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    1.

    Calculate the mass percent of different elements present in Sodium Sulphate


    (Na2SO4).
    2. Calculate the amount of carbon dioxide that could be produced when
    (i) 1 mole of carbon is burnt in air.
    (ii) 1 mole of carbon is burnt in 16 g of dioxygen.
    (iii) 2 moles of carbon are burnt in 16 g of dioxygen.
    3. Calculate the mass of sodium acetate (CH3COONa) required to make 500 mL of
    0.375 molar aqueous solution. Molar mass of sodium acetate is 82.0245g mol-1.
    4. Calculate the concentration of nitric acid in moles per litre in a sample which has a
    density, 1.41 g mL-1 and the mass per cent of nitric acid in it being 69%.
    5. Determine the molecular formula of an oxide of iron in which the mass per cent of
    iron and oxygen are 69.9 and 30.1 respectively.Given that the molar mass of the
    oxide is 159.69 g mol-1
    6. In three moles of ethane (C2H6), calculate the following :
    (i) Number of moles of carbon atoms.
    (ii) Number of moles of hydrogen atoms.
    (iii) Number of molecules of ethane.
    7. What is the concentration of sugar (C12H22O11) in mol L-1 if its 20 g are dissolved
    in enough water to make a final volume up to 2L?
    8. If the density of methanol is 0.793 kg L-1 , what is its volume needed for making 2.5
    L of its 0.25 M solution?
    9. Express the following in the scientific notation:
    (i) 0.0048
    (ii) 234,000
    (iii) 8008
    (iv) 50000.00000
    (v) 6.0012
    10. How many significant figures are present in the following?
    (i) 0.0025
    (ii) 208
    (iii) 5005
    (iv) 126,000
    (v) 500.0
    (vi) 2.0034
    11. Fill in the blanks in the following conversions:
    (i) 1 km = …………………. Mm = …………………. Pm
    (ii) 1 mg = …………………. Kg = …………………. Ng
    (iii) 1 mL = …………………. L = …………………. Dm3
    12. Calculate the molarity of a solution of ethanol in water in which the mole fraction of
    ethanol is 0.040 (assume the density of water to be one).
    13. Use the data given in the following table to calculate the molar mass of naturally
    occuring argon isotopes:

    Isotope Isotopic molar mass Abundance

    36Ar 35.96755 g mol-1 0.337%

    38Ar 37.96272 g mol-1 0.063%

    40Ar 39.9624 g mol-1 99.600%

    14. Chlorine is prepared in the laboratory by treating manganese dioxide (MnO2) with
    aqueous hydrochloric acid according to the reaction

    4HCl (aq) + MnO2(s) → 2H2O(l) + MnCl2(aq) + Cl2(g)

    How many grams of HCl react with 5.0 g of manganese dioxide?

    15. A welding fuel gas contains carbon and hydrogen only. Burning a small sample of it
    in oxygen gives 3.38 g carbon dioxide , 0.690 g of water and no other products. A
    volume of 10.0 L (measured at STP) of this welding gas is found to weigh 11.6 g.
    Calculate (i) empirical formula, (ii) molar mass of the gas, and (iii) molecular
    formula.
    16. Calculate amount of water formed when 16g of methane is burnt.
    17. How many moles of methane are required to produce 22g CO2 after combustion.
    18. 50.0kg of N2 and 10.0Kg of H2 are mixed to produce NH3 calculate 1. Ammonia
    formed 2. Identify the Limiting reagent
    19. A solution is prepared by adding 2g of a substance A to 18g of water . Calculate the
    mass percent of the solute.
    20. A sample of drinking water was found to be severely contaminated with chloroform,
    CHCl3, supposed to be carcinogenic in nature. The level of contamination was 15
    ppm (by mass).
    (i) Express this in per cent by mass.
    (ii) (ii) Determine the molality of chloroform in the water sample.
    21. A vessel contains 1.6 g of dioxygen at STP (273.15 K, 1 atm pressure). The gas is now
    transferred to another vessel at constant temperature, where pressure becomes
    half of the original pressure. Calculate
    (i) volume of the new vessel.
    (ii) number of molecules of dioxygen

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