PART T EST- 2

Class : XII (NUCLEUS)

Time : 3 hour Max. Marks : 60
INSTRUCTIONS
1. The question paper contain pages and 3-parts. Part-A contains 6 objective question , Part-B contains 2
questions of "Match the Column" type and Part-C contains 4 subjective type questions. All questions are
compulsory. Please ensure that the Question Paper you have received contains all the QUESTIONS
and Pages. If you found some mistake like missing questions or pages then contact immediately to
the Invigilator.
PART-A
(i) Q.1 to Q.6 have One or More than one is / are correct alternative(s) and carry 4 marks each.
There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.
PART-B
(iii) Q.1 to Q.2 are "Match the Column" type which may have one or more than one matching options and
carry 8 marks for each question. 2 marks will be awarded for each correct match within a question.
There is NO NEGATIVE marking. Marks will be awarded only if all the correct alternatives are selected.
PART-C
(iv) Q.1 to Q.4 are "Subjective" questions. There is NO NEGATIVE marking. Marks will be awarded
only if all the correct bubbles are filled in your OMR sheet.
2. Indicate the correct answer for each question by filling appropriate bubble(s) in your answer sheet.
3. Use only HB pencil for darkening the bubble(s).
4. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.
5. The answer(s) of the questions must be marked by shading the circles against the question by dark HB pencil
only.
PART-A PART-B PART-C
For example if only 'B' For example if Correct Ensure that all columns
choice is correct then, match for (A) is P, Q; for (4 before decimal and 2
the correct method for (B) is P, R; for (C) is P after decimal) are filled.
filling the bubble is and for (D) is S then the Answer having blank
A B C D correct method for filling column will be treated as
the bubble is incorrect. Insert leading
P Q R S zero(s) if required after
For example if only 'B & (A) rounding the result to 2
D' choices are correct decimal places.
then, the correct method (B) e.g. 86 should be filled as
for filling the bubbles is 0086.00
A B C D (C) .
.
(D) .
The answer of the .
question in any other .
manner (such as putting .
, cross , or partial .
shading etc.) will be .
treated as wrong. .
.
 PART A
Q.1

Compound B has a neutralisation equivalent 112'G' is a dichloro alkane.

(A*) A = ,B= ,C= ,E= ;F=

& G = ClCH2CH2CH2CH2Cl

(B) A = ,B= ,C= ,E=

& G = ClCH2CH2CH2CH2CH2Cl

(C) A = ,B= ,C= ,E= ,F=

& G = ClCH2CH2CH2CH2CH2Cl

(D) A = ,B= ,C= ;

E= ;F= & G = ClCH2CH2CH2CH2CH2Cl

[Sol:

Q.2 Identify A, B, C, D, E & F in the following reactions

(A) A = ,B= ,D= ,E= ,F=

&G=
 (B*) A = ,B= ,D= ,E= ,

F= &G=

(C) A = ,B= ,D= ,E= ,F= &G=

(D) Both B & C is possible

[Sol: (A)

(B)

(D)
 (E)

(F) 3  H 2SO 4 (G)

HNO
  

P–disubstituted provide us single mononitroderivative]

Q.3 Select the correct statement(s)

If S = f (E, V, n1, n2) & A = f (T, V, n1, n2)
(A*) S is equal to f (E, V, n1, n2) (B) S is equal to f (E, V, n1, n2)
(C*) A is equal to f (T, V, n1, n2) (D) A is equal to f (E, V, n1, n2)
[Sol: S = f (E, V, n1, n2)
& E, V, n1, n2 all are extensive vairable
 S = f (E, V, n1, n2)
A = f (T, V, n1, n2)
here T is intensive variable
 A = f (T, V, n1, n2) [A, C] ]

Q.4 Which of the following statement(s) is/are correct

I  III 
(A*) GaCl2 is actually Ga Ga Cl 4 
 
(B) Metallocenes are inorganic benzene
(C*) Cyclo Phosphazene (P3N3Cl6) is inorganic analogue of benzene
(D*) B6H62– is a closo borane with octahedral structure
[Sol: (B) Metallocenes are not inorganic benzene

(C) cyclo phosphazene (P3N3Cl6) is inorganic analogue of benzene

(D) F = 3b + 4c + h + x – 2n
b = no. of boron atoms
 c = no. of carbon atoms
h = no. of hydrogen atoms
x = no. of negative charges
n = b + c = no. of vertices
for B6H62–
b = 6, h = 6, x = 2, c = 0, n = b + c = 6 + 0 = 6
so no. of vertices = 6
F = 2 × 6 + 4 × 0 + 6 + 2 – 2 × 6 = 14
 n = 6  14 = 2 × 6 + 2
 Thus it satisfies the no. of framework electrons. F(=2n+2). Thus it is six vertices regular
polydeltahedron i.e., octahedral and it belongs to closo borane. BnHn2– category.

Octahedron

Q.5 Identify the correct statement(s)

(A) BF3 is a stronger Lewis acid than BCl3
(B*) Ga melts at ~300C and its density decreases when it solidifies.
(C*) Unusually high melting point of boron is due to its structure
(D*) Borazine is more reactive towards HCl than benzene due to weak B = N bond.

Q.6 In the titration of CH3COOH, with NaOH, the difference in number of NaOH molecules added and
CH3COO– present at equilibrium at pH = 7.5 per litre of titrating mixture is equal to
1 9
(A) ×6.023×1016 (B*) × 6.023 ×1016
10 10
99
(C) zero (D) × NA
10 10
[Sol: (B) At equilibrium, from charge balance equation
[Na+] + [H+] = [OH–] + [CH3COO–]
Here [Na+] = moles of [OH–] added / lt.
 [OH–]o – [CH3COO–] = [OH–] – [H+]
10 14 1014  1015
 
= +
– [H ] =
H 107.5

9 1015 9  10 7
= =
107.5 10

9  10 7 9
 Molecules = NA = × 6.023×1016]
10 10
 PART B

Q.1 Match the following

Column I Column II
(A) Canary yellow precipitate with (NH4)2MoO4 (P) NO3–
(B) Brown ring test (Q) NO2–
(C) Acid radical which evolves gas with conc. HCl (R) AsO43–
(D) Acid radical which gives gas with dil. H2SO4 (S) PO43–
[Ans: (A)  R, S; (B)  P, Q; (C)  P; (D)  Q]

Q.2 Match the following

List I List II

(A) CO2is evolved from (P)

NaHCO3 by the reaction of

(B) Compounds gives yellow oily (Q)

liquid on reaction with NaNO2 + HCl

(C) Compounds which on reaction (R)

with

gives para red dye.

(D) Compound which have maximum % (S)

of enol form
[Ans: (A)  P; (B)  R, S (C)  Q, (D)  Q]
PART C

Q.1 When zinc is refined by electrolysis, the desired half-reaction at the cathode is
Zn2+(aq) + 2e–  Zn(s)
A competing reaction, which lowers the yield, is the formation of hydrogen gas :
2H+(aq) + 2e–  H2(g)
If 91.26% of the current flowing results in zinc being deposited, while 8.74% produces hydrogen gas,
how many liters of H2, measured at STP, form per kilogram of zinc? [Zn = 64]
[Sol: Zn (aq) + 2e  Zn(s)
2+ –

2H+(aq) + 2e–  H2(g)

Let i amp. current is used.
 current used in Zn deposition = (0.9126 i) amp
& current used in H2 production = (0.0874 i) amp
 Now equivalents of Zn deposited
0.9126 i t  1000  2 
=   ..............(1)
F  64 
& equivalents of H2 produced
0.0874 i  t
= x ..............(2)
F
Dividing (2) by (1)
x 0.0874
=
 1000  0.9126
  2
 64 
 x=3
 Volume of H2 at STP = 11.2 × 3 = 33.6 litre ]

Q.2 A gaseous compound 'A' reacts by three independent first order processes
(as shown in figure) with rate constant 2×10–3, 3 × 10–3 and 1.93 × 10–3
sec–1 respectively for products B, C and D respectively. If initially pure 'A'
was taken in a closed container with P = 2.079 atm, find the partial pressure
of 'B' (in atm) after 100 sec from start of experiment.
[Sol. Overall rate constant = k = k1 + k2 + k3 = 6.93 × 10–3 [Ans. 0.3]
0.693
t1/2 = = 100 sec
6.93 103
2.079
After one t1/2 PB + P C + P D = atm
2
PB k1 200
PB  PC  PD = k k k =
1 2 3 693
200 2.079
PB = × = 0.3 atm ]
693 2

Q.3 Calculate the emf of following cell

Ag(s) |AgBr(s)| KBr (0.002 M) ||Ag2CrO4(saturated solution) |Ag (s)
Ksp (Ag2CrO4) = 4 × 10–12
 2.303RT 
Ksp (AgBr) = 2 × 10–13  F  0.059 (log 2 = 0.3)
 
[Sol: Ag(s) |AgBr(s)| KBr (0.002 M) ||Ag2CrO4(saturated solution) |Ag (s)
 Ag | Ag+(C1) || Ag+(C2) | Ag
Now for C1
K sp 2  10 13
[Ag+] = C1 =
Br   =
0.002
= 10–10

Now for C2
Ag2CrO4 (s) 2Ag+ + CrO42–
[Ag+]2 [CrO42–] = Ksp
 Ag  Ag 
 2 
= Ksp
2
[Ag+]3 = 2 Ksp
 [Ag+] = C2 = (2Ksp)1/3 = (8 × 10–12)1/3 = 2 × 10 -4
0.059  C 2 
So, Emf = log 
1  C1 

0.059  2  10 4 
= 1 log 10 

 10 
= 0.37 volts

Q.4 An NH4+ – NH3 buffer is supposed to keep the pH of the solution constant during the following reaction
within the safe limit.
CH3COOCH3(aq) + 2H2O (l)  CH3COO–(aq) + H3O+(aq) + CH3OH(aq)
If this buffer solution had these initial conditions,
[CH3COOCH3]o = 0.020 M,
[NH4+]o = 0.100 M
[NH3]o = 0.06 M
What would be the difference in initial pH & final pH after the completion of reaction.
(pKb of NH3 = 4.74; log 2 = 0.3, log3 = 0.48)
NH 3   0.06 
[Sol: pH1 = pKa + log

NH 4 
= 9.26 + log  
 0 .1 
= 9.26 – 0.22 = 9.04
After the reaction, NH3 + H+  NH4+
[NH4+] = 0.1 +0.02 = 0.12 M
[NH3] = 0.06– 0.02 = 0.04 M
 0.04 
 pH2 = 9.26 + log   = 9.26 – 0.48 = 8.78
 0.12 
pH = 9.04 – 8.78 = 0.26 Ans. ]
 PART T EST- 2
Class : XII (NUCLEUS)
Time : 3 hour Max. Marks : 60
INSTRUCTIONS
1. The question paper contain pages and 3-parts. Part-A contains 6 objective question , Part-B contains 2
questions of "Match the Column" type and Part-C contains 4 subjective type questions. All questions are
compulsory. Please ensure that the Question Paper you have received contains all the QUESTIONS
and Pages. If you found some mistake like missing questions or pages then contact immediately to
the Invigilator.
PART-A
(i) Q.1 to Q.6 have One or More than one is / are correct alternative(s) and carry 4 marks each.
There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.
PART-B
(iii) Q.1 to Q.2 are "Match the Column" type which may have one or more than one matching options and
carry 8 marks for each question. 2 marks will be awarded for each correct match within a question.
There is NO NEGATIVE marking. Marks will be awarded only if all the correct alternatives are selected.
PART-C
(iv) Q.1 to Q.4 are "Subjective" questions. There is NO NEGATIVE marking. Marks will be awarded
only if all the correct bubbles are filled in your OMR sheet.
2. Indicate the correct answer for each question by filling appropriate bubble(s) in your answer sheet.
3. Use only HB pencil for darkening the bubble(s).
4. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.
5. The answer(s) of the questions must be marked by shading the circles against the question by dark HB pencil
only.
PART-A PART-B PART-C
For example if only 'B' For example if Correct Ensure that all columns
choice is correct then, match for (A) is P, Q; for (4 before decimal and 2
the correct method for (B) is P, R; for (C) is P after decimal) are filled.
filling the bubble is and for (D) is S then the Answer having blank
A B C D correct method for filling column will be treated as
the bubble is incorrect. Insert leading
P Q R S zero(s) if required after
For example if only 'B & (A) rounding the result to 2
D' choices are correct decimal places.
then, the correct method (B) e.g. 86 should be filled as
for filling the bubbles is 0086.00
A B C D (C) .
.
(D) .
The answer of the .
question in any other .
manner (such as putting .
, cross , or partial .
shading etc.) will be .
treated as wrong. .
.
 PART A
Q.1

Compound B has a neutralisation equivalent 112'G' is a dichloro alkane.

(A*) A = ,B= ,C= ,E= ;F=

& G = ClCH2CH2CH2CH2Cl

(B) A = ,B= ,C= ,E=

& G = ClCH2CH2CH2CH2CH2Cl

(C) A = ,B= ,C= ,E= ,F=

& G = ClCH2CH2CH2CH2CH2Cl

(D) A = ,B= ,C= ;

E= ;F= & G = ClCH2CH2CH2CH2CH2Cl

[Sol:

Q.2 Identify A, B, C, D, E & F in the following reactions

(A) A = ,B= ,D= ,E= ,F=

&G=
 (B*) A = ,B= ,D= ,E= ,

F= &G=

(C) A = ,B= ,D= ,E= ,F= &G=

(D) Both B & C is possible

[Sol: (A)

(B)

(D)
 (E)

(F) 3  H 2SO 4 (G)

HNO
  

P–disubstituted provide us single mononitroderivative]

Q.3 Select the correct statement(s)

If S = f (E, V, n1, n2) & A = f (T, V, n1, n2)
(A*) S is equal to f (E, V, n1, n2) (B) S is equal to f (E, V, n1, n2)
(C*) A is equal to f (T, V, n1, n2) (D) A is equal to f (E, V, n1, n2)
[Sol: S = f (E, V, n1, n2)
& E, V, n1, n2 all are extensive vairable
 S = f (E, V, n1, n2)
A = f (T, V, n1, n2)
here T is intensive variable
 A = f (T, V, n1, n2) [A, C] ]

Q.4 Which of the following statement(s) is/are correct

I  III 
(A*) GaCl2 is actually Ga Ga Cl 4 
 
(B) Metallocenes are inorganic benzene
(C*) Cyclo Phosphazene (P3N3Cl6) is inorganic analogue of benzene
(D*) B6H62– is a closo borane with octahedral structure
[Sol: (B) Metallocenes are not inorganic benzene

(C) cyclo phosphazene (P3N3Cl6) is inorganic analogue of benzene

(D) F = 3b + 4c + h + x – 2n
b = no. of boron atoms
 c = no. of carbon atoms
h = no. of hydrogen atoms
x = no. of negative charges
n = b + c = no. of vertices
for B6H62–
b = 6, h = 6, x = 2, c = 0, n = b + c = 6 + 0 = 6
so no. of vertices = 6
F = 2 × 6 + 4 × 0 + 6 + 2 – 2 × 6 = 14
 n = 6  14 = 2 × 6 + 2
 Thus it satisfies the no. of framework electrons. F(=2n+2). Thus it is six vertices regular
polydeltahedron i.e., octahedral and it belongs to closo borane. BnHn2– category.

Octahedron

Q.5 Identify the correct statement(s)

(A) BF3 is a stronger Lewis acid than BCl3
(B*) Ga melts at ~300C and its density decreases when it solidifies.
(C*) Unusually high melting point of boron is due to its structure
(D*) Borazine is more reactive towards HCl than benzene due to weak B = N bond.

Q.6 In the titration of CH3COOH, with NaOH, the difference in number of NaOH molecules added and
CH3COO– present at equilibrium at pH = 7.5 per litre of titrating mixture is equal to
1 9
(A) ×6.023×1016 (B*) × 6.023 ×1016
10 10
99
(C) zero (D) × NA
10 10
[Sol: (B) At equilibrium, from charge balance equation
[Na+] + [H+] = [OH–] + [CH3COO–]
Here [Na+] = moles of [OH–] added / lt.
 [OH–]o – [CH3COO–] = [OH–] – [H+]
10 14 1014  1015
 
= +
– [H ] =
H 107.5

9 1015 9  10 7
= =
107.5 10

9  10 7 9
 Molecules = NA = × 6.023×1016]
10 10
 PART B

Q.1 Match the following

Column I Column II
(A) Canary yellow precipitate with (NH4)2MoO4 (P) NO3–
(B) Brown ring test (Q) NO2–
(C) Acid radical which evolves gas with conc. HCl (R) AsO43–
(D) Acid radical which gives gas with dil. H2SO4 (S) PO43–
[Ans: (A)  R, S; (B)  P, Q; (C)  P; (D)  Q]

Q.2 Match the following

List I List II

(A) CO2is evolved from (P)

NaHCO3 by the reaction of

(B) Compounds gives yellow oily (Q)

liquid on reaction with NaNO2 + HCl

(C) Compounds which on reaction (R)

with

gives para red dye.

(D) Compound which have maximum % (S)

of enol form
[Ans: (A)  P; (B)  R, S (C)  Q, (D)  Q]
PART C

Q.1 When zinc is refined by electrolysis, the desired half-reaction at the cathode is
Zn2+(aq) + 2e–  Zn(s)
A competing reaction, which lowers the yield, is the formation of hydrogen gas :
2H+(aq) + 2e–  H2(g)
If 91.26% of the current flowing results in zinc being deposited, while 8.74% produces hydrogen gas,
how many liters of H2, measured at STP, form per kilogram of zinc? [Zn = 64]
[Sol: Zn (aq) + 2e  Zn(s)
2+ –

2H+(aq) + 2e–  H2(g)

Let i amp. current is used.
 current used in Zn deposition = (0.9126 i) amp
& current used in H2 production = (0.0874 i) amp
 Now equivalents of Zn deposited
0.9126 i t  1000  2 
=   ..............(1)
F  64 
& equivalents of H2 produced
0.0874 i  t
= x ..............(2)
F
Dividing (2) by (1)
x 0.0874
=
 1000  0.9126
  2
 64 
 x=3
 Volume of H2 at STP = 11.2 × 3 = 33.6 litre ]

Q.2 A gaseous compound 'A' reacts by three independent first order processes
(as shown in figure) with rate constant 2×10–3, 3 × 10–3 and 1.93 × 10–3
sec–1 respectively for products B, C and D respectively. If initially pure 'A'
was taken in a closed container with P = 2.079 atm, find the partial pressure
of 'B' (in atm) after 100 sec from start of experiment.
[Sol. Overall rate constant = k = k1 + k2 + k3 = 6.93 × 10–3 [Ans. 0.3]
0.693
t1/2 = = 100 sec
6.93 103
2.079
After one t1/2 PB + P C + P D = atm
2
PB k1 200
PB  PC  PD = k k k =
1 2 3 693
200 2.079
PB = × = 0.3 atm ]
693 2

Q.3 Calculate the emf of following cell

Ag(s) |AgBr(s)| KBr (0.002 M) ||Ag2CrO4(saturated solution) |Ag (s)
Ksp (Ag2CrO4) = 4 × 10–12
 2.303RT 
Ksp (AgBr) = 2 × 10–13  F  0.059 (log 2 = 0.3)
 
[Sol: Ag(s) |AgBr(s)| KBr (0.002 M) ||Ag2CrO4(saturated solution) |Ag (s)
 Ag | Ag+(C1) || Ag+(C2) | Ag
Now for C1
K sp 2  10 13
[Ag+] = C1 =
Br   =
0.002
= 10–10

Now for C2
Ag2CrO4 (s) 2Ag+ + CrO42–
[Ag+]2 [CrO42–] = Ksp
 Ag  Ag 
 2 
= Ksp
2
[Ag+]3 = 2 Ksp
 [Ag+] = C2 = (2Ksp)1/3 = (8 × 10–12)1/3 = 2 × 10 -4
0.059  C 2 
So, Emf = log 
1  C1 

0.059  2  10 4 
= 1 log 10 

 10 
= 0.37 volts

Q.4 An NH4+ – NH3 buffer is supposed to keep the pH of the solution constant during the following reaction
within the safe limit.
CH3COOCH3(aq) + 2H2O (l)  CH3COO–(aq) + H3O+(aq) + CH3OH(aq)
If this buffer solution had these initial conditions,
[CH3COOCH3]o = 0.020 M,
[NH4+]o = 0.100 M
[NH3]o = 0.06 M
What would be the difference in initial pH & final pH after the completion of reaction.
(pKb of NH3 = 4.74; log 2 = 0.3, log3 = 0.48)
NH 3   0.06 
[Sol: pH1 = pKa + log

NH 4 
= 9.26 + log  
 0 .1 
= 9.26 – 0.22 = 9.04
After the reaction, NH3 + H+  NH4+
[NH4+] = 0.1 +0.02 = 0.12 M
[NH3] = 0.06– 0.02 = 0.04 M
 0.04 
 pH2 = 9.26 + log   = 9.26 – 0.48 = 8.78
 0.12 
pH = 9.04 – 8.78 = 0.26 Ans. ]