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Ch7 Heat

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CHAPTER 7

HEAT & THERMAL EXPANSION


Learning objective

The objective of this chapter is to impart students with:


 Definition of heat and temperature.
 Formula for temperature scale.
 The concept of thermal equilibrium, heat capacity, specific heat capacity,
latent heat.
 Able to understand calorimetry principle: conduction and convention.
TEMPERATURE SCALE

Temperature is generally measured using either the


Fahrenheit (°F) or the Celsius (°C) scale.
Kelvin (K) begins at absolute zero, meaning it has
no negative numbers or no temperature below 0 K.
Temperature Symbol Ice Point Steam Difference
scale Point
Celsius °C 0 100 100 °C

Fahrenheit °F 32 212 180 °F

Kelvin K 273.15 373.15 100 K

Ice point and steam point of temperature scales


Conversion formulae: Celsius, Fahrenheit and Kelvin

◦ Celsius to Kelvin: 𝑇𝐾 = 𝑇𝐶 + 273.15

◦ Celsius to Fahrenheit: 𝑇𝐹 = 1.8𝑇𝐶 + 32

𝑇𝐹 + 32
◦ Fahrenheit to Celsius: 𝑇𝐶 =
1.8
Example 1:

A friend suffering from flu has a slight fever. His body temperature is
37.20°C. What is
his temperature in
i) Kelvin
ii) degree Fahrenheit, °F.
HEAT AND INTERNAL ENERGY

- Heat, Q is energy transferred from one object to another due to


differences in a temperature.
- Heat flows from high temperature to lower temperature until thermal
equilibrium is achieved.
- SI unit: Joule (J) or Calorie (Cal).

- Internal energy (thermal energy): the sum of the molecular kinetic energy,
molecular potential energy and other kinds of molecular energy in
substance.
- Molecular kinetic energy: originates from the random motion (or vibration) of
the molecules.
- Molecular potential energy: due to forces that acts between the atom of
a molecule and between molecules.
Heat Capacity, C
 Amount of heat/energy needed to raise the temperature of substance
by 1°C or 1K.

𝑄
C= 𝑆𝐼 𝑢𝑛𝑖𝑡 = 𝐽𝐾 −1
∆𝑇

Specific Heat Capacity, c


 The heat capacity per unit mass

𝑄
C= 𝑆𝐼 𝑢𝑛𝑖𝑡 = 𝐽𝑘𝑔−1 𝐾 −1
𝑚∆𝑇
Example:

A piece of copper of mass 500 g at temperature 20 K is heated until its


temperature becomes 120 K. Determine the amount of heat absorbed by
the piece of copper. Given specific heat capacity of copper is 0.385
kJ/kg/K.
Example:
Heat energy is released or absorbed according to
Conservation of Heat Energy.

“for a closed and isolated system, the heat energy is


conserved.”
Σ𝑄𝑔𝑎𝑖𝑛 = Σ𝑄𝑙𝑜𝑠𝑡
: total heat energy is always the same.
Example:
Example:

A 350 g unknown cube at 100⁰C is dropped into a 100 g aluminium cup


containing 750 g of water at 25 ⁰C. By assuming there is no heat lost to the
surroundings, calculate the final temperature of the system.
Given; specific heat of water, aluminium, and unknown cube are 4186
J/kg/K, 900 J/kg/K, and 1757.55 J/kg/K resppectively.
EXERCISE

Convert the following term;


1. -30 °F to °C
2. 150 °C to °F
3. -273 °C to °F
4. 57 °C to K
5. 90 K to °C

A 50 g of Aluminum block at 400 °C is dropped into a 500 g copper calorimeter containing


200 g of water at 30 °C. What will be the temperature of the system when equilibrium is
established? Given specific heat of copper = 388.83 J/kg/ K , specific heat capacity of water =
4181 J/kg/ K and specific heat capacity of aluminum = 880 J/kg/ K
THERMAL EXPANSION
- Tendency of matter to change in shape, area, and volume in response
to a change in temperature, through heat transfer.
Definition: the change in ________________ in response to a change in temperature.
Thermal expansion Formula
Linear expansion ∆𝐿 = 𝐿𝑜 𝛼∆𝑇
𝐿 = 𝐿𝑜 (1 + 𝛼∆𝑇)

Area expansion ∆𝐴 = 𝐴𝑜 𝛽∆𝑇


𝐴 = 𝐴𝑜 (1 + 𝛽∆𝑇)

Volume expansion ∆𝑉 = 𝑉𝑜 𝛾∆𝑇


𝑉 = 𝑉𝑜 (1 + 𝛾∆𝑇)
EXAMPLE:
A copper rod has a length of 9.00 cm at 25 °C (αcopper = 17x10- 6 /°C).
a) What is the length of the rod at the freezing point of water?
b)What is the temperature if the new length of the rod is 9.027 cm?
Solution:
EXAMPLE:
A metal rod of length 7 m is being heated to 35° C. If the length of rod
expands to 7.12 m
after some time, calculate the linear expansion coefficient (Room temperature
is 27°C).
EXAMPLE:
EXAMPLE:
ALL THE BEST!
EXAMPLE:
A zinc disc has a hole 40 mm in radius punched in center. Later, the disc at
27°C is placed in boiling water for few minutes. Calculate the new area of
the hole. (Given αZn = 2.6x10-5/ °C )

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