KAMALA NIKETAN MONTESSORI SCHOOL

Class XII 2022-23

Chemistry-1
Time: 3 Hours Max. Marks: 70
General Instructions:
1. There are 35 questions in this question paper with internal choice.
2. SECTION A consists of 18 multiple-choice questions carrying 1 mark each.
3. SECTION B consists of 7 very short answer questions carrying 2 marks each.
4. SECTION C consists of 5 short answer questions carrying 3 marks each.
5. SECTION D consists of 2 case-based questions carrying 4 marks each.
6. SECTION E consists of 3 long answer questions carrying 5 marks each.
7. All questions are compulsory.
8. Use of log tables and calculators is not allowed.

SECTION-A
Directions (Q. Nos. 1-18) : The following questions are multiple-choice questions with one correct answer.
Each question carries 1 mark. There is no internal choice in this section.

1. The boiling points of alcohols are higher than those of hydrocarbons of comparable masses due to:
(a) ion-dipole interaction (b) dipole -dipole interaction
(c) hydrogen bonding (d) vander Waals forces

2. The role of a catalyst is to change :

(a) enthalpy of reaction
(b) Gibbs’ energy of reaction
(c) equilibrium constant
(d) activation energy of reaction

3. The value of KH for Ar(g), CO (g),2 HCHO(g) and CH (g) are 4

40.39, 1.67, 1.83 # 10-5 and 0.413
respectively. Arrange these gases in increasing order of solubility.
(a) Ar < CO2 < CH4 < HCHO (b) Ar < CH4 < CO2 < HCHO
) HCHO < CH4 < CO2 < Ar (d) HCHO < CO2 < CH4 < Ar
Page 2 Sample Paper 1 CBSE Chemistry Class 12

4. Out of the following, the strongest base in aqueous solution is:

(a) dimethylamine (b) aniline
(c) methylamine (d) trimethylamine

5. Out of the following transition elements, the maximum number of oxidation states are shown by:
(a) Cr (Z = 24) (b) Sc (Z = 21)
(c) Fe (Z = 26) (d) Mn (Z = 25)

6. What is the correct IUPAC name of the given compound?

(a) 2-carboxyl-2-methylpropanoic acid

(b) 2-ethyl-2-methylpropanoic acid
(c) 3-methylabutance carboxylic acid
(d) 2, 2-dimethylbutanoic acid

7. For the reaction, 2X + Y $ X2Y

What will be the expression for instantaneous rate of the reaction?
(a) + 1 d (Y )
(b) - 1 d (X2Y)
2 dt 2 dt
- d (X)
(c) 2dt
(d) None of these

8. For the reaction 2H2O2 $ 2H2O + O2, r = k[H2O2]. The reaction is of :

(a) first order (b) second order
(c) third order (d) zero order

9. The compound obtained by the reaction of nitrous acid on aliphatic primary amine is:
(a) alkyl nitrite (b) alcohol
10. A graph was plotted between the molar conductivity of various electrolytes (NaCl, HCl and NH OH)
1
and4 c (in mol L- ). Which of the following is the correct set?

(a) I (NH4OH), II (HCl), III (NaCl)

(b) I (NaCl), II (HCl), (III) (NH4OH)
(c) I (HCl), II (NaCl), III (NH4OH)
(d) I (NH4OH), II (NaCl), III (HCl)

11. Using valence bond theory, the complex [Cr(NH ) ]3+3 6can be described as :
(a) d 2sp3, inner orbital complex, paramagnetic
(b) d 2sp3, outer orbital complex, diamagnetic
(c) sp3d 2, outer orbital complex, paramagnetic
(d) dsp2, inner orbital complex, diamagnetic

12. Which of the following compound will not undergo azo coupling reaction with benzene diazonium
chloride?
(a) Phenol (b) Aniline
(c) Nitrobenzene (d) Anisole

13. Major product obtained on reaction of 3-phenyl propene with HBr in presence of organic peroxide is:
(a) 3-phenyl-2-bromopropane (b) 3-phenyl-1-bromopropane
(c) 1-phenyl-3-bromopropane (d) 1-phenyl-2-bromopropane
14. During dehydration of alcohols to alkenes by heating with concentrated H2SO4, the initiation step is:
(a) elimination of water
(b) formation of an ester
(c) protonation of alcohol molecule
(d) formation of carbocation

Directions (Q. Nos. 15-18) : Each of the following questions consists of two statements, one is Assertion and
the other is Reason. Give answer :

15. Assertion : Vanadium had the ability to exhibit a wide range of oxidation states.
Reason : The standard potentials Vanadium are rather small, making a switch between oxidation states
relatively easy.
(a) Both Assertion and Reason are true but Reason is not a correct explanation of Assertion.
(b) Both Assertion and Reason are true and Reason is the correct explanation of Assertion.
(c) Assertion is fake but Reason is true.
(d) Assertion is true but Reason is fake.

16. Assertion : DNA has a double strand helix structure.

Reason : The two strands in a DNA molecule are exactly similar.
(a) Both Assertion and Reason are true but Reason is not a correct explanation of Assertion.
(b) Both Assertion and Reason are true and Reason is the correct explanation of Assertion.
(c) Assertion is fake but Reason is true.
(d) Assertion is true but Reason is fake.

17. Assertion : Tertiary butylamine can be prepared by the action of NH3 on tert-butylbromide. Reason :
Tertiary butyl bromide being 3° alkyl halide prefers to undergo elimination on the treatment with a
base.
(a) Both Assertion and Reason are true but Reason is not a correct explanation of Assertion.
(b) Both Assertion and Reason are true and Reason is the correct explanation of Assertion.
(c) Assertion is fake but Reason is true.
(d) Assertion is true but Reason is fake.
18. Assertion : IUPAC name of the compound
CH3 - CH - O - CH2 - CH2 - CH3
y
CH3
is 2-Ethoxy-2-methylethane.
Reason : In IUPAC nomenclature, ether is regarded as hydrocarbon derivative in which a hydrogen
atom replaced by —OR or —OAr group
[where R = alkyl group and Ar = aryl group]
(a) Both Assertion and Reason are true but Reason is not a correct explanation of Assertion.
(b) Both Assertion and Reason are true and Reason is the correct explanation of Assertion.
(c) Assertion is fake but Reason is true.
(d) Assertion is true but Reason is fake.

SECTION-B
Directions (Q. Nos. 19-25) : This section contains 7 questions with internal choice in two questions. The
following questions are very short answer type and carry 2 marks each.

19. Time required to decompose SO2Cl2 to half of its initial amount is 60 minutes. If the decomposition is
a first order reaction, calculate the rate constant of the reaction.

20. Which one of the following pairs of substances undergoes SN2 substitution reaction faster and why?

(i)

(ii)

21. A cell is constructed between copper and silver

Cu (s) y Cu2+(aq) z Aq+(aq) y Aq (s)
If the two half-cells are working under standard condition, then calculate the emf of the cell.
EcCu /Cu =+ 0.34 V, EcAg /Ag =+ 0.80 V
2+ +

22. Identify compounds (A) and (B) in the following reactions and write
chemical equation : the related balanced
T
Page 6

Complete and name the following reaction:

(i) RNH2 + CHCl3 + 3KOH $
(ii) RCONH2 + Br2 + 4NaOH $

23. (i) Sketch the zwitter ionic form of α -amino acetic acid.
(ii) What type of linkage holds together the monomers in DNA?

24. A zinc rod is dipped in 0.1 M solution of ZnSO4. The salt is 95% dissociated at this dilution at 298K.
Calculate the electrode potential.
[Ec(Zn /Zn)
2+ =− 0.76 V]

25. (i) Give the electronic configuration of the d -orbitals of Ti in [Ti(H O) ]3+ ion
2
and
6
explain
why this complex is coloured ? [At. No. of Ti = 22]
(ii) Write IUPAC name of [Cr(NH3)3 (H2O)3]Cl3.
oo
Determine the structure and magnetic behaviour of [CoCl ]2– using
4 valence bond theory.

SECTION-C
Directions (Q. Nos. 26-30) : This section contains 5 questions with internal choice in two questions. The
following questions are short answer type and carry 3 marks each.

26. (i) Draw the structural formulas and write IUPAC names of all the isomeric alcohols with the
molecular formula C5H12O.
(ii) Classify the isomers of alcohols given in part (a) as primary, secondary and tertiary
alcohols.

27. Answer the following questions :(Any three)

(i) What do you mean by depression in freezing point?
(ii) How can the molecular weight of a non-volatile substance be calculated by freezing point
depression method? Only give the formula.
(iii) Measurement of osmotic pressure method is preferred for the determination of molar mass of
macromolecules such as proteins and polymers.
(iv) Elevation of boiling point of 1M KCl solution is nearly double than that of 1 M sugar solution.
CBSE Chemistry Class 12 Sample Paper 1 Page 7

28. (i) Write the IUPAC name of the following complex :

[Co(NH3)4(H2O)Cl]C12
(ii) What is the difference between an Ambidentate ligand and a Bidentate ligand?
(iii) Out of [Fe(NH ) 3]36+ and [Fe(C O ) ]23– 4, 3which complex is more stable and why ?

29. What happens when :

(i) N-ethylethanamine reacts with benzenesulphonyl chloride.
(ii) Benzylchloride is treated with ammonia followed by the reaction with Chloromethane.
(iii) Aniline reacts with chloroform in the presence of alcoholic potassium hydroxide.
oo
(i) Write the IUPAC name for the following organic compound :

(ii) Complete the following

C H NO Sn/HCl
C HBF4 D
A Br2 /KOH B NaNO2 /HCl
6 5 2
273 - 278 K T

30. How will you convert ethanal to the following compounds?

(i) Butane-1, 3-diol
(ii) But-2-enal
(iii) But-2-enoic acid

SECTION-D
Directions (Q. Nos. 31-32) : The following questions are case-based questions. Each question has an internal
choice and carries 4 marks each. Read the passage carefully and answer the questions that follow.

31. The rate law for a chemical reaction relates the reaction rate with the concentrations or partial
pressures of the reactants. For aA + bB $ C with no intermediate steps
a general reaction

in its reaction mechanism, meaning that it is an elementary reaction, the rate law is given
by r = k [A]x [B]y , where [A] and [B] express the concentrations of A and B in moles per litre.
Exponents x and y vary for each reaction and are determined experimentally. The value of k varies with
conditions that affect reaction rate, such as temperature, pressure, surface area, etc. The sum of these
exponents is known as overall reaction order. A zero order reaction has a constant rate that is independent
of the concentration of the reactants. A first order reaction depends on the concentration of only one
reactant. A reaction is said to be second order when the overall order is two. Once we have determined
the order of the reaction, we can go back and plug in one set of our initial values and solve for k
Page 8 Sample Paper 1 CBSE Chemistry Class 12

(i) Calculate the overall order of a reaction which has the following rate expression :
Rate = k [A]1/2[B]3/2
(ii) What is the effect of temperature on rate of reaction?
(iii) A first order reaction takes 77.78 minutes for 50% completion. Calculate the time required for
30% completion of this reaction log 10 = 1, log 7 = 0.8450.

oo
(iv) A first order reaction has a rate constant 1 # 10-3 per sec. How long will 5g of this reactant take to
reduce to 3 g?
(log 3 = 0.4771; log 5 = 0.6990)

32. An amino acid is a compound that contains both carboxyl group and an amino group. Although, many
types of amino acids are known, the α -amino acids are the most significant in the biological world
because they are the monomers from which proteins are constructed. A general structural formula of an
α -amino acid is shown in figure below.

Although, figure (a) is a common way of writing structural formulas for amino acids, it is not accurate
because it shows an acid (—COOH) and a base (—NH2) within the same molecule. These acidic and
basic groups react with each other to form a dipolar ion or internal salt (figure (b)). The internal salt of
an amino acid is given the special name Zwitter ion. Note that a Zwitter ion has no net charge, it contains
one positive charge and one negative charge.
Because they exist as Zwitter ions, amino acids have many of the properties associated with salts. They
are crystalline solids with high melting points and are fairly soluble in water but insoluble in non-polar
organic solvents such as ether and hydrocarbon solvents.
According to the above passage, answer the following questions :
(i) Amino acids are usually colourless, crystalline solids. They behave like salts rather than simple
amines or carboxylic acids. Why amino acids show such a behaviour?
(ii) Amino acids are essential and non-essential depending upon their need. One of the essential
amino acid is lysine. Can you say why lysine is considered an essential amino acid?
(iii) Here are given some amino acids—lysine, Tyrosine, Glycine, Alamine. One of these amino acids
is not optically active. Which one is that amino acid? Also, provide the reason.

oo
(iv) The pka , and pka , of an amino acid are 2.3 and 9.7 respectively. What would be the
1 2

isoelectric point of the amino acid? Calculate by defining it.

 Page 9

SECTION-E
Directions (Q. Nos. 33-35) : The following questions are long answer type and carry 5 marks each. Two
questions have an internal choice.

33. (i) The cell in which the following reaction occurs:

2Fe3+ (aq) + 2I−(aq) $ 2Fe2+ (aq) + I2(s)
has EcCell = 0.236 Volt at 298K. Calculate the standard
Gibbs energy of the cell reaction.
(Given : 1F = 96,500 C mol–1)
(ii) How many electrons flow through a metallic wire if a current of 0.5 A is passed for 2 hours?
(Given : 1F = 96,500 C mol–1)
(iii) Explain the following with reason :
(a) Chlorine can displace iodine from KI solution but iodine can not displace bromine from
KBr solution.
(b) Following reaction is possible or not.
Hg + H2SO4 $ HgSO4 + H2

34. (i) Account for the following :

(a) Transition metals from large number of complex compounds.
(b) The lowest oxide of transition metal is basic whereas the highest oxide is amphoteric or
acidic.
(c) Ec value for the Mn3+/Mn2+ couple is highly positive (+1.57 V) as compare to
Cr3+/Cr2+.
(ii) Write one similarity and one difference between the chemistry of lanthanoid and actinoid
elements.

(i) (a) How is the variability in oxidation states of transition metals different from that of the
p -block elements ?
(b) Out of Cu+ and Cu2+, which ion is unstable in aqueous solution and why ?
(c) Orange colour of Cr2O2-7 ion changes to yellow colour when treated with an alkali.
Why ?
(ii) Chemistry of actinoids is complicated as compared to lanthanoids. Give two reasons.
Page 10

35. (i) Write the product (s) in the following reactions:

(a) D
(c) I
B
A
L

CH3 — CH = CH − CN −
H
(
b
)
H

? O

(ii) Give simple chemical test to distinguish between the following pairs of compounds :
(a) Butanal and Butan-2-one.
(b) Benzoic acid and Phenol.

oo
(i) An organic compound (A) with molecular formula C3H7NO on heating with Br2 and KOH
forms a compound (B), compound (B), on heating with CHCl3 and alcoholic KOH produces a foul
smelling compound (C) and on reacting with C6H5SO2Cl forms a compound
(D) which is soluble in alkali. Write the structures of (A), (B), (C) and (D).
(ii) Give reasons to support the answer :
(a) Presence of alpha hydrogen in aldehydes and ketones is essential for aldol condensations.
(b) 3-Hydroxy pentan-2-one shows positive result to Tollen’s test.