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DELHI PRIVATE SCHOOL L.LeC.
Affiliated to C.B-S.E.. DELHI
D P S (Approved & Recognized By Ministry Of Education —United Arab Ermirates)
FE/CHEEEQP/1122/C 02-MAR-2023

EEE CONSORTIUM
FINAL EXAMINATION (2022-23)
Subject: CHEMISTRY Max. Marks: 70
Grade: 11 Time: 3 hrs
Name: Section: Roll No:
General Instructions:
Read the following instructions carefully.
a) There are 35 questions in this question paper with internal choice.
b) SECTION A consists of 18 multiple-choicequestions carrying I mark each.
c) SECTION B consists of 7 very short answer questions carrying 2 marks each.
d) SECTION C consists of 5 short answer questions carrying 3 marks each.
e) SECTION D consists of 2 case- based questions carrying 4 marks each.
f) SECTION E consists of 3 long answer questions carrying 5 marks each.
g) All questions are compulsory.
h) Use of log tables and calculators is not allowed
SECTION A
The following questions are multiple-choice questions with one correct answer. Each
question carries I mark. There is no internal choice in this section.
Find the molecule with the maximum dipole moment. 1
(a) Cl-14 (b) NH3 (c)C02 (d) NF3
Q2 How many ml of water must be added to 200 ml of 0.65 M HCI to further dilute the 1
solution to 0.20 M ?
(a)450 ml (b) 750 ml (c) 550 ml (d) 500 ml
Q3 The element with atomic number 35 belongs to: 1

(a) d —Block (b) f— Block (c) p —Block (d) s —Block

Q4 The I.U.P.A.C. name of the following compound is: 1

CH3

CH3
(a) 2-Bromo-3-metylbutanoic acid
(b) 3-Bromo-2-metylbutanoic acid
(c) 2--Bromo-2-metylbutanoic acid
(d) 3-Bromo-3-metylbutanoic acid
During change of 02 to 022- ion, the electron adds on which of the following orbitals ? 1
(a) o* orbital (b) 7torbital (c) orbital (d) orbital
Which of the following pairs of gases contains the same number of molecules? 1
(a) 16 g of 02 and 14 g ofN2 (b) 6 g of 02 and 22 g of C02
(c) 28 g ofN2 and 22 g of C02 (d) 32 g of C02 and 32g ofN2
Q7 Oxidation number of P in 1)043-,Of S in S042-and that of Cr in Cr2072-are respectively: 1
(a) +3, +6 and +5 (b) +5, +3 and +6
(c) +3, +6 and +6 (d) +5, +6 and +6
Q8 Isopropyl bromide on Wurtz reaction gives: 1
(a) Hexane (b) Propane
(c) 2, 3 —Dimethylbutane (d) Neohexane
Q9 Find the pair with sp2hybridisation of the central atom: 1
(a) NH3 and N02-
(b) BF3 and NH2-
(c) BF3 and N02-
(d) NH2- and H20
(210 In a process, 701 J of heat is absorbed by a
system and 394 J of work is done by the 1
system. What is the change in internal energy for the
process?
(a) 307 J (b) 209 J (c) 394 J (d) 500 J
(211 In a reversible chemical reaction at equilibrium,
if the concentration of any one of the 1
reactants is doubled, then the equilibrium constant will:
(a) Also be Doubled (b) Be Halved
(c) Remain the Same (d) Become One-Fourth
Q12 Arrange the following in order of increasing oxidation
number of Mn: 1
(a) MnC12, Mn02, (b) MnC12, , Mn02
(c) , MnC12, Mn02 (d) Mn02, , MnC12
(213 Benzene reacts with CH3Cl in the presence of anhydrous AIC13to
form: 1
(a) Chlorobenzene (b) Benzyl chloride (c) xylene (d) toluene
Q14 The ion which is iso-electronic with CO is
1
(a) CN (b) 02- (c) N2 (d) 02
Q15 In the following questions from Q15 to Q18 a statement of assertion followed by
a 1
statement of reason is given. Choose the correct answer out of the following choices.
(a)Both assertion and reason are wrong.
(b)Both assertion and reason are correct statements but reason is not correct explanation
of assertion.
(c)Assertion is correct statement but reason is wrong statement.
(d) Both assertion and reason are correct statements and reason is correct explanation of
assertion.
(e) Assertion is wrong statement but reason is correct statement.
Assertion (A): The empirical mass of ethene is half of its molecular mass.
Reason (R): The empirical formula represents the simplest whole number ratio of
various atoms present in a compound.
Q16 Assertion (A): Boron has a smaller first ionisation enthalpy than beryllium. 1
Reason (R): The penetration of a 2s electron to the nucleus is more than the 2P electron
hence 2P electron is more shielded by the inner core of electrons than the 2s electrons.
Q17 Assertion (A): A liquid crystallises into a solid and is accompanied by decrease in 1
entropy.
Reason (R): In crystals, molecules organise in an ordered manner.
(218 Assertion (A): For any chemical reaction at a particular temperature, the equilibrium 1
constant is fixed and is a characteristicproperty.
Reason (R): Equilibrium constant is independent of temperature.
SECTION B
This section contains 7 questions with internal choice in two questions. The following
questions are very short answer type and carry 2 marks each.
(219 Two elements C and D have atoniic numbers 36 and 58 respectively. On the basis of 2
electroivic configuration predict the group, and period to which each element belongs.
Q20 Give reason for the following: 2
(i)Neither q nor w is a state function but q + w is a state function.
(ii)A real crystal has more entropy than an ideal crystal.
OR
Discuss the effect of temperature on the spontaneity of an exothermic reaction.
(221 A reaction between ammonia and boron trifluoride is given below: 2

:NH; + REV:BF;
Identify the acid and base in this reaction. Which theory explains it?
OR
If decomposition is depicted as,
PC15(g) ePC13 (g) + C12 ArH0= 124.0 kJ mol-
What would be the effect on Kc iP
(i) pressure is increased.
(ii) the temperature is increased.
2
Q22 For each of the following pairs, predict which one has lower first ionization enthalpy?
(i) N or O(ii) Na or Na+
2
Q23 Balance the following redox reaction:
Cr207- + Cr+3 + S042- (acidic medium)
2
Q24 Draw the resonance structures for C6H5N02.
N02

2
(225 Derive the relationship Cp —cv R.
SECTION C
This section contains 5 questions with internal choice in two questions. The following
questions are short answer type and carry 3 marks each.
Q26 Use the molecular orbital theory to show that N2 would be expected to have a triple 3

bond, F2 a single bond and Ne2 no bond.

Q27 Yellow light emitted from a sodium lamp has a wavelength (X)of 580 nm. Calculate the 3

frequency O) and wave number of the yellow light.

OR
Find energy of each of the photons which:
15
(i) corresponds to light of frequency 3 x 10 1-lz.
(ii) have wavelength of 0.50 AO
Q28 (i)Why is benzene extra-ordinarily stable though it contains three double bonds? 3
(ii)Arrange benzene, n-hexane and ethyne in decreasing order of acidic behaviour. Also
give reason for this behaviour.
OR
How will you convert the following compounds into benzene?
(i) Ethyne (ii) Ethene (iii) Hexane.
Q29 A hydrocarbon 'A' adds one mole of hydrogen in the presence of Pt as catalyst to form 3
n-hexane. 'A' is oxidized vigorously with KMnO,l, a single carboxylic acid containing
three carbon atoms is isolated. Give the structure and nanne of 'A' , explain and name the
reactions.
(230 The enthalpy of combustion of methane, graphite and dihydrogen at 298 K are -890.3 3
KJ mol -l , —393.5KJmol-l and —285.8 KJ mol-respectively. Calculate enthalpy of
formation of CHA(g)?
SECTION D
The following questions are case-based questions. Each question has an internal choice
and carries 4 (1+1+2) marks each. Read the passage carefully and answer the questions
that follow.
Q31 The identity of a substance is defined not only by the types of atoms or ions it contains, 4
but by the quantity of each type of atom or ion. The experimental approach required the
introduction of a new unit for amount of substances, the mole, which remains
indispensable in modern chemical science. The mole is an amount unit similar to familiar
units like pair, dozen, gross, etc. It provides a specific measure ofthe number of atoms or
molecules in a bulk sample of matter. A mole is definedas the amount of substance
containingthe same number of discrete entities (atoms, molecules,ions, etc.) as the
number of atoms in a sample of pure 12C weighing exactly 12g. One Latin connotation
for the word "mole" is "large mass" or "bulk," which is consistent with its use as the name
for this unit. The mole provides a link between an easily measured macroscopic property,
bulk mass, and an extremely important fundamental property, number of atoms,
molecules and so forth. The number of entities composing a mole has been experimentally
determined to be 6.02214179 x 1023.
6.02214179x 1023, a fundamentalconstantnamed Avogadro's number (NA) or the
Avogadro constant in honour of Italian scientist Amedeo Avogadro. This constant is
properly reported with an explicit unit of "per mole," a convenientlyroundedversion
being Consistent with its definitionas an amount unit, I mole of any
element contains the same number of atoms as I mole of any other element. The masses
of I mole of different elements, however, are different, since the masses of the individual
atoms are drastically different. The molar mass of an element (or compound) is the mass
in grams of I mole of that substance, a property expressedin units of grams per mole
(g/mol).
(i) A sample ofcopper sulphate pentahydrate contains 8.64 g of oxygen. How many grams
of Cu is present in the sample? CBS
(a) 0.952g (b) 3.816g (c) 3.782g (d)8.64g
(ii) The mass of oxygen gas which occupies 5.6 litres at STP could be
(a) gram atomic mass of oxygen
(b) one fourth of the gram atomic mass of oxygen
(c) double the gram atomic mass of oxygen
(d) half of the gram atomic mass of oxygen
(iii) Find the number of moles and number of atoms of H and S in 10 mole of I-IS.
OR
Calculate the number of atoms of each element in 245 g ofKC103.
electrons. 4
(232 Orbitals are regions or spaces where there is a maximum probability of finding
Qualitatively, these orbitals can be distinguished by their size, shape, and orientation. An
nucleus.
orbital of small size means there is more chance of finding the electron near the
electron
Shape and orientation mean the direction in which the probability of finding the
Each orbital is
is maximum. Atomic orbitals can be distinguished by quantumnumbers.

to explain spectra of
define energy, shape, and orientation but these are not sufficient
 multi-electrons atoms. Spin quantum number (ms ) determines the spin of electrons. Spin
angular momentum of the electron has two orientations relative to the chosen axis which
are distinguished by spin quantum numbers ms which can take values +1/2 and —1/2.
(i)How many orbitals are associated with n = 3?
(c) 18 (d) 32
(ii)How many maximum electrons are possible in an orbital of3d.
(c) 10
(iii) What is the shape of 's' and 'p' orbitals?
OR
Name two d-orbitals that are on-axis.
SECTION E
The following questions are long answer type and carry 5 marks each. Two questions
have an internal choice.
Q33 (i) Complete the following: 5
(a) Isopropyl bromide alc. KOH A HBr
Heat eroxl e
(b) 1,1,2,2-tetrachloroethane Zn alcohol A Iron tube B
Heat 675K
(ii) An unsaturated hydrocarbon A adds two molecules ofH2 and on reductive
ozonolysis gives butan-1,4-dial, ethanal and propanone, Give the structure of A, write its
IUPAC name and explain the reactions.
Q34 (i)Write bond-line formulas for: tertiary butylalcohol, 2,3-Dimethylbutanol 5
(ii) Give the TUPAC names of the following compounds:

C12CHCH20H
(b) (c)
OR
(i) Write two points of differences between homolytic fission and heterolytic fission
(ii) Arrange the following carbocations in increasing order of their stability:(CH3)3C+,
CH3CH2+ ,(CH3)2CH+
Justify your answer.
Q35 (i) Describe the effect of: 5
(a) Addition of H2 (b) Addition of CH30H
(c) Removal of CO (d) Removal of CH30H
on the equilibrium of the reaction: 2H2(g) + CO(g) +4 CH30H
(ii) 13.8g ofN204 was placed in a IL reaction vessel at 400K and allowed to attain
equilibrium: N204 (g) ++ 2N02 (g) ; The total pressure at equilibrium was found to be
9.15 bar. Calculate Kc, KPand partial pressure at equilibrium.
OR
(i)State Le-Chatelier principle and mention the factors affecting equilibrium.
(ii) A mixture of 1.57 mol ofN2, 1.92 mol ofH2 and 8.13 mol ofNH3is introduced into
a 20 L reaction vessel at 500 K. At this temperature, the equilibrium constant Kc for the
reaction.
(g) + (g) 1.7 x 10-2.
Is this reaction at equilibrium? If not, what is the direction of net reaction?