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SAFETY DATA SHEET (Regulation (EC) n°1907/2006 - REACH) Version 12.1 (10/07/2020) - Page 1/6
ADEO-SERVICES
AXTON - PH MINUS SPA POWDER - 70609350

SAFETY DATA
(REACH Regulation (EC) n° 1907/2006 - n° 2015/830)

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier Product
name: AXTON - PH LESS POWDER SPA Product code:
70609350
1.2. Relevant identified uses of the substance or mixture and uses advised against
pH regulator
SWIMMING POOL WATER TREATMENT
1.3. Details of the supplier of the safety data sheet
Company name: ADEO SERVICES.
Address: 135 Rue Sadi Carnot.59790.RONCHIN.France.
Telephone: No. AZUR 0810 634 634. Fax: .
reglementation.clp@leroymerlin.fr
www.leroymerlin.fr
Distributer

1.4. Emergency telephone number: +33 (0)1 45 42 59 59.

Company/Organization: INRS / ORFILA http://www.centres-antipoison.net.

SECTION 2: HAZARDS IDENTIFICATION 2.1.

Classification of the substance or mixture According
to Regulation (EC) No 1272/2008 and its adaptations.
Serious eye damage, Category 1 (Eye Dam. 1, H318).
This substance does not present a physical hazard. See the recommendations concerning the other products present in the room.
This substance does not present any danger to the environment. No damage to the environment is known or foreseeable under normal conditions of
use.

2.2. Label elements

According to Regulation (EC) No. 1272/2008 and its adaptations.
Hazard pictograms:

GHS05
Signal word:
DANGER
Product identifier:
016-046-00-X SODIUM HYDROGEN SULPHATE
Hazard statements and supplemental hazard information: H318
Causes serious eye damage.
Precautionary Statements - General:
P101 If medical advice is needed, keep container or label at hand.
P102 Keep out of reach of children.
P103 Carefully read and follow all instructions.
Precautionary advice - Prevention:
P280 Wear eye protection.
Precautionary Statements - Response:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if the victim
wears them and if they can be easily removed. Continue rinsing.

P310 Immediately call a POISON CENTER or doctor.

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2.3. Other hazards

In use, may form flammable/explosive dust-air mixture.
The substance does not meet the criteria for a PBT or vPvB substance according to Annex XIII of the REACH Regulation (EC) No 1907/2006.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1. Substances
Composition :
Identification (EC) 1272/2008 Note
INDEX: 016-046-00-X GHS05 Dgr Eye % 100.00 %
CAS: 7681-38-1 Dam. 1, H318
EC: 231-665-7
REACH: 01-2119552465-36-XXXX

SODIUM HYDROGEN SULPHATE

SECTION 4: FIRST AID

In general, in case of doubt or if symptoms persist, always call a doctor.
NEVER give anything by mouth to an unconscious person.
4.1. Description of first aid measures
In case of eye contact:
Wash thoroughly with fresh, clean water for 15 minutes, holding the eyelids apart.
Whatever the initial state, systematically address the subject to an ophthalmologist, showing him the label.
If there is pain, redness or visual discomfort, consult an ophthalmologist.
In case of skin contact:
Beware of the product that may remain between the skin and the clothes, the watch, the shoes, etc.
If swallowed:
Consult a doctor showing him the label.
4.2. Most important symptoms and effects, both acute and delayed
No data is available.
4.3. Indication of any immediate medical attention and special treatment needed
No data is available.

SECTION 5: FIRE FIGHTING MEASURES Not flammable.

5.1. Extinguishing media

Suitable extinguishing media In
the event of a fire, use:
- dry sand

- powders
- carbon dioxide (CO2)
Unsuitable extinguishing media
In case of fire, do not use:
- water

- water jet
5.2. Special hazards arising from the substance or mixture
A fire will often produce a thick black smoke. Exposure to decomposition products may pose health risks.
Do not inhale the smoke.
In the event of a fire, the following may
be formed: - sulfur dioxide (SO2)

5.3. Tips for firefighters

Due to the toxicity of the gases emitted during the thermal decomposition of the products, the responders will be equipped with self-contained
insulating breathing apparatus.

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SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective

equipment and emergency procedures Refer to protective measures listed in sections 7
and 8.
For non-rescuers
Avoid all contact with skin and eyes.
For rescuers
The workers will be equipped with appropriate personal protective equipment (Refer to section 8).
6.2. Environmental precautions
Prevent entry into sewers or waterways.
6.3. Methods and material for containment and cleaning up
Recover the product by mechanical means (sweeping/vacuuming): do not generate dust.
6.4. Reference to other sections
No data available.

SECTION 7: HANDLING AND STORAGE

The requirements relating to storage rooms apply to the workshops where the substance is handled.
7.1. Precautions for safe handling Wash hands after each use.

Remove and wash contaminated clothing before reuse.

Provide safety showers and eyewash fountains in workshops where the substance is constantly handled.
Fire prevention:

Prohibit access to unauthorized persons.

Recommended equipment and procedures:
For personal protection, see section 8.
Observe precautions stated on label as well as labor safety regulations.
Absolutely avoid contact of the substance with the eyes.
Prohibited equipment and procedures:
Smoking, eating and drinking are prohibited in premises where the substance is used.
7.2. Conditions for safe storage, including any incompatibilities
No data is available.
Storage
Keep out of the reach of children.
Packaging
Always keep in packaging made of an identical material to the original.
7.3. Specific end use(s)
No data is available.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

No data is available.
Predicted No Effect Concentration (PNEC):
SODIUM HYDROGENOSULFATE (CAS: 7681-38-1)
Environment compartment:
PNECs: Soil 1.54 mg/kg

Environment compartment: Fresh water

PNECs: 11.09 mg/l

Environment compartment: Sea water

PNECs: 1.09 mg/l

Environment compartment: Water with intermittent

PNECs: release 17.66 mg/l

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Environment compartment: Freshwater sediment

PNECs: 40.2mg/kg

Environment compartment: marine sediment

PNECs: 4.02mg/kg

Environment compartment: Wastewater treatment plant

PNECs: 800mg/l

8.2. Exposure controls

Individual protection measures, such as personal protective equipment
Pictogram(s) of obligation to wear personal protective equipment (PPE):

Use clean and properly maintained personal protective equipment.

Store personal protective equipment in a clean place away from the work area.
When using, do not eat, drink or smoke. Remove and wash contaminated clothing before reuse. Provide ventilation
adequate, especially in enclosed areas.
- Eye / face protection
Avoid contact with eyes.
Before any handling of powders or emission of dust, it is necessary to wear goggles complying with the NF standard.
EN166.
Wearing corrective glasses does not constitute protection.
Provide eyewash stations in workshops where the product is handled constantly.
- Hand protection

Wear suitable protective gloves for prolonged or repeated skin contact.

Use suitable protective gloves resistant to chemical agents in accordance with standard NF EN374.
The selection of gloves must be made according to the application and the duration of use at the workstation.
Protective gloves must be chosen according to the workstation: other chemical products that can be handled, protective
physical requirements (cuts, stings, thermal protection), dexterity required.
Type of gloves recommended:
- Natural latex
- Nitrile rubber (Butadiene-acrylonitrile copolymer (NBR))
- PVC (Polyvinyl chloride)
- Butyl rubber (Isobutylene-isoprene copolymer)
Recommended Features:
- Waterproof gloves complying with standard NF EN374
- Body protection
Staff personnel will wear a regularly cleaned work uniform.
After contact with the product, all soiled parts of the body must be washed.
- Respiratory protection
Avoid inhalation of dust.
FFP mask type:
Wear a single-use dust filtering half mask in accordance with standard NF EN149.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties
General informations
Physical state : Powder.
Color : Colorless - yellow
Important Health, Safety and Environmental Information
pH in aqueous solution: <2 (1%)
pH: Unspecified.
Boiling point/range: Not concerned.
Flash point range: Not concerned.
Steam pressure (50°C): Not concerned.

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Water solubility: Soluble. at 20°C: 1080 g/l

Melting point/range: Not concerned.
Auto-Ignition Point/Range: Not concerned.
Decomposition point/interval: Not concerned.
9.2. Other information
No data is available.

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity

No data is available.
10.2. Chemical stability
This substance is stable under the handling and storage conditions recommended in section 7.
10.3. Possibility of hazardous reactions
No data available.
10.4. Conditions to Avoid
To avoid :

- the formation of dust -

freezing Dust can form an
explosive mixture with air.
10.5. Incompatible materials
Keep away from:
- water

10.6. Hazardous decomposition products

Thermal decomposition can release/form: - sulfur
dioxide (SO2)

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects May
cause irreversible eye effects, such as ocular tissue damage or serious visual impairment which is not fully reversible within a 21-day observation
period.
Serious eye damage is characterized by destruction of the cornea, persistent corneal opacity, inflammation of the iris (iritis).

11.1.1. Substances
No toxicological information is available on the substances.

SECTION 12: ECOLOGICAL INFORMATION

12.1. Toxicity

12.2. Persistence and

degradability No data available.
12.3. Bioaccumulative potential

No data is available.
12.4. Mobility in soil

No data is available.
12.5. Results of PBT and vPvB assessment
No data is available.
12.6. Other Adverse Effects
No data is available.

SECTION 13: DISPOSAL CONSIDERATIONS Proper waste management of

the substance and/or its container should be determined in accordance with the provisions of Directive 2008/98/EC.

13.1. Waste treatment methods

Do not pour into sewers or waterways.

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Waste :
Waste management is done without endangering human health and without harming the environment, and in particular without creating a risk for water, air, soil,
fauna or flora.
Recycle or dispose of in accordance with the legislation in force, preferably by a collector or an approved company.
Do not contaminate the ground or water with waste, do not dispose of it in the environment.
Soiled packaging:
Completely empty the container. Keep the label on the container.
Give to a certified disposal contractor.

SECTION 14: TRANSPORT INFORMATION

Exempt from transport classification and labelling.
14.1. UN number
-

14.2. UN Proper Shipping Name

-

14.3. Transport hazard class(es)

-

14.4. Packing group

-

14.5. Environmental hazards

-

14.6. Special precautions for user

-

SECTION 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture - Classification and labeling information
given in section 2:
The following regulations have been taken into account:
- Regulation (EC) No. 1272/2008 amended by Regulation (EU) No. 2020/217 (ATP 14)
- Packaging information: No data available.

- Particular dispositions :
No data is available. 15.2. Chemical
Safety Assessment No data available.

SECTION 16: OTHER INFORMATION

As the working conditions of the user are not known to us, the information given in this safety data sheet is based on the state of our knowledge and on both
national and community regulations.
It is always the responsibility of the user to take all necessary measures to meet the requirements of local laws and regulations.

The information given in this safety data sheet should be considered as a description of the safety requirements relating to this substance and not as a
guarantee of its properties.
Text(s) of the phrases mentioned in section 3:
H318 Causes serious eye damage.
Abbreviations:
PNEC: Predicted No Effect Concentration.
ADR: European Agreement relating to the International Carriage of Dangerous Goods by Road.
IMDG: International Maritime Dangerous Goods.
IATA: International Air Transport Association.
ICAO: International Civil Aviation Organization.
RID: Regulations concerning the International carriage of Dangerous goods by rail.
GHS05: Corrosion.
PBT: Persistent, bioaccumulative and toxic. vPvB:
Very persistent and very bioaccumulative.
SVHC: Substance of Very High Concern.

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