Chemisty

DODOMA CENTRAL FITNESS PAPER CHEMISTRY PAPER 1: SERIES No.
Time: 2:30 The following constant may be use (i) (ii) (iii)
(iv)
Speed of light = 3x10 msec 1 a.m.u =K.0X10 Kg Plancks constant =6.63 x10 J Sec
R = 8.31 Jmol K or 0.0821dm atm Mol K Plancks constant =6.63 x10 J Sec R = 8.31 Jmol K or 0.0821dm atm Mol K
(v) (vi) (vii)
1. (a) Define the following term (i)Quantum numbers (ii) Hybridization (iii) (b)Complete the following chart
2(a) Explain what convergence limit and what is its significance (b)(i)An electrons which is in n=5 is supplied with energy equivalent to 1.72 x 10 J .Calculate kinetic energy of electron when ejected. (c)Consider an atom with energy level diagram shown in the figure below
An electron (e) is located at E state what will happen when an atom is incident to the following energy (i)Less than E E (ii)Equal to E E (iii)Less than E E but greater than E E (iv)Equal to E E (v) Greater than E -E 3. (a)State the Law of mass action. (b)Distinguish between equilibrium constant and reaction quotient. (c)Ammonium hydrogen sulphide ( ) solid was introduced in a 1litre bulb at 18 C and 1 atmospheric pressure. The bulb then heated to 127 C. When ammonium hydrogen sulphides dissociate and establish this equilibrium At equilibrium the total pressure was measured to be 2.16atm calculate equilibrium constant for this reaction. (a) State 4 (a) (i) A homogeneous catalyst (ii) heterogeneous catalyst (iii)Autocatalyst (b)(i)Consider the following reversible reaction 2so + o 2so H -180KJMol
Is the production of so is fevered at high temperature or low temperature (c)(i) Distinguish between activation energy and activation complex (ii)State VANT HOFFS LAW OF MOBILE 5.(a)Using the kinetic theory of gas equation PV= MCN deduce (i)The gas law equation PV=nRT (ii)Charles law equation (b)The van der Waals equation ( P+a/v )(V-b)=RT where a and b are constants is used to describe the behavior of real gas. What is significance of the term a/v and b in this equation? (c)Calculate molecular mass of a gas which has a density of 2.615g/dm at 289K and 101 Nm 6.(a)State PARTITION law (b)500 of 1.5M of ammonia solution were shacked with 50cm of chloroform in separated funnel. After allowing the layer to settle 20cm of chloroform layer were withdraw and titrated with M/20 Hydrochrolic acid 22.9cm of the acid were required for neutralization .Find the partion coefficient of ammonia between water and chloroform at the temperature of experiment.
SECTION:B Answer only three questions from this section 7. (a)(i)State the modern periodic law (ii)What are the two factors which enhance arrangement of elements in the periodic table according to increase atomic number (b) Define the following term (i)Electro negativity (ii) polarizing power (iii) Isoelectric series (iii)
(c)Why does barium nitrate impact apple green colouration to the Bunsen flame while magnesium nitrate does not when heated in open flame although both are the salt of group two elements of periodic table? 8. (a)Discuss the position of hydrogen in the periodic table (b)Explain why first member of each group show properties which are not similar to other group member. ( c) Explain the following chemical phenomena using equation if possible (i) (ii) (iii) (iv) aluminum chloride is good Lewis acid concentrated nitric acid render s aluminum passive The relative molecular weight of aluminum chloride in the vapor state is twice than expected value The NH Cl solution is acid
9 (a) what is difference between hydration and hydrolysis? (b)Give two supportive reaction equation to show Cleary the contrast between hydrolysis and hydration (b)(i)Explain why extraction of aluminum does not required aqueous material (ii)Iodine and chlorine are both found in the same group of the periodic table but hydrogen iodide is strong reducing agent than hydrogen chloride (c)Aluminum and beryllium are diagonally related in the periodic table .By considering this element s explain why element which are related diagonally have similar properties .Give at least five diagonal properties between aluminum and beryllium.
10(a) Explain in term of their electronic configuration why Fe ions are ready oxidized to Fe ion but Mn ion are not ready oxidized to Mn ions (b)Explain the following chemical phenomena using equation where possible (i) Beryllium oxide is amphoteric (ii)Nitrogen hydride has high exceptionally high boiling point compared to the the hydride of its group member (c)Explain what is screening effect..? and can screening effect used to determine reactivity SECTION:C Answer three (3 )questions from this section 11. (a)Name the following compound using IUPAC system of nomenclature (i) CH C Br (ii) OH
(ii)CH C C CH OH (iii) CH C CH CH C CH
(iv )CH C O CH
(iii) 4.1g of bromoalkane was reacted with excess sodium hydroxide solution. The resulting solution was acidified with excess nitric acid and dilute to exactly 250cm .25cm of this solution required 33.28cm of 0.1M of AgNO solution for complete precipitate of silver bromide (i)Calculate a relative molecul ar mass of a bromoalkane (ii)From your answer in (i) above deduce molecular formulae of a bromoalkane (iii)Write possible isomers
12.(a) Indicate how the following mixture could be separated without distillation (i)Butyne and But-2-yne (ii) Butene and butane
(b)Give equations that illustrate good method to synthesis each of the following C H CH +F CO C H (i)2-bromobutane from 1-bromobutane ii)1-bromobutane from 2-bromobutane (iii)CH CH CH CH CH CH from CH CH CH CHOH 13. Consider the reactions below (i) (ii) (iii) (iv) (v) (vi) C H CH +F CH CO C H CH (i) A+O +Zn+H O (C H O)+(C H O) (ii)B D (iii) 2B +Cold NaOH E(C H O ) (iv ) D+SOCl F+HCl +SO (vi)CH C C H CH +Conc HCl G
CH
(a)Name type of reactions from (i) to (vi) (b)Write the symmetric IUPAC names and structure of compound A,B,C,D,E,F and G 14 0.037g of alcohol was added to CH mgI and gas involved measured 11.2cm at STP what is molecular mass of alcohol Suppose the alcohol is primary alcohol and non branched .Show how you will convert that alcohol to (i)Ethanal only (ii)Propanone (ii)Ethane
Prepared by FRANK CYPRIAN SARARA 0717248208 24/09/2011

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DODOMA CENTRAL FITNESS PAPER CHEMISTRY PAPER 1: SERIES No.

(v) (vi) (vii)

Prepared by FRANK CYPRIAN SARARA 0717248208 24/09/2011

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