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Problem 2A.4

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BSL Transport Phenomena 2e Revised: Chapter 2 - Problem 2A.

4 Page 1 of 2

Problem 2A.4
Loss of catalyst particles in stack gas.

(a) Estimate the maximum diameter of microspherical catalyst particles that could be lost in
the stack gas of a fluid cracking unit under the following conditions:

Gas velocity at axis of stack = 1.0 ft/s (vertically upward)


Gas viscosity = 0.026 cp
Gas density = 0.045 lbm /ft3
Density of a catalyst particle = 1.2 g/cm3

Express the result in microns (1 micron = 10−6 m = 1µm).

(b) Is it permissible to use Stokes’ law in (a)?

Answers: (a) 110 µm; Re = 0.93

Solution

Convert all the given quantities to SI units and assign variables to them. The conversion factors
can be found on page 868 and 870.

ft 1m m
Gas velocity at axis of stack v∞ = 1.0 × ≈ 0.3049
s 3.28 ft s
10−3 Pa · s
Gas viscosity µ = 0.026 ×
cp = 2.6 × 10−5 Pa · s
1cp

 3
lbm 1 kg 3.28 @
ft kg
Gas density ρg = 0.045 3 × × ≈ 0.7203 3

ZftZ 2.2046 
lbm 1m m
 3
g 1 kg cm
100 H kg
Density of a catalyst particle ρc = 1.2 H 3 × × = 1200 3
H
cmH 1000 g 1m m

Part (a)

Gas particles in a stack flow upward. Those at the center of the stack travel at the highest
velocity since they are furthest from the walls. Consequently, to find the maximum diameter of a
catalyst particle, we consider one at the center of the stack. Catalysts that are lost do not rise up
with the rest of the gas; rather, they fall at terminal velocity in the stack and have an acceleration
of zero. The sum of the forces acting on one in the y-direction must be equal to zero. The
gravitational force is pulling the catalysts down, and the buoyant and kinetic (drag) forces are
pushing them up.

X
Fy = F − Fg = 0
4 3 4 3
= πR ρg g + 2πµRv∞ + 4πµRv∞ − πR ρc g =0
|3 {z } | {z } | {z }
form drag friction drag
|3 {z }
buoyant force weight of catalyst
4
= πR3 g(ρg − ρc ) + 6πµRv∞ = 0
3

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BSL Transport Phenomena 2e Revised: Chapter 2 - Problem 2A.4 Page 2 of 2

Figure 1: Free body diagram of a catalyst particle at the center of a stack. Define upward forces
to be positive.

Solve this equation for the radius R.


s
6µv∞ 3
R= ·
g(ρc − ρg ) 4
s
9µv∞
=
2g(ρc − ρg )
s
9(2.6 × 10−5 Pa · s)(0.3049 m/s)

2(9.81 m/s2 )(1200 − 0.7203) kg/m3
≈ 5.5 × 10−5 m

The diameter is twice the radius.


D = 2R ≈ 2(5.5 × 10−5 m)
1 micron
≈ 1.1 × 10−4 

m = 110 microns
10−6 
m

Part (b)

Calculate the Reynolds number.

Dv∞ ρg (1.1 × 10−4 m)(0.3049 m/s)(0.7203 kg/m3 )


Re = ≈
µ (2.6 × 10−5 Pa · s)
≈ 0.93

Since the Reynolds number is less than 1, Stokes’ law is valid.

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