12 - TPP - Aliphatic Hydrocarbons

MathsflixByHashimZia PhysicsKaManjan ChemistryBySaadWaqar
CHEMISTRY ALIPHATIC HYDROCARBONS – PRACTICE PROBLEMS

1. In the combustion reaction of alkanes if Ethane 6. Incomplete oxidation of methane in the limited
is used how many moles of oxygen are supply of air forms
required?
a. CO2 and H2O
a. 3 b. CH3OH
b. 4 c. CO + H2 + C
c. 7 d. CO + H2O + C
d. 3.5
Explanation 7. Up to how many carbons alkane are gases?

The combustion reaction of alkanes has a standard
reaction that is a. 3
CnH2n+2 + (3n/2 + 1/2) O2 → nCO2 + (n + 1) H2O. In the b. 4
case of combustion of ethane, n = 2. That means the c. 5
number of moles of oxygen required is 3(2)/2 + 1/2 = 3.5 d. 6
2. Select the incorrect statement regarding the 8. Which of the following will be acidic?
boiling points of alkanes.
a. 1-butyne
a. Boiling point increases with stronger Vander Waal’s b. Propyne
forces c. Hexane
b. Surface area is the only factor which determines the d. All of the above
boiling point of alkane
c. Boiling point of straight chain alkanes is greater
than that of branched chain alkanes 9. Molozonide is unstable and changes into
d. The boiling point of cycloalkanes is always higher ozonide by:
than that of linear alkanes
a. Reduction
b. Oxidation
3. Reactivity due to pi-electrons is present in c. Hydrolysis
d. Rearrangement
a. Alkane
b. Alkene
c. Alkyne 10. β, β-dichlorodiethyl sulpide is also known as:
d. Both a and b
a. Laughing gas
b. Bio gas
4. Order of ease of halogenation in alkane is: c. Mustard Gas
d. Phosgene gas
a. I2>Cl2>Br2>F2
b. F2>Cl2>I2>Br2
c. F2>Cl2>Br2>I2 11. When 2-butyne is treated with
d. Cl2>F2>Br2>I2 dil.H2SO4/HgSO4, the product formed is
a. Butanol
5. Dehydrohalogenation of ethyl halide gives: b. 2-Butanol
c. 2-Butanone
a. Ethane d. Butanal
b. Ethyne
c. Ethene
d. all of the above are possible 12. An organic compound on treatment with Br2 in
CCl4 gives a bromo derivative of an alkene. The
compound will be
a. CH2 – CH = CH2
b. CH2 – CH = CH – CH2
c. HC ≡ CH
d. CH2 = CH2
PREPARED AND COMPILED BY: ENGR. HAFIZ MUHAMMAD SAAD WAQAR

MathsflixByHashimZia PhysicsKaManjan ChemistryBySaadWaqar
CHEMISTRY ALIPHATIC HYDROCARBONS – PRACTICE PROBLEMS
13. In the compound CH2 = CH – CH2 – CH2C = CH2 19. The addition of HCl to 2-pentene gives which of
the C3 – C4 bond is of the type the following?
a. sp – sp² a. 2- chloropentane
b. sp³ – sp³ b. 2- chloropentyne
c. sp – sp³ c. 3- chloropentane
d. sp² – sp³ d. 2- chloro-2-methyl butane
14. The order of the bond length of (i) ethane, (ii) 20. Sodium propionate on decarboxylation with
ethene, (iii) acetylene and (iv) benzene is: soda-lime gives
a. i > ii > iii > iv a. Propane

b. i > ii > iv> iii b. Pentane
c. i > iv > ii > iii c. Butane
d. iii > iv > ii > i d. Ethane
15. Alkaline KMnO4 oxidizes acetylene to which of 21. Chlorination of an alkane involves the attack of
the following?
a. A Base
a. Acetic Acid b. A free radical
b. Glyoxal c. A nucleophile
c. Oxalic Acid d. An Electrophile
d. Ethylene Glycol
22. Complete oxidation of ethane yields:

16. Which alkane cannot be synthesized by Kolbe’s
reaction of sodium salt of carboxylic acid? a. Ethanal
b. Ethanol
a. Butane c. CO2 and H20
b. Hexane d. Ethanoic Acid
c. Methane
d. Ethane
23. Which compounds is liquid at room
temperature?
17. Alcoholic solution of caustic potash is a
specific reagent for which technique? a. C4H10
b. C15H32
a. Dehydration c. C3H8
b. Dehalogenation d. C20H42
c. Hydration
d. Dehydrohalogenation
24. The addition of unsymmetrical reagent to an
unsymmetrical alkene is in accordance with the
18. According to ____, When an alkyl halide is rule of:
treated dry ether, a symmetry alkane with Na in
dry ether, a symmetry alkane is obtained. a. Hund’s Rule
b. Pauli’s Rule
a. Wurtz Reaction c. Markonikov’s Rule
b. Grignard’s Reaction d. Anti-Markonikov’s Rule
c. Kolbe’s Electrolysis Method
d. None of Above
25. Unsaturated nature of alkene can be detected by
a. Decolorisation of bromine water

b. Ozonolysis
c. Decolorisation of KMnO4 solution
d. All of the above
PREPARED AND COMPILED BY: ENGR. HAFIZ MUHAMMAD SAAD WAQAR

12 - TPP - Aliphatic Hydrocarbons

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MathsflixByHashimZia PhysicsKaManjan ChemistryBySaadWaqar

CHEMISTRY ALIPHATIC HYDROCARBONS – PRACTICE PROBLEMS

Explanation 7. Up to how many carbons alkane are gases?

PREPARED AND COMPILED BY: ENGR. HAFIZ MUHAMMAD SAAD WAQAR

a. i > ii > iii > iv a. Propane

22. Complete oxidation of ethane yields:

a. Decolorisation of bromine water

PREPARED AND COMPILED BY: ENGR. HAFIZ MUHAMMAD SAAD WAQAR

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