Le u slmpi{y eqn O in

uin9 the methari

veietion sepeation vasiables

diffenentia
Thu
a is the POatial
eqn
eqn
the e in
I n
function
The
the uce

a tom.
Aydngen
to
to methad Sepera tion
Accordinq
iS the
vaaua bla (1, 6, p)
wave func tion
Pnaluct 3 individual

namelyH
Siro
S ito ad
the entre eqn b b
y
multipi9
,and dividin9
thoughout b
Sub eqn
and aAan{

sihe( (1 sin sine

+ 2my
sie E1TSo
T
Ps Co)

sin (sine l o

+ Siro E t

Now -he let hancd side egn s he

functton and .whilo RHS is he fund

o alone
equattng both LHS RHS n to a
e qen
Same ConSant N we 9et
get

Reaangirg
2

Called Azimuthal equa hon

The egn & i s
ofhydogen atom.
When we Bubstitut
the RHS

divide he entire eqn

we
en , and teimy
The vaaou
eaiAanging
by sne and
by
we indthat
2

( 4TS
sine > Sino

3 sine P2

alone
eqn has LHS haing e rms

E alone
and RHS having
Constant 2 ¢ +1) we4et
same
Squating to

d
d
4T
 m
2
P Sin -(Sine
ao
sino
Eqn is callod Radiol eq Hydugen

abm
atom
iS Calld Hydogen
pola eqn
Solution of Azimuthal Ean
solution e q n
=A exp (im b)
Ps C4)

and p+2T
Fo o=
rauo One. i0,
2 should be sinqu
Cp+2m)
Ae ' L Aeme
tonditon
in eqn
thi
To satsty an ntegen Therelone
be zem
ba to
mA
Q
pesmittcd
vaus MA
on anulaL Momant u m

m O, t1,t2
orbital quantum NOo
Hc
c a l l d Magne
is

Solution f pola qn
associaton
*qn has idss Solution

Pam, Cwsed.
Tus polay
Legende polynomial
the uppes limit M
solutton decides
eqn
and hnce
M O , fl,t2

is aysoua ted Lagu er r e

The sdnen
 Ln,
Lo,
) Thu soln tmotag-fhrus O8ing
olynomal
quantum num beP
M
Cigkt pon moy
Cn-) Azimuthal 9uantum
O , 1, 2 nam bN
n I2, 3 (pincipe quantum hum be) The m

a tom
he e n
Hydo he
The Enegj
et
is 9ven b
En eme
8E W her

13.6

En eV

Rigid Rota tor

W

Conside27 two point maMes ad Ma oined

od. The two
massless
trge-tha by Agd
ke o dunbel
mauss es aA watin9

Cw
m

About an a thDugh thei contme

mas C. Normal to he 'ne foina ng

mase
then
Osing the Rola tion

M7 Ma Ti

about
The morment Ineatia 1he yS ttm
teame Y a nd
aUS Sotation in
he
The

get
M, Ma -
M+M2
The
is he Ae ducod mas
where
s tem
M M2

M+M
he hotatin9 dumbel by
We can seplaw
mos
at
a t Ca
a df's tanuY
di's tante
O singtu point

the anfs Tota tien. Potcntial enea94

7
hom
fs taken as zeo. Iince
t h e dunbt
joint toge
toge thar
ae jdy
a mass es
+he hem emauung
dfstan co btween
Lwth he
the o t a tron

unatfee te d duing
angula momentum and eneng y
he
as aigid vtator
mp
P : Iw

E Tu
 m angula Speccd he
the
w 1s The
tunM
aototton

Awdinq f
quantum hooy, nguwou
mu Hiple h
mentum hou ld be Integral T

So P- Td kh
2T

E
T 8n°1

Nhene k is he Integes

7 Denve permittd en level igid

Rotator
The general egn schodinger q
Spheucal Polas coovdinaita in ven by

o-
(E-v) -v) p=

tonstant
taken as )) T h e
The
As s a

is zeD
in egn
S fac tor
VPoentia Enegy e
zerm
s.

moment
ís plawd

Tne6Ha I
 eq igi d uta to1 edutes
Schmodinge

Sine (sine SinO

The soln
C2qn can be applied by the
vaiablei.
method sepeaa ticn

Assume yo, ) - 9,t) Ps(¢)

both 8idas 1
Sub in and divid ing

9, 2
W 9et
Sire

Sin o (sire ,(e)\ eE sio = -. V2

the
quontity m and equa ting
Difinn the S
samme 9uantrty
guant"y
LHS Rts egn to

we get
- m

(o)

Sin /stne P1(02)+ 87 E stro =m

m
pividng in eq

sine
(s ) o)5(0).
-
Soln egn 2c6)tim

s he #ve intcgu
nhere

Substitu ting 8nTE

I eqn , and

Rowritting

Sine
sto)+(c )
Sinto
to)=o

ean Can e sdved Considerg

The whole ean vaiable
egn vauable
* and changing

Can be found askCK+)

CC value

8TE k C+)

Qs Aotational
des igna ted
Hese
humber
uantuun
k C+I) h
E

Cnd the alau

Ene
Eneg lerel ae discle te
values Cun be detemined equ ation
Ergen