PART-2(CHEMISTRY)

Section-A
This Section contains 25 multiple choice questions. Each question has four choices (a), (b), (c) and
(d) out of which ONLY ONE is correct.

1. What is the hybridization of sulphur in the its crown ring structure?

(a) sp (b) sp2
(c) sp3 (d) sp3d

2. The Vander Waal gas constant a is given by which of the following relation in term(s) of
critical point(s)?
V RTc
(a) c (b)
3 8 Pc
2
(c) 9 RTcVc (d) 3PV
c c

3. What is correct IUPAC name of following compound?

Br Cl

Br CH3
Br
Cl CH3
Cl
CH3
I
(a) 3,7,8-tribromo-2-chloro-5-(2-chloro-3-iodobutyl)-5-(3-chloropropyl)nonane
(b) 2,3-dibromo-5-(2-bromo-3-chlorobutyl)-7-chloro-5-(3-chloropropyl)-8-iodononane
(c) 3-bromo-5-(2,3-dibromobutyl)-2-chloro-5-(2-chloro-3-iodobutyl)-5-(3-chloropropyl)nonane
(d) 2,3,7-tribromo-8-chloro-5-(2-chloro-3-iodobutyl)-5-(3-chloropropyl)nonane

4. Which is not correct about CH3CH=CH-CHCl-CH=CHCH3?

(a) There are 4 stereoisomers.
(b) Mixture of all stereoisomers can be separated into 3 fractions on fractional distillation.
(c) There are 5 diastereomers pairs.
(d) All stereoisomers are optically inactive.

5. Which of the following has all bond length equal?

(a) PCl5 (b) PF5
(c) B2H6 (d) I2Cl6

6. Which relation is not true about mean free path for a gas?
(a) It is directly proportional to temperature at given density of gas.
(b) It is inversely proportional to pressure at given temperature for fixed amount of gas.
(c) It is directly proportional to volume of fixed amount of gas.
(d) It is constant for an ideal gas if number of gas molecules per liter of volume is fixed.
7. What is correct IUPAC name of following compound?
Br H3C
Br CH3
H3C OH
Cl
HO CH3 Br
I CH3
(a) 4,5,5- tribromo-4-chloro-9-iodo-2,7,8-trimethyldecane-2,9-diol
(b) 3,4,4-tribromo-3-chloro-8-iodo-1,1,6,7-tetramethylnonane-2,9-diol
(c) 6,6,7-tribromo-7-chloro-2-iodo-3,4,9-trimethyldecane-2,9-diol
(d) 5,5,6-tribromo-6-chloro-2-iodo-1,2,3,8-tetramethylnonane-2,9-diol

8. Which of the following compound has D configuration?

OH OH
OHC OHC
(a) (b)
HO HO HO
OH
OH
OHC OH
(c) CH2OH (d) OHC

OH
HO HO HO HO

9. Which of the following molecule is not planar?

(a) I2Cl6 (b) Al2Cl6
(c) XeF4 (d) B3N3H6

dP
10. At temperature 405 K and 70 ml of one mol of NH 3, it has = 0 , then which of the
dV
following options is not correct?
(a) Tc=1320 C (b) Tb=10940 C
(c) Vc=0.07 L/mol (d) Vander Waal constant b=70ml/mol

11. What is correct IUPAC name of following compound?

Br COOH
H3C
Cl
HO COOH
(a) 5-bromo-6-chloro-8-hydroxy-8-methylnon-4,6-dien-2-ynedioic acid
(b) 5-bromo-6-chloro-8-hydroxy-8-methylnona-4,6-dien-2-ynedioic acid
(c) 5-bromo-4-chloro-2-hydroxy-2-methylnona-4,6-dien-2-ynedioic acid
(d) 5-bromo-4-chloro-2-hydroxy-2-methylnon-4,6-diene-2-ynedioic acid
12. Which of the following can not show tautomerism?

O
O

(a) (b)
N
H
O
OH
HN NH
(c) (d) N N
O N O
H HO N OH

13. Which of the following is not linier molecule?

(a) I 3− (b) I (CN )−2
(c) NO2 (d) C2 (CN )2

14. Two containers having same temperature, one of volume 8 liter has hydrogen at pressure 2
atm and other of volume 4 liter has oxygen at pressure 1 atm. What is the ratio of root
mean square velocity of hydrogen to oxygen?
(a) 4 (b) 0.25 (c) 2 (d) 8

15. What is correct IUPAC name of following compound?

H3C

CH3
EtO I
Br
HO CHO
(a) 6-bromo-6-ethoxy-7-hydroxy-2-iodo-2,5-dimethylcycloheptanecarbaldehyde
(b) 3-bromo-3-ethoxy-2-hydroxy-7-iodo-4,7-dimethylcycloheptanecarbaldehyde
(c) 6-bromo-6-ethoxy-7-hydroxy-2-iodo-2,5-dimethylcycloheptanemethanal
(d) 3-bromo-3-ethoxy-2-hydroxy-7-iodo-4,7-dimethylcycloheptylmethanal

16. Which option is not correct about following compounds?

CH3 CH3

and

Br Br Br Br
(a) Both are optically inactive.
(b) Both are diastereomer of each other.
(c) Both can be separated by chromatography.
(d) Both have same boiling point.
17. Which of the following options does not have correct order of dipole moment
(a) CH 3Cl  CH 2Cl2  CHCl3  CCl4
(b) CH 3Cl  CH 3 F  CH 3 Br  CH 3 I
(c) HCl > HF > HBr > HI
CN OH
H3C CH3

(d) > >

OH CH3
CH3

18. Equal mass of SO2 and CH4 are introduced in two different vessel SO2 in 4 liter vessel and
CH4 in 2 liter vessel at same temperature. Both vessels have identical pin holes. What is
ratio rate of diffusion of SO2 to CH4 if rate is calculated in mols/sec?
(a) 1:2 (b) 1:8 (c) 1:16 (d) 1:4

19. What is correct IUPAC name of following compound?

H3C

H3C CH3

COOEt
COOEt COOMe

(a) 2,6-diethyl 6-methyl (2Z)-3-methylhept-2-en-4-yne-2,6,6-tricarboxylate

(b) 2,6-diethyl 2-methyl (5Z)-5-methylhept-5-en-3-yne-2,2,6-tricarboxylate

(c) 2,6-diethyl -2-methyl-(5E)-5-methylhept-5-en-3-yne-2,2,6-tricarboxylate

(d) 2,6-diethyl 6-methyl (2E)-3-methylhept-2-en-4-yne-2,6,6-tricarboxylate

20. Which of the following is not correctly matched with respect to structural isomerism?
OH
H3C CH3 H3C CH3 and H3C
and H2C CH3 O O CH3
(a) (b)
HO Metamers
Position Isomers

H3C O
N and H3C NH CH3
CH3
(c) (d) H3C CH3 and H3C
CH3
Functional Isomers O O
H3C
Metamers
O
 Section-B
This Section contains 5 single digit numerical questions. Each question has answer from 0 to 9.

21. How many of the following species have non integral bond order i.e. they have fractional
bond order?
O22+ , N 22+ , O2+ , NO , CO , CO + , O2− , NO 2+ , CN − , NO 2− , N 2−

22. A piston fitted cylinder with volume 4 L contains mixture of gases along with aqueous
tension, but no liquid water is present. When piston is moved to compress up to volume 2 L
total pressure found is 15 atm and when piston is again moved to compress up to volume
1 L, total pressure found is 29 atm. what will be the total pressure inside the cylinder if
piston is moved to expend up to volume 8 L?
(Assume no volume change due to condensed liquid if any)

23. In the correct IUPAC name of the following compound what is the locant position of Br?
COOH
Br
H3C CH2

HOOC HOOC COOH

24. When following compound is subjected to monochlorination i.e. by reaction one hydrogen is
replaced by a Cl atom. Isomeric mixture of compounds so formed is subjected to fractional
distillation. In how many fractions they can be separated?
CH3
CH3
Cl2/hv
Isomeric Monochlorinated Produtcs
monochlorination
CH3
CH3

25. When a container of volume V, containing ideal gas at pressure 4 atm and temperature 300
K is connected by a tube with another container of volume 2V, containing ideal gas at
pressure 8 atm and temperature 600 K. What will be final pressure of each container if
temperature is kept constant i.e. V container at 300 K and 2V container at 600 K?

V 2V
Tube

P=4 atm P=8 atm

T=300 K T=600 K