ATI Zircadyne® Zirconium

Technical Data Sheet

Zircadyne® 702
Zircadyne® 705
Zirconium Alloys
(UNS R60702 and UNS R60705)

INTRODUCTION

®
Zircadyne alloys are composed of 95.5% to 99.2% zirconium and hafnium with a maximum hafnium content of 4.5%. Zircadyne
mill products are available in two chemical grades each sharing excellent corrosion resistance and also having slightly different
physical and mechanical properties. Zircadyne 702 Zirconium is commercially pure. Zircadyne 705 zirconium is alloyed with niobium
to increase its strength and improve its formability. Table 1 shows the chemical composition of Zircadyne alloys. The presence of
hafnium in Zircadyne alloys does not significantly influence the physical, mechanical, or corrosion properties.

Zirconium, a reactive metal, has a high affinity for oxygen that results in the formation of a protective oxide layer in air at room
temperature. This protective oxide gives Zircadyne alloys their superior corrosion resistance and this oxide layer can be enhanced
through a heat treating process. A properly formed enhanced oxide layer serves as an excellent bearing surface against a variety of
materials, imparts impressive erosion resistance in high velocity systems, and can improve the corrosion resistance in certain
aggressive environments.

Zircadyne alloys exhibit good ductility even at cryogenic temperatures and good strength comparable with other common
engineering alloys. In addition to being integral to the oxide layer, oxygen is an interstitial strengthening element in Zircadyne alloys.
Zircadyne alloys do not exhibit a low temperature ductile to brittle transition.

Table 1. Typical Chemical Compositions of Zircadyne® Alloys

Grade Zr 702 Zr 705

UNS Designation R60702 R60705

Element Weight % Weight %

Zirconium + Hafnium, min 99.2 95.5
Hafnium, max 4.5 4.5
Iron + Chromium, max 0.20 0.20
Tin – –
Hydrogen, max 0.005 0.005
Nitrogen, max 0.025 0.025
Carbon, max 0.05 0.05
Niobium (Columbium) – 2.0 – 3.0
Oxygen, max 0.16 0.18

Data are typical, are provided for informational purposes, and should not be construed as maximum or minimum values for specification Allegheny Technologies Incorporated
or for final design, or for a particular use or application. The data may be revised anytime without notice. We make no representation or 1000 Six PPG Place
warranty as to its accuracy and assume no duty to update. Actual data on any particular product or material may vary from those shown Pittsburgh, PA 15222-5479 U.S.A.
herein. TM is trademark of and ® is registered trademark of ATI Properties, Inc. or its affiliated companies. ® The starburst logo is a www.ATImetals.com
registered trademark of ATI Properties, Inc. © 2012 ATI. All rights reserved.

VERSION 1 (2/26/2012): PAGE 1 of 6

 ATI Zircadyne® Zirconium

Technical Data Sheet

Table 2 lists the thermal properties for Zircadyne alloys. Zircadyne alloys have a thermal conductivity that is more than 30% higher
than those of stainless steel alloys making Zircadyne alloys ideal for heat exchanger applications. The linear coefficient of thermal
expansion of Zircadyne alloys is nearly one-third of the value for stainless steel giving Zircadyne alloys superior dimensional stability
at elevated temperatures.

Table 2. Thermal Properties of Zircadyne® Alloys

Zr 702 Zr 705
Melting Point 1852°C 1840°C
Specific Heat, KJ/kg-K (0-100°C) 0.2847 0.2805
Vapor Pressure (mm Hg)
2000°C (3632°F) 0.01 –
3600°C (6512°F) 900 –
Thermal Conductivity, w/m-°K (BTU/hr-ft-°F), 300-800K 22 (13) 17.1 (10)
-6
Coefficient of Thermal Expansion x 10 /°C 5.8 (3.2) 3.6 (2.0)
149°C (300°F) 6.3 (3.5) 4.9 (2.7)
260°C (500°F) 7.0 (3.9) 5.6 (3.1)
371°C (700°F) 7.4 (4.1) 5.9 (3.3)
Latent Heat of Fusion (cal/gm) 60.4 –
Latent Heat of Vaporisation (cal/gm) 1550 –

Zircadyne 702 alloy has a hexagonal close-packed crystal structure (alpha) below approximately 865°C (1590°F) which transforms
to a body-centered cubic crystal structure (beta) above this temperature. Zircadyne 705 alloy is a two phase system composed of a
hexagonal close-packed crystal structure (alpha) and body-centered cubic crystal structure (beta) below approximately 920°C
(1688°F). Above this temperature, Zircadyne 705 alloy transforms to a body-centered cubic crystal structure (beta). Due to the
nature of hexagonal close-packed deformation systems which have only one predominant slip system and three predominant twin
systems at typical fabrication temperatures, wrought Zircadyne alloys are anisotropic. Table 3 lists the crystallographic
characteristics of Zircadyne alloys.

Typical wrought and annealed Zircadyne alloys exhibit a uniform equiaxed grain structure. All Zircadyne alloy mill products are
supplied in the annealed condition, unless specified otherwise.

MECHANICAL PROPERTIES

Table 4 lists physical property data for Zircadyne® alloys. The modulus of elasticity for Zircadyne alloys decreases rapidly at
elevated temperatures as shown in Table 4. Zircadyne alloys have a density that is less than 20% of nickel and iron based stainless
alloys.

Table 3. Atomic and Crystallographic Properties of Zircadyne® Alloys

Zr 702 Zr 705
Atomic Number 40 (pure Zr) –
Atomic Weight 91.22 (pure Zr) –
Atomic Radius

Data are typical, are provided for informational purposes, and should not be construed as maximum or minimum values for specification Allegheny Technologies Incorporated
or for final design, or for a particular use or application. The data may be revised anytime without notice. We make no representation or 1000 Six PPG Place
warranty as to its accuracy and assume no duty to update. Actual data on any particular product or material may vary from those shown Pittsburgh, PA 15222-5479 U.S.A.
herein. TM is trademark of and ® is registered trademark of ATI Properties, Inc. or its affiliated companies. ® The starburst logo is a www.ATImetals.com
registered trademark of ATI Properties, Inc. © 2012 ATI. All rights reserved.

VERSION 1 (2/26/2012): PAGE 2 of 6

 ATI Zircadyne® Zirconium

Technical Data Sheet

Å (Zero Charge) 1.60 –1.62 (pure Zr) –
Å (+4 Charge) 0.80 – 0.90 (pure Zr) –
Crystal Structure
Alpha Phase HCP* below 865°C (1590°F) –
Beta Phase BCC* above 865°C (1590°F) BCC* above 920°C (1688°F)
Alpha + Beta Phase – HCP*-BCC* below 920°C (1688°F)

*HCP: Hexagonal Close-Packed, BCC: Body Centered Cubic

Table 4. Physical Properties of Zircadyne® Alloys

Zr 702 Zr 705
Modulus of Elasticity, GPa (psi x 106)
Room Temperature 99.2 (14.4) 94.7 (13.7)
38°C (100°F) 98.6 (14.3) 93.8 (13.6)
93°C (200°F) 93.1 (13.5) 90.5 (13.1)
149°C (300°F) 86.9 (12.6) 87.3 (12.7)
204°C (400°F) 80.7 (11.7) 84.2 (12.2)
260°C (500°F) 75.2 (10.9) 81.0 (11.7)
316°C (600°F) 69.6 (10.1) 77.8 (11.3)
371°C (700°F) 64.1 (9.3) 74.6 (10.8)
6
Shear Modulus of Elasticity, GPa (psi x 10 )
Room Temperature 36.2 (5.25) 34.5 (5.0)
Poisson's Ratio 0.35 0.33
3 3
Density, g/cm (lbs/in ) 6.51 (0.235) 6.64 (0.240)

Table 5 and Figures 1 and 2 show the typical mechanical property data for Zircadyne® alloys in the annealed condition. The data
shown are the average of the longitudinal and transverse values at specific temperatures. The yield strength was determined using
the 0.2% offset method. Like most non-ferrous metals, Zircadyne alloys exhibit a gradual transition from elastic to plastic behavior.
Some of the physical and mechanical properties of Zircadyne zirconium are affected by its anisotropy. These properties include
thermal expansion, yield strength, ultimate tensile strength, elongation, notch toughness, and bend ductility whose magnitudes vary
anisotropically with the direction of the material.

Table 5. Typical Mechanical Properties of Zircadyne ® Alloys (Cold Worked and Annealed)
ASTM Room 93°C 149°C 204°C 260°C 316°C 371°C
Min Value Temp. (200°F) (300°F) (400°F) (500°F) (600°F) (700°F)

Zircadyne® 702 (R60702)

Data are typical, are provided for informational purposes, and should not be construed as maximum or minimum values for specification Allegheny Technologies Incorporated
or for final design, or for a particular use or application. The data may be revised anytime without notice. We make no representation or 1000 Six PPG Place
warranty as to its accuracy and assume no duty to update. Actual data on any particular product or material may vary from those shown Pittsburgh, PA 15222-5479 U.S.A.
herein. TM is trademark of and ® is registered trademark of ATI Properties, Inc. or its affiliated companies. ® The starburst logo is a www.ATImetals.com
registered trademark of ATI Properties, Inc. © 2012 ATI. All rights reserved.

VERSION 1 (2/26/2012): PAGE 3 of 6

 ATI Zircadyne® Zirconium

Technical Data Sheet

Ultimate Tensile Strength, 379 468.1 364.0 303.7 229.6 200.6 197.9 156.5
MPa (ksi)

(55) (67.9) (52.8) (44.2) (33.3) (29.1) (28.7) (22.7)

Yield Strength, MPa (ksi) 207 321.1 267.5 195.8 139.3 128.9 97.2 82.0
(30) (46.6) (38.8) (28.4) (20.2) (18.7) (14.1) (11.9)
Elongation, % (0.2% offset) 16 28.9 31.5 42.5 49.0 49.0 40.1 44.1
®
Zircadyne 705 (R60705)
Ultimate Tensile Strength, 552.0 615.0 494.7 388.9 369.3 326.1 299.7 281.0
MPa (ksi)

(80) (89.2) (71.8) (56.4) (53.6) (47.3) (43.5) (408)

Yield Strength, MPa (ksi) 379.0 506.1 390.7 272.3 261.8 195.8 190.2 173.0
(55) (73.4) (56.7) (39.5) (38) (28.4) (27.6) (25.1)
Elongation, % (0.2% offset) 16.0 18.8 30.5 31.7 33.0 28.9 29.0 27.8

The ductility in both Zircadyne alloys increases significantly with temperature. This improved ductility combined with a lower yield
strength at 400°F provides improved conditions for severe forming operations.

Zircadyne alloys work harden rapidly. A stress relief heat treatment at 565°C (1050°F ± 50°F) for 1/2 to 1 hour at temperature can
be utilized to relieve residual stresses.

ASME ALLOWABLE STRESS

Both Zircadyne alloys are approved for use in the construction of pressure vessels designed to the ASME Boiler and Pressure
Vessel Code. Zircadyne 705 zirconium requires a stress relief heat treatment within 14 days after welding. Tables 6A and 6B list the
allowable stress values for Zircadyne alloys per the ASME Boiler and Pressure Vessel Code, Section II, Part D (2008a).

Table 6A. ASME Allowable Stress Values for Zircadyne® 702 and Zircadyne® 705 Zirconium for Unfired Pressure Vessels
(Customary)
Material ASME Alloy Minimum Minimum Maximum Allowable Stress in Tension for Metal Temperatures, °F
Form and Specification Grade Tensile Yield
Condition Number Strength Strength -20 to 100 150 200 300 400 500 600 700
ksi ksi ksi ksi ksi ksi ksi ksi ksi ksi
Data are typical, are provided for informational purposes, and should not be construed as maximum or minimum values for specification Allegheny Technologies Incorporated
or for final design, or for a particular use or application. The data may be revised anytime without notice. We make no representation or 1000 Six PPG Place
warranty as to its accuracy and assume no duty to update. Actual data on any particular product or material may vary from those shown Pittsburgh, PA 15222-5479 U.S.A.
herein. TM is trademark of and ® is registered trademark of ATI Properties, Inc. or its affiliated companies. ® The starburst logo is a www.ATImetals.com
registered trademark of ATI Properties, Inc. © 2012 ATI. All rights reserved.

VERSION 1 (2/26/2012): PAGE 4 of 6

 ATI Zircadyne® Zirconium

Technical Data Sheet

Plate, SB 551 702 55 30 15.7 15.1 13.7 11.2 9.1 7.4 6.0 5.2
Sheet,
Strip 705 80 55 22.9 – 19.0 16.2 14.3 12.9 11.9 11.3
Seamless SB 523 702 55 30 15.7 15.1 13.7 11.2 9.1 7.4 6.0 5.2
Tubing
705 80 55 22.9 – 19.0 16.2 14.3 12.9 11.9 11.3
Welded SB 523 702 55 30 13.4 12.8 10.8 9.5 7.7 6.3 5.1 4.5
Tubing (a)
705 80 55 22.9 – 19.0 16.2 14.3 12.9 11.9 11.3
Forgings SB 493 702 55 30 15.7 15.1 13.7 11.2 9.1 7.4 6.0 5.2
705 80 55 22.9 – 19.0 16.2 14.3 12.9 11.9 11.3
Bar SB 550 702 55 30 15.7 15.1 13.7 11.2 9.1 7.4 6.0 5.2
705 80 55 22.9 – 19.0 16.2 14.3 12.9 11.9 11.3
Seamless SB 658 702 55 30 15.7 15.1 13.7 11.2 9.1 7.4 6.0 5.2
Pipe
705 80 55 22.9 – 19.0 16.2 14.3 12.9 11.9 11.3
Welded SB 658 702 55 30 13.4 12.8 11.6 9.5 7.7 6.3 5.1 4.5
Pipe (a)
705 80 55 19.4 – 16.1 13.8 12.2 11.0 10.1 9.9

(a) 85% joint efficiency has been used in determining the allowable stress value for welded product.

Table 6B. ASME Allowable Stress Values for Zircadyne® 702 and Zircadyne® 705 Zirconium for Unfired Pressure Vessels
(Metric)
Material ASME Alloy Minimum Minimum Maximum Allowable Stress in Tension for Metal Temperatures, °C
Form and Specification Grade Tensile Yield
Condition Number Strength Strength -30 to 40 65 125 175 225 275 325 375
MPa MPa MPa MPa MPa MPa MPa MPa MPa MPa
Plate, SB 551 702 380 205 108.0 104.0 84.3 70.1 58.7 47.9 40.3 35.5
Sheet,
Strip 705 550 380 158.0 144.0 119.0 105.0 94.7 86.8 81.2 77.6
Seamless SB 523 702 380 205 108.0 104.0 84.3 70.1 58.7 47.9 40.3 35.5
Tubing
705 550 380 158.0 144.0 119.0 105.0 94.7 86.8 81.2 77.6
Welded SB 523 702 380 205 92.4 88.4 71.4 59.7 49.4 40.7 34.1 30.9
Tubing (a)
705 550 380 134.0 122.0 101.0 89.5 80.8 73.9 68.9 66.0
Forgings SB 493 702 380 205 108.0 104.0 84.3 70.1 58.7 47.9 40.3 35.5
705 550 380 158.0 144.0 119.0 105.0 94.7 69.4 81.2 77.6
Bar SB 550 702 380 205 108.0 104.0 84.3 70.1 58.7 47.9 40.3 35.5
705 550 380 158.0 144.0 119.0 105.0 94.7 86.8 81.2 77.6
Seamless SB 658 702 380 205 108.0 104.0 84.3 70.1 58.7 47.9 40.3 35.5
Pipe
705 550 380 158.0 144.0 119.0 105.0 94.7 86.8 81.2 77.6
Welded SB 658 702 380 205 92.4 88.4 71.4 59.7 49.4 40.7 34.1 30.9

Data are typical, are provided for informational purposes, and should not be construed as maximum or minimum values for specification Allegheny Technologies Incorporated
or for final design, or for a particular use or application. The data may be revised anytime without notice. We make no representation or 1000 Six PPG Place
warranty as to its accuracy and assume no duty to update. Actual data on any particular product or material may vary from those shown Pittsburgh, PA 15222-5479 U.S.A.
herein. TM is trademark of and ® is registered trademark of ATI Properties, Inc. or its affiliated companies. ® The starburst logo is a www.ATImetals.com
registered trademark of ATI Properties, Inc. © 2012 ATI. All rights reserved.

VERSION 1 (2/26/2012): PAGE 5 of 6

 ATI Zircadyne® Zirconium

Technical Data Sheet

Pipe (a) 705 550 380 134.0 122.0 101.0 89.5 80.8 73.9 68.9 66.0

(a) 85% joint efficiency has been used in determining the allowable stress value for welded product.

Data are typical, are provided for informational purposes, and should not be construed as maximum or minimum values for specification Allegheny Technologies Incorporated
or for final design, or for a particular use or application. The data may be revised anytime without notice. We make no representation or 1000 Six PPG Place
warranty as to its accuracy and assume no duty to update. Actual data on any particular product or material may vary from those shown Pittsburgh, PA 15222-5479 U.S.A.
herein. TM is trademark of and ® is registered trademark of ATI Properties, Inc. or its affiliated companies. ® The starburst logo is a www.ATImetals.com
registered trademark of ATI Properties, Inc. © 2012 ATI. All rights reserved.

VERSION 1 (2/26/2012): PAGE 6 of 6