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Thermo

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Summary thermodynamics

Conduction
𝑇ℎ − 𝑇𝑐
𝑃 = 𝑘𝐴 ( )
𝐿 Radiation
𝑃 = 𝜎𝐴𝑒𝑇 4
𝑇ℎ − 𝑇𝑐 4
𝑃 = 𝑘𝐴 ( ) 𝜎 = 5.669𝑥10−8 𝑊/𝑚2 𝐾
∑𝑖 𝐿𝑖 /𝑘𝑖
𝑇ℎ − 𝑇𝑐
𝑃 = 𝑘𝐴 ( )
𝑅
𝐹
𝑝=
𝑄 = 𝑚𝑐∆𝑇 𝐴

𝑛 = 𝑁/𝑁𝐴
𝑄 = 𝑚𝑙
𝑝𝑉 = 𝑛𝑅𝑇 3
𝐸𝑘 = 𝑘 𝑇
2 𝐵
3
𝑄 = ∆𝑈 + 𝑊 𝑈 = 𝑛𝑅𝑇
2

𝑊 = 𝑝∆𝑉
∆𝑄 𝑉
∆𝑆 = 𝑆 = 𝑛𝑅𝑙𝑛 ( )
𝑇 𝑉𝑚

𝑇𝑐𝑜𝑙𝑑
𝜂𝑐𝑎𝑟𝑛𝑜𝑡 = 1 − 𝑢𝑠𝑒𝑓𝑢𝑙 𝑤𝑜𝑟𝑘
𝑇ℎ𝑜𝑡 𝜂=
𝑒𝑛𝑒𝑟𝑔𝑦 𝑖𝑚𝑝𝑢𝑡
Isobaric Isovolumetric
𝑊 = −𝑃∆𝑉 𝑊=0
∆𝑈 = 𝑄
Isothermal
Adiabatic 𝑄 = −𝑊
∆𝑈 = 𝑊 ∆𝑈 = 0

Monoatomic gas
𝑉𝑖 3
𝑊 = 𝑛𝑅𝑇𝑙𝑛 ( ) ∆𝑈 =
𝑛𝑅𝑇
𝑉𝑓 2
∆𝑈 = 𝑛𝐶𝑣 ∆𝑇
Constant volume Constant pressure
3 5
𝑄 = 𝑛𝐶𝑣 ∆𝑇 𝐶𝑣 = 2 𝑅 𝑄 = 𝑛𝐶𝑝 ∆𝑇 𝐶𝑝 = 2 𝑅
𝐶𝑝 5 Adiabatic
𝛾= = 𝛾 𝛾
5
𝐶𝑣 3 𝑃𝑖 𝑉𝑖 = 𝑃𝑓 𝑉𝑓 𝑝𝑉 3
• A-B Isothermal expansion at 𝑇ℎ the
gas absorbs energy |𝑄ℎ | and does
work 𝑊𝐴𝐵
• B-C Adiabatic expansion. No energy
leaves or enters the system. The
temperature decreases. The gas does
work 𝑊𝐵𝐶 .
• C-D Isothermal compression. The gas
expels energy |𝑄𝑐 |. There is work
done on the gas 𝑊𝐶𝐷 .
• D-A Adiabatic compression.
Temperature increase to 𝑇ℎ . Work
done on the gas 𝑊𝐷𝐴 .

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