100 Barr Harbor Dr., West Conshohocken, PA 19428 Reprinted from the Annual Book of ASTM Standards. Copyright ASTM
Standard Specification for
Aluminum Oxide Powder 1 This standard is issued under the fixed designation F 7; the number immediately following the designation indicates the year of original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope TABLE 1 Chemical Requirements
1.1 This specification covers aluminum oxide (alumina) Composition, %
Element or Compound powder in two classes of particle size, two chemical grades, Grade 1 Grade 2 and two levels of acidity, for use as an insulating coating or as Alumina (Al2O3), min 99.65 99.65 an ingredient of ceramic mixtures for components of electronic Silica (SiO2), max 0.03 0.12 Magnesia (MgO), max 0.02 0.01 devices as follows: Ferric oxide (Fe2O3), max 0.04 0.04 1.1.1 Particle Sizes: Total alkali (as Na2O), max 0.04 0.04 1.1.1.1 Class A—Particle size No. 500 nominal mesh Carbon (C), max 0.01 0.01 Calcium oxide (CaO), max 0.02 0.01 (nominal average particle size 5 24.3 µm). Zirconium oxide (ZrO2), max 0.01 0.01 1.1.1.2 Class B—Particle size No. 900 nominal mesh Boron (B), max 0.001 0.002 (nominal average particle size 5 1.7 µm). Gallium oxide (Ga2O3), max 0.3 No other single metallic impurity 0.02 0.02 1.1.2 Chemical Grades—Grades 1 and 2 as specified under to exceed chemical requirements in Section 3. Composition, ppm 1.1.3 Acidity Levels: pH (acid) 4.5 to 6.5 and pH (neutral) Water-soluble matter (as NaCl), max 300 300
6.5 to 7.5. 1.2 The following safety hazards caveat pertains only to the test methods in this specification. This standard does not 5. Sampling purport to address all of the safety concerns, if any, associated 5.1 Each lot of alumina shall be properly sampled in with its use. It is the responsibility of the user of this standard accordance with standard techniques, such as Practice C 183. to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to 6. Test Methods use. 6.1 Water-Soluble Content: 2. Referenced Documents 6.1.1 Procedure—Determine the total water-soluble content 2.1 ASTM Standards: by measuring the electrical conductivity of a 100-mL distilled C 183 Practice for Sampling and the Amount of Testing of or deionized water extract from a 5-g sample of alumina. Hydraulic Cement 2 Elutriate by vigorously shaking the alumina suspension in a E 70 Test Method for pH of Aqueous Solutions with the flask for 1 to 2 min, allowing the solids to settle and decanting Glass Electrode 3 the clear supernatant liquid after 60 min. Measure the conduc- tivity of the liquid with a standard cell and bridge. Correct this 3. Chemical Composition measurement for the “blank” reading on a similarly treated 3.1 For a specified particle size and level of acidity, the equal volume of the same pure water. Convert the net increase aluminum oxide shall conform to the requirements of Table 1 in conductivity of the water extract first to parts of water- as to chemical composition. soluble content as sodium chloride (NaCl) per million parts of water (factor is 1 micromho 5 0.5 ppm NaCl), then relate to 4. Physical Properties the actual weight of elutriated alumina. For example, on a 4.1 The alumina shall be “chalk white,” dry, free from typical 100-mL extract 10 micromhos (net) or 5 parts of NaCl lumps, and of particle size distribution as agreed upon between per million of water in this volume of liquid is equivalent to purchaser and seller. 100 parts of NaCl per million of alumina on the basis of a 5-g sample. 1 6.1.2 Calculation—Determine the parts per million of This specification is under the jurisdiction of ASTM Committee F-1 on Electronics and is the direct responsibility of Subcommittee F01.03 on Metallic water-soluble content as follows: Materials. ppm 5 10 7 Kc@~Rb 2 Rx! /RbRx# (1) Current edition approved Nov. 10, 1995. Published January 1996. Originally published as F 7 – 58 T. Last previous edition F 7 – 70 (1991). 2 Annual Book of ASTM Standards, Vol 04.01. where: 3 Annual Book of ASTM Standards, Vol 15.05. Kc 5 cell constant, cm −1,
1 F7
Rb 5 specific resistance of test water, V·cm, and TABLE 3 50 % Point Results of Particle Size Distribution Analysis on Typical Material—Diameter in Micrometers A , B Rx 5 specific resistance of alumina extract in test water, V·cm. Method Material (Class—Grade)† 6.2 Particle Size: A-1 A-2 B-1 B-2 6.2.1 Determine particle size distribution by any of the Sharples Micromerograph 13.2 6.2 5.1 4.8 following methods: (a) Coulter counter, (b) M.S.A. centrifuge Cahn Sedimentometer 15.5 7.0 4.7 4.7 M.S.A. centrifuge 14.0 7.1 4.2 4.2 method, (c) Cahn Sedimentometer, or (d) Sharples Coulter counter 17.1 8.1 6.6 5.2 Micromerograph. A From Subcommittee I round-robin test results—Nov. 8, 1967. B NOTE 1—Procedures for determining particle size by the methods Variations between laboratories should not exceed 3 % on similar instruments. † Editorally corrected. shown in Table 2 are described in the operating manuals of the equipment listed. 6.2.2 Number average particle size may be taken as the 6.3.1 Weigh out 20 g of the sample and transfer to a clean 50 % point on the particle size distribution curve or may be 100-mL beaker. Add 20 mL of distilled or deionized water and measured by the Fisher sub-sieve sizer. make into a slurry using a clean stirring rod. Stir for 1 to 2 min. 6.2.3 A density of 3.97 g/cm3 for aluminum oxide will be Wash electrodes thoroughly with distilled or deionized water, used in all calculations. remix slurry, immerse electrodes into slurry approximately 6 to 6.2.4 Particle size distribution of acceptable material in both 12 mm, and measure pH in accordance with Test Method E 70. Class A and Class B will be by agreement between purchaser 6.3.2 Any weight of slurry in the above ratio may be used and seller. Sample size and method of dispersion will be provided there is sufficient slurry to immerse electrodes to the identical in all test correlations, as specified in Table 2. Typical proper depth. results are shown in Table 3. 6.3.3 Wash electrodes immediately after using with several 6.2.5 Number average particle size of acceptable material in hundred millilitres of distilled or deionized water, removing the both Class A and Class B will be by agreement between adhered slurry with the aid of a pipe cleaner. It is important for purchaser and seller. accuracy to prevent buildup of the slurry on the electrodes. 6.2.6 Complete dispersion of samples is essential and recommended procedure in Table 2 shall be followed. 7. Keywords 6.3 Hydrogen-Ion Concentration (pH): 7.1 alumina; particle sizing methods; powder
TABLE 2 Requirements for Sample Sizes and Dispersing Agents
Sample Sample Dispersing Method Concentration Dispersing Agent Size, g Medium Weight% Coulter counter A 0.25 0.1 methanol LiCl-38g/gal M.S.A. centrifuge 1.0 0.03 H2O Na2SiO3 to pH 5 10.5 Cahn Sedimentometer 0.4 0.03 H2O 0.1 % Na2P4O7 Sharples Micromerograph 0.06 N2 none A The instrument manufacturer recommends the following: sample size—0.0025 g, sample concentration—0.001 weight % , dispersing medium—0.9 % NaCl in H2O, and dispersing agent—0.1 % Na2P4O7.
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