PART T EST- 2

Class : XII (Nucleus)

Time : 3 hour Max. Marks : 180
INSTRUCTIONS
1. The question paper contain pages and 3-parts. Part-A contains 18 objective question , Part-B contains 6
questions of "Match the Column" type and Part-C contains 12 subjective type questions. All questions are
compulsory. Please ensure that the Question Paper you have received contains all the QUESTIONS
and Pages. If you found some mistake like missing questions or pages then contact immediately to
the Invigilator.
PART-A
(i) Q.1 to Q.18 have One or More than one is / are correct alternative(s) and carry 4 marks each.
There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.
PART-B
(iii) Q.1 to Q.6 are "Match the Column" type which may have one or more than one matching options and
carry 8 marks for each question. 2 marks will be awarded for each correct match within a question.
There is NEGATIVE marking. 0.5 mark will be deducted for each wrong answer.
PART-C
(iv) Q.1 to Q.12 are "Subjective" questions & carry 5 marks. There is NO NEGATIVE marking. Marks
will be awarded only if all the correct bubbles are filled in your OMR sheet.
2. Indicate the correct answer for each question by filling appropriate bubble(s) in your answer sheet.
3. Use only HB pencil for darkening the bubble(s).
4. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.
5. The answer(s) of the questions must be marked by shading the circles against the question by dark HB pencil
only.
PART-A PART-B PART-C
For example if only 'B' For example if Correct Ensure that all columns
choice is correct then, match for (A) is P, Q; for (4 before decimal and 2
the correct method for (B) is P, R; for (C) is P after decimal) are filled.
filling the bubble is and for (D) is S then the Answer having blank
A B C D correct method for filling column will be treated as
the bubble is incorrect. Insert leading
P Q R S zero(s) if required after
For example if only 'B & (A) rounding the result to 2
D' choices are correct decimal places.
then, the correct method (B) e.g. 86 should be filled as
for filling the bubbles is 0086.00
A B C D (C) .
.
(D) .
The answer of the .
question in any other .
manner (such as putting .
, cross , or partial .
shading etc.) will be .
treated as wrong. .
.
 PART - A
Select the correct alternative(s) (choose one or more than one)
Q.1 A uniformly charged thin non conducting shell of radius R is charged with Q units of charge. The escape
velocity of a particle of charge –q and mass m from surface of conductor is
Qq Qq Qq Qq
(A) (B) (C) (D)
4 0 R 2 0 mR 0 mR 4 0 mR

Q.2 A test tube of length l is immersed invertically into a vessel containing mercury of
density (m). It is immersed in such a way so that its closed end just touches the
mercury level. Mercury was found to rise to a height x in the tube as shown. The
pressure at A is (Here Atmospheric pressure is equal to l length of mercury):
(A) (l – x) mg (B) xmg
(C) (2l – x) mg (D) (l – 2x) mg
Q.3 An adiabatic container is divided into two equal parts, with an ideal gas at pressure P and temperature T
at one side and vacuum on the other side. On making a hole in the separating wall
(A) work done by gas will be nRT
(B) change in internal energy of gas will be zero
(C) internal energy depends on temperature of gas
(D) work done by gas is zero
Q.4 Figure shows a network of capacitors and resistances.
Potentials of some of the points are given. Then
(A) potential at M = 2.6 V
(B) Potential at N = –1.6 V
(C) Charge across 2f capacitor is 8.4 C
(D) Charge across 2f capacitor is 4.2 C
Q.5 As a liquid of density  flows through the tube shown below in a streamlines way

(A) volume rate of flow reduces from a1 to a2

(B) volume rate of flow increases from a1 to a2
(C) h is a measure of pressure difference at A and B
(D) pressure at A has to be more than that at B by hg

Q.6 Two large black plane surfaces are maintained at constant temperature T1 & T2
(T1 > T2) & placed in vacuume. Two thin black plates are placed between the
two surfaces and is parallel to these. After sometime steady condition are obtained.
By what factor () is the steady heat flow reduced due to presence of black
plates?
1 1
(A)  = (B)  = (C)  = 1 (D)  = 0
2 3
Q.7

Compound B has a neutralisation equivalent 112'G' is a dichloro alkane.

(A) A = ,B= ,C= ,E= ;F=

& G = ClCH2CH2CH2CH2Cl

(B) A = ,B= ,C= ,E=

& G = ClCH2CH2CH2CH2CH2Cl

(C) A = ,B= ,C= ,E= ,F=

& G = ClCH2CH2CH2CH2CH2Cl

(D) A = ,B= ,C= ;

E= ;F= & G = ClCH2CH2CH2CH2CH2Cl

Q.8 Identify A, B, C, D, E & F in the following reactions

(A) A = ,B= ,D= ,E= ,F= &G=

(B) A = ,B= ,D= ,E= ,

F= &G=
 (C) A = ,B= ,D= ,E= ,F= &G=

(D) Both B & C is possible

Q.9 Select the correct statement(s)

If S = f (E, V, n1, n2) & A = f (T, V, n1, n2)
(A ) S is equal to f (E, V, n1, n2) (B) S is equal to f (E, V, n1, n2)
(C) A is equal to f (T, V, n1, n2) (D) A is equal to f (E, V, n1, n2)

Q.10 Which of the following statement(s) is/are correct

I  III 
(A) GaCl2 is actually Ga Ga Cl 4 
 
(B) Metallocenes are inorganic benzene
(C) Cyclo Phosphazene (P3N3Cl6) is inorganic analogue of benzene
(D) B6H62– is a closo borane with octahedral structure

Q.11 Identify the correct statement(s)

(A) BF3 is a stronger Lewis acid than BCl3
(B) Ga melts at ~300C and its density decreases when it solidifies.
(C) Unusually high melting point of boron is due to its structure
(D) Borazine is more reactive towards HCl than benzene due to weak B = N bond.
Q.12 In the titration of CH3COOH, with NaOH, the difference in number of NaOH molecules added and
CH3COO– present at equilibrium at pH = 7.5 per litre of titrating mixture is equal to
1 9 99
(A) ×6.023×1016 (B) × 6.023 ×1016(C) zero (D) × NA
10 10 10 10
Q.13 From the point P(4, 5), two chords PA and PB of length 2 units each are drawn to the circle
x2 + y2 = 41. Then equation of chord AB is
(A) x + y = 2 (B) 4x + 5y = 39 (C) x – 5y = 37 (D) none

n  2  b
  3k   2  3
Q.14 If n    n
Lim
 n =  f ( x ) dx then
k 1     0
(A) b = 1 (B) f (x) = (9x2 + 2)
n   3k  2  n   3k  2 
   2 3    2 3
(C) Lim
n 
  n   n = 15 (D) Lim
n 
  n  n =5
k 1   k 1  

Q.15 Consider the following 4 statements. Which of the following statement(s) is/are false
(A) There exist no plane containing the point (1, 0, 0) ; (0, 1, 0) ; (0, 0, 1) and (1, 1, 1)
   
(B) If a plane with normal vector N is perpendicular to a vector V then N ·V = 0
(C) If two planes are perpendicular then every line in one plane is perpendicular to every line on the
other plane.
(D) Let P1 and P2 are two perpendicular planes. If a third plane P 3 is perpendicular to P1 then it
might be parallel or perpendicular or at an angle of 45° to P2.
Q.16 Which of the following statements concerning the function

5x 2  10x  15
 , if x  3
f (x) =  x2  x  6 are correct

4, if x  3
(A) f (x) is continuous for all x  – 2
(B) f (x) is always decreasing
(C) f (x) has no vertical asymptotes
(D) f (x) has one horizontal asymptote.

Q.17 If C0, C1, C2, ....................Cn are binomial coefficients then

 2 2
2
n 2
n

Lt C n    c n 1    C n  2  .......................(1)   C 0  is
n
 3 3 3 
(A) 0 (B) 1 (C) –1 (D) 2

Q.18 If 4a2 + b2+2c2 + 4ab – 6ac – 3bc = 0, then the family of lines ax + by + c = 0 is concurrent at one or
the other of the two points whose co-ordinates are
 1  1
(A)   1,   or (–2, –1) (B) (–1, –1) or   2,  
 2  2

1  1 
(C) (–2, 2) or  , 1 (D) (1, 2) or  , 1 ‘
2  2 
 PART - B
MATCH THE COLUMN
INSTRUCTIONS:
Column-I and column-II contains four entries each. Entries of column-I are to be matched with some
entries of column-II. One or more than one entries of column-I may have the matching with the same entries
of column-II and one entry of column-I may have one or more than one matching with entries of column-II.

Q.1 In the circuit shown in figure, there are three identical capacitor C1, C2,
C3 each having capacitance 'C'. The switch 'S' is kept closed to point–1
for long time, then at time t = 0 switch 'S' is shifted to position–2 from
position–1
Column I Column II
2
(A) Final charge on capacitor C1 (P) CV 2
3
4
(B) Work done by Battery having emf V2 = V (Q) CV 2
3
2
(C) Final charge on capacitor C2 (R) CV
3
CV
(D) Amount of heat produced in the circuit after (S)
3
shifting the switch 'S' from (1) to (2)
Q.2 Match the following. (Here gas is ideal, P = pressure, V = volume,  = ratio of molar specific heat at
constant pressure & constant volume)
Column I Column II
P
(A) Adiabatic Bulk modulus of gas (P) –
V
2
(B) Slope of P–V graph in isothermal (Q)   1
process
(C) Degree of freedom (R) P

(D) Molar heat capacity at constant pressure (S)   1
divided by R

Q.3 Match the following

Column I Column II
(A) Canary yellow precipitate with (NH4)2MoO4 (P) NO3–
(B) Brown ring test (Q) NO2–
(C) Acid radical which evolves gas with conc. HCl (R) AsO43–
(D) Acid radical which gives gas with dil. H2SO4 (S) PO43–
Q.4 Match the following
List I List II

(A) CO2is evolved from (P)

NaHCO3 by the reaction of

(B) Compounds gives yellow oily (Q)

liquid on reaction with NaNO2 + HCl

(C) Compounds which on reaction (R)

with

gives para red dye.

(D) Compound which have maximum % (S)

of enol form
Q.5 Column–I Column–II
(A) If as many more words as possible be formed (P) 201
out of letters of the word “POTATO” then the no.
of words in which the relative order of vowels &
consonent remain unchanged is
(B) Number of positive integral solutions satisfying the
equation (x1 + x2 + x3) (y1 + y2) = 77, is (Q) 420
(C) Let A be the set of four digit numbers a1a2a3a4
where a1 > a2 > a3 > a4 then n(A) (R) 8
(D) The no. of dissimilar terms in the exapnsion
100
 2 1 
of the  x  2  1 is (S) 210
 x 
Q.6 Column–I Column–II


(A) If the line r  2 î  ˆj  3 k̂   ( î  ˆj  2 k̂ ) (P) 3
makes angles , ,  with xy, yz and zx planes
respectively then sin2 + sin2 + sin2 is
1 1 1
(B) If 0!20! + 2!18! + 4!16! + .................. (Q) 1

1 1 2a
...... 18!2! + = then (b – a) =
20! b!
(C) The equal sides of an isosceles triangle with fixed (R) 0
base 'b' are decreasing at the rate of 3cm/sec. The
rate at which its area is decreasing when the two
equal sides are equal to the base, is b a where a is

24n K
(D) The fractional part of is where K is (S) 2
15 15
 PART - C
Q.1 A sample of monoatomic ideal gas occupies 5.00 L at atmospheric pressure
and temperature 300 K (point A). It is heated at constant volume to 3.00
atm (point B) then it is allowed to expand isothermally to 1.00 atm (point
C) and at last compressed isobarically to its original state. If the gas is
monoatomic then calculate the total amount of heat (in joules) given to the
gas during whole cycle. (Here R = 8.30 Joule/mole0K; Patm = 105Pa;
1L = 10–3 m3; ln3 = 1.1)
Q.2 In the circuit shown in figure switch 'S' is closed for long time, then at time
t = 0 it is again opened. Find the charge on capacitor (in C) at time t = 6s
(here e–1 = 0.37)
Q.3 A rod of length L = 1m with thermally insulated lateral surface has uniform cross-section. The coefficient
1
of thermal conductivity of the material of the rod varies with temperature as K 
. The ends of the rod
T
are maintained at temperature T1 = 200C & T2 = 800C. Find the temperature (in0C) at the mid point of
rod.
Q.4 Five identical large conducting plates each of area A are placed parallel
to each other at separation 'd'. Plates 1 & 3 are connected by thin
conducting wire & plate 2 & 5 are connected by another thin conducting
wire. The junction of plate 1 & 3 and plate-4 are connected by a battery
having emf 'V' (as shown in figure). The system is in steady state. Now
Plate-1 is moved upward slowly so that it come in contact with Plate 2.
Calculate the amount of work done (in J) by battery during motion of
0 A
plate-1. (Here = 20F, V = 10 volts)
d
Q.5 When zinc is refined by electrolysis, the desired half-reaction at the cathode is
Zn2+(aq) + 2e–  Zn(s)
A competing reaction, which lowers the yield, is the formation of hydrogen gas :
2H+(aq) + 2e–  H2(g)
If 91.26% of the current flowing results in zinc being deposited, while 8.74% produces hydrogen gas,
how many liters of H2, measured at STP, form per kilogram of zinc? [Zn = 64]
Q.6 A gaseous compound 'A' reacts by three independent first order processes
(as shown in figure) with rate constant 2×10–3, 3 × 10–3 and 1.93 × 10–3
sec–1 respectively for products B, C and D respectively. If initially pure 'A'
was taken in a closed container with P = 2.079 atm, find the partial pressure
of 'B' (in atm) after 100 sec from start of experiment.
Q.7 Calculate the emf of following cell
Ag(s) |AgBr(s)| KBr (0.002 M) ||Ag2CrO4(saturated solution) |Ag (s)
Ksp (Ag2CrO4) = 4 × 10–12
 2.303RT 
Ksp (AgBr) = 2 × 10–13  F  0.059 (log 2 = 0.3)
 
Q.8 An NH4+ – NH3 buffer is supposed to keep the pH of the solution constant during the following reaction
within the safe limit.
CH3COOCH3(aq) + 2H2O (l)  CH3COO–(aq) + H3O+(aq) + CH3OH(aq)
If this buffer solution had these initial conditions,
[CH3COOCH3]o = 0.020 M,
[NH4+]o = 0.100 M
[NH3]o = 0.06 M
What would be the difference in initial pH & final pH after the completion of reaction.
(pKb of NH3 = 4.74; log 2 = 0.3, log3 = 0.48)
Q.9 If the function f(x) = 2x3 - 9ax2 + 12a2x + 1, where a > 0, attains its maximum and minimum at p and q
respectively such that p2 = q, then a equals
Q.10 y = f (x) is a parabola, having it's axis parallel to y-axis. If the line y = x touches this parabola at x = 1,
then f '' (1) + f ' (0) is
 4  54k  x k  8
Q.11 The largest real value for x such that   4  k !  k!   3 is of the form of p q  r then the value of
k 0   
2 2 2
p + q + r is
 a
[log a x ]
Q.12 If the value of definite integral  x ·a dx where a > 1, and [x] denotes the greatest integer, is
1

e 1
then the value of [a] equals where [ ] mean GIF
2