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Acids, Bases & Salts 3 MS PDF

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1 (a (i) Ca2+ + 2F → CaF2 [2]

Not balanced ONLY [1]


Both species must be correct for first mark. Second mark is for correct balancing.

(ii) Mole ratio Ca2+: F is 1:2 [1]


Answer must mention moles
accept argument based on charges or number of ions
accept 2 moles of NaF react with 1 mole of CaCl2
NOT just “2” in equation
If fluorine must specify atoms or ions

(iii) to remove traces of solutions or to remove soluble


impurities or to remove a named salt sodium chloride
or sodium fluoride or calcium chloride [1]
To remove impurities is not enough

(iv) to dry (precipitate) or to remove water or to evaporate water [1]


NOT to evaporate some of water NOT to crystallise salt

(b) T3(PO4)2 allow correct example [1]


explain why 8 cm3 react fully [1]
comment about mole ratio [1]

[Total: 8]

2 (a) pH < 7 [1]


example [1]

pH > 7 [1]
example [1]
NOT amphoteric oxides Be, Al, Zn, Pb, Sn etc

pH = 7 [1]
example H2O, CO, NO [1]
the two marks are not linked, mark each independently
NOT amphoteric oxides Be, Al, Zn, Pb, Sn etc.

(b) (i) shows both basic and acidic properties [1]

(ii) a named strong acid [1]


a named alkali [1]

[Total: 9]

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3 (a)
a) magnesium + sulphuric acid = magnesium sulphate + hydrogen [1]
ACCEPT hydrogen sulphate

(ii) Li2O + H2SO4  Li2SO4 + H2O [2


formulae correct but not balanced [1]

(iii) CuO + H2SO4  CuSO4 + H2O [2


OR CuO + 2HCl  CuCl2 + H2O
OR CuO + 2HNO3  Cu(NO3)2 +H2O
formulae correct but not balanced [1]

(iv) sodium carbonate + sulphuric acid  sodium sulphate + carbon dioxide + water [1]

(b) it accepts a proton [2]


it accepts a hydrogen ion [1] ONLY

(c) sulphuric acid is completely ionised [1]


or few molecules and many ions
ethanoic acid is partially ionised [1]
or many molecules and few ions
[Total: 10]

4 (i) method C [1]


sulphuric acid (allow if given in equation) [1]
zinc oxide + sulphuric acid = zinc sulphate + water [1]

(ii) method A [1]


hydrochloric acid [1]
KOH + HCl = KCl + H2O [1

(iii) method B [1]


potassium iodide or any soluble iodide [1]
Pb2+ + 2I = PbI2 accept a correct equation even if soluble iodide is wrong [2]
Not balanced - Pb2+ + I = PbI2 ONLY [1]

[Total: 10]

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5 (a (i) equilibrium to left or many molecules and few ions or
partially ionised or reverse reaction favoured [1]

(ii) Water donates proton [1]


methylamine accepts a proton [1]
NOTE If hydrogen ion then ONLY [1] provided both are correct

(b) less than 12 more than 7 [1]


smaller concentration of hydroxide ions or partially dissociated or
poor proton acceptor or poor H+ acceptor [1]
NOT it is a weak base

(c) (i) CH3NH2 + HCl = CH3NH3Cl [1]


methylammonium chloride [1]
NOTE the equation must be as written, the equation with sulphuric acid has been
given as guidance.

(ii) brown precipitate [1]


ACCEPT orange or red/brown or brick red or brown/red

(iii) sodium hydroxide or any named strong base [1]


[Total: 9]

6 (a) ammonia 10
hydrochloric acid 1
sodium hydroxide 13
ethanoic acid 4
All correct [2]
Two correct [1]

(b) With strong acid bulb brighter [1]


faster rate of bubbles [1]
OR corresponding comments for weak acid

(c) proton NOT hydrogen ion [1]


H+ not conditional on proton [1]
Only way for [2] is proton and H+

(d)
d) CaO and MgO [1]

(ii) CO2 and SO2 [1]

(iii) Al2O3 [1]

(iv) CO [1]

[TOTAL = 10]

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