DPP-2

Periodic Classification
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Calculate screening constant for the valence electron in Boron (B)

A 2.6 B 3.2

C 2.4 D 2.8
Calculate screening constant for the valence electron in Boron (B)

A 2.6 B 3.2

C 2.4 D 2.8
Solution :

B :1s2 2s22p1

σ =(2×0.85) + (2×0.35) = 2.40

Calculate effective nuclear charge for valence electron of Be

A 2.05 B 1.95

C 4 D 2.25
Calculate effective nuclear charge for valence electron of Be

A 2.05 B 1.95

C 4 D 2.25
Solution :

Be(4): 1s2 2s2

σ= (1×0.35)+ (2×0.85) = 2.05

Z* = Z-σ =4 -2.05 = 1.95

Order of screening effect of electrons of s, p, d, f orbitals of a given
shell of an atom on its outer shell electrons is

A s>p>d>f

B f > d > p >s

C p<d<s<f

D f>p>s>d
Order of screening effect of electrons of s, p, d, f orbitals of a given
shell of an atom on its outer shell electrons is

A s>p>d>f

B f > d > p >s

C p<d<s<f

D f>p>s>d
In which of the following pair, both the species are isoelectronic but
first one is large in size than the second?

A S2-, O2-

B Cl-, S2-

C F-, Na+

D N3-, P3-
In which of the following pair, both the species are isoelectronic but
first one is large in size than the second?

A S2-, O2-

B Cl-, S2-

C F-, Na+

D N3-, P3-
Solution :

F-, and Na+ are isoelectronic. For isoelectronic species , more the magnitude of
negative charge , more will be the atomic radii.

Hence F- > Na>+

The correct order of ionic size of N3-, Na+, F-,Mg2+ and O2- is

A Mg2+ >Na+ > F- >O2- >N3-

B N3- < F- <O2- > Na+ > Mg2+

C Mg2+ < Na+ < F- < O2- < N3-

D N3- > O2- > F- > Na+ < Mg2+

The correct order of ionic size of N3-, Na+, F-,Mg2+ and O2- is

A Mg2+ >Na+ > F- >O2- >N3-

B N3- < F- <O2- > Na+ > Mg2+

C Mg2+ < Na+ < F- < O2- < N3-

D N3- > O2- > F- > Na+ < Mg2+

Solution :

N3- O-2 F- Na+ Mg+2

z 7 8 9 11 12

e 10 10 10 10 10

z/e 0.7 0.8 0.9 1.1 1.2

More the z/e, lesser will be the radius

Which of the following atom has largest size

A Cs

B K

C Kr

D Xe
Which of the following atom has largest size

A Cs

B K

C Kr

D Xe
Solution :

Group Group

1 18

P=4 K Kr

P =5 Rb Xe

P= 6 Cs

Cs will have largest radius

Choose the correct order of atomic size for the following elements.

A Al > Cl > S > P

B Cl > S > P > Al

C S > Cl > P > Al

D Al > P > S > Cl

Choose the correct order of atomic size for the following elements.

A Al > Cl > S > P

B Cl > S > P > Al

C S > Cl > P > Al

D Al > P > S > Cl

Solution:

Al>P> S>Cl

Along the period size decreases

Which of the following ions has the smallest radius?

A Li+

B Na+

C Be2+

D K+
Which of the following ions has the smallest radius?

A Li+

B Na+

C Be2+

D K+
Solution :

Li+ Be2+ P =2

Na+ P=3

K+ P =4

Li+ and Be2+ are isoelectronic

Li+ Be2+

z 3 4

e 2 2

z/e 1.5 2

More the z/e lesser the radius Be+2 < Li+ < Na+ < K+
Which one of the following ions has the highest value of ionic radius?

A O2-

B B3+

C Li+

D F-
Which one of the following ions has the highest value of ionic radius?

A O2-

B B3+

C Li+

D F-
Solution :

O2- and F- will be larger than Li+ and B+3

O2- F-

z 8 9

e 10 10

z/e 0.8 0.9

More the z/e, lesser the radius

Among 3rd row elements from group 1 to 17, atomic size is maximum
for

A sodium

B argon

C magnesium

D chlorine
Among 3rd row elements from group 1 to 17, atomic size is maximum
for

A sodium

B argon

C magnesium

D chlorine
Solution:

Noble gas have largest size among the period .

Which of the following order is correct for the size of Fe3+, Fe and
Fe2+?

A Fe < Fe2+ < Fe3+

B Fe2+ < Fe3+ < Fe

C Fe < Fe2+ < Fe2+

D Fe3+ < Fe2+ < Fe

Which of the following order is correct for the size of Fe3+, Fe and
Fe2+?

A Fe < Fe2+ < Fe3+

B Fe2+ < Fe3+ < Fe

C Fe < Fe2+ < Fe2+

D Fe3+ < Fe2+ < Fe

Solution:

With increase in positive charge on the element, radius decrease.

Fe3+ < Fe2+ < Fe

State, which one of the following has the largest atomic radius?

A Cs

B Mg

C Ba

D Cr
State, which one of the following has the largest atomic radius?

A Cs

B Mg

C Ba

D Cr
Solution :

Li Be

Na Mg

K Ca Sc Ti V Cr

Rb Sr

Cs Ba

Cs and Ba, will be larger than others. Out of Cs and Ba, Cs will be larger as
along the period, size decreases
Which one of the following has the smallest atomic radius?

A F

B Cl

C Cs

D Mg
Which one of the following has the smallest atomic radius?

A F

B Cl

C Cs

D Mg
Solution :

Li Be B C N O F

Na Mg Cl

K Ca

Rb Sr

Cs Ba

Along the period size decreases and down the group size increases, F will Be
smallest
Ionic radii is

A inversely proportional to effective nuclear charge

B inversely proportional to square of effective nuclear charge

C directly proportional to effective nuclear charge

D directly proportional to square of effective nuclear charge

Ionic radii is

A inversely proportional to effective nuclear charge

B inversely proportional to square of effective nuclear charge

C directly proportional to effective nuclear charge

D directly proportional to square of effective nuclear charge

Solution :
Select correct statement about radius of an atom

A Values of van der Waals’ radii are larger than those of covalent radii because
the van der Waals’ forces are much weaker than the forces operating between
atoms in a covalently bonded molecule

B The metallic radii are smaller than the van der Waals’ since the bonding
forces in the metallic crystal lattice are much stronger than the van der
Waals’ forces

C Both (a) & (b) are correct

D None of the above is correct

Select correct statement about radius of an atom

A Values of van der Waals’ radii are larger than those of covalent radii because
the van der Waals’ forces are much weaker than the forces operating between
atoms in a covalently bonded molecule

B The metallic radii are smaller than the van der Waals’ since the bonding
forces in the metallic crystal lattice are much stronger than the van der
Waals’ forces

C Both (a) & (b) are correct

D None of the above is correct

Solution:

(a) Vander waals’ Radius is larger than covalent and Metallic as vander waals’
forces are weakest

Radius: Covalent < Metallic < Vander waals’

Force: Covalent > Metallic > Vander waals’

Given that covalent radius of F(EN=4) and Cl(EN=3) are 71 pm and 99
pm, find the bond length of F-Cl molecule.

A 170 pm

B 71 pm

C 165 pm

D 161 pm
Given that covalent radius of F(EN=4) and Cl(EN=3) are 71 pm and 99
pm, find the bond length of F-Cl molecule.

A 170 pm

B 71 pm

C 165 pm

D 161 pm
Solution :

In picometer units,

Bond length = RA + RB - 9 |XA - XB| = 71 + 99 - 9(4-3) = 161 pm

Which of the following ions should have smallest size

A Mg2+

B Na+

C O2-

D F-
Which of the following ions should have smallest size

A Mg2+

B Na+

C O2-

D F-
Solution :

Mg2+
Between isoelectronic species, larger the atomic number ,smaller the ion
Which of the following represents correct order of size

A N < Be < B

B Cl- < S2- < P3-

C Mg < Ba < Sr

D Al+ < Al2+ < Al3+

Which of the following represents correct order of size

A N < Be < B

B Cl- < S2- < P3-

C Mg < Ba < Sr

D Al+ < Al2+ < Al3+

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