Tablas 2do corte
Tablas 2do corte
Tablas 2do corte
Quantity Conversion
Length 1
m = 100 cm
= 3.28084 (ft)= 39.3701 (in)
Mass 1 kg = 103 g
= 2.20462(lbm)
Force 1 N = 1 kg·m·s−2
= 105 (dyne)
= 0.224809(1bf)
Pressure 1 bar = 105kg·m−1·s−2 = 105N·m−2
= 105Pa = 102kPa
6 −2
= 10 (dyne)·cm
= 0.986923 (atm)
= 14.5038 (psia)
= 750.061 (torr)
Volume 1 m3 = 106cm3 = 103liters
= 35.3147 (ft)3
= 264.172 (gal)
Density 1 g·cm−3= 103kg·m−3
= 62.4278 (lb m)(ft)−3
Energy 1 J = 1 kg·m2 ·s−2 = 1 N·m
= 1 m3 ·Pa = 10−5 m3 ·bar = 10 cm3·bar
= 9.86923 cm3·(atm)
= 107(dyne)·cm = 10 7 (erg)
= 0.239006 (cal)
= 5.12197 × 10−3 (ft)3(psia) = 0.737562 (ft)(lb f)
= 9.47831 × 10−4 (Btu) = 2.77778 × 10−7kW·h
Power 1 kW = 103W = 103kg·m2 ·s−3 = 103J·s−1
= 239.006 (cal)·s −1
= 737.562 (ft)(l
b f)·s −1
= 0.947831 (Btu)·s−1
= 1.34102 (hp)
R = 8.314J·mol−1 ·K−1
= 8.314 m3 ·Pa·mol−1
·K−1
= 83.14cm3·bar·mol−1·K−1= 8314 cm3·kPa·mol−1·K−1
= 82.06cm3 ·(atm)·mol−1 ·K−1
= 62,356cm3 ·(torr)·mol−1 ·K−1
−1 −1 −1 −1
= 1.987(cal)·mol ·K = 1.986(Btu)(lb mole) (R)
= 0.7302(ft) ( atm)(lb mol) (R) = 10.73 (ft) ( psia)(lb mol) (R)
3 −1 −1 3 −1 −1
= 1545(ft)(lbf)(lb mol)−1
(R)−1
Appendix B
Table B.2 Constants for the Antoine Equation for Vapor Pressures of Pure Species
Molar Vc
mass ω Tc/K Pc/bar Zc cm3·mol−1 Tn/K
Methane 16.043 0.012 190.6 45.99 0.286 98.6 111.4
Ethane 30.070 0.100 305.3 48.72 0.279 145.5 184.6
Propane 44.097 0.152 369.8 42.48 0.276 200.0 231.1
n-Butane 58.123 0.200 425.1 37.96 0.274 255. 272.7
n-Pentane 72.150 0.252 469.7 33.70 0.270 313. 309.2
n-Hexane 86.177 0.301 507.6 30.25 0.266 371. 341.9
n-Heptane 100.204 0.350 540.2 27.40 0.261 428. 371.6
n-Octane 114.231 0.400 568.7 24.90 0.256 486. 398.8
n-Nonane 128.258 0.444 594.6 22.90 0.252 544. 424.0
n-Decane 142.285 0.492 617.7 21.10 0.247 600. 447.3
Isobutane 58.123 0.181 408.1 36.48 0.282 262.7 261.4
Isooctane 114.231 0.302 544.0 25.68 0.266 468. 372.4
650
APPENDIX B. Properties of Pure Species 651
Molar Vc
mass ω Tc/K Pc/bar Zc cm3·mol−1 Tn/K
Cyclopentane 70.134 0.196 511.8 45.02 0.273 258. 322.4
Cyclohexane 84.161 0.210 553.6 40.73 0.273 308. 353.9
Methylcyclopentane 84.161 0.230 532.8 37.85 0.272 319. 345.0
Methylcyclohexane 98.188 0.235 572.2 34.71 0.269 368. 374.1
Ethylene 28.054 0.087 282.3 50.40 0.281 131. 169.4
Propylene 42.081 0.140 365.6 46.65 0.289 188.4 225.5
1-Butene 56.108 0.191 420.0 40.43 0.277 239.3 266.9
cis-2-Butene 56.108 0.205 435.6 42.43 0.273 233.8 276.9
trans-2-Butene 56.108 0.218 428.6 41.00 0.275 237.7 274.0
1-Hexene 84.161 0.280 504.0 31.40 0.265 354. 336.3
Isobutylene 56.108 0.194 417.9 40.00 0.275 238.9 266.3
1,3-Butadiene 54.092 0.190 425.2 42.77 0.267 220.4 268.7
Cyclohexene 82.145 0.212 560.4 43.50 0.272 291. 356.1
Acetylene 26.038 0.187 308.3 61.39 0.271 113. 189.4
Benzene 78.114 0.210 562.2 48.98 0.271 259. 353.2
Toluene 92.141 0.262 591.8 41.06 0.264 316. 383.8
Ethylbenzene 106.167 0.303 617.2 36.06 0.263 374. 409.4
Cumene 120.194 0.326 631.1 32.09 0.261 427. 425.6
o-Xylene 106.167 0.310 630.3 37.34 0.263 369. 417.6
m-Xylene 106.167 0.326 617.1 35.36 0.259 376. 412.3
p-Xylene 106.167 0.322 616.2 35.11 0.260 379. 411.5
Styrene 104.152 0.297 636.0 38.40 0.256 352. 418.3
Naphthalene 128.174 0.302 748.4 40.51 0.269 413. 491.2
Biphenyl 154.211 0.365 789.3 38.50 0.295 502. 528.2
Formaldehyde 30.026 0.282 408.0 65.90 0.223 115. 254.1
Acetaldehyde 44.053 0.291 466.0 55.50 0.221 154. 294.0
Methyl acetate 74.079 0.331 506.6 47.50 0.257 228. 330.1
Ethyl acetate 88.106 0.366 523.3 38.80 0.255 286. 350.2
Acetone 58.080 0.307 508.2 47.01 0.233 209. 329.4
Methyl ethyl ketone 72.107 0.323 535.5 41.50 0.249 267. 352.8
Diethyl ether 74.123 0.281 466.7 36.40 0.263 280. 307.6
Methyl t-butyl ether 88.150 0.266 497.1 34.30 0.273 329. 328.4
Methanol 32.042 0.564 512.6 80.97 0.224 118. 337.9
Ethanol 46.069 0.645 513.9 61.48 0.240 167. 351.4
1-Propanol 60.096 0.622 536.8 51.75 0.254 219. 370.4
1-Butanol 74.123 0.594 563.1 44.23 0.260 275. 390.8
1-Hexanol 102.177 0.579 611.4 35.10 0.263 381. 430.6
2-Propanol 60.096 0.668 508.3 47.62 0.248 220. 355.4
Phenol 94.113 0.444 694.3 61.30 0.243 229. 455.0
652 APPENDIX B. Properties of Pure Species
Molar Vc
mass ω Tc/K Pc/bar Zc cm3·mol−1 Tn/K
Ethylene glycol 62.068 0.487 719.7 77.00 0.246 191.0 470.5
Acetic acid 60.053 0.467 592.0 57.86 0.211 179.7 391.1
n-Butyric acid 88.106 0.681 615.7 40.64 0.232 291.7 436.4
Benzoic acid 122.123 0.603 751.0 44.70 0.246 344. 522.4
Acetonitrile 41.053 0.338 545.5 48.30 0.184 173. 354.8
Methylamine 31.057 0.281 430.1 74.60 0.321 154. 266.8
Ethylamine 45.084 0.285 456.2 56.20 0.307 207. 289.7
Nitromethane 61.040 0.348 588.2 63.10 0.223 173. 374.4
Carbon tetrachloride 153.822 0.193 556.4 45.60 0.272 276. 349.8
Chloroform 119.377 0.222 536.4 54.72 0.293 239. 334.3
Dichloromethane 84.932 0.199 510.0 60.80 0.265 185. 312.9
Methyl chloride 50.488 0.153 416.3 66.80 0.276 143. 249.1
Ethyl chloride 64.514 0.190 460.4 52.70 0.275 200. 285.4
Chlorobenzene 112.558 0.250 632.4 45.20 0.265 308. 404.9
Tetrafluoroethane 102.030 0.327 374.2 40.60 0.258 198.0 247.1
Argon 39.948 0.000 150.9 48.98 0.291 74.6 87.3
Krypton 83.800 0.000 209.4 55.02 0.288 91.2 119.8
Xenon 131.30 0.000 289.7 58.40 0.286 118.0 165.0
Helium 4 4.003 −0.390 5.2 2.28 0.302 57.3 4.2
Hydrogen 2.016 −0.216 33.19 13.13 0.305 64.1 20.4
Oxygen 31.999 0.022 154.6 50.43 0.288 73.4 90.2
Nitrogen 28.014 0.038 126.2 34.00 0.289 89.2 77.3
Air† 28.851 0.035 132.2 37.45 0.289 84.8
Chlorine 70.905 0.069 417.2 77.10 0.265 124. 239.1
Carbon monoxide 28.010 0.048 132.9 34.99 0.299 93.4 81.7
Carbon dioxide 44.010 0.224 304.2 73.83 0.274 94.0
Carbon disulfide 76.143 0.111 552.0 79.00 0.275 160. 319.4
Hydrogen sulfide 34.082 0.094 373.5 89.63 0.284 98.5 212.8
Sulfur dioxide 64.065 0.245 430.8 78.84 0.269 122. 263.1
Sulfur trioxide 80.064 0.424 490.9 82.10 0.255 127. 317.9
Nitric oxide (NO) 30.006 0.583 180.2 64.80 0.251 58.0 121.4
Nitrous oxide (N2O) 44.013 0.141 309.6 72.45 0.274 97.4 184.7
Hydrogen chloride 36.461 0.132 324.7 83.10 0.249 81. 188.2
Hydrogen cyanide 27.026 0.410 456.7 53.90 0.197 139. 298.9
Water 18.015 0.345 647.1 220.55 0.229 55.9 373.2
Ammonia 17.031 0.253 405.7 112.80 0.242 72.5 239.7
Nitric acid 63.013 0.714 520.0 68.90 0.231 145. 356.2
Sulfuric acid 98.080 ... 924.0 64.00 0.147 177. 610.0
† Pseudoparameters for y N2= 0.79 and y O2 = 0.21. See Eqs. (6.78)–(6.80).
APPENDIX B. Properties of Pure Species 653
Table B.2: Constants for the Antoine Equation for Vapor Pressures of Pure Species
B
ln Psat∕ kPa = A − ______
t ∕ °C + C
Latent heat of vaporization at the normal boiling point (ΔHn), and normal boiling point (tn)
Based primarily on data presented by B. E. Poling, J. M. Prausnitz, and J. P. O’Connell, The Properties of Gases and
Liquids, 5th ed., App. A, McGraw-Hill, New York, 2001.
*Antoine parameters adapted from J. Gmehling, U. Onken, and W. Arlt, Vapor-Liquid Equilibrium Data Collection,
Chemistry Data Series, vol. I, parts 1–8, DECHEMA, Frankfurt/Main, 1974–1990.
†Antoine parameters A are adjusted to reproduce the listed values of t .
n
656 APPENDIX C. Heat Capacities and Property Changes of Formation
Alkanes:
Methane CH4 1500 4.217 1.702 9.081 −2.164 ......
Ethane C2H6 1500 6.369 1.131 19.225 −5.561 ......
Propane C3H8 1500 9.011 1.213 28.785 −8.824 ......
n-Butane C4H10 1500 11.928 1.935 36.915 −11.402 ......
iso-Butane C4H10 1500 11.901 1.677 37.853 −11.945 ......
n-Pentane C5H12 1500 14.731 2.464 45.351 −14.111 ......
n-Hexane C6H14 1500 17.550 3.025 53.722 −16.791 ......
n-Heptane C7H16 1500 20.361 3.570 62.127 −19.486 ......
n-Octane C8H18 1500 23.174 4.108 70.567 −22.208 ......
1-Alkenes:
Ethylene C2H4 1500 5.325 1.424 14.394 −4.392 ......
Propylene C3H6 1500 7.792 1.637 22.706 −6.915 ......
1-Butene C4H8 1500 10.520 1.967 31.630 −9.873 ......
1-Pentene C5H10 1500 13.437 2.691 39.753 −12.447 ......
1-Hexene C6H12 1500 16.240 3.220 48.189 −15.157 ......
1-Heptene C7H14 1500 19.053 3.768 56.588 −17.847 ......
1-Octene C8H16 1500 21.868 4.324 64.960 −20.521 ......
Miscellaneous organics:
Acetaldehyde C2H4O 1000 6.506 1.693 17.978 −6.158 ......
Acetylene C2H2 1500 5.253 6.132 1.952 ...... −1.299
Benzene C6H6 1500 10.259 −0.206 39.064 −13.301 ......
1,3-Butadiene C4H6 1500 10.720 2.734 26.786 −8.882 ......
Cyclohexane C6H12 1500 13.121 −3.876 63.249 −20.928 ......
Ethanol C2H6O 1500 8.948 3.518 20.001 −6.002 ......
Ethylbenzene C8H10 1500 15.993 1.124 55.380 −18.476 ......
Ethylene oxide C2H4O 1000 5.784 −0.385 23.463 −9.296 ......
Formaldehyde CH2O 1500 4.191 2.264 7.022 −1.877 ......
Methanol CH4O 1500 5.547 2.211 12.216 −3.450 ......
Styrene C8H8 1500 15.534 2.050 50.192 −16.662 ......
Toluene C7H8 1500 12.922 0.290 47.052 −15.716 ......
Miscellaneous inorganics:
Air 2000 3.509 3.355 0.575 ...... −0.016
Ammonia NH3 1800 4.269 3.578 3.020 ...... −0.186
Bromine Br2 3000 4.337 4.493 0.056 ...... −0.154
Carbon monoxide CO 2500 3.507 3.376 0.557 ...... −0.031
Carbon dioxide CO2 2000 4.467 5.457 1.045 ...... −1.157
Carbon disulfide CS2 1800 5.532 6.311 0.805 ...... −0.906
Chlorine Cl2 3000 4.082 4.442 0.089 ...... −0.344
Hydrogen H2 3000 3.468 3.249 0.422 ...... 0.083
Hydrogen sulfide H2S 2300 4.114 3.931 1.490 ...... −0.232
Hydrogen chloride HCl 2000 3.512 3.156 0.623 ...... 0.151
Hydrogen cyanide HCN 2500 4.326 4.736 1.359 ...... −0.725
Nitrogen N2 2000 3.502 3.280 0.593 ...... 0.040
Nitrous oxide N2O 2000 4.646 5.328 1.214 ...... −0.928
Nitric oxide NO 2000 3.590 3.387 0.629 ...... 0.014
Nitrogen dioxide NO2 2000 4.447 4.982 1.195 ...... −0.792
Dinitrogen tetroxide N2O4 2000 9.198 11.660 2.257 ...... −2.787
Oxygen O2 2000 3.535 3.639 0.506 ...... −0.227
Sulfur dioxide SO2 2000 4.796 5.699 0.801 ...... −1.015
Sulfur trioxide SO3 2000 6.094 8.060 1.056 ...... −2.028
Water H2O 2000 4.038 3.470 1.450 ...... 0.121
†Selectedfrom H. M. Spencer, Ind. Eng. Chem., vol. 40, pp. 2152–2154, 1948; K. K. Kelley, U.S. Bur. Mines Bull.
584, 1960; L. B. Pankratz, U.S. Bur. Mines Bull. 672, 1982.
664 APPENDIX D. The Lee/Kesler Generalized-Correlation Tables