L1 according to


dielectric.

For Silicone: GX 10 800 µH


GX 20 400 µH

For Ceramic: GX 10 200 µH


GX 20 100 µH

The above diagram shows connections for a GX20 on Silicone


For Ceramic remove link and reconnect wire to 100.

These connections are recommended settings. In the case of


different electrode discharge areas and dielectric materials, these
settings may vary, as this forms part of the matching circuit.

GX10 / 20 240V - English


23

SECTION 09
Parts List
GX10 / 20 - 240V

CABINET ASSEMBLY

CCT REFERENCE CCT DESCRIPTION PART NO

Inverter Control PCB 301.3004


Voltage Feedback PCB 301.3008
Power Supply PCB 301.3009
GX10 Heatsink Assembly 301.3005
GX 20 Heatsink Assembly 301.3006

L1 Inductor 111.0087
C1 Capacitor 1500 uf 102.0044
C2 Capacitor 10 uf 102.0055
C3 Capacitor 0.1 uf 1000v 102.0065
CT1,2,3 Current Transformers 111.0085
BR1 Rectifier Bridge 103.0093
Mains Filter 103.0106
Fan 240V 124.0046
Fan Filter 124.0047
RL1,2,3,4 Relay LY4 122.0096

FS1,2 Fuse Holder 123.0031


Fuse 500mA 122.0068
FS3 GX20 - 10CT Fuse 123.0054
GX10 – 6CT Fuse 123.0051

R1 Resistor 10R 101.0097


R2 Resistor 10k 101.0098

TH1 Thermal Switch 70C 122.0011

GX10 / 20 240V - English


24

GX10 / 20 - 240V

DOOR ASSEMBLY

CCT REFERENCE CCT DESCRIPTION PART NO.

LP2,4,5,6 Green LED 123.0067


LP3 Red LED 123.0066
LP1 Green LED 123.0069

S1 Start/Stop Button 122.0144


Start Contact 122.0118
Stop Contact 122.0119

CB1 25 Amp Circuit 122.0050


Breaker

RV1 5k Potentiometer/
Power Control 101.0089
Dial Mechanism 202.0049

DM1 Digital Meter 125.0007


Meter Interface PCB 301.3010

GX10 / 20 240V - English


25

COMPONENTS USED ON HEATSINK ASSEMBLY / INVERTER


CCT

CCT REF CCT DESCRIPTION PART NO QTY USED


GX10 GX 20
Q1 - 8 Mosfet (MTM 15N50) 103.0100 4 8
D1, 3, 5, 7 Diode (BYW81P1150) 103.0099 4 4
D2, 4, 6, 8 Diode (BYT12P1600) 103.0098 4 4
ZD1 - 16 Zener Diode (BZX61C15) 103.0025 16 8
R1 - 8 Resistor 22R 101.0004 8 4
C1 - 2 Capacitor 0.47 uf 102.0028 2 2

GX10 / 20 240V - English


26

Section 10

MACHINERY SAFETY

1. Corona treatment equipment operates at very high voltages ( up to


15000 volts) at electrodes. It is essential that the utmost caution is
taken when operation and maintaining equipment, where dangerous
voltages are present they are indicated by the hazardous voltage
warning label ISO 3864 No. B.3.6.
No access is permitted to the area indicated by this symbol UNLESS
the power supply is isolated.

2. The treatment process produces ozone gas as a by product. It is the


customer's responsibility to ensure that the unit is connected to a
suitable extraction system and or catalytic converter constructed from
corrosion resistant materials.
Ozone extraction outlets are identified by the above label.
(See Appendix 1.)

GX10 / 20 240V - English


27

3. The Generator is equipped with a dust filtration system indicated by the


caution symbol ISO 3864 No B.3.1 symbol. If this system blocks see
routine maintenance section, as the unit may overheat
4. When isolating the Generator supply a small time delay of <5 seconds
is needed for power to drain from capacitors via leakage resistors.
Service engineers opening the doors should be aware of this.

5. Care must be taken to avoid injury from moving parts, such as rotating
rolls, moving electrode assemblies and sensor probes at roll ends.
Where risk is considered high guards are fitted.

6. Some machines are designed to be 'open' construction. It is the


customer's responsibility to ensure access is safe. Fence type guards
or other protection can be ordered separately at order placement or
subsequently.

NB Sherman Treaters cannot specify guarding of interfaces between


their machinery and the machinery into which it is to be incorporated
because of the unique requirements of each installation. Therefore,
Sherman Treaters have supplied machinery with residual mechanical
and electrical risks which must be safe-guarded by the user. Access
to Sherman Treaters machinery must be prevented at all times when
the HT electrodes are energised.

GX10 / 20 240V - English


28

11 Ozone: Health Hazards and Precautionary Methods

Guidance Note EH38 from the


Health and Safety Executive OZONE : Health Hazards
and Precautionary
Measures
Environmental Hygiene Series 38 (July 1983)

These Guidance Notes are published under five subject headings: Medical, Environmental
Hygiene, Chemical Safety, Plant and Machinery and General.

INTRODUCTION

1. This guidance note contains information on the principal hazards to health from ozone
and on potential sources of exposure. General advice on precautionary measures, control
techniques and legal requirements is given.

2. Ozone, O3, is a toxic gas possessing a distinctive odour and is a normal constituent of
the earth’s atmosphere. Ozone is produced deliberately for a variety of industrial purposes
and is also produced naturally from oxygen whenever ultra-violet radiation or electrical
discharges occur, e.g. at high altitudes or by the action of lightning. Such natural occurrence
is unlikely to produce concentrations hazardous to man.

3. Because of its strong tendency to decompose and to release oxygen, ozone is extremely
reactive and is a powerful oxidising agent which reacts explosively with oil and grease.
Nevertheless it can be used with safety in industry. For example, since it readily oxidises
organic matter, it is used as a bactericide and algaecide.

4. Ozone itself is a distinctly blue coloured gas (bp – 111.9ºC) and is about one and a half
times heavier than air (density 2.144g/l). Ozone is used as “ozonised air”, a colourless gas
produced when ozone is generated from part of the oxygen in air (see para 13). Ozone
cannot be stored or transported in vessels because it decomposes spontaneously in the
presence of oxidisable impurities, humidity and solid surfaces. The rate of decomposition
increases with temperature.

5. Background concentrations in our immediate atmosphere vary as a function of season,


weather conditions, altitude and humidity

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EFFECTS OF OZONE

6. Low concentrations of ozone have a significant effect upon textiles, fabrics, organic dyes,
metals, plastics and paints and cause the characteristic cracking of stressed rubber,
commonly called “weathering”. A few substances, however, are resistant to the oxidising
effect of ozone and these include glass and some stainless steels.
1-8
7. The acute toxicity of ozone to man has long been recognised and is well documented .
The symptomatic and clinical effects of ozone at various concentrations are summarised in
Table 1. Ozone is irritant to mucous membranes of eyes and respirator tract, and high
concentrations can cause pulmonary oedema.

8. It is possible that there are secondary sites of reaction to ozone characterised by a


defect in oxygen dissociation from oxyhaemoglobin in the tissues. Even at an exposure level
of 0.1ppm ozone, premature ageing may result in man if exposure is sufficiently prolonged.

EXPOSURE LIMITS

9. The Health and Safety at work etc Act 1974 requires every employer to ensure, so far as
is reasonably practicable, the health of all his employees and others who may be affected by
the work he undertakes. The Act also places duties in respect of health and safety matters on
the self-employed. The Factories Act 1961 requires factory occupiers to take all practicable
measures to protect employed persons against inhalation of fume. The general policy
adopted by the Health and Safety Executive is that exposure to hazardous substances should
be kept at low as is reasonably practicable and in any case exposure should be kept within
published standards by the application of engineering controls or other suitable control
techniques. The Health and Safety Executive publishes, in guidance notes in the RH series,
information on exposure limits applied in the UK.

10. The recommended exposure limit for ozone is 0.1ppm (0.2mg/m³) calculated as an 8-
hour time-weighted average concentration. There is also a short-term exposure limit for
ozone of 0.3ppm (0.6mg/m³) calculated as a 15-minute time-weighted average concentration.

SOURCES OF EXPOSURE

11. Ozone is made using ultra-violet radiation or electrical discharge either intentionally for
the purpose of a specific process or incidentally to a process. It is an unstable substance but
is rate of decomposition varies widely according to temperature and humidity. A given ozone
output yielding a faint trace of ozone in a workroom atmosphere on a humid day may created
an undesirable concentration on a dry day.

INTENTIONAL PRODUCTION

12. Ozone is usually produced intentionally by silent electrical discharge in air. Alternative
means of production such as bombardment of air with ultra-violet or ionising radiation, or
electrolysis of cooled sulphuric acid , are uncommon in practice.

13. There are basically three types of ozone generator in use, working at:

(a) Atmospheric pressure – typically a box through which material to be treated with
ozone is passed, and in which a silent electrical discharge is initiated through the
air be means of metal electrodes. This system is often used for surface treatment
of plastic film.

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30

(b) Reduced pressure – found in swimming pool disinfection plants whereby dried air is
drawn through glass tubes across which is a silent electrical discharge is struck.
The reduced pressure is generated by a sidestream from the circulating pool water
forming a venturi vacuum.

(c) Positive pressure – found in potable water treatment plants and throughout industry
generally. Dried air is blown through glass tubes across which a silent electrical
discharge is struck and this ozonised air emerges at positive pressure.

14. The processes for which ozone is produced are outlined below.

SURFACE TREATMENT

15. Various industries which manufacture or use plastic packaging in its various forms use
ozone to pre-treat the plastic surface immediately before printing.

ELECTRICAL DISCHARGES

16. Ozone is generally produced around high voltage equipment and by electrical discharges
in specific processes e.g.

(a) Arc welding – reactive metals such as aluminium and titanium, and also stainless
steel are arc welded in an inert shield of argon or carbon dioxide. The intense
radiation from the arc produces significant quantities of ozone.

(b) Static eliminators are often used in industry to remove static electricity from
recently moulded plastic articles, and continuous use of them in a poorly ventilated
room could lead to the build-up of an irritating level of ozone above the
recommended exposure limit. The main factor which determines the amount of
ozone produced is the voltage across the collector plates; the higher the voltage
the more ozone is produced.

(c) Electrostatic precipitators are used to remove dust and some airborne
contaminants from the air and they produce ozone also. More ozone is produced if
there are rough or sharp edges on, for example, new metal parts since intense
local voltage gradients are produced.

VENTILATION

17. Areas into which ozone may escape must be equipped with adequate ventilation and
extraction facilities. In ozone plant rooms, it is recommended that ten changes of room air per
hour be achieved to enable dangerous accumulations of gas to be dispersed within a few
minutes.

18. Ozone should be prevented from entering the workroom air by the use of exhaust
appliances placed close to the source of emission. The ozone may then be passed through
appropriate filters before discharge to a safe place in the open air. In the case of ozonators
operating under negative pressure, the process acts as its own exhaust ventilator. In the
case of atmospheric pressure ozonators, effective local exhaust ventilation is necessary
because the ozonators are not enclosed. Cinema projection lamps should present no ozone
hazard provided adequate mechanical exhaust ventilation is fitted to the lamp housing and
the exhausted air is vented to a safe place. Many processes incidentally producing ozone
(e.g. welding, ultra-violet curing inks) will have some ventilation provided to deal with other
problems from process.

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SAFE SYSTEMS OF WORK

19. In order to ensure that plant and processes are properly operated and controlled to
minimise risk to health, satisfactory safe systems f work need to be established and
maintained by means of appropriate training and supervision.

20. All people operating ozone plant should be given full training in all aspects of the
operation of the ozonator and associated equipment and should be trained in emergency and
first aid procedures. Emergency action plans should be prepared for all sites where ozone is
generated deliberately in potentially hazardous quantities.

21. Special care may be required when opening sealed plant for maintenance purposes.
10
Guidance Note GS5 should be consulted for detailed advice on permit-to-work systems and
precautions on entry into confined spaces.

22. Work on ozone plant should only be undertaken by a person specifically authorised to do
the work. Such a person should be trained and be competent to do the work in a safe
manner. When carrying out repairs or maintenance work on an ozonator, the ozonator
transformer must be isolated and locked off, and a permit to work must be issued, to avoid
risks from ozone and from electrical hazard.

23. The cleaning materials used for cleaning ozone units and pipework must be free from oil
or grease.

24. In the event of an ozone leak a plant restart should not be attempted until the source of
leakage has been investigated and rectified. Leak detection by nose is not satisfactory
because even slight leaks cause the sense of smell to be numbed and lead to the false
conclusion that a leak no longer exists.

25. Appropriate warning signs indicating the presence of a potential toxic gas hazard should
be displayed on ozone plant access doors or in passageways leading to the plant room.

MONITORING

26. Ozone detectors may be used to provide audible and visual warnings of ozone leaks.
Such alarm signals may be used to initiate emergency procedures, or to automatically turn on
plant room ventilation and shut down the ozonator. Ozone-in-air monitors are essential in
plant rooms where ozonators and associated equipment operate under positive pressure,
because of the greater risk of ozone leakage outward. The monitors in such situations should
actuate automatic ozonator shut down at 0.3ppm ozone or less, while actuating warning
alarms at 0.1ppm or less.

27. Minor ozone leaks can be detected and located by means of moist starch/potassium
iodide paper which turns blue on exposure to ozone.

28. It is essential to carry out regular testing and calibration of all sensor equipment used.

EXHAUST EMISSION

29. Process gas venting to atmosphere should pass through an ozone destructor device or
be released in such a way as to present no hazard. A destructor is a catalyst filter or other
device which causes ozone to decompose in a controlled manner to oxygen. Provided the
discharge point allows adequate dilution a destructor device may not be necessary. If a
catalyst bed, for example activated carbon, is used as an ozone destructor it is possible that
the bed could become exhausted during a period of operation and this should be borne in
mind when arranging maintenance schedules.

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32

30. Deflection weather caps are not recommended for discharge stacks since these hinder
dispersal. Vertical discharge stacks are recommended with a discharge velocity of 15-20m/s
to aid dispersal and avoid re-circulation into buildings. Stacks and extraction vents should be
carefully sited so that they do not feed fresh air ventilation intakes.

31. The control of ozone input to a process is crucial since excess ozone can lead to high
levels of vented ozone.

32. Activated carbon filters must under no circumstances be exposed to ozone


concentrations higher than 20g/m³ since the reaction may become auto-accelerated and lead
to an explosion. The automatic shutdown is a safeguard against this risk.

FIRST AID

33. If a person is overcome by ozone, the following precautions should be adopted:

(a) Remove the patient to a warm uncontaminated atmosphere and loosen tight
clothing at the neck and waist.

(b) Keep the patient at rest.

(c) If the patient has difficulty in breathing, oxygen may be administered provided that
a suitable apparatus and a trained operator are available.

(d) If breathing is weak or has ceased, artificial respiration should be started. The
mouth-to-mouth or mouth-to-nose methods are preferred.

(e) Seek medical aid.

34. Ozone poisoning should be treated symptomatically. This may include bed rest,
analgesics to relieve pain, and antibiotics as may be prescribed by a medical practitioner.

SAMPLING AND ANALYTICAL METHODS

35. Sampling strategies to monitor the extent of exposure to ozone or to assess compliance
with exposure limits should be carefully planned and the advice of an occupational hygienist
may prove useful. Short-term sampling may be used to identify peak exposures and to assist
in the prevention of acute gassing incidents. It may not be valid, however, to use the results
of such sampling for the determination of time-weighted average long-term exposures.
Personal atmospheric sampling is to be recommended when assessing the actual pattern and
duration of exposure. (Further information is contained in Health and Safety Executive
guidance notes on Exposure Limits).

36. The traditional method of determining ozone in air may be used12 but continuous ozone
monitors are now available which use a variety of techniques including onemiluminescence,
ultra-violet photometry and electro-onemical cells. Relatively inexpensive gas detector tubes
are also available. These are ideal for spot check, provided that interfering gases, such as
oxidising agents, are known to be absent.

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STATUTORY REQUIREMENTS

37. The general duties of employers, the self-employed, manufacturers, suppliers and of
employees at work are contained in the Health and Safety at Work etc Act 1974. Other
relevant statutory provisions include the Factories Act 1961, the Offices, Shops and a Railway
Premises Act 1963 and the various regulations and orders made under these Acts. The
following is a brief summary of the principal requirements with regard to potential ozone
health risks:

(a) Health and Safety at work etc Act 1974

s.2 & 3 general duties of employers and the self-employed


s.6 general duties of manufacturers
s.7 general duties of employees

(b) Factories Act 1961

s.4 provision of ventilation


s.30 dangerous fumes
s.63 removal of dust of fumes

(c) Offices, Shops and Railway Premises Act 1963

s.7 provision of ventilation

(d) The Shipbuilding and Ship-Repairing Regulations 1960 – Regulation 53

The Iron & Steel Foundries Regulations 1953 – Regulation 7


The Non-Ferrous Metals (Smelting and Founding) Regulations 1962 – Regulation
11
The Electricity (Factories Act) Special Regulations 1944
The Notification of Accidents and Dangerous Occurrences Regulations 1980
The Health and Safety (First Aid) Regulations 1981.

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34

THIS EQUIPMENT WAS SUPPLIED TO YOU BY:

C
S Corona Supplies Ltd
for all your corona needs

26 Foresters
Bicester Road
Oakley
Bucks
HP18 9PY. UK.
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Fax: +44 (0) 1844 237649
E-mail: sales@coronasupplies co.uk

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