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    Iupac SC

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    SAMEER KUMAR

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    © All Rights Reserved
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    Iupac SC

    Uploaded by

    SAMEER KUMAR
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    01. IUPAC SC

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    14 views3 pages

    Iupac SC

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    IUPAC

    CRASH COUrse
    JEEt
    CHEMISTRY
    PSS PROBLEM SOLVING SHEET
    01 IUPAC

    Q.1 Which of the following are homologues.


    (A) CH3CH2–NH2 and CH3CH2NH–CH3 (B) CH3–OH and CH3-CH2-OH
    OH CH2OH

    (C) and (D) CH3COOH and CH3–COOCH3


    Q.2 Number of 1°, 2° and 3° hydrogen in isooctane is:
    (A) 9,8,1 (B) 12,5,1 (C) 15,2,1 (D) None of these
    Q.3 Identify total number of 2° amines in given compound?
    Me
    N O
    N
    NH
    N
    O
    (A) 1 (B) 2 (C) 3 (D) 4
    Q.4 Find out the hybridisation state of carbon atoms in given compound from left to right.
    CH3 – CH = CH – CH = C = CH – C º C – CH3
    (A) sp3 sp2 sp2 sp2 sp sp2 sp sp sp3 (B) sp3 sp2 sp2 sp sp sp sp sp sp3
    (C) sp3 sp2 sp2 sp2 sp2 sp2 sp sp sp3 (D) sp3 sp sp sp2 sp sp2 sp sp sp3
    CH 3 − CH 2 − CH 2 − CH − COOH
    |
    CH 2
    Q.5 |
    C=O
    |
    OH
    Number of carbon in selected principal carbon chain for IUPAC nomenclature will be
    (A) 3 (B) 4 (C) 5 (D) 6
    Q.6 Select the correct statement.
    (A) Homologoues can not be represented by same general formula
    (B) C5H11– has seven alkyl groups
    (C) C4H9 – has four alkyl groups
    CH 3
    |
    (D) CH 3 − C − NH 2 & NH2 are homologues
    |
    CH 3

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    IUPAC
    Q.7 Homologues have
    (A) Same molecular formula (B) Same general formula
    (C) Same structural formula (D) Same physical properties
    Q.8 Total number of 3° hydrogens present in given compound are ?

    (A) 4 (B) 5 (C) 7 (D) 8


    Q.9 In which of the following compound there is absence of secondary carbon.
    (A) 2, 3, 3, 4 - Tetra methyl Pentane (B) 2, 2, 3, 3 - Tetramethyl Pentane
    (C) 3-Ethyl- 2, 4-dimethyl Pentane (D) 3 - Ethyl Pentane
    Q.10 Which of the following is the triad of a homologous series -
    (A) CH3NH2, (CH3)2NH, (CH3)3N
    (B) C2H5OH, (CH3)2CHOH, (CH3)3COH
    (C) Ph–OH, PhCH2OH, PhCH2CH2OH
    (D) CH2 = CH2, CH3 – CH = CH2, C2H5 – CH = CH2
    OH
    HO OH

    OH
    Q.11 Number of 2° alcoholic group present in structure are.....
    HO OH
    OH
    (A) 3 (B) 2 (C) 4 (D) 5
    Q.12 How many different type of functional groups are present in following structure.

    NH2 O
    OCH3
    O
    HO
    NH2
    O O
    (A) 5 (B) 4 (C) 6 (D) 7
    Q.13 Which of the following pair represents homologue.

    O
    O
    (A) OH (B) O
    OH CH2 – CH 2 – OH
    O O

    (C) OH OH (D)
    Q.14 Which compound has same number of 1°, 2°, 3° carbon atoms?

    (A) (B) (C) (D)


    Q.15 Which statement is correct :
    (A) In secondary amine nitrogen is attached to 2° carbon atom.
    (B) MeNH2, Me2NH, Me3N are homologues of each other
    (C) HCOOCH3 and CH3CH2COOH are homologues of each other
    (D) Isooctane has one 4° carbon atom.
    Q.16 What is the general formula of alkyl group ?
    (A) CnH2n+2 (B) CnH2n (C) CnH2n+1– (D) CnH2n–2

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    IUPAC
    Q.17 Which of the following groups is attached to the cyclohexane ring in the following compound.

    (A) Methyl (B) n-Propyl (C) Iso-propyl (D) Neo-pentyl


    Q.18 Which of the following alkyl group are possible from Iso-butane ?
    (A) Iso-Butyl & n-butyl (B) Sec. butyl & Ter. butyl
    (C) n-butyl & Ter. butyl (D) Iso-butyl & Ter. butyl
    Q.19 Which of the following has 3º carbon.
    CH3 CH3
    (A) CH3–CH–CH2–CH3 (B) CH3–C–OH (C) (D) CH3–C–CH3
    NH3 CH3 CH3
    Q.20 The number of primary, secondary and tertiary amines possible with the molecular formula C3 H 9 N is:
    (A) 1,2,2 (B) 1,2,1 (C) 2,1,1 (D) 3,0,1
    Q.21 Number of hydrogen atoms in the given compound is :

    (A) 8 (B) 10 (C) 14 (D) 16


    Q.22 How many alkyl groups are possible for iso-octane.
    Q.23 (a) Total number 1° and 3 ° alcohols possible for C5H11OH.
    (b) Total number of different functional groups in following compounds.
    OH
    N OH
    N
    N N–H
    N

    SH NH2

    Q.24
    (a) Number of carbon atoms in the principal carbon chain
    (b) Number of side chain
    (c) Number of methyl substitutent in the principal carbon chain
    (d) Number of ethyl substitute in principal carbon chain

    Answer Key
    Q.1 (B) Q.2 (C) Q.3 (B) Q.4 (A) Q.5 (B) Q.6 (C) Q.7 (B)
    Q.8 (A) Q.9 (A) Q.10 (D) Q.11 (C) Q.12 (A) Q.13 (C) Q.14 (D)
    Q.15 (D) Q.16 (C) Q.17 (C) Q.18 (D) Q.19 (B) Q.20 (C) Q.21 (C)
    Q.22 0004 Q.23 (a) 5 (b) 6 Q.24 7642

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