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    13 Amines

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    ChemGuru 4 U
    The document provides questions from past exams on the topic of amines from March 2014 to March 2018. The questions cover various amine reactions including Hoffmann bromamide degradation, carbylamine reaction, reduction of nitrocompounds, Gabriel synthesis, and relative basicities of amines.

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    © All Rights Reserved
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    13 Amines

    Uploaded by

    ChemGuru 4 U
    20 views2 pages
    The document provides questions from past exams on the topic of amines from March 2014 to March 2018. The questions cover various amine reactions including Hoffmann bromamide degradation, carbylamine reaction, reduction of nitrocompounds, Gabriel synthesis, and relative basicities of amines.

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    13.AMINES

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    The document provides questions from past exams on the topic of amines from March 2014 to March 2018. The questions cover various amine reactions including Hoffmann bromamide degradation, carbylamine reaction, reduction of nitrocompounds, Gabriel synthesis, and relative basicities of amines.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    20 views2 pages

    13 Amines

    Uploaded by

    ChemGuru 4 U
    The document provides questions from past exams on the topic of amines from March 2014 to March 2018. The questions cover various amine reactions including Hoffmann bromamide degradation, carbylamine reaction, reduction of nitrocompounds, Gabriel synthesis, and relative basicities of amines.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 2

    Amines

    March 2014

    1. Explain Hoffmann Bromamide degradation for the preparation of Aniline.


    2. Give the IUPAC name of ethyl methyl amine.
    3. What is Hinsberg reagent? Between CH3NH2 and C6H5NH2 which is more basic?

    July 2014

    1. Explain carbylamines reaction with example.


    Br2/ NaOH NaNO2, HCl at O0C
    2. CH3CONH2-----------------→P --------------------------→ Q
    Identify P and Q. Name the reaction occurring in step (i)

    March 2015

    1. Identify the reactant A in the following reaction : A + 2RX →R4N+X-


    2. Explain Hoffmann’s bromamide degradation reaction for the preparation of methanamine.
    3. Which is more basic among aqueous solutions of aniline and ammonia? Give one reason.

    July 2015

    1. Write the IUPAC name of (CH3)2N-CH2-CH3.


    2. Explain the Hoffmann’s bromamide reaction.
    3. Name the major product formed when nitrous acid is treated with
    a. methylamine and b. aniline at low temperature

    March 2016 (Cancelled)

    1. How do you prepare methanamine from Hoffmann Bromamide degradation reaction?


    2. Complete the following reactions:
    H2/Pd ethanol
    a. Nitrobenzene --------------------------→
    273-278K
    b. aniline + NaNO2 + 2HCl ----------------------→
    3. Give reason: Ammonia is more basic than aniline.

    March 2016

    1. Explain carbylamines reaction.


    2. What is the action of bromine water on benzenamine(aniline) at room temp.
    3. The pKb values of ammonia, methanamine and benzenamine are 4.75, 3.38 and 9.38
    respectively. Arrange them in the increasing order of their basic strength.

    July 2016

    1. Explain the reduction fonitrocompounds to amines with an example.


    2. Why aromatic primary amines cannot be prepared by Gabriel synthesis?
    3. How is aniline converted to phenyl isocyanide? Write the equation.

    March 2017
    1. How primary amine is prepared by Hoffmann bromamide degradation reaction? Write
    equation.
    2. I) write IUPAC name of CH2CH2NH2.
    ii) arrange the following amines in the order of their increasing basic strength in aqueous
    solution (CH3)3N , (CH3)2NH , CH3NH2
    3. Complete the following equation:
    273-278K
    C6H5NH2 + NaNO2 + 2HCl ----------------------→

    July 2017

    1. Explain Hoffmann broamamide degradation reaction.


    2. Name the major product formed in the following conversion:
    a. when nitrous acid is treated with methylamine
    b. Benzene diazonium chloride is treated with KI
    3. Which is more basic among methylamine and aniline?

    March 2018

    1. Explain carbylamine reaction with equation.


    2. How does nitrobenzene reduced to aniline? Give equation.
    3. Write the IUPAC name of C6H5-N(CH3)2

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