GC 2014en

221-40609A
GC-2014 Gas Chromatograph

INSTRUCTION MANUAL
Read the instruction manual thoroughly before you use the product.
Keep this instruction manual for future reference.
2004-2006 Shimadzu Corporation. All rights are reserved, including those to reproduce this
publication or parts there of in any form without permission in writing from Shimadzu Corporation.
Information in this publication is subject to change without notice and does not represent a
commitment on the part of the vendor.
Any errors or omissions which may have occurred in this publication despite the utmost care
taken in its production will be corrected as soon as possible, but not necessarily immediately
upon detection.
Note that Shimadzu does not have any obligation concerning the effects resulting from the appli-
cation of the contents of this manual.
I
About this USERs MANUAL
GC-2014 user's manual consists of the two separate manuals as described below.
Operation Manual Part number: 221-40607
It describes procedures necessary to operate the instrument.
Instruction Manual Part number: 221-40609 (this manual)
It describes the instrument's functions and how to use them.
Safety precautions are included in the operation manual. Please read them before using the instrument.
Label conventions for this manual are provided below.
WARNING
Indicates a potentially hazardous situation which, if not avoided,
could result in serious injury or possibly death.
CAUTION
Indicates a potentially hazardous situation which, if not avoided,
may result in minor to moderate injury or equipment damage.
NOTE
Emphasizes additional information that is provided to ensure the
proper use of this product.
WARNING LABELS
WARNING LABELS
This page is intentionally left blank.
i GC-2014
1 Installation
1.1 Verification of Installation Location . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
1.2 Power supply and wiring . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
1.3 Gas Supply Plumbing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
2 Before Use
2.1 Setting Analytical Flow Lines . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
2.2 Outputting Analog Signals to the Chromatopac . . . . . . . . . . . . . . . . . . . . . . . . . . 20
2.3 Outputting Digital Signals to a Personal Computer . . . . . . . . . . . . . . . . . . . . . . . . 23
2.4 Connecting a RS-232C Cable to the Chromatopac C-R8A . . . . . . . . . . . . . . . . . . 25
2.5 Connecting Auto Injector/Auto Sampler AOC-20 Series . . . . . . . . . . . . . . . . . . . . 27
2.6 Connecting the Relay Terminals . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29
3 Installing Packed Columns and Setting Analytical Flow Lines
3.1 Installation Location for Packed Columns . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
3.2 Dual-Column Packed FID Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
3.3 Single-Column Packed FID Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
3.4 Packed TCD Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39
3.5 Packed Analysis Using the Single DET . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42
4 Installing Capillary Columns and Setting Analytical Flow Lines
4.1 Installation Location for Capillary Columns . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47
4.2 Capillary Analysis Using the Dual FID
(When a detector adapter with purge is used) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49
4.3 Capillary Analysis Using the Dual FID
(When a makeup gas flow controller is used) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52
4.4 Capillary TCD Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54
4.5 Single DET . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58
5 Analysis
5.1 Analysis Flow Chart . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61
5.1.1 Preparation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61
5.1.2 Setting Parameters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61
5.1.3 Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 62
Contents
Contents
ii GC-2014
5.2 Notes for Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63
6 Basic Key Operation
6.1 Keypad Description and Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67
6.1.1 Keypad operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 68
6.1.2 Screen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
6.1.3 Status indicators . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70
6.2 Adjusting The Display . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 71
6.3 Basic Key Operations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72
6.3.1 Screen display . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72
6.3.2 Moving the cursor . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73
6.3.3 Entering numeric values . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74
6.3.4 Changing a selection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74
6.3.5 Changing item names . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75
6.4 Getting Help . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77
6.4.1 Screen description . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77
6.4.2 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77
7 Starting and Stopping the GC [SYSTEM]
7.1 [SYSTEM] Key Main Screen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79
7.1.1 Screen Description . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79
7.1.2 Parameter . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80
7.1.3 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81
7.2 Specifying Clean Up Parameters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 82
7.2.1 Screen Description . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 82
7.2.2 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 83
7.2.3 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
7.3 Specifying Start Procedures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86
7.3.2 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87
7.3.3 Example: starting the system with carrier gas flow . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87
7.4 Specifying the Stop Procedures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88
7.4.1 Screen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88
7.4.2 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88
7.4.3 System shut down examples . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89
8 Setting the Analytical Parameters and File Management
8.1 [SET] Key Main Screen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91
8.1.1 Main screen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91
8.1.2 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 92
8.1.3 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94
8.2 File Management . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95
8.2.2 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95
8.2.3 Copying a file . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96
8.2.4 Renaming a file . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96
8.2.5 Initializing a file . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 97
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8.3 Specifying the Analytical Flow Line Components ([Line Config]) . . . . . . . . . . . . 98
8.4 Changing Items Displayed with [Customiz] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101
8.4.1 Screen description . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101
9 Monitoring the GC
9.1 [MONIT] key Main Screen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103
9.1.2 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105
9.1.3 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105
9.2 Monitoring the Temperature with [Temp Mon] . . . . . . . . . . . . . . . . . . . . . . . . . . . 106
9.2.2 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 106
9.3 Monitoring the Flow Rate with [Flow Mon] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107
9.3.2 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107
9.4 Zero Point Adjustment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 108
10 Starting and Stopping Analysis
10.1 Making an Injecting and Starting an Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . 109
10.1.1 Verifying the gas chromatograph status . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 109
10.1.2 Making manual injection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 110
10.1.3 Starting the analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 111
10.2 Terminating the Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 112
10.2.1 Terminating the analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 112
10.2.2 External devices . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 112
11 Creating an Oven Temperature Program
11.1 [COL] Key Main Screen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113
11.1.2 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114
11.1.3 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114
11.2 Temperature Programs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 115
11.2.1 Isothermal analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 115
11.2.2 Programmed analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 115
11.2.3 Creating a temperature program . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 115
12 Injection Port
12.1 Packed Column Injection Port (Dual INJ) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119
12.1.1 Setting the temperature with [INJ] key . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 120
12.1.2 Setting the Flow Rate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 122
12.1.3 Entering Columns Parameters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 124
12.1.4 Creating a Flow Rate Program . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125
12.2 Split/Splitless Injection System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 126
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12.2.1 Setting the temperature with [INJ] key . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 127
12.2.2 Setting the flow rate with [FLOW] key . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 129
12.2.3 Setting column parameters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133
12.2.4 Gas saver . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134
12.2.5 Pressure program . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 135
12.2.6 Creating a Flow rate program . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 137
12.2.7 Split ratio program . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 139
12.2.8 Septum purge . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141
12.2.9 High pressure injection and splitter fix mode . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143
12.3 Direct Injection System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 145
12.3.1 Setting the temperature . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 146
12.3.2 Setting the flow rate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147
12.4 AFC and APC Offset Calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149
12.5 Setting the Flow Rate Parameters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 150
13 Detector
13.1 Hydrogen Flame Ionization Detector (FID) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153
13.1.1 Principle of FID operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153
13.1.2 Setting the detector . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 154
13.1.3 Setting the Detector Gas (manual flow controller) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 157
13.1.4 Setting the detector gas flows(APC) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 159
13.1.5 Igniting and Extinguishing the FID . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161
13.2 Thermal Conductivity Detector (TCD) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164
13.2.1 Principle of TCD operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164
13.2.2 Setting the detector . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165
13.2.3 TCD Zero Point Adjustment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 169
13.3 Filter Signal Time Constant . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 170
13.4 Background Compensation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 171
14 Diagnosis
14.1 Standard Diagnosis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 173
14.1.2 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 173
14.1.3 Diagnosis Parameters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174
14.1.4 Diagnosis parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175
14.1.5 Starting the diagnosis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 177
14.1.6 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 177
14.1.7 Stopping/exiting the diagnosis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 178
14.1.8 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 178
14.1.9 Diagnosis results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 179
14.1.10 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 179
14.2 Log Reading Menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 181
14.2.2 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 181
14.2.3 GC Operation log . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 182
14.2.4 Analysis log . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 183
14.2.5 Parameter log . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 185
14.2.6 Error log . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 186
14.2.7 Diagnostic log . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 187
14.3 Analysis Counter . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 188
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14.3.2 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 189
14.3.3 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 189
14.4 Coolant Consumption Counter . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 190
14.4.2 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191
14.4.3 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191
14.5 Standard Installation Test . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 192
14.5.2 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 192
14.5.3 Test procedure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 193
14.6 Peak Generator . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 194
14.6.2 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 194
14.6.3 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 194
15 Optional Devices
15.1 Auto Injector Parameters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 195
15.1.2 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 196
15.1.3 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 197
15.1.4 AOC priority analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 198
15.1.5 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 198
15.1.6 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199
15.1.7 Other AOC parameters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199
15.1.8 Other AOC Parameter . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 200
15.1.9 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 201
15.1.10 Auto-sampler carousel and other optional parameters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 202
15.1.11 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 202
15.2 Setting AUX Temperature . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 203
15.2.2 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 203
15.2.3 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 203
15.2.4 On/Off setting . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 204
15.2.5 On/Off parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 204
15.3 Setting the AUX APC Parameters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205
15.3.2 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 206
15.3.3 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 206
15.4 Setting the AUX AMC Parameters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 207
15.4.2 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 208
15.4.3 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 208
15.5 Setting the CRG Parameters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 209
15.5.2 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210
15.5.3 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210
16 Special Functions
16.1 Time Scheduler . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 211
16.1.1 description Screen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 211
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16.1.2 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 211
16.1.3 Setting the mode . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 212
16.1.4 Editing a time schedule . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 213
16.1.5 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 213
16.1.6 Creating a new time schedule . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 214
16.1.7 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 214
16.1.8 Parameters available in the time scheduler . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 215
16.1.9 Changing schedule parameters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 215
16.1.10 Time schedule example . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 216
16.1.11 Starting/stopping a time schedule . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 217
16.1.12 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 217
16.1.13 Copying and deleting a time schedule . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 218
16.2 Batch Schedule . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 219
16.2.2 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 220
16.2.3 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 220
16.2.4 Creating a new batch schedule . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 221
16.2.5 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 222
16.2.6 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 223
16.2.7 Editing a batch schedule . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 223
16.2.8 Batch processing Setup example . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 224
16.3 Time Program . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 225
16.3.2 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 225
16.3.3 Creating a new time program . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 226
16.3.4 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 226
16.3.5 Time Program parameters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 227
16.3.6 Editing a time program . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 228
16.3.7 Time program setup example . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 229
16.4 Pre-Run Program . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 231
16.4.2 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 231
16.4.3 Creating a new Pre-Run program . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 232
16.4.4 Editing a Pre-Run program . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 232
16.4.5 After Pre-Run program is finished . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 232
16.4.6 Pre-Run Program set up example . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 233
16.5 Direct Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 234
16.5.2 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 234
16.5.3 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 234
16.6 GC Configuration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 235
16.6.2 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 235
16.6.3 Setting the date and time . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 236
16.6.4 Setting the maximum temperature limits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 237
16.6.5 Setting transmission parameters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 238
16.6.6 Setting the Ready Check Parameters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 239
16.6.7 Parameter Configuration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 241
16.6.8 Customizing Component Names . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 246
16.6.9 Setting the link device code . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 250
16.6.10 Temperature offset . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 251
16.6.11 Other Settings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 252
16.7 Service and Maintenance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 255
16.7.2 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 255
16.7.3 INSTALLATION (POSITION) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 256
16.7.4 INSTALLATION (PIPING) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 258
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16.7.5 INITIALIZATION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 261
16.7.6 Power consumption . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 262
16.8 Stopwatch . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 263
16.8.2 PF menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 263
16.8.3 Timing with inverse measurement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 263
16.9 Key Lock and Parameter Lock . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 264
16.9.2 Key locking . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 265
16.9.3 Parameter locking . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 266
16.10 ROM Version No. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 269
16.10.2 Parameter list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 269
17 Printing
17.1 Printing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 271
17.1.1 Connection to Chromatopac . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 271
17.1.2 Parameters to be printed . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 271
17.2 AOC commands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 275
17.3 Program Parameters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 277
17.4 Event No. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 279
18 Error Messages
18.1 Error Messages . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 283
18.1.1 System errors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 283
18.1.2 Temperature control errors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 286
18.1.3 Pressure/flow rate errors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 289
18.1.4 Communication errors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 293
18.1.5 Detector errors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 294
18.1.6 Program errors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 296
18.1.7 Operations errors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 297
18.1.8 Optional device error (AOC-20i/s) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 300
18.1.9 Warning messages . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 301
19 Index
Contents
viii GC-2014
1
1.1 1. 1.
GC-2014
1 Installation
1.1Verification of Installation Location
Q Installation location requirements
Consider the following points to ensure safe and appropriate unit operation when selecting
the installation site.
1. Ambient temperature and humidity
For optimal performance, operate this unit within the following temperature and humidity
specifications.
Temperature range: 18 C to 28 C
Relative humidity range: 50 % to 60 % (Avoid use under conditions where
condensation forms)
Operating temperature range: 5 C to 40 C
Operating humidity range: 5 % to 90 % (Avoid use under conditions where con-
densation forms)
2. Installation location
Install the unit on a firm, stable and flat base.
(The GC-2014ATF model weighs approximately 50 kg.)
3. Corrosive gas and dust
Avoid exposure to corrosive gas and excessive dust to prolong the service life and maintain
optimal unit performance.
4. Electro-magnetic fields and power supply noise
This unit should not be used near strong electro-magnetic fields. The power supply must
have little or no noise. These items can cause instrument problems.
5. Other precautions
For optimal performance, avoid the following conditions during installation:
(1) Fluctuating ambient temperature.
(2) Temperature changes from heating or air conditioning.
(3) Direct sunlight.
(4) Vibrations.
1 Installation
1.1 Verification of Installation Location
2
GC-2014
Installation clearances
Hot air is vented at the back of the unit when the column oven cools. Consider the following
during installation.
1. Do not place flammable materials behind the unit.
2. Allow a clearance of 400 mm or more between the back cover and the wall.
3. Allow a clearance of 50 mm or more on the left side.
4. Allow a clearance of 100 mm or more on the right side in order to have a space to open/
close the oven door.
5. Reserve extra space for maintenance and inspection behind the unit.
When the optional exhaust air duct (P/N 221-70675-91) is used, rear space of 200 mm or more is
required.
WARNING
Hot air
Hot air is exhausted from the vent. Do not place flammable materials
where they will be exposed to the heat.
Minimum 400 mm
Minimum 100 mm Minimum 50 mm
D
e
p
t
h

6
0
7

m
m
H
e
i
g
h
t

6
9
0

m
m
Width 400 mm
NOTE
1 Installation
1.1 Verification of Installation Location
3
GC-2014
Moving the GC
Move the GC carefully so it does not get bumped or jarred.
1. The GC weighs approximately 50 kg (GC-2014ATF).
2. Two people must carry the GC, one on the left and one on the right, with their hands
between the rubber legs on the left and right side of the unit.
3. Do not hold the oven door when carrying the GC because it may break the door.
4. Do not put your hands on the rubber legs or along the front/rear direction of the unit
because your fingers may get trapped under the unit when placing it on a table.
1 Installation
1.2 1.
4
GC-2014
1.2Power supply and wiring
Before connecting the power supply, verify the following items.
Q Power supply voltage
Use a power source with the following specifications to maintain optimal unit performance.
Commended power voltage: 115 VAC 5 %
230 VAC 5 %
Frequency 50/60 Hz
Operating power voltage: 115 VAC 10 %
230 VAC 10 %
Frequency 50/60 Hz
Q Power supply capacity
Calculate the power supply capacity by considering the total power consumption of the
individual components as shown below.
Connect the power source to a terminal with sufficient capacity.
GC-2014ATF (TCD, FID models):1,950 VA (115 V model)/2,750 VA (230 V model)
Optional temperature control block (INJ, etc.): 150 VA/pc
Maximum power is 2600 VA (115 V model), 3400 VA (230 V model)
Performance of the unit may be affected if the power supply voltage fluctuates or the capacity is
insufficient.
Q Connecting the power cable
The power cable of the 230 V model uses a plug.
Fig. 1.2.1 Plug
WARNING
HIGH VOLTAGE
1.Before connecting the power cable to the distribution board, turn
OFF the power to the distribution board.
2.The power supply must have a circuit breaker.
3.Do not place heavy items on the power cable.
WARNING
Make sure to ground the cable properly. Insufficient grounding may cause an
electric shock in the event of a breakdown.
Be careful to wire the plug correctly, as outlined on the next page to avoid
damage to the unit or supply fuse.
NOTE
NOTE
1 Installation
1.2 Power supply and wiring
5
GC-2014
The power cable for 115 V model is color-coded as follows.
Black ... Connected to HOT of AC line.
White ... Connected to NEUTRAL of AC line.
Green ... Grounding (GROUND)
Fig. 1.2.2Power cable
Q Symbol conventions
~ : AC
: Off, Open
: On, Close
Q Heating energy generation
The following graph shows the heating values generated by the unit.
Fig. 1.2.3
Black
White
Green
Power cable
ON status
Power switch
OFF status
0
0
0.5
1
1.5
2
2.5
3
3.5
100 200 300 400
Temperature ( )
H
e
a
t

g
e
n
e
r
a
t
i
o
n

(
1
0
6

J
/
h
o
u
r
)
1 Installation
1.2 Power supply and wiring
6
GC-2014
Q Fuse
The following fuses are used in the GC-2014.
Q Allowing the GC to dry after transport.
Under some transport conditions, condensation may form inside the GC components. To
avoid injection port or detector heater unit short-circuits, allow the unit sufficient time to dry
after transport, and follow the procedure below after installation.
(1) Seal the injection port and detector without attaching a column. (Refer to the figure
below.)
(2) Remove the injection ports (INJ) and detectors (DET) from all configured analytical flow
lines to prevent the heater from turning ON.
(3) Set the column oven temperature to 300 C and start the GC.
(4) Keep the column temperature at 300 C for 2 hours or more.
Fuse, No.
Rated current/voltage
Type *
Classification depending
on IEC127. 115 V model 230 V model
F1, F2 15 A/250 V 10 A/250 V T
F3, F4 5 A/250 V 3.15 A/250 V T
F5, F6 5 A/250 V 5 A/250 V T
CAUTION
GC-2010 may get wet from humidity in some transport conditions. In
such case drying-out is necessary to avoid a short circuit at the
heater in the injection port or the detector.
Thermal
insulation cup
Graphite ferrule
with a wire
Column nut
(or Column nut
of injection port)
When a capillary column connecting
joint is used
2NWI
When a packed column connecting
joint is used
7
1 Installation
1.3 1.
GC-2014
1.3Gas Supply Plumbing
Q Supply gases
The following gases and associated purity values are required to maintain the optimum
performance of the unit.
For detectors other than FID and TCD, refer to the instruction manual corresponding to each detector.
1. Gas types
Carrier gas types
(Packed FID analysis)
Both helium and nitrogen can be used. Nitrogen is more reasonable in terms of price.
(Packed TCD analysis)
Using helium or hydrogen as carrier gas helps analyzing other materials at high
sensitivity. Because hydrogen is flammable, helium is generally used for safety.
However, to analyze helium or hydrogen, use nitrogen or argon as carrier gas. Nitrogen
is convenient to analyze minor components in the air because the nitrogen peak is not
detected when it is used as carrier gas.
(Capillary analysis)
Helium is the most suitable for separation.
Although nitrogen, which is more reasonable than helium, can also be used, the optimum
separation conditions may not be reached.
Makeup gas types
(Capillary FID)
Both helium and nitrogen can be used. Nitrogen has a slightly higher sensitivity.
(Capillary TCD)
The same gas is used as makeup gas and reference gas for capillary TCD.
Select a type of gas by the same method to select carrier gas.
2. Gas purity
Helium (carrier gas, makeup gas) : 99.995 % or higher
Nitrogen (carrier gas, makeup gas) : 99.995 % or higher
Argon (carrier gas, makeup gas) : 99.995 % or higher
Hydrogen (FID detector gas) : 99.995 % or higher
Air (FID detector gas) : Dry air (oil and other organic components eliminated)
Compressed air(must be suppressed by an oil-free
compressor and dehumidified)
CAUTION
1.Gas supply pressure should not exceed the maximum pressure
listed below.
Excessive pressure may break pressure control valve or other parts.
2.When sharing a gas source with other instruments, check
specifications of all instruments to be used including this unit and
supply gas so that requirements of all the instruments can be
satisfied at the same time.
1 Installation
1.3 Gas Supply Plumbing
8
GC-2014
3. Gas supply pressures
Carrier gas 300 - 980 kPa (Hydrogen: 300 - 500 kPa)
Makeup gas 300 - 980 kPa
Hydrogen 300 - 500 kPa
Air 300 - 500 kPa
The relationship of kPa and bar is as follows
100 kPa = 1 bar
Convert units between kPa and kgf/cm
2
as follows.
1 kPa = 1.0
2
10
-2
kgf/cm
2
1 kgf/cm
2
= 98.1 kPa
Convert the units between kPa and psi as follows.
1 kPa = 1.45 10
-1
psi
1 psi = 6.89 kPa
NOTE
1 Installation
9
GC-2014
Q High pressure gas cylinder precautions
General precautions are provided below.
Consult state and local regulations for specific precautions.
Keep gas cylinders away from the lab, preferably outdoors, but not exposed to direct sun-
light. The area must be well-ventilated. Use tubing to bring the gases to the lab.
The temperature of gas cylinders must not exceed 40 C. Flammable items must be kept at
least 2 m from a gas cylinder.
When using high pressure gases, pay strict attention to ventilation, and perform daily leak
checks. In particular, when using flammable gases (such as hydrogen), never smoke or
allow open flame within 5 m of the equipment. Fire extinguishers must be present.
Secure gas cylinders firmly with cylinder clamps so they cannot fall over. Use oil-free pres-
sure valves only. Never use tubing which has contacted oil. When finished with the gas,
tighten the main valve of the cylinder immediately.
WARNING
HIGH PRESSURE
Gas cylinders are under high pressure. When handling gas cylinders,
instruction and safety measures provided by the gas supplier must be
strictly observed to prevent accidents.
1 Installation
10
GC-2014
Q Precautions on handling hydrogen gas
WARNING
HYDROGEN GAS PRECAUTIONS
Hydrogen can explode if it is allowed to accumulate in a poorly venti-
lated area.
1.Connect gas lines correctly. Hydrogen is released into the room if
the tubing is accidentally connected to the air inlet.
2.When the unit is not in use, close the main valve of the hydrogen
gas cylinder. Check for leaks at the main valve.
3.Every time the unit is used, check for leaks along the flow line from
gas cylinder to the unit interior.
4.To prevent an explosion due to a hydrogen gas leak, the room in
which the unit is used should be well ventilated. Prohibit the use of
open flame in this room.
5.Close the main valve of the hydrogen cylinder immediately after
completing the analyses. Then, turn OFF the unit and perform
normal shut-down procedures.
WARNING
HYDROGEN GAS HANDLING PRECAUTIONS
The accumulation of hydrogen gas inside the column oven can cause
an explosion.
Close all hydrogen regulator valves not in use and stop gas supply.
(When a manual regulator valve is used, turn its control to make the
pressure zero. For APC, turn off the APC for hydrogen gas.) Seal the
column connection.
When a detector that uses hydrogen gas is not in use
Capillary adapter
Graphite ferrule
with a wire
Column nut
Plug
1 Installation
11
GC-2014
CAUTION
Hydrogen gas supply precautions
Make sure that the supply pressure to the flow controller does not
exceed 500 kPa.
If the flow controller fails with a hydrogen gas supply pressure over
500 kPa, a dangerous situation exists. Lange amounts of leaking
hydrogen could cause the FID flame to expand out of the detector.
Hydrogen gas is lighter than air. If it leaks, it can accumulate near the
ceiling. Pay strict attention to ventilation so that leaking hydrogen is
vented out of the room and cannot accumulate.
WARNING
Hydrogen carrier gas precautions
If much hydrogen gas is released into the poorly ventilated room, it
may cause the explosion.
1.In order to prevent hydrogen gas accumulate in the room, attach
tubes to split vent, purge vent, TCD vent and ECD vent. Discharge
the gas to open air or a ventilation equipment (such as the draft
chamber).
2.Install the GC in the well ventilated area. (Ex. in the draft chamber)
3.In order to measure hydrogen gas concentration, equip a hydrogen
gas sensor in the room. Keep the hydrogen concentration low.
1 Installation
12
GC-2014
Q Supply gas tubing
There are two types connections in the Gas Chromatograph: Type M and Type G. Type M
connections are located at the main tubing connections in the instrument interior and exte-
rior. The metal fittings contact directly.
Type G connectors, which are used in high temperature areas, are connected by tightening
three to five aluminum gaskets between the fittings.
Fig. 1.3.1 Joining Type M fittings
Fig. 1.3.2 Joining Type G fittings
Tightening the tubing connections
Tools
2 wrenches 1012 (standard accessory)
Use the 12 mm wrench for Type M connections and the 10 mm wrench for type G
connections.
Fig. 1.3.3 Tightening the joints
MF fitting
MM fitting
GF fitting
Alminum gaskets (3-5 pcs)
GM fitting
1 Installation
13
GC-2014
Q Tubing between the gas cylinder and gas chromatograph
Fig. 1.3.4 Tubing between the gas cylinder and gas chromatograph
Use tubing with a 3 mm O.D. and 2 mm I.D. between the gas cylinder and gas chromatograph.
The use of a gas filter is highly recommended. Contaminated tubing or poor quality gases
can interfere with baseline stability.
<Option> Gas filter (P/N 221-05619-01)
This absorbs organic compounds and moisture in the supply gas, improving its
purity. The filter can be regenerated by baking in the GC oven at 250 C with
30 mL/min carrier gas purging the filter.
Capacity: Approx. 200 mL
Absorbent: Molecular sieve 5 A
Fig. 1.3.5Gas filter
Gas filter <option>
Gas
cylinder
1 Installation
14
GC-2014
Q Gas chromatograph tubing connections
Connections are provided on the rear panel of the unit for connecting external tubing.
They are labeled as follows.
Carrier gas ..................... CARRIER
(L and R mean the left and right side of dual INJ.)
Makeup gas ................... MAKE UP
Hydrogen ....................... HYDROGEN
Air .................................. AIR
Fig. 1.3.6 Plumbing (Example of the GC-2014ATF+SPL model)
Flow controller
for the dual FID
Right Left
AFC for SPL AFC for the dual INJ
Supply the carrier gas for the left inlet of the dual INJ to CARRIER L
and the carrier gas for the right inlet of the dual INJ to CARRIER R.
1 Installation
15
GC-2014
Q Checking for gas leaks
After plumbing the unit, check for gas leaks according to the following guidelines.
(1) Open the main valve of the gas cylinder.
(2) Adjust the gas supply to the specified pressures.
(3) Check for leaks with leak detecting fluid (option) or soapy water on all connections.
Bubbles can be observed if a leak exists.
(4) If a leak is detected:
Further tighten the connection, or retighten it.
Replace the seal material.
(5) Wipe off the leak detecting fluid or soapy water using a wet cloth.
Electronic leak detectors can also be used for hydrogen and helium leaks.
<Option> Snoop Gas leak detecting fluid (P/N 670-11514)
Fig. 1.3.7 Leak detecting fluid
LIQUID LEAK DE
1 Installation
16
GC-2014
17
2.1 2. 2.
GC-2014
2 Before Use
2.1Setting Analytical Flow Lines
GC-2014 does not operate normally without setting analytical flow lines. Always set
analytical flow lines before using the unit. Refer to Chapter 3. Installing Packed Columns
and Setting Analytical Flow Lines and Chapter 4. Installing Capillary Columns and Setting
Analytical Flow Lines for detailed descriptions.
Setting analytical flow lines creates the following benefits during operation.
1. Conditions of analytical parameters for
each line can be set and monitored.
For example, when the [SET] key of
the gas chromatograph is pressed,
temperatures of columns, injection
ports, and detectors as well as carrier
gas flow rate can be set and monitored
on a single screen.
2. A protective mechanism operates to
foster more stable operation conditions.
For example, when a carrier gas
cylinder becomes empty while TCD is
used, the flow controller detects an
error and automatically lowers the
column temperature and stops
conduction to the TCD filament in order
to prevent damage to the column and
TCD filament.
2 Before Use
2.1 Setting Analytical Flow Lines
18
GC-2014
Q Analytical flow lines
An analytical flow line consists of the flow
controller, injection port, column, detector cell,
and detector amp as shown in Fig. 2.1.1.
During analysis, the flow controller feeds
carrier gas to the injection port, a sample
injected to the injection port goes through the
column to reach to the detector cell, and a
detected signal is amplified by the detector
amp to be outputted.
In order to allow the gas chromatograph to
recognize these units as an analytical flow line,
specification for the connection between them
is necessary.
For regular analysis, specify the combination
between an injection port and detector to
which a column is connected. (Refer to the
following page for setting procedures.)
Connections of the flow controller(s) and injection
port(s) and connections of detector cell(s), and
detector amplifier(s) are specified by a serviceperson
at shipment or installation. They do not need to be
specified for regular analysis.
Fig. 2.1.2 shows a representative example of
the line configuration for packed column FID
analysis using the GC-2014.
In this example, the dual INJ and dual FID are
connected with two columns and the difference
between two FID signals is outputted from the
dual FID amp. Two columns are used because
the dual INJ and dual FID are recognized as a
single unit respectively. However, this is
considered to be a single line.
Outputted Signal
Column
Injection
port
flow
comtrol
Detector
amp
Detector
cell
Fig. 2.1.1 Concept of
analytical flow lines
NOTE
Column(L) Column(R)
L
(L) (R)
Dual INJ R
L R
Dual AFC
Dual FID
amp
Dual FID
Outputted Signal
Fig. 2.1.2 An example of
analytical flow lines
2 Before Use
2.1 Setting Analytical Flow Lines
19
GC-2014
How to set lines
(1) Press the [SET] key then press the
[PF2] key (Line Config).
(2) Move the cursor to the unit to be set in a
line and select a line using [ Y ] [ Z ] keys.
Make sure to specify an injection port
and a detector to which a column is
connected in the same line. Any
number from LINE1 through LINE4 can
be selected.
Precautions for setting analytical flow lines
1. Specify units to be used as part of a line.
Only units specified as part of a line are temperature-regulated.
Gas is controlled only for injection ports (flow controllers) specified as part of a line.
Examples
If an injection port that a column is connected is not specified as part of a line, carrier
gas does not flow. If the column's temperature rises in this condition, the column may be
damaged.
To keep feeding gas to units or maintain their temperature even though they will not be
used for analysis for a while, specify the units as part of a line.
2. Remove the units not in use from a line.
Examples
If a detector without a column stays on a line, it may damage TCD filament or cause an
error such as FID ignition error.
If the setting for the flow controller is turned OFF without removing an injector port
without a column from a line, an error is detected and the protection mechanism works
to lower the column temperature.
If a split/splitless injection port (SPL) without a column is not removed from a line, an
error is detected and the protection mechanism works to lower the column temperature.
CAUTION
Set analytical flow lines correctly.
Incorrectly set analytical flow lines hinder the unit's normal operation
and may also damage columns or detectors at worst.
2 Before Use
2.2 2.
20
GC-2014
2.2Outputting Analog Signals to the Chromatopac
GC-2014 can output analog signals for two channels, and detector signals to be outputted to
each channel can be set using keys. When a detector is changed, output can be changed
using keys without changing the connection on the back of the GC.
Connecting the Chromatopac signal cable
Connect the attached Chromatopac signal cable to the connector (ANALOG OUT1 or 2) on
the back of the GC. (Fig. 2.2.1)
Using this cable, analog signals can be outputted and the Chromatopac can be started when
the GC starts. (Refer to 16.6.9 Setting the link device code)
A
N
A
L
O
G
O
U
T

2
A
N
A
L
O
G
O
U
T

1
A
O
C
I
N
J
E
C
I
O
R
1
I
N
J
E
C
I
O
R
2
S
A
M
P
L
E
R
E
V
E
N
T
O
P
T
I
O
N
1
2
3
4
5
6
R
S
-
2
3
2
C
R
S
-
2
3
2
C
O
P
1
L
IN
K
S
T
A
R
T
O
U
T
/R
E
A
D
Y
IN
START I N
READY OUT
AOC POWER SUPPLY
START OUT
Back of the GC
AOC built-in power source
ANALOG OUT 1=Ch1
ANALOG OUT 2=Ch2
Fig. 2.2.1 Connecting the Chromatopac signal cable
2 Before Use
2.2 Outputting Analog Signals to the Chromatopac
21
GC-2014
Setting analog signal output
1. Set a line
(1) Press the [SET] key then press the
(2) Specify an injection port and detector
to which a column is connected in the
same line.
The screen on the right shows an
example where a column is connected
to the dual INJ and dual FID.
Without specifying a detector in a line, the screen to set analog signal output below does not appear.
2. Set analog signal output.
(1) Press the [DET] key.
(2) The outlined part is a parameter for
analog signal output for all detectors.
Set the parameter following the
description below.
For Background signal save/
compensation and Detector signal
subtraction, refer to Chapter 13
Detector [DET].
Signal Output Port
Specify a connector number to output
analog signals.
(ANALOG OUT 1 = Ch1, ANALOG OUT 2 = Ch2)
Channel number of a detector specified at
the last is effective. (If TCD signal was
outputted to Ch1 formerly and FID signal is
newly specified to be outputted to Ch1 as
shown in the screen on the right, TCD
signal becomes OFF automatically.)
NOTE
2 Before Use
2.2 Outputting Analog Signals to the Chromatopac
22
GC-2014
Signal Attenuation or Signal Range
Names of items automatically change according to types of analog signals as listed below.
Set multiplying power (attenuation rate) of output signals for all types. Change the setting
when the peak obtained by the data processing unit is saturated.
Signal attenuation: When analog signal type is wide
Output signal becomes smaller when the setting is changed from x 1 x 2
-1
x 2
-2
x 2
-3
x 2
-4
Signal range: When analog signal type is linear
Output signal becomes smaller when the setting is changed from x1 x10
-1
x10
-2
x 10
-3
x 10
-4

Analog Signal Type
Set a signal type according to the type of Chromatopac to be connected. If this is set
incorrectly, data cannot be processed correctly.
Wide : C-R8A, C-R7A, C-R7Aplus
Linear: Chromatopacs other than C-R8A, C-R7A, C-R7Aplus
Calibration of analog wide range signal
When the GC is connected to the Chromatopac (C-R8A, C-R7A, C-R7Aplus) with a
chromatopac signal cable and the analog signal type described above is set to Wide,
calibration is necessary in order to match the zero level of the GC and Chromatopac.
Perform calibration in the following cases.
When the GC and Chromatopac are connected for the first time (during installation)
When the GC or Chromatopac is changed with other instrument.
When a connection channel number is changed by switching a connector on the GC side
When a two-channel board is installed on the Chromatopac and a connection channel
number is changed by switching a connector on the Chromatopac side
Calibration is not necessary when a detector is changed (e.g. when signal to be outputted to Ch1 is
changed from TCD to FID).
The following is calibration procedures.
(1) Press the [DET] key on the GC to turn OFF the detector control.
(2) Load the BASIC calibration program.
C-R7A, C-R7Aplus: Type LOAD ZCALIB on the [Win3] key screen.
C-R8A: Type LOAD 8.ZCALIB.BAS when key input is possible.
(3) Press the [RUN] key of the Chromatopac.
(4) Enter the Chromatopac channel number when the following sentence is displayed.
C-R7A, C-R7Aplus: Channel No. (1:CH1 2:CH2) : ?
C-R8A: CH No. (1:CH1 2:CH2) : ?
(5) Enter Y when the sentence below is displayed to save calibration results on the
Chromatopac. If they are not saved on the disk, calibration is required again when
starting the Chromatopac after turning its power off.
C-R7A, C-R7Aplus: Save to disk (Y: Yes N: No) : ?
C-R8A: Save to the disk (Y: Save N: No) : ?
(6) Press the [DET] key of the GC to turn ON the detector control.
NOTE
23
2 Before Use
2.3 2.
GC-2014
2.3Outputting Digital Signals to a Personal
Computer
GC-2014 can be directly connected to a personal computer to output digital signals.
GCsolution software allows a PC to control the unit and take data.
For operation of GCsolution, refer to its instruction manual.
Connecting the RS-232C cable
Connect the RS-232C cable attached to GCsolution workstation to the connector on the
back of the GC. (Fig. 2.3.1)
To connect one PC with more than one GCs, separate RS-232C cables are necessary and
an expanded COM port needs to be attached to the PC.
AOC built-in power source has the same connector. Connect the cables correctly. NOTE
A
N
A
L
O
G
O
U
T

2
A
N
A
L
O
G
O
U
T

1
A
O
C
I
N
J
E
C
I
O
R
1
I
N
J
E
C
I
O
R
2
S
A
M
P
L
E
R
E
V
E
N
T
O
P
T
I
O
N
1
2
3
4
5
6
R
S
-
2
3
2
C
R
S
-
2
3
2
C
O
P
1
L
IN
K
S
T
A
R
T
O
U
T
/R
E
A
D
Y
IN
START I N
READY OUT
AOC POWER SUPPLY
START OUT
RS-232C
Back of the GC
Fig. 2.3.1 Connection of RS-232C cable
2 Before Use
2.3 Outputting Digital Signals to a Personal Computer
24
GC-2014
Setting transmission parameters
(1) Select 6. GC CONFIGURATION on
the [FUNC] key screen and then select
3. TRANSMISSION PARAMETER.
(2) Set transmission parameters.
Protocol = LEVEL3
Baud rate (bps) = 115200
(3) Press the [PF2] key (Apply).
Turning ON the power of the GC is not
necessary.
NOTE
25
2 Before Use
2.4 2.
GC-2014
2.4Connecting a RS-232C Cable to the
Chromatopac C-R8A
Connecting the GC-2014 and Chromatopac C-R8A with a RS-232C cable allows for various
functions such as printing out parameters of the GC.
For detailed information about C-R8A, refer to its instruction manual.
Connecting RS-232C cable
Connect an optional RS-232C cable to the connector on the back of the GC. (Fig. 2.4.1)

AOC built-in power source has the same connector. Connect the cables correctly. NOTE
A
N
A
L
O
G
O
U
T

2
A
N
A
L
O
G
O
U
T

1
A
O
C
I
N
J
E
C
I
O
R
1
I
N
J
E
C
I
O
R
2
S
A
M
P
L
E
R
E
V
E
N
T
O
P
T
I
O
N
1
2
3
4
5
6
R
S
-
2
3
2
C
R
S
-
2
3
2
C
O
P
1
L
IN
K
S
T
A
R
T
O
U
T
/R
E
A
D
Y
IN
START I N
READY OUT
AOC POWER SUPPLY
START OUT
Back of the GC
RS-232C
Fig. 2.4.1 Connection of RS-232C cable
2 Before Use
2.4 Connecting a RS-232C Cable to the Chromatopac C-R8A
26
GC-2014
Setting transmission parameters
Set transmission parameters when performing digital-transmission between the GC and
Chromatopac for the first time. (This is not required for each operation.)
1. Set transmission parameters for the GC
(1) Select 6. GC CONFIGURATION on
the [FUNC] key screen and then select
3. TRANSMISSION PARAMETER.
Protocol = LEVEL2
Baud rate (bps) = 9600
Stop bit = 1 bit
Parity = EVEN
(3) Press the [PF2] key (Apply).
Turning ON the power of the GC is not
necessary.
2. Set transmission parameters for the C-R8A
(1) Press the [CONFIG] key and then press the [T] key (T:TRS).
(2) Press the [ ] key until the STD2 Port (RS-232C) Setup screen appears.
MODE = 12917 (Protocol LEVEL2, Stop bit 1 bit, Parity EVEN)
#No. = 8 (logical port number)
BPS = 9600 (baud rate)
(4) After completing setting, press the [EXIT] key and then press the [Y] key to save the
settings.
(5) After changing transmission parameters, reboot the C-R8A to enable the new settings.
Procedures to start digital transmission
After setting transmission parameters, start digital transmission.
1. Start digital transmission.
(1) Type OPEN TRS 8 using the C-R8A keyboard and press the [Enter] key.
(2) The transmission port will open and transmission between the GC and C-R8A will start.
To turn OFF the power of the GC or Chromatopac after opening the transmission port, type CLOSE
TRS 8 using the C-R8A keyboard and press the [Enter] key.
PORT | MODE | #No. | BPS
STD2 | 12917 | 8 | 9600
NOTE
NOTE
27
2 Before Use
2.5 2.
GC-2014
2.5Connecting Auto Injector/Auto Sampler
AOC-20 Series
Connecting the GC-2014 and the auto injector/auto sampler power source unit using an
AOC RS-232C cable allows AOC parameters to be set using the GCs keyboard.
Refer to AOC-20 users manual for details about AOC-20.
Cable connections
Connect the READY/START cable attached to the AOC built-in power source and the AOC
RS-232C cable to the connectors on the back of the GC. (Fig. 2.5.1)
Connect the AOC power cable to the connector on the back of the GC and the auto injector
or auto sampler.
There are two identical RS-232C connectors. Make sure to make the correct connections. NOTE
A
N
A
L
O
G
O
U
T

2
A
N
A
L
O
G
O
U
T

1
A
O
C
I
N
J
E
C
I
O
R
1
I
N
J
E
C
I
O
R
2
S
A
M
P
L
E
R
E
V
E
N
T
O
P
T
I
O
N
1
2
3
4
5
6
R
S
-
2
3
2
C
R
S
-
2
3
2
C
O
P
1
L
IN
K
S
T
A
R
T
O
U
T
/R
E
A
D
Y
IN
START I N
READY OUT
AOC POWER SUPPLY
START OUT
Back of the GC
SMAPLER=auto sampler
INJECTOR1=auto injector
AOC power cable
READY/START cable
Wire the cables according to the
numbers on them. Press the
buttons on the terminal when
inserting or removing cables.
Connect the cable to the "AOC"
connector and "RS-232C"
connector on the AOC built-in
power source.
AOC RS-232C cable
Button Cable inlet
1
2
3
4
5
6
Fig. 2.5.1 Connection of the AOC-20 series
2 Before Use
2.5 Connecting Auto Injector/Auto Sampler AOC-20 Series
28
GC-2014
Setting AOC parameters
1. Set a line.
(1) Press the [SET] key and then press the
(2) Specify AOC1 on the line with the
injection port that the auto injector has
been attached to.
(3) The GC and AOC built-in power source
will be automatically linked.
2. Set AOC parameters.
(1) Press the [OPTION] key. If other option
screens appear, press the [OPTION]
key repeatedly until the AOC
Parameter screen appears.
(2) Set AOC parameters.
Parameters will be transmitted to the
AOC as soon as they are set.
For detailed information about setting AOC
parameters, refer to 15.1 Auto Injector
Parameters or AOC-20 users manual.
If the AOC Parameter screen is not
displayed, check the connection of RS-
232C cable and settings for line
configuration.
NOTE
29
2 Before Use
2.6 2.
GC-2014
2.6Connecting the Relay Terminals
By using the optional relay cable (P/N221-48568-91), relay that operates according to event
commands can be used.
For detailed information about setting events, refer to 16.3 Time Program or 16.5 Direct
Operation.
For example, if the cable is connected to COM and NO found in Fig. 2.6.1, they are
connected by EVENT91 and disconnected by EVENT-91. If it is connected to COM and
NC, they will be connected by EVENT-91 and disconnected by EVENT91.
1 3
1
2
A
N
A
L
O
G
O
U
T

2
A
N
A
L
O
G
O
U
T

1
A
O
C
I
N
J
E
C
I
O
R
1
I
N
J
E
C
I
O
R
2
S
A
M
P
L
E
R
E
V
E
N
T
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P
T
I
O
N
1
2
3
4
5
6
R
S
-
2
3
2
C
R
S
-
2
3
2
C
O
P
1
L
IN
K
S
T
A
R
T
O
U
T
/R
E
A
D
Y
IN
START I N
READY OUT
AOC POWER SUPPLY
START OUT
Back of the GC
COM
NC
NO
COM
NC
NO
EVENT91
EVENT92
(Red)
(White)
(Black)
(Yellow)
(Blue)
(Green)
Fig. 2.6.1 Connecting a relay cable
2 Before Use
2.6 Connecting the Relay Terminals
30
GC-2014
31
3.1 3. 3.
GC-2014
3.1Installation Location for Packed Columns
Injection ports and detectors for packed columns can be installed in positions described in
Table 3.1.1 and Fig. 3.1.1.
Table 3.1.1 Installation location for injection ports/detectors for packed columns
Installation location numbers indicate the positions of column connecting joints.
Name Possible installation location
Injection ports
Dual INJ 1-2, 2-3, 3-4
Single INJ 1, 4
Detectors
Dual FID 6-7
TCD 9-10
Single DET 5, 6, 7, 8
Fig. 3.1.1Fig. 3.1.1 Installation location for injection ports/detectors for packed
columns (layout viewed from the top of the unit)
3.1 Installation Location for Packed Columns
32
GC-2014
Check which units the joints found on the column oven correspond to.
Fig. 3.1.2 shows the layout for the GC-2014ATF+SPL model.
Left and right sides viewed from the front of the unit are indicated as L (left) and R (right)
respectively.
Fig. 3.1.2 Column connecting joints (GC-2014ATF+SPL model)
SPL
Dual INJ
Dual FID
. 4
L R
TCD
. 4
33
3.2 3.
GC-2014
3.2Dual-Column Packed FID Analysis
Connecting the left (L) sides and right (R) sides of the dual INJ and dual FID with columns
respectively allows for analysis with the dual-column configuration.
Dual-column configuration is used in following cases.
1. Same type of columns are connected to the left and right sides in order to background-
compensate the increase of the baseline during programmed temperature analysis.
2. Different types of columns are connected to the left and right sides in order to obtain a
different chromatogram when a sample is injected to the left (L) side and right (R) side
of the dual INJ.
Do not cross the columns (L/R). It hinders correct analysis.
Fig. 3.2.1 Dual-column configuration
NOTE
Column (L) Column (R)
Dual FID
L

(L) (R)

Dual INJ
R
L R
Dual AFC
3.2 Dual-Column Packed FID Analysis
34
GC-2014
Setting analytical flow lines
Setting analytical flow lines is described below.
For procedures to install columns and input analytical conditions, refer to the operation
manual.
1. Set a line.
(1) Press the [SET] key and then press the [PF2] key (Line Config).
(2) Set the dual INJ (DINJ) and dual FID (DFID) on a same line.
LINE1 is specified in the example below. Lines 1 through 4 can be selected.
2. Set the dual AFC.
(1) Press the [FLOW] key.
(2) Set Control mode to Dual.
3.2 Dual-Column Packed FID Analysis
35
GC-2014
3. Set the dual FID.
(3) Set Signal polarity as described below.
: The FID (L) - FID (R) signal is outputted.
(When a sample is injected into the dual INJ (L))
: The FID (R) - FID (L) signal is outputted.
(When a sample is injected into the dual INJ (R))
+
-
3.3 3.
36
GC-2014
3.3Single-Column Packed FID Analysis
Connecting either of the left (L) sides or right (R) sides of the dual INJ and dual FID with a
column allows for analysis with the single-column configuration.
Single-column configuration is used in following cases.
1. Background-compensation is unnecessary because the baseline level does not
increase during isothermal analysis.
2. Background-compensation is unnecessary because the baseline level does not
increase so much even during programmed temperature analysis.
1. When single-column configuration is set, unspecified flow controller does not supply gases. Make
sure to remove unspecified column to prevent deterioration.
2. Make sure to stop the FID detector gas supply (hydrogen and air) on unspecified side. (Turn the
control of the flow controller to set the pressure to zero.)
3. Do not cross the columns (L/R). It hinders correct analysis.

Fig. 3.3.1Single-column configuration (FID)
(A column is connected to the left (L) sides.)
NOTE
Column (L)
Dual FID
L

(L) (R)

Dual INJ R
L R
Dual AFC
3.3 Single-Column Packed FID Analysis
37
GC-2014
manual.
1. Set a line.
(2) Set the dual INJ (DINJ) and dual FID (DFID) on a same line.
(2) Set Control mode as described below.
Set to Single L when the column is connected to the left (L) side of the dual INJ and Single
R when it is connected to the right (R) side.
3.3 Single-Column Packed FID Analysis
38
GC-2014
Set to Single L when the column is connected to the left (L) side of the dual FID and Single
39
3.4 3.
GC-2014
3.4Packed TCD Analysis
Connecting the left (L) sides and right (R) sides of the dual INJ and TCD with columns
respectively allows for analysis with the dual-column configuration.
Dual-column configuration is used in following cases.
1. Almost equal columns are connected on the left and right sides to balance TCD's zero
point for analysis.
2. Different types of columns are connected to the left and right sides in order to obtain a
different chromatogram when a sample is injected to the L and R of the dual INJ.
1. Do not cross the columns (L/R). It hinders correct analysis.
2. If left and right columns are extremely different (e.g. liquid quantity, flow rate), zero point may not be
achieved by turning the control on the right side of the GC unit. In this case, adjust the column flow
rate on the side that a sample is not analyzed (reference side).
Fig. 3.4.1 Dual-column configuration (TCD)
CAUTION
1.Carrier gas has to be fed to both of left and right (L/R) sides of the
TCD. Using the TCD without carrier gas will damage the filament.
2.During analysis with a single column, connect a pipe to the other
flow path instead of a column and feed carrier gas.
Column (L) Column (R)
L

(L) (R)

Dual INJ R
Dual AFC
TCD
L R

NOTE
3.4 Packed TCD Analysis
40
GC-2014
manual.
1. Set a line.
(2) Set the dual INJ (DINJ) and TCD (DTCD) on a same line.
3.4 Packed TCD Analysis
41
GC-2014
3. Set the TCD.
: The TCD (L) - TCD (R) signal is outputted.
(When a sample, which a plus peak is detected, is injected into the dual INJ (L))
: The TCD (R) - TCD (L) signal is outputted.
(When a sample, which a plus peak is detected, is injected into the dual INJ (R))
TCD signals do not necessarily have a plus peak because they are determined by relationship of heat
conduction between a substance to be analyzed and carrier gas. However, the data processing unit
normally calculates the area of a plus peak. When a minus peak is detected, signal polarity needs to
be inverted into a plus peak. In this case, inject a sample into the opposite inlet of the one instructed on
the popup screen shown below.
Signal polarity can be changed using the time program during analysis. (For detailed descriptions
about setting the time program, refer to 16.3 Time Program)
+
-
NOTE
3.5 3.
42
GC-2014
3.5Packed Analysis Using the Single DET
To perform glass packed column analysis using the unit with the single DET (single FID,
ECD, FPD, and FTD for packed analysis), move the dual INJ to the front of the single DET
prior to connecting a column.
1. When a SUS column is used, the dual INJ does not need to be moved.
2. If the single packed INJ is installed in front of the single DET, analysis can be performed without
moving the dual INJ. For detailed descriptions, refer to instruction manual of the single packed INJ.
Fig. 3.5.1 Single DET configuration
CAUTION
Dual INJ is set on the single mode so carrier gas is not fed to the
unspecified port (L on the figure above). Do not connect a column to
the port.
L

(L) (R)

Dual INJ R
Dual AFC
Dual FID/TCD
Column
L R
Single DET
NOTE
3.5 Packed Analysis Using the Single DET
43
GC-2014
Procedures to move the dual INJ
Move the dual INJ following the procedures below. Perform backward processes to return it
to its original position.
(1) Set the dual INJ temperature at room temperature or lower and wait until it becomes
40 C or less.
(2) Turn OFF the power of the GC unit.
(3) Remove the column connected to the dual INJ.
(4) Detach wiring connected to the dual INJ in order to improve workability.
(5) Unfasten the three screws that fasten the dual INJ (Fig. 3.5.2 (a)) and pull the dual INJ
upward.
(Sems screws with a flat washer are used. Be careful not to drop flat washers.)
(6) Take out the heat insulator laid on the bottom of the dual INJ using tweezers or other
similar tools.)
WARNING
Carry out the procedures after the injection port becomes 40 C or
less to prevent burns.
CAUTION
Some insulation materials include ceramic fibers.
Refer to When Handling Insulation of Introduction in the GC-2014
Operation manual before you handle these materials.
CAUTION
When cutting a heat insulator, handle a cutting knife, etc. with care.
Fig.3.5.2 (a)
Screws (sems screws + flat washers)
Single DET
Dual INJ
44
GC-2014
(7) Cut out the heat insulator using a cutting knife, etc. as shown in Fig. 3.5.2 (a).
(The heat insulator is approximately 3 cm thick. Cut the sheet metal on the bottom of the
heat insulator as well.)
(8) Move the cut heat insulator to the left.
(9) Insert the dual INJ on top of the heat insulator that has been taken out in step (6) and
fasten it with three screws. (Refer to Fig. 3.5.2 (c)).
(10) Connect the wiring that has been removed in step (4) to the dual INJ as it was originally.
Fig.3.5.2 (b)
Fig.3.5.2 (c)
50mm
Screws (sems screws + flat washers)
45
GC-2014
manual.
1. Set a line.
(2) Set the dual INJ (DINJ) and single DET (PECD in the screen below) on a same line.
Set to Single L when the column is connected to the left (L) side of the dual INJ and Single
46
GC-2014
47
4.1 4. 4.
GC-2014
4.1Installation Location for Capillary Columns
Injection ports and detectors for capillary columns can be installed in positions described in
Table 4.1.1 and Fig. 4.1.1.
(Injection ports and detectors that can be used for packed columns are included.)
Table 4.1 Installation location for injection ports/detectors for capillary columns
Installation location numbers indicate the positions of column connecting joints.
Name Possible installation location
Injection ports
SPL 1, 4
WBI 1, 4
Dual INJ 1-2, 2-3, 3-4
Single INJ 1, 4
Detectors
Dual FID 6-7
Single DET 5, 6, 7, 8
FTD-2014c 11, 12
TCD 9-10
Fig. 4.1.1 Installation location for injection ports/detectors for capillary columns
(layout viewed from the top of the unit)
4.1 Installation Location for Capillary Columns
48
GC-2014
Check which units the joints found on the column oven correspond to.
Fig. 4.1.2 (a) and (b) show the layout for the GC-2014ATF+SPL model and GC-2014AFsc
model. Left and right sides viewed from the front of the unit are indicated as L (left) and R
(right) respectively.
Fig.4.1.2 (a) Column connecting joints (GC-2014ATF+SPL model)
Fig.4.1.2 (b) Column connecting joints (GC-2014AFSC model)
SPL
Dual INJ
Dual FID
. 4
. 4
Dual TCD
. 4
52.
Single FID
49
4.2 4.
GC-2014
4.2Capillary Analysis Using the Dual FID
(When a detector adapter with purge is used)
To perform capillary analysis using a unit with the dual FID, makeup gas needs to be
supplied to the FID that a column is connected to.
In order to supply makeup gas, attach a detector adapter with purge (P/N 221-34012-91) to
the joint of the dual FID. Connect the purge piping of the adapter to the dual INJ so that
makeup gas is supplied from the dual AFC through the dual INJ.
(The dual AFC is off the line and operates as an independent mass flow controller.)
Although an adapter and column are connected to the right (R) sides of the dual INJ and
dual FID in the figure below, they can be connected to either side (L/R).
Fig. 4.2.1 Dual FID (detector adapter)
Column Detector
adapter
with purge
Dual FID
L
(L) (R)
Dual INJ R
L

R

Dual AFC
SPL
AFC
4.2 Capillary Analysis Using the Dual FID (When a detector adapter with purge is used)
50
GC-2014
For procedures to install an adopter and columns and input analytical conditions, refer to the
operation manual.
1. Change the dual AFC configuration.
(1) Select 6. GC CONFIGURATION on the [FUNC] key screen and then select 9. Other
configuration.
(2) Specify AMC.LR at DAFC unit.
2. Set a line.
(2) Set the SPL and dual FID (DFID) on a same line.
If the dual AFC is specified for AMC.LR, the indication of DINJ disappears. NOTE
4.2 Capillary Analysis Using the Dual FID (When a detector adapter with purge is used)
51
GC-2014
3. Set the makeup gas flow rate.
(1) Press the [OPTION] key.
(2) Set AMC.L when the detector adopter is connected to the left (L) side of the dual INJ
and set AMC.R when it is connected to the right (R) side.
Start control and set the makeup gas flow rate and gas type.
4.3 4.
52
GC-2014
4.3Capillary Analysis Using the Dual FID
(When a makeup gas flow controller is used)
To perform capillary analysis using a unit with the dual FID, makeup gas needs to be
supplied to the FID that a column is connected to.
In order to supply makeup gas, the optional makeup gas flow controller (P/N 221-70877-91:
1 flow path, 221-70877-92: 2 flow paths) are used.
Prior to installing a column, install the detector adapter (P/N 221-33193-91) to the detector's
joint.
Although an adapter and column are connected to the right (R) side of the dual FID in the
figure below, they can be connected to either side (L/R).
Fig. 4.3.1 Dual FID (flow controller)
Column
Dual FID
L
(L) (R)
Dual INJ R
L

R

Dual AFC
SPL
AFC
Detector
adapter
Hydrogen
Makeup gas
Flow controller
4.3 Capillary Analysis Using the Dual FID (When a makeup gas flow controller is used)
53
GC-2014
For procedures to install an adopter and columns and input analytical conditions, refer to the
operation manual.
1. Set a line.
(2) Set the SPL and dual FID (DFID) on a same line.
4.4 4.
54
GC-2014
4.4Capillary TCD Analysis
To perform capillary analysis using a unit with the TCD, makeup gas needs to be supplied to
the TCD joint that a column is connected to and carrier gas (called reference gas) also
needs to be supplied to the TCD joint that a column is not connected.
In order to supply makeup gas, install the detector adapter with purge (P/N 221-34012-91) to
the TCD joint. Connect the purge piping of the adapter to the dual INJ so that makeup gas is
supplied from the dual AFC through the dual INJ.
(The dual AFC is off the line and operates as an independent mass flow controller.)
Reference gas is supplied from the dual AFC when the dual INJ and TCD are connected
with a MF-MF joint.
The figure above shows an example where makeup gas and reference gas are connected to
the left (L) and right (R) sides of the dual INJ respectively and a column and reference gas
piping are connected to the left (L) and right (R) sides of the TCD respectively. They can be
connected to either side (L/R).
Fig. 4.4.1Capillary TCD
CAUTION
1.Carrier gas (makeup gas and reference gas) has to be fed to both
of left and right (L/R) sides of the TCD. Using the TCD without
carrier gas will damage the filament.
2.When makeup gas and reference gas are supplied from the dual
AFC, TCD filament's protection mechanism does not work even if
an error occurs.
MF-MF
piping
L R
Column
Detector
adapter
with purge
TCD
L

(L) (R)

Dual INJ
R
Dual AFC
SPL
AFC
4.4 Capillary TCD Analysis
55
GC-2014
manual.
1. Change the dual AFC configuration.
(1) Select 6. GC CONFIGURATION on the [FUNC] key screen and then select 9. Other
configuration.
(2) Specify AMC.LR at DAFC unit.
2. Set a line.
(2) Set the SPL and dual TCD (DTCD) on a same line.
If the dual AFC is specified for AMC.LR, the indication of DINJ disappears. NOTE
56
GC-2014
3. Set the makeup gas/reference gas flow rates.
(1) Press the [OPTION] key.
(2) The left (L) side of the dual INJ corresponds to AMC.L and the right (R) side
corresponds to AMC.R. Start controlling both AMC.L and AMC.R and set the flow rates
and gas types according to the connection of detector adopter and reference gas
piping.
4. Set the TCD.
: The TCD (L) - TCD (R) signal is outputted.
(When a column is connected to TCD (L) and a sample that a plus peak is
detected is injected)
: The TCD (R) - TCD (L) signal is outputted.
(When a column is connected to TCD (R) and a sample that a plus peak is
detected is injected)
+
-
57
GC-2014
TCD signals do not necessarily have a plus peak because they are determined by relationship of heat
conduction between a substance to be analyzed and carrier gas. However, the data processing unit
normally calculates the area of a plus peak. When a minus peak is detected, signal polarity needs to
be inverted into a plus peak.
Signal polarity can be changed using the time program during analysis. (For detailed descriptions
about setting the time program, refer to 16.3 Time Program.)
NOTE
4.5 4.
58
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4.5Single DET
To perform capillary analysis using a unit with the single DET (single FID, ECD, FPD, and
capillary FTD), makeup gas is used as described below.
Install the detector adapter to the detector joint then install a column. Detector adapter
comes with all single DET units listed above.
A makeup gas flow controller comes with them.
Makeup gas is unnecessary.
Fig. 4.5.1Single DET (In case of FID)
Single FID, ECD, and capillary FTD
FPD
Column
Detector
adapter
Single DET
SPL
AFC
Hydrogen
Makeup gas
Flow controller
4.5 Single DET
59
GC-2014
manual.
1. Set a line.
(2) Set the SPL and single DET (SFID in the screen below) on a same line.
4.5 Single DET
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61
5.1 5. 5.
GC-2014
5 Analysis
5.1Analysis Flow Chart
For detailed descriptions about analysis procedures, refer to the operation manual.
5.1.1 Preparation
Injection port preparation Select an injection port suitable to the sample injection method.
Confirm that the septum and insert are properly attached.
Check dirt on the septum and the number of injections and replace it
when necessary (after approximately 100 injections).
Column preparation Attach the column to the injection port and detector correctly.
When the above preparations are complete, turn ON the GC (power switch on the lower
right side of the GC).
5.1.2 Setting Parameters
Set the column information Set parameters on the [FLOW] key screen. Set the column inner diameter,
and the flow rates column length, and the film thickness on [Column] (PF menu). For
the SPL and WBL, set the purge flow rate on [Purge] as well.
(When the column flow rate is set by the AFC, changing the column
temperature changes the column flow rate.)
Set the temperature of the Set the temperatures on the [INJ] and [DET] key screens. (If the detector
detector and the injection port is set to Off, turn it On.) When the APC is used, set hydrogen, air,
makeup gas, etc. from [DET Gas] (PF menu).
Set the COL temperature and From the screen of the [COL] key, set the column initial temperature
the temperature program and the temperature program. Temperature settings must be within
the allowable column and detector ranges.
Start GC control Press the [SYSTEM] key to display the main screen.
Press [Start GC] (PF menu) to start GC control.
Press the [MONIT] key, and ensure that the temperature of each
zone, the gas flow rate, the gas pressure, etc. are correct.
Set the detector From the screen of the [DET] key, set the range and the time filter
constant.
Ensure that the temperature of the detector is rising, then ignite the
FID or set the TCD current value.
When all parameters reach their respective setup values, the STATUS indicator light
becomes green and the system is ready for analysis.
When the dual packed INJ is used, a monitor injection screen to show the inlet to be used
appears.
The default zero parameter, Zero at Ready zeroes the detector sig-
nal when the GC is ready.
5 Analysis
5.1 Analysis Flow Chart
62
GC-2014
5.1.3 Analysis
Set the data processing Perform the required settings for the data processing unit, such as
unit specifying the processing parameters.
Check the baseline Press the [MONIT] key, and ensure that the baseline is stable.
When the baseline is stable, you can start analysis. Press [Zero
Adg] (PF menu) to zero the detector output if necessary.
Inject the sample Aspirate the sample in the syringe, inject it into the GC injection port,
and press [START] to analyze it.
WARNING
Wear protective goggles when using a
syringe to inject samples.
The syringe plunger could be expelled
due to injection port back pressure.
Sample could get into the eyes.
By holding and supporting the plunger
from the side with your middle finger,
you can smoothly inject the sample and
keep the plunger in the syringe.
Do not bend the plunger when holding
the syringe in this position.
Hold here
(Example)
How to hold a syringe
when injection
63
5 Analysis
5.2 5.
GC-2014
5.2Notes for Analysis
Q Analytical column
Make sure that carrier gas is flowing through the column before increasing the column
oven temperature because the column cannot separate compounds properly when its
liquid phase is oxidized. This is especially important for polar columns. Press the
[SYSTEM] key and set a start time so that carrier gas flows for the set time prior to
temperature control of the heated zones.
Selection of the analysis column is very important in GC analysis. In general, select a
liquid phase whose polarity and chemical characteristics are similar to those of the
analysis target compound to obtain good peak shape. However, highly polar columns
require low temperatures and do not last long.
Therefore, when analyzing an unknown sample, begin by analyzing it on a neutral column
with a higher allowable temperature limit. Switch to a more polar column if necessary.
Q Sample injection modes(Capillary column analysis)
[Split injection]
In capillary columns, the inner diameter is small and the sample load capacity is low. Unlike
packed columns, only a small (1-2 L) amount of sample can be injected at onetime. The
split injection mode only allows part of the injected sample to enter the column. This method
is useful for samples of high consentration or about which nothing is known.
Try to perform a split injection method first. Set the split ratio to approximately 1:50. If the
target peak is too large, increase the split ratio. If the target peak is too small or cannot be
detected, decrease the split ratio. Select a proper split ratio in this way.
If the peak is still small with a split ratio set to 1:10 or less, try the splitless injection method.
[Splitless injection]
In the splitless injection method, almost all of the sample amount injected is introduced in the
column by temporarily suspending the split flow.
This method is effective for analyzing a low concentration sample which cannot be easily
analyzed by the split injection method.
To reduce band broadening and sharpen peaks, create a temperature ramp program. The
column initial temperature is set to a temperature lower than the boiling point of the sample
solvent.
[Direct injection]
In the direct injection method, almost the entire amount of injected sample is introduced into
a wide bore column. Because the inner diameter of the wide bore column is 0.53 mm or
more, separation is not as good as that of a column with smaller inner diameter. Because
the peak shape is broad, sensitivity may not be good enough.
For the direct injection method, the WBI (Wide Bore Injection) injection port is required.
5 Analysis
5.2 Notes for Analysis
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Q Setting the heated zone temperatures
The temperature of the injection port, the column oven and the detector are set individually.
Usually, the injection port and the detector are set to a temperature 20 C higher than the
column.
Never set the column temperature higher than the detector because the detector could
become contaminated.
When creating a temperature program, be careful not to set the final oven temperature
higher than that of the detector.
Q Column temperature program
Use a temperature program mainly to analyze samples with a wide boiling point range.
When developing analytical conditions for an unknown sample or a sample which will gener-
ate an unpredictable elution attend, use an initial program with a temperature increase rate
of approximately 10 C/min. Based on the results, check the temperature range in which the
peaks appear, then examine the analytical conditions. This procedure facilitates time pro-
gram development.
Q Injection counter
The injection port septum and the glass insert are required to be inspected and replaced
periodically. The GC-2014 probides a function which counts the number of injections. When
the number of injections exceeds the limit, you are prompted to perform maintenance. (What
is actually counted is the number of START times.)
Select the analysis counter on the [DIAG] key screen to set and reset the counter limit. Set
the limit to perform maintenance on a regular basis.
The septum/glass insert replacement cycle varies, depending on the analytical conditions
and samples. If the glass insert is easily contaminated (when analyzing non-volatile com-
punds for example), set a low counter limit. On the other hand, when analyzing cleaner sam-
ples, the limit can be increased.
Q Starting up the GC
Turn on the power and/or press the [SYSTEM] key to display the GC starup screen. On this
screen, specify the files used for instrument startup and instrument cleaning (column bake -
out).
Press [Start GC] (PF menu) to start temperature control of each heated zone accoding to the
parameters set in the file.
A start up method should be used to initialize the system once it has been turned on. Set the
start up method to auto to start the file as soon as the power is on; this helps with instru-
ment recovery after a power failure.
The initial step in the startup method should be turning on the carrier gas flow. After a set
time, increase the injection port and detector temperatures. The column oven temperature
can then be set to increase. The oven temperature increases last to protect the column from
damate and the detctor from contamination. The GC-2014 is designed to control the temper-
atures so that the column temperature never exceeds the detector temperature, even if all
temperatures are set to increase at the same time.
A clean up method uses higher oven temperatures than those used for the analysis. After
set bake-out time, return the temperatures to their normal analytical parameter.
5 Analysis
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Q Shutting down the GC
To shut down the system, select [Stop GC] (PF menu) on the [SYSTEM] key screen. Then,
the system stops temperature control after the period of time set as the stop time, flows the
carrier gas for the period of time set as the flow-off time, then stops.
When shutting down the GC, the temperature of each part should be decreased at first, then
the carrier gas should be stopped so that the column can be protected. It is convenient to
use the stop time and the flow-off time.
Do not turn off the power, before select [Stop GC] (PF menu).
When shutting down the GC, the heated zones are cooled, and then the carrier gas flow is
turned off. To accomplish these in the correct sequence automatically, use a stop time (this
stops temperature control at the set time) and flow off time (turns off carrier gas flow at the
set time). Do not turn off the GC without first selecting [Stop GC] (PF menu).
Q Obtaining reproducible analysis results
Follow these suggestions to obtain reproducible results:
Using an AOC-20i auto injector is suggested in order to inject a sample to obtain highly
reproducible results.
Do not increase the temperatures of unused injection ports.
The GC is designed to perform optimally at room temperatures of 18-28 C. Room tem-
peratures above 28 C will negatively inpact reproducibility.
5 Analysis
66
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67
6.1 6. 6.
GC-2014
6.1Keypad Description and Operation
The keypad functions control the unit, and displays the operational status.
START STOP DIAG SYSTEM
STATUS TEMP FLOW
PF1 PF2 PF3
MONIT SET
COL FUNC
FLOW 7 8 9
INJ 4 5 6
DET 1 2 3
OPTION 0
HELP CE ENTER
ON
OFF
START/
STOP key
Starts/stops analysis.
Screen Displays 16 lines of
information at a time on
the large display area.
Displays the list of
frequently accessed
items.
Monitors the GC status
and the chromatogram.
MONIT key
SYSTEM
key
Starts/stops the GC.
DIAG key Executes and allows
diagnosis settings.
PF key Selects PF (programmable
functions) displayed at the
bottom of the screen.
Toggle key Toggles among PF items
displayed.
Toggle key
+
Cursor
keys
Sets On/Off of backlight
and adjustment of
contrast.
Cursor
keys
Moves the cursor up,
down, left and
right respectively.
Numeric
keys
Inputs numeric values.
ENTER
key
Validates input or
selection.
CE key Clears a numeric input
or error.
HELP key Explains currently
displayed items.
UNIT keys Displays the setup
screen for the zone
indicated on the key.
FUNC key Displays items
which are not
frequenty used.
SET key
STATUS/
TEMP/
FLOW lamp
Indicates the status of
the entire GC, the
heater and the flow
controller, respectively.
S T A T U S
lamp
TEMP lamp
Flow lamp
S Y S T E M
key
DIAG key
PF key
Toggle key
Cursor keys
ENTER
CE key
START key
STOP key
Screen
MONIT key
FUNC key
UNIT key
HELP key
+
6.1 Keypad Description and Operation
68
GC-2014
6.1.1 Keypad operation
The keypad is used to operate the system and make parameter settings. The table below
shows the function of each key.
Name Function
START key Starts the temperature program, pressure/flow rate program and time program.
If a Pre-Run program is set, the Pre-Run program starts.
STOP key Stops the program.
DIAG key Performs unit self-diagnosis.
Also, used for maintenance functions such as confirmation of various logs, part
replacement status, and standard signal out put.
SYSTEM key Starts/stops GC.
Manages the analytical condition file.
PF key Selects the PF menu displayed at bottom of the screen.
(PF = programmable function)
Toggle key Toggles through the PF menu displayed at bottom of the screen.
MONIT key Monitors the GC status and analysis status.
Displays the GC temperature, pressure and flow rate status for each heated zone,
as well as chromatograms.
SET key Accesses commonly-used items, such as temperature, pressure and flow rate for
each component on one screen.
Manages the analytical condition file like the [SYSTEM] key.
FUNC key Accesses less frequently used items.
COL key Sets the oven temperature program.
FLOW key Sets the carrier gas flow rate parameters, such as pressure, flow rate and split
ratio.
INJ key Sets the temperature of injection port (or temperature program for an OCI/PTV).
DET key Sets the detector temperature, range and current or other detector-related param-
eters.
OPTION key Sets the parameters for auto injector, AUX temperature controller, AUX APC, AUX
AMC, and CRG.
HELP key Describes the procedure and sugggests valid parameter ranges.
Jumps to a desired item using an index function.
Cursor key
[ ], [ ], [ ] and [ ]
Moves cursor up, down, left and right.
A blinking cursor indicates the location of parameter value entry.
[ ] and [ ] keys may be used to change the selection.
Numeric keys
[0] ~ [9]
Enter numeric values.
Clear key
[CE] key
Clears the current numeric value.
Clears display and alarm during an error.
ENTER key Validates parameter input or item selection.
+
-
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6.1.2 Screen
The areas of the 16-line screen display a variety of items. These items are divided by lines
on the screen.
If all items cannot be displayed on one screen, and are displayed in the message
line. Scroll through the screen by moving the cursors.
Q [Return] (PF menu)
[Return] (PF menu) displayed in the PF menu line returns the display to the previous screen.
[Return] (PF menu) is displayed in PF1.
Q Actual and set values
Actual (current) values are highlighted, while set values are underlined. The actual value
blinks when it is NOT READY (the actual value has not reached the set value). When the
values are equal (READY status), the actual value stops blinking.
When the DINJ is used When the SPL is used
Fig. 6.1.1
When the DINJ is used When the SPL is used
Fig. 6.1.2
Displays the screen
title and the GC
status (READY,
NOT READY or
RUN etc.).
Displays a message
or error about the
operating procedure.
Displays the menu
selected by the [PF]
key.
Actual values Set values
Actual values Set values
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6.1.3 Status indicators
Three status lights indicate the GC status regardless of the screen display. The STATUS,
TEMP and FLOW lights indicate the GC status, the temperature control status and the gas
control status, respectively. Light color and illumination are also used to indicate instrument
parameter status.
Q STATUS indicator
Q TEMP indicator
Q FLOW indicator
Color Status Meaning
Off Power is OFF.
Green
On System is ready.
Blinking Program, like the temperature program, are executing.
Yellow
On System is OFF. Alternatively, the system is ON, but is not ready.
Blinking Diagnosis, baking or flow controller calibration is being executed.
Red On An error has occurred in system.
Off Temperature control is not performed.
Green
On All temperature controlled zones are ready.
Blinking Temperature program is running.
Yellow
On One of the temperature controlled zones is not ready.
Blinking Temperature program is finished, and system is being cooled.
Red On An error related to temperature control has occurred.
Off Gas control is not performed.
Green
On All gas control lines are ready.
Blinking
Pressure/flow rate program is running, it is sampling time, or
high pressure injection is occurring.
Yellow
On One of the gas control lines is not ready.
Blinking
Pressure/flow rate program is finished, and default values are
being set.
Red On An error related to gas control has occurred.
71
6.2 6.
GC-2014
6.2Adjusting The Display
In the following procedure, [Toggle] + [ ] key indicates that [ ] key is pressed while pressing and
holding the [Toggle] key.
Turn the backlit LCD display on and off by pressing [Toggle] + [ ] to turn it off and [Toggle]
+ [ ] to turn it on.
When the keypad is not in use, turning the backlit LCD display off is recommended, to pro-
long the life of the display.
The display turns off automatically with the backlit display saver (See 16.6.11 Other
Settings). When the display turns itself off, turn it back on by pressing any key.
To adjust the contrast the contrast, stand in front of the screen and press the [Toggle] + [ ]
or [ ] keys.
Fig. 6.2.1
NOTE
PF1 PF2 PF3

MONIT SET
COL FUNC
FLOW 7 8 9
INJ 4 5 6
DET 1 2 3
ON
OFF
[Toggle] key
6.3 6.
72
GC-2014
6.3Basic Key Operations
6.3.1 Screen display
Use the following 10 keys to display the parameter and status screens:
[DIAG], [SYSTEM], [MONIT], [SET], [FUNC], [COL], [FLOW], [INJ], [DET] and [OPTION].
Access the main function screens by pressing one of these keys, then the secondary
screens by selecting a PF menu item displayed at the bottom of the screen. (Because the
PF menu includes direct operations, some PF menu items do not have secondary screens.)
Q PF menu item selection
Select a desired PF menu item by pressing the PF keys ([PF1], [PF2] and [PF3]) underneath
the screen, which correspond to PF menu items.
Fig. 6.3.1
If the PF menu continues over two or more pages, press the [Toggle] key to display the
desired PF menu, then press the [PF] key.
Example:
1st page of PF menu
Press the [Toggle] key to display the 2nd page.
PF1 PF2 PF3
MONIT SET
ON
PF menu
PF key
[Toggle] key
File LineConfg Customiz
Indicates page 1.
Indicates page 2.
PF menu
PF key
-
Toggle key
6.3 Basic Key Operations
73
GC-2014
6.3.2 Moving the cursor
Use the four keys, [ ], [ ], [ ] and [ ] to move the cursor to an item to be set.
However, for screens with listed items, only the [ ] and [ ] keys may be available to move
the cursor. The [ ] and [ ] keys may perform a different function.
Q Moving the cursor using the [ ], [ ], [ ] and [ ] keys
Example: Main screen of the [COL] key
Q Moving the cursor using only the [ ] and [ ] keys
Example: Main screen of the [FLOW] key
Fig. 6.3.2
Fig. 6.3.3
Move the cursor using the

[], [], [ ] and [ ] keys.
Move the cursor to each

parameter using the [ ]
and [ ] keys.
Items marked with and
use the [ ] and [ ]
keys to change the selection.
In this case, the selection is
changed from OnOff On.

74
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6.3.3 Entering numeric values
Enter a numeric value using the following procedure:
(1) Move the cursor to an item to be set.
(2) Use the numeric keys to enter a number.
(3) Press the [ENTER] key to validate the input.
The value becomes valid when the [ENTER] key is pressed.
If you move the cursor or display another screen before pressing the [ENTER] key, the value is
deleted.
To clear a value before pressing the [ENTER] key, press the [CE] key.
6.3.4 Changing a selection
Parameters marked with and are changed by making another selection. Change
the selection using the following procedure.
(1) Move the cursor to the item.
(2) Select a desired choice by pressing the [ ] and [ ] key.
(3) Press the [ENTER] key to validate the selection.
The selection change becomes valid when the [ENTER] key is pressed.
If you move the cursor or display another screen before pressing the [ENTER] key, the change is not
made.
To clean the selection before pressing the [ENTER] key, press the [CE] key.
Fig. 6.3.4
NOTE
NOTE
Change the selection by
pressing the [ ] and [ ] key.
In this example, the selection
changes in this order:
On Off On ...
Press the [ENTER] key to
validate the selection.

75
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6.3.5 Changing item names
Customize file names and other names with alphanumeric characters and symbols. Change
the name using the following procedure:
(1) Move the cursor to an item to be changed using the [ ] and [ ] keys.
(2) Move the cursor to a character to be changed using the [ ] and [ ] keys.
(3) Input a character as described in the following section on entering characters. The
character input procedure described below.
(4) Press the [ENTER] key to validate the input.
(5) Repeat steps (2) to (4) to enter a name.
(6) Press the [CE] key to delete one character at the cursors current position.
Fig. 6.3.5

76
GC-2014
Q Entering characters
Initially, the character input screen is in the upper case mode. Press [LowerChr] (PF menu)
to select the lower case mode. Press [NumerChr] (PF menu) to select the numeric mode.
Alphabetic mode (upper case/lower case)
Numeric mode
Press the [0] to [9] keys to input numbers 0 to 9.
Press the [-] and [ ] keys to toggle the symbols.
Key Toggled characters
1
A/a B/b C/c A/a
2
D/d E/e F/f F/f
3
G/g H/h I/i G/g
4
J/j K/k L/l J/j
5
M/m N/n O/o M/m
6
P/p Q/q R/r P/p
7
S/s T/t U/u S/s
8
V/v W/w X/x V/v
9
Y/y Z/z Y/y
0
0 1 2 3 4 5 6 7 8 9 0
(blank) (blank)
(blank)
77
6.4 6.
GC-2014
6.4Getting Help
The Help function describes items on the setup screens.
Understanding the items helps to quickly and efficiently set up analytical parameters and proceed
analyses smoothly.
6.4.1 Screen description
If you do not know the meaning of an item on the screen, press the [HELP] key on the
screen to display the item and its description. For example, the screen shown in Fig. 6.4.1
appears when the [HELP] key is pressed on the [DIAG] key screen.
Items which may be difficult to understand are linked to further descriptions. Set the cursor
on one of these underlined items and press [Display] (PF menu) to access to the linked
descriptions. Fig. 6.4.2 shows the pop-up screen linked to the word log on the screen
shown in Fig. 6.4.1.
6.4.2 PF menu
[Display]
[Back]
Fig. 6.4.1 Help screen Fig. 6.4.2 Linked screen
PF menu Description
Return Returns to the screen displayed before the [HELP] key was pressed.
Display Displays the explanation on an item at the cursor position.
Back Returns to the previous screen.
6.4 Getting Help
78
GC-2014
79
7.1 7. 7.
GC-2014
7.1[SYSTEM] Key Main Screen
7.1.1 Screen Description
The [SYSTEM] key main screen contains parameters related to starting and stopping the
GC. When you press the [SYSTEM] key while the GC is in the system Off status, the screen
shown in Fig. 7.1.1 appears. (However, if automatic start was set, the GC starts as soon as
the power is turned on, and the screen shown in Fig. 7.1.1 does not appear.) To set up
parameters related to the GC start, such as start time and clean up method on or off, press
[Start GC] (PF menu). The GC starts, then enters standby mode according to the main
screen setting.
However, if the GC is in system ON mode, pressing the [SYSTEM] key will access the
screen shown in Fig. 7.1.2. Here, set up parameters relating to turning off the GC (such as
stop time, flow off time, sleep time, etc.). Once the parameters have been specified, press
[Stop GC] (PF menu) to begin the GC stop operations. If no program is running, the stop
time countdown begins immediately. If a program is running, the countdown begins once the
program is finished. When the countdown elapses, the GC stops and shuts down according
to the GC stop parameters.
Fig. 7.1.1 Main screen accessed in system
Off status
Fig. 7.1.2 Main screen accessed in system
On status
7.1 [SYSTEM] Key Main Screen
80
GC-2014
7.1.2 Parameter
CURRENT FILE
Selection: File No. 09, Default: File No. 0
Changes the currently loaded file.
The GC will be controlled based on the parameters in the specified file.
START TIME
Range: 0.06000.0 min, Default: 0.0 min
Sets the period of time after flow control starts until temperature/detector control starts.
START TEMP/DET
Selection: Yes/No, Default: Yes
Select Yes to start temperature/detector control after the start time is finished.
Select No to continuously flow the carrier gas and not to start temperature/detector control.
DETECTOR
Selection: On/Off, Default: On
Prepaies the configured detector for analysis, but does not ignite the FID or FPD.
AUTO IGNIT
Ignites the FID/FPD detector automatically.
Select On for the FID/FPD detector to stand by in the ignited status. Select Off for it to
standby without igniting.
CLEAN UP
Selection: Off/ Analysis Para/Clean Up Para, Default: Off
Clean up indicates running a GC program without injecting sample. Select whether to run
the clean up program after the GC enters Ready status.
If the maximum temperature of the clean up oven temperature program is too close to
maximum temperature of the column, select Analysis Para to perform clean up using a
regular analysis program.
STOP TIME
Sets the period of time after [Stop GC] (PF menu) is pressed (or after a program finishes if
the program was running) to stop temperature control and cool the heated zones.
FLOW OFF TIME
Range: 0.06000.0 min, Default: --- (because the gas control is set to Cont.)
Sets the period of time after temperature/detector control ends until gas control ends.
This item cannot be set if Flow Control is Cont (that is, if carrier gas is kept flowing).
FLOW CONTROL
Selection: End/Cont, Default: Cont
Select [End] to stop gas control after the flow OFF time finishes. This stops the flow of carrier
gas.
Select [Cont] to continue the carrier gas flow.
SLEEP TIME
Range: 0.06000.0 min, Default: --- (because the RESTART GC is set to Off.)
Sets the period of time after temperature/detector control ends until the GC restarts.
This item cannot be set if the GC is set to not restart.
RESTART GC
Selection: On/Off, Default: Off
Select [On] to restart the GC after the sleep time elapses.
Select [Off] to disable automatic GC restart.
7.1 [SYSTEM] Key Main Screen
81
GC-2014
7.1.3 PF menu
PF menu
item
Description
Reference
section
Start GC Starts GC according to the parameters on the [SYSTEM] key main screen.

Stop GC
Starts GC according to the parameters on the [SYSTEM] key main screen.
If no program is running,the stop time countdown begins immediately when
[Stop GC] (PF menu) is selected.
If [Stop GC] is selected while a program is running, the stop time countdown
begins after the program finishes.
File
Displays the file list to change to another method file.
On this sub screen, select files to load, edit, copy, initialize and rename.
8.2
Clean Up
Sets clean up parameters.
In system ON status, select direct operation (PF menu) to run the clean up.
7.2
Start Seq
Sets the parameters for the next GC start up.
Start time, detector and clean up parameters on this sub screen are
immediately reflected on the [SYSTEM] key main screen.
7.3
Stop Seq
Sets the stop procedures.
This item is not displayed in system ON status.
7.4
Maint INJ
Prepares the GC for maintenance of the injection port (replacement of
septum, glass insert, etc.) .
When GC is ready for maintenance, the message GC is ready for maintenance
appears.
4.3 General
maintenance
procedures
in the operation
manual
Anal.
Restores the GC for analysis after performing injection port maintenance.
When pressed after maintenance of injection port is completed.

7.2 7.
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7.2Specifying Clean Up Parameters
7.2.1 Screen Description
Select [Clean Up] (PF menu) from the [SYSTEM] key main screen to display the clean up
parameter setup screen shown in Fig. 7.2.1. The parameters set for the clean up program
are set by including Clean Up Para as part of the GC start procedure.
Clean up should be performed to eliminate contamination before analysis.
Reform the clean up when the gas chromatograph has not been used for a while or if a new
column has been installed.
(a) DINJ (b) SPL
Fig. 7.2.1 Setting the clean up parameters
7.2 Specifying Clean Up Parameters
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7.2.2 Parameter list
Q Main screen of clean up
COLUMN OVEN
TEMP
Range: 0.0400.0 C, Default: 25.0 C
Sets the default value of the column oven temperature for the clean up method.
The clean up oven temperature should be 20 to 30 C higher than the temperature
program used for actual analysis. (Neither temperature should exceed the maximum
temperature indicated on the column).
If the clean up oven temperature exceeds the maximum column temperature, indicate
that the regular analysis parameters should be used for clean up by setting Analysis
Para for the start procedure.
FLOW
Dual packed INJ (DAFC is used)
L column flow rate, R column flow rate
Range: 0.0100.0 ml/min, Default: 50.0 ml/min
Sets the initial pressure for the clean up column flow rate.
SPL(AFC is used)
INLET PRESS
Range: 0.0970.0 kPa (Refer to Fig. 12.2.5.), Default: 100.0 kPa
Sets the default value of the column inlet pressure for the clean up method.
PURGE FLOW RATE
Range: Refer to Fig. 12.2.15, Default: 3.0 ml/min
Sets the septum purge flow rate for the clean up method. The septum purge removes
contamination in the injection port near the septum. If the split ratio is set to -1.0, the
total flow rate remains fixed regardless of to the oven temperature.
SPLIT RATIO
Range: -1.0/0.09999.9, Default: -1.0
Sets the split ratio for the clean up method.
Set the split ratio to -1.0 for the total flow rate to remain fixed regardless of the oven
temperature.
INJECTION PORT
Temperature
Sets the injection port temperature for the clean up method.
DETECTOR
Temperature
Range: 0.0400.0 C (FID), Default: 250.0 C
Sets the detector temperature for the clean up method.
For any detector other than an FID, its set temperature must be within the valid range of
the detector.
Makeup flow rate
The range and default value depends upon the kind of detector. Refer to the values
given for each detector.
This sets the flow rate of an inert gas supplied to the detector side during clean up.
AMC.L, AMC.R
Flow rate
Sets the AMC.L, R flow rate for the clean up method. (Usually equivalent to the flow rate
of the inert gas supplied to the detector.)

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This item is only valid when DAFC is set to AMC.LR.
AUXAPC
Pressure
Range: 0.0970.0 kPa, Default: 100.0 kPa
Sets the AUX APC pressure for the clean up method.
This item is only valid when an AUX APC has been installed.
AUXAMC
Flow rate
Sets the AUXAMC flow rate for the clean up method. This item is only valid when an
AUX AMC has been installed.
When a manual flow controller is used, turn the control of the pressure regulator to set a pressure.
Q Clean up column oven temperature program
(The clean up temperature program consists of a single program ramp.)
CLEAN UP RATE
Range: END/-250.00250.00 C/min, Default: END
Sets the rate of column temperature increase for the clean up program.
CLEAN UP TEMP
Sets the final temperature for the column oven temperature clean up program.
Do not exceed the maximum column temperature.
CLEAN UP TIME
Sets the final temperature hold time for the clean up program.
Q Clean up column Inlet pressure program (when the AFC control mode is pressure)
(The clean up pressure program consits of a single program ramp.)
CLEAN UP RATE
Range: END/-400.00400.00 kPa, Default: END
Sets the rate of column inlet pressure for the clean up program.
CLEAN UP PRESS
Range: 0.0970.0 kPa (Refer to Fig. 12.2.5.) , Default: 0.0 kPa
Sets the final pressure for the column inlet pressure clean up program.
CLEAN UP TIME
Sets the final pressure hold time for the clean up program.
Q Clean up flow rate program (when the DAFC and AFC control mode is flow rate)
(The clean up total flow rate program consists of a single program ramp.)
CLEAN UP RATE
Range: END/-400.00400.00 ml/min
2
, Default: END
Sets the rate of total flow increase for the clean up program.
CLEAN UP FLOW RATE
Range: 0.0100.0 ml/min (DAFC), 0.01,200.0 ml/min (AFC)
(refer to Fig. 12.2.5), Default: 50.0 ml/min
Set the final flow rate for the total flow rate clean up program.
NOTE
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CLEAN UP TIME
Sets the final flow rate hold time for the clean up program.
7.2.3 PF menu
PF menu Description
Reference
section
Temp Prog Sets the column oven temperature for the clean up program. 11.2
Press Prog
Sets the column inlet pressure for the clean up program.
It is displayed when the control mode is pressure on the [FLOW] key
screen of the AFC.
12.5.5
Flow Prog
Sets the flow rate for the clean up program.
Sets the column flow rate program for the DAFC and the total flow rate
program for the AFC.
Display is possible for the DAFC and when the control mode is set at flow
rate on the [FLOW] key screen of the AFC.
12.5.6
Run
Displayed only while GC is in system ON status. Immediately runs the clean
up program.

Stop
Stops clean up.
This item is displayed only when the clean up program is in progress.

Next Line Displays the clean up program set up screen for another analytical flow line.

7.3 7.
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7.3Specifying Start Procedures
Select [Start Seq] (PF menu) from the [SYSTEM] key main screen to display the start
procedure setup screen shown in Fig. 7.3.1.
On this screen, set whether the system automatically starts (Auto Start) when the power is
next turned on, or whether the system does not start until [Start GC] (PF menu) is pressed
(Manual Start). Alternatively, only carrier gas flow is turned on the next time the power is
turned on. To start the system, select [Start GC] (PF menu) as for a manual start. This is
known as a semi-auto start. Finally, an analysis file can be set to begin the next time the
power is turned on or the GC is restarted. Any settings changed on this screen are reflected
in the [SYSTEM] key main screen.
Fig. 7.3.1 Setting the start procedures for the next GC restart
7.3 Specifying Start Procedures
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FILE LOAD
Selection: File No. 09, Default: Current file
Selects a file to be loaded the next time the power is turned on or the GC restarted.
START GC
Selection: Auto Start/ Manual Start/Semi-Auto, Default: Manual Start
Sets the start method for the next time the power is turned on:
Select Auto Start to automatically start the GC.
Select Manual Start to start the GC by presssing [Start GC] (PF menu) from the [SYSTEM]
key main screen.
Select Semi-Auto to start carrier gas flow only. The GC must still be started by pressing
[Start GC] (PF menu) from the the [SYSTEM] key main screen.
START TIME
Sets the period of time after gas control starts until temperature/detector control starts.
The Start Time value on the [SYSTEM] key main screen is set here.
The start time set here can be overridden by entering another start time in the [Start GC] (PF menu)
screen.
This function is useful if the preset start time is too long.
START TEMP/DET
Select Yes to start temperature/detector control after the start time is elapses.
Select No to continue carrier gas flow only without starting temperature/detector control.
DETECTOR
Prepares the configured detector for analysis, but does not ignite the FID or FPD.
The DETECTOR setting on the [SYSTEM] key main screen is set here.
AUTO IGNITE
Establishes FID/FPD ignition conditions.
Select On for the FID/FPD detector to stand by in the ignited status. Select Off for it stand
by without igniting.
The AUTO IGNIT setting on the [SYSTEM] key main screen is set here.
CLEAN UP
Selection: Off/Analysis Para/Clean Up Para, Default: Off
When performing clean up, select whether to use an analysis method or the program set in
[Clean Up] (PF menu).
The CLEAN UP setting on the [SYSTEM] key main screen is set here.
7.3.3 Example: starting the system with carrier gas flow
In this example, carrier gas flows for a certain period of time before temperature control
begins. The length of time the carrier gas should flow depends on how long the carrier gas
flow was shut off.
If the same column is used in the same analytical flow line as the day before:
set a START TIME of approx. 10 minutes.
If a different column is installed on the same flow line that has been in use:
set a START TIME of approx.10 minutes.
If the system has been out of use for a time with no column connected:
set a START TIME of 1 to several hours.
NOTE
7.4 7.
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7.4Specifying the Stop Procedures
7.4.1 Screen
Select [Stop Seq] (PF menu) from the [SYSTEM] key main screen to display the stop
procedure setup screen shown in Fig. 7.4.1. Stop Seq is displayed only when the system is
in OFF status.
The stop procedure setup screen consists of parameters equivalent to those on the
[SYSTEM] key main screen when the GC is in system ON status, except that the current file
cannot be changed.
Parameter changes on the stop procedure setup screen are reflected on the [SYSTEM] key
main screen.
STOP TIME
Sets the period of time after [Stop GC] (PF menu) is pressed (or after a program finishes if
the program was running) to stop temperature/detector control.
The STOP TIME value on the [SYSTEM] key main screen is set here.
FLOW OFF TIME
Range: 0.06000.0 min, Default: --- (because the gas control is set to Cont.)
Sets the period of time between the end of temperature/detector control and the end of gas
control.
This item cannot be set if Flow Control is Cont (that is, if carrier gas is kept flowing).
The [FLOW OFF TIME] setting on the [SYSTEM] key main screen is set here.
Fig. 7.4.1 Setting the stop procedures
7.4 Specifying the Stop Procedures
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FLOW CONTROL
Selection: End/Cont, Default: Cont
Select End to end gas control after the flow off time elapses.
Select Cont to continue the carrier gas flow.
The GAS CONTROL setting on the [SYSTEM] key main screen is set here.
SLEEP TIME
Range: 0.16000.0 min, Default: --- (because the RESTART GC could be set to Off.)
Sets the period of time after temperature/detector control ends until the GC restarts.
This item cannot be set if the GC is not set to restart automatically.
The SLEEP TIME setting on the [SYSTEM] key main screen is set here.
RESTART GC
Select On to restart the GC once the sleep time has elapsed.
Select Off to not restart the GC automatically.
The Restart GC setting on the [SYSTEM] key main screen is set here.
7.4.3 System shut down examples
The following examples show various situations where STOP TIME and FLOW OFF TIME
can be used effectively.
After the end of an analysis, each heated zone is cooled. Once the column over is
cool, carrier gas flow is shut off.
STOP TIME = 0 minutes
FLOW CONTROL = End
FLOW OFF TIME = Approx. 20 minutes
A column is conditioned, then the column over is cooled. Carrier gas flow is then
shut down.
STOP TIME = Column conditioning time
FLOW CONTROL = End
At the end of an analysis, each heated zone is cooled, but carrier gas is kept flowing
for rapid equilibration for the next days analysis. The next day, the system is automati-
cally restarted (15 hours = 900 minutes later), and temperature control resumes.
START TIME = 0 minutes (because the carrier gas continued to flow)
STOP TIME = 0 minutes
FLOW CONTROL = Cont (to keep carrier gas flow on)
RESTART GC = On
SLEEP TIME = 900 minutes (at the end of the SLEEP TIME, the GC
restarts)
At the end of an analysis, each heated zone is cooled, and the carrier gas flow is
stopped once the column oven is cool. The following day (15 hours = 900 minutes
later), carrierr gas flow is turned back on and temperature control begins.
START TIME = 10 minutes (because carrier gas flow was off)
STOP TIME = 0 minute
FLOW CONTROL = End
RESTART GC = On
SLEEP TIME = 900 minutes (at the end of the SLEEP TIME, the GC
restarts)
7.4 Specifying the Stop Procedures
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91
8.1 8. 8.
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8.1[SET] Key Main Screen
8.1.1 Main screen
Press the [SET] key to display the main screen shown in Fig. 8.1.1 and to make frequently
used parameter settings.
To make changes to the [COL], [FLOW], [INJ], and [DET] parameters, the [customiz] (PF
menu) key is pressed. Changes to these parameters are reflected in the [SET] key main
screen.
The screen shows parameters of a line that consists of an injection port, detectors, and
options connected to a column (two columns for the dual packed column INJ). The combina-
tion can be changed on the [Line Config] (PF menu) sub screen.
When the system is turned on, the temperatures are controlled for the components in the
flow line. If the AFC is present, carrier gas is supplied to the injection port specified. If APC is
present, detector gases are supplied to the detector specified.Temperatures are not con-
trolled, and gases are not supplied, to components which are not part of the analytical flow
line. Although two or more detectors can be set for a line, only one injection port can be set.
(a) When the DINJ is used (b) When the SPL is used
Fig. 8.1.1 [SET] key main screen
8.1 [SET] Key Main Screen
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COLUMN OVEN
Sets the default temperature in the oven temperature program.
Flow
When the packed INJ (DAFC) is used
L. inlet pressure, R. inlet pressure
Column inlet pressures are indicated. (L: left side, R: right side)
L. column flow rate, R. column flow rate
Range: 0.0100.0 ml/min, Default: 50 ml/min
Enter the column flow rate. Set the initial flow rate to set a flow rate program. When the
control mode is set to Single L or Single R, only the specified side is displayed.
When the SPL, etc. (AFC) is used
INLET PRESS
Sets the column inlet pressure.
The initial pressure must be set in order to create a pressure program.
When the control mode is set to pressure, the system keeps the column inlet pressure at a
constant value while the oven temperature program is running.
COLUMN FLOW RATE
Default:
1
1.00 ml/min
Sets the carrier gas flow rate at the capillary column exit (atmospheric pressure at 25 C).
When you set the carrier gas flow rate, the system calculates the column inlet pressure
based on the inner diameter and the length of the column. The column flow rate is set
separately so that the carrier gas flow rate desired occures at the initial temperature in the
oven temperature program.
LINEAR VELOCITY
Default:
2
30.0 cm/s
Sets the average linear velocity of the carrier gas flowing in the capillary column.
When you set the linear velocity, the system calculates the column inlet pressure based on
the inner diameter and the length of the column. The linear velocity is set separately so that
the linear velocity desired occures at the initial temperature in the oven temperature
program.
When the control mode is set to linear velocity, the column inlet pressure automatically
changes so that the linear velocity remains constant even while the oven temperature
program is running.
TOTAL FLOW RATE
Range: 0.01200.0 ml/min (Refer to Fig. 12.2.5.), Default: 500.0 ml/min
The total flow rate varies depending on the injection mode as follows:
In split or splitless mode, the total flow rate is equivalent to column flow rate + split flow rate
+ septum purge flow rate.
In direct mode, the total flow rate is equivalent to column flow rate + septum purge flow rate.
SPLIT RATIO
Range: -1.0/0.09999.9, Default: -1.0
The split ratio is split flow rate / column flow rate.
When you set a split ratio, the system sets the total flow rate based on the calculated carrier
gas flow rate and split flow rate, so that the desired split ratio occurs at the oven
temperature.
Set the split ratio to -1.0 to fix the total flow rate regardless of the oven temperature.
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PURGE FLOW RATE
Set the septum purge flow rate.
SAMPLING TIME
Sets the sampling time for splitless analysis.
The sampling time indicates the period of time after analysis starts until the split flow line is
opened.
SPLIT MODE
Selection: SPLIT/SPLITLESS/DIRECT, Default: SPLIT
SPLIT: Controls the column inlet pressure and the total flow rate so that the column
inlet pressure and split ratio occur as specified.
SPLITLESS: Closes the split flow line during the sampling time so that the set column inlet
pressure is controlled by the Total Flow Controller.
Opens the split flow line and controls the Electronid Split Controller so that the
preset column inlet pressure occurs (Refer to Fig. 12.2.2.) after the sampling
time elapses.
DIRECT: Closes the split flow line and the set column inlet pressure (in pressure mode)
or the set total flow rate (in flow mode) occurs. When making direct injection
analyses, select WBI in the setup screen so that SPLIT mode is not available.
CONTROL MODE
Selection: PRESS/VELOCITY/FLOW (for direct injection mode), Default: PRESS
When the injection mode is set to SPLIT or SPLITLESS
PRESS: Controls the system so that the column inlet pressure remains constant.
VELOCITY: Controls the system so that the linear velocity remains constant.
When the injection mode is set to DIRECT
PRESS: Controls the system so that the column inlet pressure remains constant.
VELOCITY: Controls the system so that the linear velocity remains constant.
FLOW: Controls the system so that the flow rate remains constant.
INJECTION PORT TEMP
Set the injection port temperature (the default temperature for a programmable injection
port).
DETECTOR TEMP
Range: 0.0400.0 C (in FID), Default: 25.0 C
Set the detector temperature.
Allowable temperature ranges vary for each detector. Refer to range specified for the detec-
tor(s) in use.
1 The column flow rate ranges from 0 to the value at which the calculated column inlet pressure is
970 kPa or less and the calculated total flow rate is 1,200 ml/min.
2 The linear velocity ranges from 0 to the value at which the calculated column inlet pressure is 970 kPa
or less.
3 The purge flow rate ranges from 0 to the total flow rate subtracted by the column flow rate and the split
flow rate.
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8.1.3 PF menu
PF menu Description
Reference
section
File
Displays file list to change the current file.
On this sub screen, you can select files to load, copy, initialize and rename.
8.2
Line Confg
Specifies the injection port, detectors and options which make up the ana-
lytical flow line.
Units set on this sub screen are displayed on the [SET] key main screen.
8.3
Customiz Set the parameters displayed on the [SET] key main screen. 8.4
Print Prints temperature, pressure and total flow rate on a Chromatopac.

Next Line
Switches through each of the parameter screens in turn. Press the [SET]
key from the [SET] key main screen to switch to the next screen.

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8.2 8.
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8.2File Management
Select [File] (PF menu) from the [SYSTEM] key main screen to display the file list shown in
Fig. 8.2.1.
To change the current file, enter a file No. or move the cursor using the [ ] and [ ] key;
then press the [Load] (PF menu) key.
8.2.2 PF menu
Fig. 8.2.1 File list screen
PF menu Description
Reference
section
Load Selects the current file.

Copy Copies file name and file contents from the source file to a destination file. 8.2.3
File Init
Initializes file name and file contents.
The current file cannot be initialized.
8.2.5
Rename Changes the file name. 8.2.4
8.2 File Management
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8.2.3 Copying a file
Select [Copy] (PF menu) on the file list screen to display the file copy screen shown in Fig. 8.2.2.
Enter the source file number (Src. File) and the destination File number (Dst. File), then press
[Copy] (PF menu). The name and contents of the source file are copied to the destination file.
8.2.4 Renaming a file
Select [Rename] (PF menu) on the file list screen to display the file rename screen shown in
Fig. 8.2.3. Move the cursor using the [ ] and [ ] keys to select the file to be renamed.
Enter the new file name using the numeric keys and the [ ] and [ ] keys. Refer to 6.3.5
Changing item names for more information..
Fig. 8.2.2 Copying File
Fig. 8.2.3 Renaming a file

8.2 File Management
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8.2.5 Initializing a file
Select [File Init] (PF menu) on the file list screen to display the file initialization screen shown
in Fig. 8.2.4. Enter the file number or move the cursor to select the file. Then press [File Init]
(PF menu).
During File initialization, the file name and contents are deleted. The parameters return to
their default settings. Once a file is initializen, the action cannot be undone. The current file
cannot be initialized.
Fig. 8.2.4 Initializing a file
8.3 8.
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8.3Specifying the Analytical Flow Line
Components ([Line Config])
Select [Line Confg] (PF menu) from the [SET] key main screen to display the Line Configu-
ration screen shown in Fig. 8.3.1.
The [SET] key main screen displays the parameters for one analytical flow line. The line
configuration screen determines the components (injection port, detector (s), and options) of
the analytical flow line.
When the system is turned on, the temperatures are controlled for the components in the
flow line. If the AFC is present, carrier gas is supplied to the specified injection port, If APC is
present, detector gases are supplied to the detector (s) specified, One injection port and up
to two detecotrs can be included in an analytical flow line, Temperatures are not controlled,
and gases are not supplied, to conponents which are not part of the analytical flow line.
The line configuration screen displays all the components installed. Move the cursor to the
desired component using the [ ] and [ ] keys. Use the [ ] and [ ] to specify the ana-
lytical flow line (1-4) to which the component belongs. Press [Enter] to validate the selection.
When two injection ports or two option units are selected for a same line, the previous unit
setting is cancelled.
DINJ is not displayed on the line configuration setup screen when AMC.LR is set for DAFC unit on
OTHER CONFIGURATIONS (16.6.11).
AUX temperature control, AUX APC, AUX AMC, manual flow controllers and dual AFC set to
AMC.LR can be set and controlled regardless to flow line configuration settings.
Fig. 8.3.1 Line configuration setup screen
NOTE
8.3 Specifying the Analytical Flow Line Components ([Line Config])
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Q Line configuration examples
SPL (split/splitless injection port) and DINJ (dual packed INJ) are installed as the injection
port. DFID (dual hydrogen flame ionization detector) and DTCD (thermal conductivity
detector) are installed as the detector.
(1) To use only a SPL and FID
Select the SPL and DFID for Line 1. In this case, only the temperature of the SPL and
DFID will be controlled. Carrier gas (including detector gas if APC is used for detector
gas) will be supplied.
(2) To use only a DINJ and DFID
Select the DINJ and DFID for Line 1. Two columns will make one line.
Fig. 8.3.2 Line configuration (Example 1)
INJ
DET
COL
8.3 Specifying the Analytical Flow Line Components ([Line Config])
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In the following examples, the PFPD (packed column flame photometric detector) is installed
as an additional detector.
(3) To use a SPL and FPD for one line and a DINJ and DFID for another line
Select the SPL and FID for Line 1 and the DINJ and DFID for Line 2.
(4) When using a single column connected to two detectors:
INJ
DET DET
COL
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8.4 8.
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8.4Changing Items Displayed with [Customiz]
Select [Customiz] (PF menu) from the [SET] key main screen to display the Display Custom-
ization screen shown in Fig. 8.4.1.
On this screen, set the items which will be displayed on the [SET] key main screen. Set an
item to On to display it on the main screen. Set the item to Off to wide its display.
Settings are the same for all lines. However, for the dual AFC, only column inlet pressure,
column flow rate, and control mode are displayed. For the AFC, when the sampling time is
set to On, the sampling time is only displayed on the SPLITLESS injection mode.
Move the cursor using the [ ] and [ ] keys to select an item to be changed; select On
or Off using the [ ] and [ ] keys, then press the [ENTER] key to validate the selection.
The default it setting displays the column inlet pressures, column flow rate, split ratio,
sampling time and the split mode.
Fig. 8.4.1Customizing the [Set] key main screen

8.4 Changing Items Displayed with [Customiz]
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9.1 9. 9.
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9 Monitoring the GC
9.1[MONIT] key Main Screen
Press the [MONIT] key to display the main monitor screen shown in Fig. 9.1.1. In the upper
portion of the main screen, monitor the status of the injection port, the column and the
detectors configured in each line. In the lower portion of the screen, monitor the
chromatogram, the temperature program, etc.
Select [Temp Mon] and [Flow Mon] (PF menu) to monitor the temperature, the pressure and
the flow rate of all injection ports, columns and detectors configured in all configured lines.
Q Detector status
The ignition status of an FID or FPD detector can be confirmed on the Monitor Screen.
For a FID:
Fig. 9.1.1 [MONIT] key main screen
Dual
Single
(Single L)
Flame = On Flame = Off
Fig. 9.1.2
The detector range (setup
value), temperature and the
voltage are displayed.
This value, multiplied by the
range (attenuation) coefficient,
is output as the analog signal.
The injection port temperature,
inlet pressure and purge flow
rate are displayed.
The column oven temperature
is displayed.
The chromatogram is dis-
played.
9 Monitoring the GC
9.1 [MONIT] key Main Screen
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Q Changing the monitor magnification (zoom)
The chromatogram and the temperature (or pressure, flow rate) program is displayed on the
lower portion of the Monitor Screen.
The signal axis and the time axis are displayed. If there is a temperature (or pressure, flow)
program, the temperature axis (or pressure axis, flow axis) is also displayed. Use the [Chng
Graph] (PF menu) key to switch the graph displayed.
Use the numeric keys and cursor keys to change the magnification and the position of each
axis on the screen.
If the temperature (or pressure, flow) program is displayed, the time axis (x-axis) cannot be changed.
Fig. 9.1.3 Monitor screen (chromatogram and temperature program)
To magnify the time axis:
: Zooms the time axis scale.
: Unzooms the time axis scale.
To magnify the signal axis:
: Zooms the signal axis scale.
: Unzooms the signal axis scale.
To maximize the display:
: Automatically adjusts the signal axis so that
the maximum value of the chromatogram
signal is displayed on the screen.
Keys to move along the time axis
: Moves the chromatogram in the + direction.
: Moves the chromatogram in the - direction.
NOTE
PF1 PF2 PF3
NIT SET
OL FUNC
OW 7 8 9
NJ 4 5 6
ET 1 2 3
TION 0

ELP CE ENTER
ON
OFF
Temperature axis
Time axis
Signal axis
4
6
2
8
5
9 Monitoring the GC
9.1 [MONIT] key Main Screen
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RETENTION TIME (Rt)
Retention time is the length of time from compound injectio to detection.
The retention time is specific to each compound. Compounds are identified based on match-
ing the retention time to a standard compound retention time.
REMAIN TIME
The longest program time subtracted by the current retention time is displayed.
LONGEST PROGRAM TIME
The longest program time indicates the total time of the longest program when comparing
the temperature program, the pressure program, the flow rate program and the time
program.
9.1.3 PF menu
PF menu Description
Reference
section
Temp Mon
Displays the current and set temperatures of column, injection port and
detector.
9.2
Flow Mon
Displays inlet pressure, total flow rate and purge flow rate for injection port,
and hydrogen flow rate, air flow rate and makeup gas flow rate for detector.
The display format depends on the typeof flow controller installed.
9.3
Zero Adj Automatically moves the baseline to zero point. 9.4
Zero Free Returns to the baseline level before zero point adjustment. 9.4
Up Moves the baseline up by 100 V from current level. 9.4
Down Moves the baseline down by 100 V from current level. 9.4
Chng Graph
Switches the graph display from chromatogram and column oven tempera-
ture program to chromatogram and pressure program. For direct injection
mode with flow control, the flow rate program is displayed instead of the
pressure program.

Chng Line
Displays the monitor screen for another configured analytical line. Switch
between monitored lines by pressing [MONIT] key from the monitor screen.

9 Monitoring the GC
9.2 9.
106
GC-2014
9.2Monitoring the Temperature with [Temp Mon]
Press [Temp Mon] (PF menu) from the [MONIT] key main screen to display the Temp Moni-
tor screen shown in Fig. 9.2.1.
Monitor the temperature of all installed column ovens, injection ports and detectors from this
screen.
Heated zones without installed components are not displayed on the screen.
9.2.2 PF menu
Fig. 9.2.1Temperature monitor
PF menu Description
Reference
section
Flow Mon Monitor pressure and flow rate for the injection ports and detectors. 9.3
NOTE
The components that are
included in the current ana-
lytical line are underlined.
107
9 Monitoring the GC
9.3 9.
GC-2014
9.3Monitoring the Flow Rate with [Flow Mon]
Press [Flow Mon] (PF menu) from the [MONIT] key main screen to display the Flow Monitor
screen shown in Fig. 9.3.1.
Monitor the flow rate and the pressure of the injection ports, and the detector gas flow rates
of the detectors.
Flow controllers that have hot been installed are not displayed on the screen.
9.3.2 PF menu
Fig. 9.3.1Flow rate monitor
PF menu Description
Reference
section
Temp Mon Monitor temperature of the column oven, injection ports and detectors. 9.2
NOTE
The name of injection port
and detectors constructing
the current line are under
lined.
Displayed items depend on
the type of injection ports,
detectors and flow controllers.
9 Monitoring the GC
9.4 9.
108
GC-2014
9.4Zero Point Adjustment
Zero point adjustment should be executed when the baseline is off-scale. If the baseline cannot
be seen on the screen, execute zero point adjustment so that the baseline returns to the zero
point. The baseline level can also be manually adjusted.
Press [Zero Adj] or [Zero Free] (PF menu) from the [Monit] key main screen, the chromatogram
displayed on the monitor screen changes as shown in Fig. 9.4.1 or Fig. 9.4.2.
Press [Up] or [Down] (PF menu) to adjust the baseline level manually.
Zero point adjustments are effective not only for the GC monitor screen, but also a con-
nected pc or Chromatopac. However, zero point adjustments made on the Chromatopac do
not adjust the monitor screen baseline level.
Zero point adjustments are only valid for the currently displayed detector. To adjusts the zero point for
another detector, first switch to its display by pressing [Chng Line] (PF menu), then execute the adjust-
ment.
For the TCD, press [Zero Free] first, turn the TCD zero point rough adjuster on the right side of the unit
to set the baseline close to 0V, and then press [Zero Adj].
Fig. 9.4.1Zero point adjustment Fig. 9.4.2 Zero free adjustment
Since the [Down] has been held down too long,
the zero point has deviated into the negative zone.
[Down]
(Held down)
[Up]
(Held down) [Zero Adj]
[Zero Adj]
[Zero Free]
NOTE
109
10.1 10. 10.
GC-2014
10.1Making an Injecting and Starting an Analysis
10.1.1 Verifying the gas chromatograph status
(1) Ensure that the STATUS indicator light is green.
(2) When the STATUS light is green, perform a zero-cause-adjustment control if necessary.
(For a description of the items which determine the Ready Status, refer to 16.6.6
Setting the Ready Check Parameters.)
For the dual packed INJ, the STATUS light becomes green and also the monitor injection
screen appears. Inject a sample following the directions displayed on the screen.
Instructions on the monitor injection screen are based on the polarity settings of the detector. When
settings are opposite from polarity in order to invert the peak, for example to analyze hydrogen using
nitrogen carrier gas on the TCD, inject a sample into the opposite inlet of the one instructed on the
screen.
Regular key operation is possible when the monitor injection screen is displayed. If there is
no key operation for a minute, the screen display automatically returns to the monitor
injection screen.
Fig. 10.1.1Monitor injection screen
NOTE
10.1 Making an Injecting and Starting an Analysis
110
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10.1.2 Making manual injection
Q Aspiration
1. Preparation
10 L Syringe
Sample
Rinse solvent
Liquid waste container
2. Syringe handling precautions
Fig. 10.1.2Typical syringe
The plunger keeps the sample from becoming contaminated. Do not bend it or touch
it. Keep it clean.
Never bend the needle.
3. Solvent pre-wash
Clean the syringe with solvent 3 to 5 times using the following procedure.
(1) Place the syringe into the rinse solvent. Pull the plunger to aspirate approximately 10
l of Solvent.
(2) Expel the solvent into the liquid waste container.
4. Sample pre-wash
Flush the syringe with sample 3 to 5 times using the following procedure.
(1) Place the syringe into the sample. Pull the plunger to aspirate approsimately 10 l of
sample.
(2) Expel the sample into the liquid waste container.
5. Preparing to inject
(1) With the needle in the sample vial, pump the plunger to eliminate air bubbles inside
the syringe.
(2) When air bubbles are eliminated, aspirate exactly 1 l of sample.
(3) Gently wipe the syringe needle with a lint-free wipe.
(4) Aspirate an additional 0.5 l of air.
Fig. 10.1.3
10.1 Making an Injecting and Starting an Analysis
111
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Q Injection
10.1.3 Starting the analysis
Start an analysis program when the STATUS light is green.
Press the [START] key to start the temperature program, the time program, the pressure
program and the flow rate program.
Any pre-set programs execute prior to the start of the analysis programs.
Aspirate sample. Insert syringe until it
touches needle guide.
Push plunger to inject
sample.
At same time, press
[START] key of gas
chromatograph.
Promptly pull out
syringe.
WARNING
Wear protective goggles when handling samples.
10.2 10.
112
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10.2Terminating the Analysis
10.2.1 Terminating the analysis
When the various programs (temperature, time, pressure, and flow rate) are finished, the
gas chromatograph automatically returns to the initial status and becomes ready.
To stop the programs before their completion, press the [STOP] key. The chromatograph
automatically returns to the ready status.
10.2.2 External devices
Q When the gas chromatograph is connected to a Chromatopac
Key operation of the gas Chromatograph
Press the [START] key of the gas chromatograph to start the Chromatopac automatically.
Pressing the GC [STOP] key, however, does not stop the Chromatopac.
The [STOP] key of the Chromatopac needs to be pressed as well.
To prevent automatic start of Chromatopac, refer to 16.6.9 Setting the link device code
Key operation from the Chromatopac
The gas chromatograph is not controlled by the Chromatopac. Pressing the Chromatopac
[START] or [STOP] key does not start or stop a GC analysis.
Q When the gas chromatograph is linked to a personal computer (pc).
Start analysis using the computer. Control for both the gas chromatograph and computer is
automatically stopped after a series of process is complete.
To inject a sample manually, start analysis using the computer so that data can be taken in,
inject the sample, and press the [START] key of the gas chromatograph.
To pause analysis, use the computer to stop it.
NOTE
113
11.1 11. 11.
GC-2014
11.1[COL] Key Main Screen
Press the [COL] key to display the column screen shown in Fig. 11.1.1. The oven temperature
program is set from this screen.
Enter a value other than 0 in the rate field displayed with END. Once a valid rate has been
entered, set the temperature (final temp) and time (hold time) for the line.
In addition to the oven temperature program, the equilibration time is set from this screen.
Equilibration time is the length of time allowed for the oven temperature to properly equili-
brate before the system is Ready.
Press the [COL] key, to move the cursor directly to the temperature portion of the ramp.
This facilitates program edits when only the temperature needs to be changed.
Fig. 11.1.1 [COL] key main screen
NOTE
Up to 20 temperatue increase/
decrease ramps can be set.
11.1 [COL] Key Main Screen
114
GC-2014
TEMP
Set the initial and the final temperature for each ramp of in the oven temperature program.
The column oven temperature should never exceed the maximum operating temperature of
the column. Keep the column temperature as low as possible to prolong the column life and
reduce detector noise. To set the maximum over temperature, refer to 16.6.4 Setting the
maximum temperature limits
TIME
Set the hold time for the initial temperature and the final temperature for each stage of the
RATE
Range: END/-250.0250.0 C/min, Default: END
Set the program rate for the oven temperature program.
Set the rate to 0; END appears and the program finishes at the previous ramp.
Move the cursor to END and set any numeric value other than 0 to complete the
temperature and the time for that ramp.
EQUILIBRATION TIME
After the programs finish and the oven temperature returns to the initial value, the
equilibration time must elapse befor the system is considered Ready. This allows for even
temperature distribution.
11.1.3 PF menu
Fan Off cannot be operated when the column oven temperature setting value is 40C or higher or a
program is running.
CAUTION
Never increase the column oven temperature while air (oxygen) is
mixed with the carrier gas. This can damage the column (especially
for polar columns).
PF menu Description
Reference
section
Del Line Deletes the current line.

Ins Line Inserts a line in line at the current cursor position.

Fan Off Stops the fan operation.

Fan On Restarts the fan operation.

Print Prints the column oven program from a Chromatopac.

NOTE
115
11.2 11.
GC-2014
11.2Temperature Programs
11.2.1 Isothermal analysis
The isothermal analysis technique keeps the column oven temperature at a constant value.
This method is useful for separating compounds within a narrow boiling point range.
11.2.2 Programmed analysis
When the sample contains compounds over a wide boiling point range, isothermal analysis
is irsufficient for separating all the compounds. At lower temperatures, the high boiling point
compounds will co-elute with wide peaks. Low concentrations of high boiling point com-
pounds may never be detected. On the other hand, at a higher temperatures, the com-
pounds with a low boiling point will co-elute too rapidly.
There is an optimal temperature for separating various compounds. Using an oven tempera-
ture that increases gradually controls the elution, and improves the separation, of all the
compounds.
11.2.3 Creating a temperature program
Q Screen terminology
1-ramp temperature program
Initial setting (TEMP).... T1
Initial setting hold time (TIME)..... a
Program rate (RATE)....
Final temperature (TMP)...... T2
Final temperature hold time (TIM)....... c
Equilibration time (ETIM)..... d
Column oven
temperature
Time
T2
T1
a
c
d
b
Program
starts.
Program
finishes.
T 2 -T 1
b
11.2 Temperature Programs
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GC-2014
Q Program creation
Fig. 11.2.1 Temperature program (Example 1)
220 (2 min)
60 (2 min)
Initial
temperature
1st stage
10 /min
5 min
160 (5 min)
120 (2 min)
60 (2 min)
5 /min
10 /min
3 min
Initial
temperature
1st stage 2nd stage
117
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Multiple-ramp temperature program (with temp increase /decrease)
Q Allowable temperature settings and ranges for temperature programs
Fig. 11.2.4Example of column oven temperature increase/decrease curve (115 V model)
Item Set Range Control Range
Default
value
Program rate
Heating
115 V model
Up to 150 C
0250
C/min
030 C/min
0 C/min
Up to 250 C 020 C/min
Heating
230 V model
Up to150 C
0250
C/min
060 C/min
Cooling
2500
C/min
Differ from the room
temperature or the
oven temperature.
Initial
temperature
1st
stage
2nd
stage
3rd
stage
70 (1 min) 70 (3 min)
200 (5 min)
120 (0 min)
-5 /min
10 /min
5 /min
250
380
400
150
20 /min
7 /min
10 /min
30 /min
50
118
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119
12.1 12. 12.
GC-2014
12 Injection Port
12.1Packed Column Injection Port (Dual INJ)
During analysis using packed columns, a sample is injected into an injection port and the entire
evaporated sample is injected to the columns. A mass flow controller is used to control the
column flow rate so gas is supplied at a specified flow rate even when the column flow path
resistance and temperature change.
The GC-2014 packed model has an injection port that two packed columns can be attached to
(dual INJ) as standard. An injection port that only one column is attached to (single INJ) is
available as an option. For the single INJ, refer to its instruction manual.
Fig. 12.1.1 Dual-column packed analysis
Control
Control
Dual AFC Dual INJ
Packed column
12 Injection Port
12.1 Packed Column Injection Port (Dual INJ)
120
GC-2014
12.1.1 Setting the temperature with [INJ] key
12.1.1.1 Screen description
Press the [INJ] key to display the main screen shown in Fig. 12.1.2 and to set the
temperature of the injection port.
Fig. 12.1.2[INJ] key main screen
12 Injection Port
121
GC-2014
12.1.1.2 Parameter list
TEMP
Set the temperature of the injection port.
Keep the injection port temperature as low as is practical to increase the service life of
the temperature sensor. In order to instantly vaporize samples inside the injection port,
set the injection port temperature approximately 30 C above the column oven
temperature (final temp). Due to the minute quantity of sample injected, the sample
vaporizes at temperatures lower than the boiling point of sample elements. To set the
injection port maximum temperature limit, refer to 16.6.4 Setting the maximum
temperature limits in 16.6 GC Configuration.
12.1.1.3 PF menu
PF menu Description
Reference
section
Print Prints the injection port temperature on Chromatopac.

Next Inj
Toggles among the setup screeens if two or more injection ports are
installed in this system.
The [INJ] key can also be used to switch screens.

12 Injection Port
122
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12.1.2 Setting the Flow Rate
Press the [FLOW] key to display the screen shown in Fig. 12.1.3 and to set parameters
for the dual AFC (Advanced Flow Controller) that controls carrier gas flow rate.
1. When the control mode is set to Single L or Single R, parameters of only specified side are
displayed.
2. Inlet pressures can be monitored but cannot be set.
CONTROL MODE
Selection: Dual/Single L/Single R, Default: Dual
When the control mode is set to Dual, flow controllers on both left and right inlets are
controlled. When it is set to Single L or Single R, a flow controller on either left or
right inlet is controlled.
COLUMN FLOW RATE
Range: 0.0100.0 ml/min, Default 50.0 ml/min
Set the flow rate of gas to be supplied to columns connected to left and right inlets. A
mass flow controller is used to control the column flow rate so gas is supplied at a
specified flow rate even when the column resistance changes due to a column
replacement or the column temperature changes.
CARRIER GAS TYPE
Selection: He/N2/H2/Ar, Default: He
Specify the type of carrier gas supplied to the AFC. This parameter is used for the
measurement/control of the flow rate. If this parameter is not set correctly, calculations
may not be performed correctly.
Fig. 12.1.3 FLOW key main screen
NOTE
Flow rate of the column
connected to the left inlet
Flow rate of the column
connected to the right inlet
12 Injection Port
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12.1.2.3 PF menu
PF menu Description
Reference
section
Column
Sets inner diameter, length, and film thickness of a column used.
Values entered here are simply for notes and they are not used for flow
rate calculations.
12.1.3
On/Off
Set the flow controller to be used to On.
When the GC starts, the AFC in the current analytical line which is set to be
On is controlled.

L Flow prog. Sets the flow rate program for the flow controller on the left inlet.
12.1.4
R Flow prog. Sets the flow rate program for the flow controller on the right inlet.
Offset
Performs offset calibration of the AFC sensor. This calibration contributes
to good reproducibility of results.
12.4
Next Flow
Toggles among the AFC set up screens when two or more AFCs are
installed in the system. The [FLOW] key can also be used to switch
screens.

12 Injection Port
124
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12.1.3 Entering Columns Parameters
Set values for column dimensions are not used for calculation for controlling the dual AFC.
Values entered here are simply for notes.
Select [Column] (PF menu) on the [FLOW] key main screen to display the screen
COLUMN I.D. (internal diameter)
Range: 0.016.00 mm, Default: 0.32 mm
COLUMN LENGTH
Range: 0.1250.0 m, Default: 25.0 m
FILM THICKNESS
Range: 0.00300.00 m, Default: 0.50 m
Fig. 12.1.4 Column parameters entering screen
Dimensions of a column
connected to the left inlet
Dimensions of a column
connected to the right inlet
12 Injection Port
125
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12.1.4 Creating a Flow Rate Program
Column flow rate can be increased or decreased during analysis by making a flow rate
program.
Select [L. Flow Prog] or [R Flow Prog] (PF menu) on the [FLOW] key main screen to
display the screen shown in Fig. 12.1.5.
FLOW RATE
Set the initial flow rate and the final flow rate for each stage of the flow rate program.
TIME
Set the hold time for the initial flow rate and final flow rate for each stage of the flow rate
program.
RATE
Range: END/-400.00 +400.00 ml/min
2
, Default: END
Set the flow rate program rate. If you set the rate to 0, END appears and the program
finishes at the previous ramp. If you move the cursor to END and set any numeric
value other than 0, the final flow rate and time for that ramp can be entered.
12.1.4.3 PF menu
Fig. 12.1.5 Flow rate program setup screen (e.g. L flow rate program)
PF menu Description
Reference
section
Del Line Deletes a line at the current cursor position.

Ins Line Inserts a line above the line that the cursor is positioned.

Print Prints the flow rate program through a Chromatopac.

Up to 7 ramps of flow rate
increase/decrease can be set.
12 Injection Port
12.2 12.
126
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12.2Split/Splitless Injection System
Q Split injection system
In a split injection system, only a portion of the sample injected into the injection port is
introduced into the capillary column. The remaining sample is sent to the split line due to
high sample volume or concentration.
Fig. 12.2.1
Q Splitless injection system
The splitless injection system is used to analyze samples of low concentration.
In a splitless injection system, the split vent is closed and the initial temperature of the column
oven is low. Then, after injection, and once the vaporized sample has moved to the column,
the split vent is open and the column temperature increased so that the condensed sample
inside the column is vaporized again and separated.
Fig. 12.2.2
Control
TFC
CARRIER
PURGE
PURGE VENT
SPLIT VENT Control
Control
ESC
SPLIT
Capillary column
Control
TFC
CARRIER
PURGE
PURGE VENT
SPLIT VENT Close
SPLIT
Capillary column
(a) During sampling time
Control
Control
TFC
CARRIER
PURGE
PURGE VENT
SPLIT VENT Control
ESC
SPLIT
Capillary column
(b) After sampling time
Control
12 Injection Port
12.2 Split/Splitless Injection System
127
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12.2.1 Setting the temperature with [INJ] key
Press the [INJ] key to display the main screen shown in Fig. 12.2.3 and to set the
temperature of the injection port.
12 Injection Port
128
GC-2014
TEMP
Set the temperature of the injection port.
Keep the injection port temperature as low as is practical to increase the service life of
the temperature sensor. In order to instantly vaporize samples inside the injection port,
set the injection port temperature approximately 30 C above the column oven
temperature (final temp). Due to the minute quantity of sample injected, the sample
vaporizes at temperatures lower than the boiling point of sample elements. To set the
injection port maximum temperature limit, refer to 16.6.4 Setting the maximum
temperature limits in 16.6 GC Configuration.
12.2.1.3 PF menu
PF menu Description
Reference
section
Print Prints the injection port temperature on Chromatopac.

Next Inj
Toggles among the setup screeens if two or more injection ports are

12 Injection Port
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12.2.2 Setting the flow rate with [FLOW] key
Press the [FLOW] key to display the screen shown in Fig. 12.2.4 and to set the AFC
(advanced flow controller) parameters. The AFC controls the pressure and the flow rate
of the carrier gas.
INLET PRESS
Range: 0.0970.0 kPa (Refer to NOTE 1), Default: 100 kPa
Set the column inlet pressure.
This sets the initial temperature of a pressure program.
When the control mode is set to PRESS, the system controls the column inlet
pressure so that it remains constant during an oven temperature program.
COLUMN FLOW RATE
Range: (Refer to NOTE 2), Default: 1.00 ml/min
Sets the carrier gas flow rate at the capillary column outlet (atmospheric pressure at
25 C).
based on the inner diameter and the length of the column and the film thickness of the
column. The column flow rate is set separately so that the carrier gas flow rate desired
occures at the initial temperature in the oven temperature program.
LINEAR VELOCITY
Range: (Refer to NOTE 3), Default: 30.0 cm/s
Sets the average linear velocity of the carrier gas flowing in the capillary column.
When you set the linear velocity, the system calculates the column inlet pressure based
on the inner diameter and the length of the column and the film thickness of the column.
Fig. 12.2.4 [FLOW] key main screen
12 Injection Port
130
GC-2014
The linear velocity is set separately so that the linear velocity desired occures at the ini-
tial temperature in the oven temperature program.
When the control mode is set to VELOCITY, the column inlet pressure automatically
changes so that the linear velocity remains constant even while the oven temperature
program is running.
SPLIT RATIO
Range: -1.0/0.09999.9, Default: -1.0
The split ratio is split flow rate / column flow rate.
When you set a split ratio, the system sets the total flow rate based on the calculated
carrier gas flow rate and split flow rate, so that the desired split ratio occurs at the oven
temperature.
Set the split ratio to -1.0 to fix the total flow rate regardless of the oven temperature.
TOTAL FLOW RATE
Range: 0.01200.0 ml/min (Refer to NOTE 1), Default: 500.0 ml/min
In split or splitless mode, the total flow rate is equivalent to column flow rate + split flow
rate + septum purge flow rate.
SPLIT MODE
Selection: SPLIT/SPLITLESS/DIRECT, Default: SPLIT
SPLIT: Controls the column inlet pressure and the total flow rate so that the
column inlet pressure and split ratio occur as specified.
SPLITLESS: Closes the split flow line during the sampling time so that the set column
inlet pressure is controlled by the Total Flow Controller.
Opens the split flow line and controls the Electronid Split Controller so that
the preset column inlet pressure occurs (Refer to Fig. 12.2.2.) after the
sampling time elapses.
DIRECT: Closes the split flow line and the set column inlet pressure (in pressure
mode) or the set total flow rate (in flow rate mode) occurs. When making
direct injection analyses, select WBI in the setup screen so that SPLIT
mode is not available.
SAMPLING TIME
Sets the sampling time for splitless analysis.
The sampling time indicates the period of time after analysis starts until the split flow line
is opened.
When setting the sampling time, ensure that the program time is longer than the sampling time.
Otherwise, the sampling time connot function correctly.
CONTROL MODE
Selection: PRESS/VELOCITY/FLOW (for direct injection mode), Default: PRESS
When the injection mode is set to SPLIT or SPLITLESS
PRESS: Controls the system so that the column inlet pressure remains constant
during an oven temperature program.
VELOCITY: Controls the system so that the linear velocity remains constant during
an oven temperature program.
When the injection mode is set to DIRECT
PRESS: Controls the system so that the column inlet pressure remains constant
during an oven temperature program.
VELOCITY: Controls the system so that the linear velocity remains constant during
NOTE
12 Injection Port
131
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CARRIER GAS TYPE
Specify the carrier gas type supplied to the AFC.
This parameter is used for the measurement/control of the flow rate.
If this parameter is not set correctly, flow rate calculations may not be performed
correctly.
(Example: If this parameter is set to N2 when He is actually used, the displayed total
flow rate, column flow rate and linear velocity are lower than the actual values.)
1. Set the column inlet pressure and total flow rate so that they are within the ranges shown in
Fig. 12.2.5.
The ranges differ according to the columns to be used and purge flow rates.
2. The column flow rate ranges from 0 to the value at which the calculated column inlet pressure is
970 kPa or less and the calculated total flow rate is 1,200 ml/min.
3. The linear velocity ranges from 0 to the value at which the calculated column inlet pressure is
970 kPa or less.
Fig. 12.2.5Available setting ranges for the AFC
NOTE
360
ml/min
720
ml/min
1200
ml/min
290 kPa 590 kPa 970 kPa
Column inlet pressure
150 kPa
Available setting ranges (He, H2)
For He and H2
T
o
t
a
l

f
l
o
w

r
a
t
e
Primary
pressure
980 kPa
Primary
pressure
600 kPa
Primary
pressure
300 kPa
150
ml/min
300
ml/min
600
ml/min
290 kPa 590 kPa 970 kPa
Column inlet pressure
Available settable ranges (N2)
T
o
t
a
l

f
l
o
w

r
a
t
e
For N2
Primary
pressure
980 kPa
Primary
pressure
600 kPa
Primary
pressure
300 kPa
12 Injection Port
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12.2.2.3 PF menu
PF menu Description
Reference
section
Column
Sets inner diameter, length and film thickness of capillary column.
Values set here are used in column inlet pressure caluculations from
column flow rate or linear velocity (or vice versa).
If these parameters are not set correctly, calculations are not performed
correctly.
12.5.3
Gas Saver The gas saver saves carrier gas by reducing the split flow rate. 12.5.4
On/Off
Set the flow controller to be used to On. When the GC starts, the AFC in
the current analytical line which is set to be On is controlled.

Press Prog Sets the column inlet pressure program. 12.5.5
Flow Prog Sets the total flow rate program. 12.5.6
Split Prog Sets the split ratio program. 12.5.7
Purge Sets the septum purge flow rate. 12.5.8
Advanced
High Pressure Injection:
Sets high pressure injection, where the column inlet pressure is kept at a
high value for a certain period of time during injection.
Splitter Fix:
Keeps the split flow rate constant.
12.5.9
Offset
Performs offset calibration of the AFC sensor.
This calibration contributes to good reproducibility of results.
3.6
Next Flow
Toggles among the AFC set up screens if two or more AFCs are installed
in this system.
The [FLOW] key can also be used to switch screens.

12 Injection Port
133
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12.2.3 Setting column parameters
For capillary columns, the column inner diameter, length, and film thickness are used to cal-
culate the column flow rate and linear velocity. Enter the column inlet pressure, and the col-
umn flow rate and linear velocity are calculated based on the column parameters.
Alternatively, by entering the column flow rate and linear velocity valves, the column param-
eters are used to calculate the corresponding column inlet pressure.
Select [Column] (PF menu) from the [FLOW] key main screen to display the Column
Diam. screen shown in Fig. 12.5.5.
COLUMN I.D.
Range: 0.016.00 mm, Default: 0.32 mm
COLUMN LENGTH
Range: 0.1250.0 m, Default: 25.0 m
FILM THICKNESS
Range: 0.00300.00 m, Default: 0.50 m
Set the internal diameter, the length and film thickness of the capillary column in use.
These parameter values are used for calculation (or the backward calculation) of the
column head pressure based on the column flow rate or the linear velocity.
Fig. 12.2.6 Column setup screen
12 Injection Port
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12.2.4 Gas saver
The gas saver function reduces the split ratio during a split of splitless analysis. This reduces
the amount of carrier gas flowing through the split flow line, conserving carrier gas.
Even though this can change the split ratio, the column inlet pressure is kept at a constant
value. In other words, changing the split ratio does not affect the carrier gas flow rate
through in the column.
Select [Gas Saver] (PF menu) from the [FLOW] key to display the Gas Saver screen
GAS SAVER
Select On to use the gas saver function.
Select Off to disable the gas saver function.
GAS SAVER SPLIT RATIO
Range: 0.09999.9, Default: 5.0
Set the split ratio which will reduce the split flow to conserve carrier gas.
Setting 0 closes the split flow line.
GAS SAVER START TIME
Specify the period of time after analysis starts until the split ratio switches to gas saver
mode.
This period of time should be longer than the time required for the sample to move from
the injection port to the column.
Setting the gas saves start time too early can provide unpredictable quantitation results.
Fig. 12.2.7 Gas saver setup screen
12 Injection Port
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12.2.5 Pressure program
You can set a program to increase and decrease the column inlet pressure during analysis.
If high-boiling point contaminants are clunting shorlty after the target compounds, a pressure
program can be used so that the oven temperature does not need to be set higher than nec-
essary. This prolongs column service life.
Select [Press Prog] (PF menu) from the [FLOW] key main screen when the control
mode is set to PRESS, to display the carrier press screen shown in Fig. 12.2.8
appears.
PRESS
Range: 0.0970.0 kPa (Refer to Fig. 12.2.5.), Default: 100 kPa
Set the initial pressure and the final pressure for each stage of the pressure program.
TIME
Set the hold time for the initial pressure and the final pressure for each stage of the
pressure program.
RATE
Range: END/-400.00400.00 kPa/min, Default: END
Set the pressure program rate.
If you set the rate to 0, END appears and the program finishes at the previous ramp.
If you move the cursor to END and set any numeric value other than 0, the pressure
and the time for that ramp can be enterd.
The pressure increase/decrease program rate control range may be limited depending on the total flow
rate setup value, the column in use and the purge flow rate.
Fig. 12.2.8 Pressure program setup screen
NOTE
Up to 7 ramps of pressure
increase or decrease can be
set.
12 Injection Port
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12.2.5.3 PF menu
12.2.5.4 Setting a pressure program
<1-ramp pressure program>
Q Program creation
<1-ramp pressure program>
PF menu Description
Reference
section


PRINT Prints the pressure program to a Chromatopac.

Fig. 12.2.9 Pressure program example
Initial pressure (PRSS)..... P1
Initial pressure hold time (TIME)...... a
Program rate (RATE).....
Final pressure (PRS)....... P2
Final pressure hold time (TIM)........ c
Pressure
P2
a
Program
starts.
Program
finishes.
Time
P 2 -P 1
b
b c
60 kPa(2 min)
100 kPa(5 min)
4 kPa/min
12 Injection Port
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12.2.6 Creating a Flow rate program
If the control mode is set to FLOW, increase and decrease the total flow rate during
analysis by making a flow rate program.
When you set a flow rate program for the APC, a corresponding pressure program is actu-
ally calculated based on of the pressure-flow rate calibration curve saved by the GC.
Select [Flow Prog] (PF menu) from the [FLOW] key main screen while the control mode
is set to FLOW to display the Carrier Flow screen shown in Fig. 12.2.10.
FLOW RATE
Range: 0.00970.0 ml/min (Refer to Fig. 12.2.5.), Default: 50 ml/min
Set the initial flow rate and the final flow rate for each stage of the total flow rate
program.
TIME
Set the hold time for the initial flow rate and the final flow rate for each stage of the flow
rate program.
RATE
Range: END/-400.00400.00 ml/min
2
, Default: END
Set the flow rate program rate.
If you set the rate to 0, END appears and the program finishes at the previous ramp.
If you move the cursor to END and set any numeric value other than 0, the pressure
and the time for that ramp can be entered.
The control range of the flow rate program may be limited depending on the column in use, purge flow
rate and gas restrictor.
Fig. 12.2.10 Flow rate program setup screen
NOTE
Up to 7 ramps of flow rate
increase/decrease can be set.
12 Injection Port
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12.2.6.3 PF menu
12.2.6.4 Setting a flow rate program
<1-ramp flow rate program>
Q Program creation
<1-ramp flow rate program>
PF menu Description
Reference
section


Print Prints the flow rate program to a hromatopac.

Fig. 12.2.11Flow rate program example
Initial flow rate (FLOW).... F1
Initial flow rate hold time (TIME)...... a
Program rate (RATE)......
Final flow rate (FLW)........ F2
Final flow rate hold time (TIM)......... c
Flow rate
F2
F1
a
c
b
Program
starts.
Program
finishes.
Time
F 2 -F 1
b
20 ml/min(10 min)
30 ml/min(5 min)
3 ml/min
2
12 Injection Port
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12.2.7 Split ratio program
You can change the split ratio during a split analysis. In addition, you can set a split ratio
program after the sampling time has elapsed during splitless analysis.
The split ratio program and the gas saver perform basically the same operation. However,
the split ratio program is used for more general purposes.
Select [Split Prog] (PF menu) from the [FLOW] key main screen when not in DIRECT
mode to display the Split Ratio screen shown in Fig. 12.2.12.
TIME
Set this parameter to display the split ratio used previously in the Split Ratio column.
SPLIT RATIO
Range: -1.0/0.09999.9, Default: -1.0
Set the split ratio.
If the split ratio is set to -1.0, the total flow rate remains constant regardless of the
oven temperature.
12.2.7.3 PF menu
Fig. 12.2.12 Split ratio program setup screen
PF menu Description
Reference
section


Print Prints the split ratio through to a Chromatopac.

A program can contain up to
7 ramps.
12 Injection Port
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12.2.7.4 Setting a split ratio program
<1-ramp program>
Q Program creation
<1-ramp program>
Fig. 12.2.13 Example of split ratio program
nitial ratio 'SPLT' S1
nitial program run time 'TME' a
Final ratio 'SPLT' S2
Split ratio
S2
S1
Program
starts.
Program
finishes.
Time
a
Split ratio = 60
Split ratio = 50
5.00 min
12 Injection Port
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12.2.8 Septum purge
Set the septum purge flow rate. The septum purge removes contamination from the injection
port at the septum.
The septum purge flow rate is set here.
Select [Purge] (PF menu) from the [FLOW] key main screen to display the septum
purge screen shown in Fig. 12.5.13.
Fig. 12.2.14 Septum purge setup screen
12 Injection Port
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FLOW RATE
Sets the septum purge flow rate.
12.2.8.3 PF menu
Fig. 12.2.15 Available setting range for the purge flow rate
PF menu Description
Reference
section
On/Off Set to On when the septum purge flow rate is applied

0
0
50
100
150
200
250
300
100 200 300 400 500
Column inlet pressure (kPa)
Setting range
P
u
r
g
e

f
l
o
w

r
a
t
e

(
m
l
/
m
i
n
)
12 Injection Port
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12.2.9 High pressure injection and splitter fix mode
Q High Pressure Injection
High pressure injection is a split/splitless injection method which keeps the column inlet
pressure at a value higher than the analysis pressure for a specified period of time while the
sample is injected. Then, the column inlet pressure returns to the normal analysis value.
High pressure injection is effective especially for the splitless injection system. High
pressure injections, can reduce the total gas volume and improve percent recovery valves.
Q Splitter Fix
If the injected sample consists of a solvent with a high vaporization expansion coefficient,
the pressure inside the injection port drastically increases when the solvent vaporizes. This
can result in too much solvent being diverted from the column, reducing sensitivity.
Sending power to the split flow valve at sample injection can keep the split ratio at its desig-
nated valve.
Select [Advanced] (PF menu) from the [FLOW] key main screen when not in DIRECT
mode to open the advanced screen shown in Fig. 12.2.16.
Fig. 12.2.16Setup screen for high pressure injection and splitter fix mode
12 Injection Port
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Q High Pressure Injection
HIGH PRESS INJECTION MODE
Select One of the following three modes.
Off : Disables high pressure injection.
On : Sets the column inlet pressure to high value immediately.
Auto : Immediately sets the column inlet pressure to high pressure. When analysis is
finished and the GC returns to the ready status, the column inlet pressure
automatically increases.
HIGH PRESS INJECTION PRESS
Set the column inlet pressure for high pressure injection.
HIGH PRESS INJECTION TIME
Set the period of time after analysis starts until the column inlet pressure returns to the
original value.
Usually, set this equal to the sampling time.
Q Splitter Fix
SPLITTER FIX MODE
Selection: Off/On/Auto, Default: Off
Select one of the following three modes.
Off : Disables splitter fix mode.
On : Fixes the split flow line immediately.
Auto : Automatically enters splitter fix mode after analysis finishes and the system returns to
ready status.
FIX TIME
Set the period of time to be in splitter fix mode.
When SPLITTER FIX MODE is set to On, indicate the period of time after SPLITTER FIX
MODE is set to On to exit splitter fix mode.
When SPLITTER FIX MODE is set to Auto, set the period of time after the analysis starts
to exit splitter fix mode.
Using splitter fix mode for long periods of time may interfere with constant pressure, negatively affect-
ing reproducibility of results.
HIGH PRESS INJECTION MODE = On HIGH PRESS INJECTION MODE = Auto
NOTE
145
12 Injection Port
12.3 12.
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12.3Direct Injection System
Q Direct injection system
In a direct injection system, a wide-bore (0.53 mm or greater) column is used. Nearly the
entire amount of sample injected is inrtoduced on the column. This usually results in better
sensitivity than narrow-bore columns with split injections. However, peak shapes are broad,
which decreases resolution and can lead to a higher S/N ratio.
The direct injection system uses a WBI (wide-bore injection) injection port. When WBI is
specified, DIRECT injection mode is automatically used and split mode is not available on
the [INJ] key main screen.
Fig. 12.3.1
Control
Control
TFC
CARRIER
PURGE
PURGE VENT
Capillary column
12 Injection Port
12.3 Direct Injection System
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12.3.1 Setting the temperature
Press the [INJ] key to display the injection port main screen shown in Fig. 12.3.2 and to
set the injection port temperature.
TEMP
Set the injection port temperature.
Keep the injection port at the lowest practical temperature for the analysis; this prolongs
the service life of the temperature sensor. To instantly vaporize the injected sample, set
the injection port temperature approximately 30 C higher than the final column oven
temperature. Because the sample quantity is usually minute, the sample is vaporized at
temperatures lower than the boiling point of sample compounds. To set the maximum
temperature limit, refer to 16.6.4 Setting the maximum temperature limits in 16.6 GC
Configuration.
12.3.1.3 PF menu
PF menu Description
Reference
section
Print Prints the temperature program to a Chromatopac.

Next Inj
Toggles to the next setup screen when two or more injection ports are

12 Injection Port
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12.3.2 Setting the flow rate
Press the [FLOW] key to display the main Flow Screen shown in Fig. 12.3.3. Set the
AFC parameters to control the carrier gas pressure and the flow rate.
INLET PRESS
Range: 0.0970.0 kPa, Default: 100.0 kPa
Set the column inlet pressure.
When creating a pressure program, this specifies the initial pressure.
When the control mode is set to PRESS, the system controls the column inlet
pressure so that it remains constant during a temperature program.
Normally, when using a wide bore column, set the column inlet pressure to a low
pressure (2040 kPa).
COLUMN FLOW RATE
Default:(Refer to NOTE 1) 1.00 ml/min
Set the carrier gas flow rate at the capillary column exit (atmospheric pressure at 25 C).
based on the inner diameter, the length and the film thickness of the column. The col-
umn flow rate is set separately so that the carrier gas flow rate desired occurs at the ini-
tial temperature in the oven temperature program.
LINEAR VELOCITY
Default:(Refer to NOTE 2) 30.0 cm/s
Set the average linear velocity of the carrier gas flowing in the capillary column.
Fig. 12.3.3 [FLOW] key main screen
12 Injection Port
148
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When you set the linear velocity, the system calculates the column inlet pressure based
on the inner diameter, the length and the film thickness of the column. The linear velos-
ity is set separately so that the linear velocity desired occurs at the initial temperature in
the oven temperature program.
If you set the control mode to VELOCITY, the column inlet pressure automatically
changes so that the linear velocity remains constant during the oven temperature
program.
TOTAL FLOW RATE
Range: 0.01200.0 ml/min (Refer to Fig. 3.5.1), Default: 50.0 ml/min
Set the total flow rate, which is the sum of column flow rate + split flow rate + septum
purge flow rate.
CONTROL MODE
Selection: PRESS/VELOCITY/FLOW, Default: PRESS
PRESS: Controls the system so that the column inlet pressure remains constant during
VELOCITY: Controls the system so that the linear velocity remains constant during an
FLOW: Controls the system so that the set flow rate remains constant.
CARRIER GAS TYPE
Specify the carrier gas type supplied to the AFC.
This parameter is used for the measurement/control of the flow rate.
If this parameter is set incorrectly, flow rate calckulations may not be performed
incorrectly.
(Example: If this parameter is set to N2 when He is actually used, the displayed total
flow rate, column flow rate and linear velocity are lower than the actual values.)
1 The column flow rate ranges is from 0 to the value at which the calculated column inlet pressure is
970 kPa or less and the calculated total flow rate is 1,200 ml/min or less.
2 The linear velocity ranges is from 0 to the value at which the calculated column inlet pressure is
970 kPa or less.
12.3.2.3 PF menu
PF menu Description
Reference
section
Column
Sets inner diameter, length and film thickness of capillary column.
Values set here are used in column inlet pressure caluculations from
column flow rate or linear velocity (or vice versa).
If these parameters are not set correctly, calculations are not performed
correctly.
12.2.3
On/Off
Set the flow controller to be used to On. When the GC starts, the AFC in
the current analytical line which is set to be On is controlled.

Press Prog Sets the column inlet pressure program. 12.2.5
FLOW Prog Sets the total flow rate program. 12.2.6
Purge Sets the septum purge flow rate. 12.2.8
Offset
Performs offset calibration of the AFC sensor.
This calibration contributes to good reproducibility of results.
12.4
Next Flow
Toggles among the AFC setup screens if two or more AFCs are installed in
this system.
The [FLOW] key can also be used to Switch screens.

NOTE
149
12 Injection Port
12.4 12.
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12.4AFC and APC Offset Calibration
The pressure and flow rate sensors of AFC and APC may become slightly off after long
periods of use. If the sensor values deviate, 0.5 kPa or 0.5 ml/min is indicated for
pressure or flow rate instead of zero even when there is no gas flowing.
In this case, perform the offset (zero point) calibration. Calibration is especially effective
when data reproducibility is important.
Calibration procedures are as follows.
1. Set the temperatures of the injection port, column oven, and detector low and wait until
they become 40 C or lower.
(AFC calibration is performed when there is no gas flowing. Stopping gas when parts'
temperatures are high may cause deterioration of columns.)
2. Press the [SYSTEM] key, select Start Seq (PF menu), and check the mode to start the
GC when the power is turned on. If it is not set to Manual Start, change it.
3. Turn off the power and reboot it.
Rebooting leaves the unit at the state of SYSTEM OFF.
Do not shut off gas supply by turning off the main valve or by any other measures.
Performing calibration without primary pressure makes the zero point off.
4. To perform AFC calibration, completely empty out the gas by detaching the septum of
the injection port.
To perform APC calibration, wait until when the pressure or flow rate does not fluctuate.
5. Press the toggle key on each flow controller's parameter setup screen until the Offset
PF menu is displayed. For AFC, press the [FLOW] key once and the toggle key twice.
6. Press Offset (PF menu).
The message Zero Calibration Start appears. Approximately 10 seconds later, the
message Zero calibration completed appears indicating that the calibration is
complete.
7. Return the septum of the injection port to its original position if it has been detached.
Fig. 12.4.1 (AFC) Fig. 12.4.2 (APC)
12 Injection Port
12.5 12.
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12.5Setting the Flow Rate Parameters
Q Linear velocity and carrier gas selection
In capillary analysis, the type and the flow rate of the carrier gas have a considerable effect
on the column efficiency. The figure below shows changes in the HETP (Height Equivalent
to Theoretical Plate) at different linear velocity valves for nitrogen, helium and hydrogen car-
rier gas.
Fig. 12.5.1 Effect on linear velocity and HETP for various carrier gases (H-V curve)
The graph above shows that the lowest HETP values are obtained when nitrogen is used as
the carrier gas and the linear velocity is set to a value a little less than 10 cm/s. However,
nitrogen is not a good carrier gas for capillary analysis for the following reasons.
(1) If the linear velocity deviates only slighty from the optimum value, the HETP increases
dramatically.
(2) To obtain the optional linear velocity, the flow rate must be low, resulting in long analysis
times.
Helium is frequently used as the carrier gas because the HETP is low over a considerably
wider linear velocity range starting at 20 cm/s.
The column efficiency of hydrogen is good at higher linear velocities than for helium. For this
reason, hydrogen can be used for rapid analyses. However, hydrogen is seldom used in
reality because it is extremely flammable, and therfore too dangerous.
Q Efficiency of an analysis
Usually, analyses are performed with a flow rate that is higher than the optimal flow rate, as
long as separation of conpounds is sufficient. This reduces the analysis time. For general
analyses on this system, setting the linear velocity to 30 cm/s is recommended.
The tables below show the column inlet pressure at which the linear velocity becomes
approximately 30 cm/s. Use the tables as the guideline for setting the column inlet pressure.
However, the inlet pressure also depends on the column type.
12 Injection Port
12.5 Setting the Flow Rate Parameters
151
GC-2014
Example 1: Column oven temperature = 50 C(carrier gas = helium)
Example 2: Column oven temperature = 200 C (carrier gas = helium)
Fig. 12.5.2 shows the relationship between the column flow rate and the column inlet pressure.
60 d
4
P P0
2
P0
2
Fc 10
3
256 L P0
Fc : Column flow rate [ml/min]
d : Column I.D [mm]
L : Column length [m]
P : Column inlet pressure [kPa]
P0 : Column outlet pressure = atmospheric pressure [kPa]
: Viscosity coefficient (19.4 Pas (helium, 20 C))
Fig. 12.5.2
Length
30 m 60 m
I.D. of column Film thickness
0.25 mm 0.25 m 100 kPa 210 kPa
0.32 mm 0.25 m 60 kPa 120 kPa
0.53 mm 1.5 m 20 kPa 40 kPa
Length
30 m 60 m
I.D. of column Film thickness
0.25 mm 0.25 m 130 kPa 275 kPa
0.32 mm 0.25 m 80 kPa 160 kPa
0.53 mm 1.5 m 30 kPa 60 kPa
NOTE
12 Injection Port
12.5 Setting the Flow Rate Parameters
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153
13.1 13. 13.
GC-2014
13 Detector
13.1Hydrogen Flame Ionization Detector (FID)
13.1.1 Principle of FID operation
In the hydrogen flame ionization detector (FID), hydrogen gas is mixed with the column
outlet gas at a certain ratio as shown in Fig. 13.1.1.The gas mixture combusts in the air
atmosphere. An electrode exists at each end of the FID jet, and DC voltage is applied
between the electrodes.
If only pure carrier gas (nitrogen, helium or argon) and hydrogen gas are mixed, little current
is produced between the electrodes. When an organic compound is mixed with the carrier
gas, current is produced proportionally to the amount of organic compound present.
This is because ions (mainly carbon ions) are generated when an organic compound
combusts within the hydrogen flame, and the generated ions are captured by the collector.
For isomers, the ion quantity generated is almost proportional to the number of carbons
contained in the compound. However, carbon atoms in a C=O form do not create a signal.
The presence o halogens in the compound decreases sensitivity.
Because the ion current obtained by the FID is very low, it is amplified into a proper voltage,
then output to a Chromatopac or personal computer.
Fig. 13.1.1
13 Detector
13.1 Hydrogen Flame Ionization Detector (FID)
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GC-2014
13.1.2 Setting the detector
Press the [DET] key to display the detector main screen shown in Fig.13.1.2. Here, set
the detector temperature, the detector gas flow rate, etc.
When the detector is configured in the analytical line, the output signal settings appear
in the lower portion of the screen.
DETECTOR CONTROLLER
When a detector is set to On, its current and voltage are controlled.
When a detector is configured in an analytical line and set to On here, the detector is
controlled and its signal monitored. However, even if a detector is set to Off, the gas
flow is controlled, and the temperature increases to the set value if the detector is
configured in an analytical line.
TEMP
Range: 0.0400 C, Default: 25.0 C
Set the detector temperature. Normally, set the detector temperature approximately
30 C higher than the final column oven temperature to prevent contamination by high
boiling point compounds.To set the maximum temperature limit, refer to 16.6.4 Setting
the maximum temperature limits in 16.6 GC Configuration.
FLAME (monitor only)
Selection: On/Off
Select On to ignite the flame.
Select Off to extinguish the flame.
(a) Dual FID (b) Single FID
Fig. 13.1.2 [DET] key main screen
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SIGNAL POLARITY
(Displayed only when Dual is selected for the control mode of the dual FID)
Selection: +/-, Default: +
Set to + to output after subtracting the right side cell signal from the left side cell signal
of the dual FID and set to - for the opposite.
FILTER TIME CONSTANT
Selection: 4 ms/5 ms/10 ms/20 ms/50 ms/100 ms/200 ms/500 ms/1 s/2 s,
Default: 200 ms (single FID), 1 s (dual FID)
This constant affects the processing of the detector signal.
As the time constant increases, noise as well as the peak height are reduced.
Select the optimum value in accordance with the peak half width. (Refer to 13.3 Filter
Signal Time Constant.)
CONTROL MODE
Selection: Dual/single L/single R, Default: Dual
Set to Dual when connecting two columns to the dual FID and Single L or R when
connecting one column.
SIGNAL OUTPUT PORT
Selection: Off/Ch1/Ch2/Ch3/Ch4, Default: (Channel is automatically assigned.)
Select the digital and analog signals output channels. Four channels are available.
However, for analog output, only Ch1 and Ch2 are available as standard.
BACKGROUND SIG. SAVE
Selection: Off/Buff 1/Buff 2, Default: Off
Background baseline signals can be saved for the purpose of background subtraction.
BACKGROUND SIG COMP.
Subtracts the saved background signal baseline from the actual baseline. This produces
a stable baseline despite considerable baseline fluctuations
DET SIG SUBTRACTION
Selection: Off/DET# 1/DET# 2/DET# 3/DET# 4, Default: Off
Subtracts the detector signal of one detector from the signal of another detector. This
function is mainly used in a dual column flow line to subtract the data acquired without
an injection from the data acquired with an injection. The background signal is elimi-
nated.
For the details on background save and background compensation, refer to 13.4
Background Compensation.
SIGNAL RANGE
Selection: 1/10
-1
/10
-2
/10
-3
/10
-4
, Default: /10
-1
Multiplies the analog signal by the coefficient 10
-x
for a linear analog signal type.
If the data processing unit is saturated, for example, change the setting from 1 to
10
-1
, from 10
-2
to 10
-3
. In case of the digital signal, the signal is always output
with 1.
SIGNAL ATTENUATION
Selection: 1/2
-1
/2
-2
/2
-3
/2
-4
, Default: /2
-1
-x
for a wide analog signal type.
If the data processing unit is saturated, for example, change the setting from 1 to 2
-1
,
from 2
-2
to 2
-3
. In case of the digital signal, the signal is always output with 1.
ANALOG SIGNAL TYPE
Selection: Linear/Wide, Default: Linear
Set this item when the GC is connected to a Chromatopac in analog format.
Wide ... Select wide when connecting the GC to the C-R8A/C-R7A/C-R7A plus.
The GC outputs square root of the original signal to the Chromatopac, and the
received signals are squared in the Chromatopac.
13 Detector
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When connecting the GC to a C-R7A/CR-7A plus for the first time, or replacing
the Chromatopac, set the detector signal output to Off and perform
calibration. (For the calibration procedure, refer to 2.2 Outputting Analog
Signals to the Chromatopac.)
Linear...Select linear when connecting the GC to any Chromatopac other than the C-
R8A/C-R7A/CR-7A plus.
When connecting the GC to the C-R8A/C-R7A/C-R7A plus and setting the
ANALOG SIGNAL TYPE to Linear, the optional signal cable (linear P/N 221-
47251-92) is required.
13.1.2.3 PF menu
PF menu Description
Reference
section
Ignite
Reduces the air flow rate, heats filament, and ignites detector when
pressed when FLAME was set to Off.
If AUTO IGNIT is set to On on the [SYSTEM] key screen, the detector is
automatically ignited after each setting reached the setting value.
13.2.2.4
Det Gas
Sets the flow rate of makeup gas, hydrogen and air if the advanced
Pressure Control (APC) is installed.
13.2.3
Ign. Set
If the Advanced Pressure Control (APC) is installed, you can set automatic
ignition and automatic re-ignition. Default value is On.

Next Det
Toggles to the setup screen of another installed detector.
The [DET] key can also be used to switch screens.

VLV On or
VLV Off
When the optional solenoid valve to shut off supply gas is installed,
hydrogen and air are shut off by the valve until ignition.
Opens the solenoid valve when VLV On is displayed and closes the valve
when VLV Off is displayed.
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13.1.3 Setting the Detector Gas (manual flow controller)
Hydrogen and air are supplied to the FID as detector gas. For capillary analysis, makeup
gas is required to prevent peak tailing and optimize FID sensitivity.
GC-2014 has flow controllers according to models as described below.
Set the detector gas flow rate following the procedures described below.
1. Turn the main valve of the gas cylinder to supply gas to the GC.
2. Open the flow controller cover on the top of the back of the unit.
Layouts for the models with the dual FID and models with the single FID are as shown
in Fig. 13.1.3 (a) and Fig. 13.1.3 (b) respectively.
3. When the optional solenoid valve to shut off supply gas (P/N 221-70782-91) is installed,
hydrogen and air are shut off by the valve until ignition. To adjust the pressure, press the
[VLV On] key on the [DET] key main screen to open the solenoid valve.
4. Turn the pressure regulators to set the pressure as described below.
Hydrogen 55 kPa (Approx. 40 ml/min)
Air 40 kPa (Approx. 400 ml/min)
Makeup gas (nitrogen) 75 kPa (Approx. 30 ml/min)
Makeup gas (helium) 80 kPa (Approx. 30 ml/min)
Pressure-flow rate calibration curves for each flow controller are shown in Fig. 13.1.4. These curves
slightly differ according to units.
Models with the dual FID (GC-2014AF, GC2014ATF, etc.)
Two flow paths of manual flow controllers with hydrogen and air
Models with the single FID (GC-2014AFsc, etc.)
One flow path of manual flow controller with hydrogen and air
One flow path of manual flow controller for makeup gas
(a) Dual FID (b) Single FID
Fig. 13.1.3Manual flow controller for FID
Top
Bottom
Hydrogen
pressure meter
Right
Flow controller
for the right side FID
Left
Flow controller
for the left side FID
Back
Hydrogen
pressure regulator
Front
Air pressure regulator
Air
pressure meter
Top
Bottom
Hydrogen
pressure meter
Back
Hydrogen
pressure regulator
Front
Air pressure regulator
Air
pressure meter
Top
Makeup gas
pressure meter
Back
Makeup gas
pressure regulator
NOTE
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Fig. 13.1.4 Pressure-flow rate calibration curves (examples)
O
6O
1OO
m!/m1n
2O 4O 6O 8O 1OO KPa
(a) Hydrogen
Hydrogen pressure
O
6OO
1OOO
m!/m1n
2O 4O 6O 8O 1OO KPa
(b) Air
Air pressure
O
1O
m!/m1n
2O 4O 6O 8O 1OO KPa
(c) Makeup gas (N2)
Makeup gas pressure
O
1O
2O 2O
8O 8O
4O 4O
6O 6O
6O 6O
m!/m1n
2O 4O 6O 8O 1OO KPa
(d) Makeup gas (He)
Makeup gas pressure
H
y
d
r
o
g
e
n

f
l
o
w

r
a
t
e
A
i
r

f
l
o
w

r
a
t
e
M
a
k
e
u
p

g
a
s

f
l
o
w

r
a
t
e
M
a
k
e
u
p

g
a
s

f
l
o
w

r
a
t
e
13 Detector
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13.1.4 Setting the detector gas flows(APC)
The FID detector gas consists of makeup gas, hydrogen and air. The makeup gas is inert
gas supplied to the detector to prevent peak tailing and optimize FID sensitivity. Usually, the
carrier gas is used as the makeup gas. Hydrogen gas and air are supplied to be combusted
inside the detector, creating the FID flame.
Select [Det Gas] (PF menu) from the [DET] key main screen to display the flow screen
When the Start Flow status is selected on the [SYSTEM] key screen, the makeup gas
flow starts. Just before the ignition procedure begins, hydrogen and air flow starts.
Selecting Stop Temp/Det status from the [SYSTEM] key main screen, gas flow stop.
Fig. 13.1.5 Setting the detector gas flows
13 Detector
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H2
Range: 0.0200.0 ml/min, Default: 40.0 ml/min(optimal flow rate)
MAKE UP
Makeup gas is inert gas to be supplied to the detector to optimize its sensitivity during
capillary analysis. Nitrogen and helium can be used for the FID. Using nitrogen is
recommended because it offers higher sensitivity. Set the value to zero for packed
analysis.
GAS TYPE
Selection: N2/He/Ar, Default: He
Set the type of gas used as the makeup gas.
Do not use hydrogen for make up gas.
Air
13.1.4.3 PF menu
PF menu Description
Reference
section
Next Flow
Switches screens to set detector gas for the left (L) and right (R) side
detectors during the dual mode of the dual FID with APC.
12.4
On/Off
Select Off to stop gas flow.
Select On to restart the gas flow.
Default value is On.

Offset
Performs offset calibration of APC sensor.
This calibration improves the reproducibility of results.
3.6
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13.1.5 Igniting and Extinguishing the FID
13.1.5.1 Confirmation prior to FID ignition
Confirm the following points prior to FID ignition.
1. Connect the column.
2. Specify the FID to be ignited in a flow line. (Refer to 8.3 Specifying the Analytical
Flow Line Components ([Line Config]))
3. Set the FID to be ignited to On. (Refer to 13.1.2 Setting the Detector.)
4. Turn the main valve of the gas cylinder to supply gas.
5. Set the flow rate of the detector gas. For APC, press [On/Off] (PF menu) on the
screen to set the detector gas so that all gas control is turned on.
(Refer to 13.1.3 Setting the Detector Gas (manual flow controller) or 13.1.4
Setting the detector gas flows(APC).)
13.1.5.2 FID ignition procedures
Q Automatic ignition
The system starts and the FID is ignited automatically.
1. Press the [SYSTEM] key and set the following parameters. Change other
parameters if necessary.

2. Start the GC.
GC starts when [Start GC] (PF menu) is pressed in manual starting and when the
power is turned on in automatic starting.
START TEMP/DET Yes
DETECTOR On
AUTO IGNITE On
(a) Main screen (b) [Start Seq] (PF menu)
Fig. 13.1.6 Setting starting procedures (automatic ignition)
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3. After the GC starts, gas control starts. Temperature/detector control starts after the
start time passes. When the detectors temperature becomes READY, the FID is
ignited automatically.
Q Manual ignition
The FID is ignited by key operation.
1. Press the [SYSTEM] key and set the following parameters. Change other
parameters if necessary.
2. Start the GC.
GC starts when [Start GC] (PF menu) is pressed in manual starting and when the
power is turned on in automatic starting.
3. After the GC starts, gas control starts. Temperature/detector control starts after the
start time passes.
4. After the detectors temperature becomes 100 C or higher, press [Ignite] (PF
menu) on the [DET] key main screen.
START TEMP/DET Yes
DETECTOR On
AUTO IGNITE Off
(a) Main screen (b) [Start Seq] (PF menu)
Fig. 13.1.7 Setting starting procedures (manual ignition)
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If the detector is set to Off when setting GC starting procedures, the setting for all detectors specified in
a respective flow line automatically becomes Off.
Always set to On when only FID is used.
To set to Off while using detectors other than FID at the same time, set the detector to
On on the [DET] key screen and then operate the ignition.
1. The messages ignition finished and ignition finished (retried) mean that ignition has been carried
out properly.
2. The message DET#1, ignition failed or other similar messages mean that ignition has failed. In
this case, the units conditions are as follows.
Hydrogen and air continue to be supplied when the manual flow controller is used.
When the optional solenoid valve to shut off supply gas is installed, hydrogen and air are shut off by
the valve.
When the APC is used, APCs valve is closed to shut off hydrogen and air supply.
3. Potential causes of ignition failure are listed below. Remove the cause then ignite the FID.
Column is not connected.
Detector gas is not supplied.
Detector gas flow rate is not proper.
Unused detector (FID or FPD) is set to On.
FID jet is clogged. Clean or replace the FID jet.
Igniter filament is broken. Replace the igniter.
4. When the optional solenoid valve to shut off supply gas is installed or ignition is carried out
immediately after opening the gas cylinders main valve, the message (retried) or ignition failed
may be displayed because hydrogen in the piping is not completely replaced.

13.1.5.3 Extinguishing the FID
Q Manual flow controller
Extinguish the FID flame by closing the main valve of the hydrogen cylinder to shut off
gas supply.
Q When the manual flow controller and the solenoid valve to shut off supply gas are installed
Press [Stop GC] (PF menu) on the [SYSTEM] key main screen. The solenoid valves
close when the detector control ends to shut off gas supply, extinguishing the FID flame.
Q APC
Press [Stop GC] (PF menu) on the [SYSTEM] key main screen. APC control ends when
the detector control ends to shut off gas supply, extinguishing the FID flame.
To extinguish the flame before the GC stops, press the [DET] key, select [DET Gas] (PF
menu), and set the control of hydrogen and air to Off on the screen. Gas supply is shut
off, extinguishing the FID flame.
START TEMP/DET Yes
DETECTOR Off
AUTO IGNITE Off
NOTE
NOTE
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13.2 13.
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13.2Thermal Conductivity Detector (TCD)
13.2.1 Principle of TCD operation
The thermal conductivity detector (TCD) can detect all compounds except the carrier gas
itself.
The metallic TCD filament is heated by the application of current. The carrier gas used has a
high thermal conductivity, such as helium. As sample compounds pass the filament, the fila-
ment temperature increases, because the thermal conductivity of the sample compounds is
less than that of the carrier gas. The filament temperature changes affect its resistance; the
resistance is measured and produces a chromatogram.
A reference filament also exists, where only carrier gas flows, to eliminate background resis-
tance fluctions.
Fig. 13.2.1
The TCD sensitivity is proportional to the difference in thermal conductivity between the
sample and the carrier gas. Because the thermal conductivity of the sample is lower than
that of the carrier gas, the TCD sensitivity increases as the thermal conductivity of the carrier
gas increases.
For high sensitivity analysis, use helium with a purity of 99.9995 % or more.
Thermal conductivity k (x10
-4
Wm
-1
K
-1
) at room temperature, 300 K
Gas
Thermal
conductivity
Gas
Thermal
conductivity
Simple
compounds
He 1499
Inorganic
compounds
CO2 166.2
H2 1815 H2O 181
N2 259.8
Organic
compounds
acetone 115
Ar 177.2 hexane 128
Reference gas
TCD cell
Filament
Output signal
Carrier gas
13 Detector
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13.2.2 Setting the detector
Press the [DET] key to display the Detector main screen shown in Fig. 13.3.2. Here, set
the detector temperature, the detector gas flow rate, etc.
When the detector is configured in the analytical line, the output signal settings appear
in the lower portion of the screen.
DETECTOR CONTROLLER
When a detector is set to On, its current and voltage are controlled.
When a detector is configured in an analytical line and set to On, the detector is con-
trolled and its signal monitored. However, the temperature increases up to the set value
if the detector is configured in the flow line even if detector control is Off.
TEMP
Set the detector temperature. The TCD sensitivity is proportional to the difference in
temperature between the detector and the filament. Accordingly, the sensitivity
increases as the detector temperature decreases. However, the detector is normally set
approximately 10 C higher than the final column oven temperature: this prevents con-
tamination in the TCD cell.
To set the maximum temperature limit, refer to 16.6.4 Setting the maximum
temperature limits.
Fig. 13.2.2 [DET] key main screen
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SIGNAL POLARITY
Selection: +/-, Default: +
When analyzing compounds with a thermal conductivity higher than the carrier gas,
baseline peaks are inverted (negative). When this occurs, switch to a polarity of - to
produce positeve peaks.
CURRENT
Range: 0200 mA, Default: 0 mA
The TCD sensitivity is approximately proportional to the cube of the current.
If the sensitivity is insufficient, increase the current within the range shown in
Fig. 13.2.3. The maximum operating current is determined by the detector temperature
and the carrier gas type. Keeping the current highre than necessary shortens the fila-
ments life and can cause baseline drift.
Fig. 13.2.3Maximum operating current
CAUTION
If the current is turned on before the carriergas + make up gas has
completely replaced the air, the filament can be blown.
Ensure that the current is set to 0 at first. Press the [SYSTEM] key
main screen, allow carrier gas to flow for approximately 10 minutes,
then set the current.
CAUTION
To avoid broken filaments and poor performance, set the current
below the valves indicated by the curves below.
Current
(mA)
200
100
0 100 200 300 400
TCD temperature(
)
Carrier gas He
Carrier gas H2
Carrier gas N2
Carrier gas Ar
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FILTER TIME CONSTANT
Selection: 4 ms/5 ms/10 ms/20 ms/50 ms/100 ms/200 ms/500 ms/1 s/2 s, Default: 1 s
This constant affects the processing of the detector signal.
As the time constant increases, noise as well as the peak height are reduced.
Select the optimum value in accordance with the peak half width. (Refer to 13.3 Filter
Signal Time Constant.)
SIGNAL OUTPUT PORT
Selection: Off/Ch1/Ch2/Ch3/Ch4, Default: (Channel is automatically assigned.)
Select the digital and analog signals output Channels. Four channels are available.
However, for analog output, only Ch1 and Ch2 are available as standard.
BACKGROUND SIG. SAVE
Background baseline signals can be saved for the purpose of background subtraction.
BACKGROUND SIG COMP.
Selection: Off /Buff 1/Buff 2, Default: Off
Subtracts the saved background signal baseline from the actual baseline. This pro-
duces a stable baseline despite considerable baseline fluctuations.
DET SIG SUBTRACTION
Selection: Off /DET#1/DET#2/DET#3/DET#4, Default: Off
Subtracts the detector signal of one detector from the signal of another detector.
For the details on background save and background compensation, refer to 13.4
Background Compensation.
SIGNAL RANGE
Selection: 1/10
-1
/10
-2
/10
-3
/10
-4
/, Default: 10
-1
-x
for a linear analog signal type. If the
data processing unit is saturated, for example, change the setting from 1 to 10
-1
,
from 10
-2
to 10
-3
SIGNAL ATTENUATION
Selection: 1/2
-1
/2
-2
/2
-3
/2
-4
/, Default: 2
-1
-x
for a wide analog signal type. If the
data processing unit is saturated, for example, change the setting from 1 to 2
-1
,
from 2
-2
to 2
-3
ANALOG SIGNAL TYPE
Selection: Linear/Wide, Default: Linear
Set this item when the GC is connected to a Chromatopac in analog format.
Wide ... Select Wide when connecting the GC to the C-R8A/C-R7A/C-R7A plus.
The GC outputs square root of the original signals to the Chromatopac, and the
received signals are squared in the Chromatopac.
When connecting the GC to a C-R7A/CR-7A plus for the first time, or replacing
the Chromatopac, set the detector signal output to Off and perform
calibration. (For the calibration procedure, refer to 2.2 Outputting Analog
Signals to the Chromatopac.)
Linear...Select linear when connecting the GC to any Chromatopac other than the C-
R7A/CR-7A plus.
When connecting the GC to the C-R8A/C-R7A/C-R7A plus and setting the
ANALOG SIGNAL TYPE to Linear, the optional signal cable (linear, P/N
221-47251-92) is required.
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13.2.2.3 PF menu
PF menu Description
Reference
section
Next Det
Toggles to the setup screeen of another detector.
The [DET] key can also be used to switch screens.

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13.2.3 TCD Zero Point Adjustment
Press [Zero Adj] (PF menu) on the [MONIT] key main screen to automatically start zero point
adjustment. When the TCD is used, the balance between sample and reference sides
becomes off after a column is replaced so the baseline may go off-scale. In this case, carry
out a zero-coarse-adjustment following the procedures described below.
TCD zero-coarse-adjustment is usually unnecessary when starting the unit after stopping it to leave the
lab on the previous day. It takes a while for the TCD baseline to stabilize. Even if the baseline is off-
scale when starting the unit, it goes close to zero when it stabilizes in many cases. Wait until the
baseline stabilizes.
1. Press [Zero Free] (PF menu) on the [MONIT] key main screen.
2. Turn the TCD zero-coarse-adjustment control shown on Fig. 13.2.4 to make the baseline close to
zero. It takes a while for the baseline to move after the control is turned. Turn the control slowly.
3. Press [Zero Adj] (PF menu) on the [MONIT] key main screen.
Fig. 13.2.4
NOTE
TCD zero -coarse
-adjustment control
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13.3Filter Signal Time Constant
Q Selecting the filter time constant
Normally, analysis can be performed with the time constant set to the default value (dual
FID, TCD: 1 s, single FID: 200 ms). In order to improve the S/N ratio, the time constant can
be changed by measuring the peak half width.
Fig. 13.3.1 shows the relationship between the peak half width and the time constant where
the S/N ratio is maximaized. For example, if the half width of a peak is 0.1 sec, the S/N
ratio is maximaized when the time constant is set to 20 ms.
Fig. 13.3.1Relationship between time constant and S/N ratio
Half width 10 s
Half width 1 s
Half width 0.1 s
4

m
s
5

m
s
1
0

m
s
2
0

m
s
5
0

m
s
1
0
0

m
s
2
0
0

m
s
5
0
0

m
s
1

s
2

s
Time constant
N
o
r
m
a
l
i
z
e
d

S
N

r
a
t
i
o
0
0.2
0.4
0.6
0.8
1
1.2
171
13 Detector
13.4 13.
GC-2014
13.4Background Compensation
If the baseline drifts considerably during programmed temperature analysis, the baseline drift can
be saved as a background baseline in GCs waveform memory (background save). Afterwards,
the background can be subtracted from the signal (background compensation). The below is
background compensation procedures.
1. Set background storage.
Select where the background baseline
should be saved on the [DET] key main
screen. Either Buff 1 or Buff 2 can be
selected.
BACKGROUND SIG. SAVE Buff 1 (or Buff 2)
BACKGROUND SIG. COMP. Off
2. Execute analysis without sample injection. Baseline fluctuation is saved in Buff 1 or
Buff 2 as background.
3. Set background compensation.
Set the background to be subtracted as the
baseline fluctuation on the [DET] key main
screen.
BACKGROUND SIG. SAVE Off
BACKGROUND SIG. COMP. Buff 1 (or Buff 2)
4. Inject a sample and execute analysis. A signal after subtracting the background is
outputted.
13 Detector
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Fig. 13.4.1 Example of programmed analysis without compensation
Fig. 13.4.2Example of programmed analysis with compensation
14.1 14.
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14 Diagnosis
14.1Standard Diagnosis
Each part of the gas chromatograph is checked for problems with the self-diagnosis function.
Perform the standard diagnosis periodicaslly to maintain optimal performance and prevent failures.
Select STANDARD DIAGNOSIS from the [DIAG] key main screen to display the Standard
Diagnosis screen shown in Fig. 14.1.1.
14.1.2 PF menu
Fig. 14.1.1 Diagnosis main screen
PF menu Description
Reference
section
Start Diag Starts standard diagnosis program. 14.1.5
Details
Displays result of the most recent diagnosis.
However, if standard diagnosis has not been executed since the power has
been turned on, default values are displayed.
[Print] (PF menu) prints out the displayed diagnosis results.
14.1.9
Diag Param
Determines setup values used for diagnostic reference and selects
diagnosis items.
14.1.3
14 Diagnosis
14.1 Standard Diagnosis
174
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14.1.3 Diagnosis Parameters
Press [Diag Param] (PF menu) from the Standard Diagnosis main screen to display the
Diagnosis Parameters screen shown in Fig. 14.1.2.
Select the items to be checked during the self-test.
Fig. 14.1.2Diagnosis setup screen
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14.1.4 Diagnosis parameter list
For each item, specify whether it is to be checked or tested. Test items are marked Yes.
Items which are ignored are marked No. Each item is marked either Yes or No. For
example, if the septum counter is marked Yes, both the INJ1 and INJ2 will be chacked.
COUNTER FOR SEPTUM
COUNTER FOR INSERT
Verifies whether the preset number of injections has been exceeded.
The ANALYSIS COUNTER limit is displayed.
CRG USE TIME
Verifies whether the valve On time exceeds the preset operating time.
The COOLANT CONSUMPTION limit is displayed.
TEMP SENSOR USE TIME
The operating time for the temperature sensor in use at 300 C or above is displayed. Refer
to the guidelines for operating time.
TEMP SENSOR DIAG
Verifies whether spiking noise has been generated, to detect deterioration of the platinum
sensor.
LCD USE TIME
Verifies whether the accumulated backlight ON time exceeds the preset operating time.
The limit 15,000 hours.
FAN USE TIME
Verifies whether the accumulated fan operating time exceeds the preset operating time.
The limit is 43,800 hours.
DC VOLTAGE (5 VDC, 24 VDC, -15 VDC, FTD 24 VDC)
Verifies whether each DC voltage has exeeded its limit.
ROOM TEMPERATURE
Verifies whether the current room temperature is within the optimal range.
The range is 5 to 40 C.
ATMOSPHERIC PRESS
Verifies whether the atmospheric pressure is within the optimal range.
PRIMARY PRESS
Verifies whether the gas supply pressure is within the maximum set pressure.
CPU REGISTER
REAL TIME CLOCK REGISTER
Verifies that each register is correctly written and read.
DETECTOR ROM
Verifies that the data saved in the detector ROM is read correctly.
DETECTOR ADC REGISTER
Verifies that the data saved in the detector A/D converter register is read correctly.
DETECTOR HV SOURCE
Verifies whether the detector high voltage power supply is within the threshold.
CAUTION
At the time of Diagnosis, set the Split mode to SPLIT. When WBI
column is used, set the split mode to DIRECT.
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DETECTOR IGNITE
Checks that the ignition pulse is normal.
DETECTOR IGNITION
Verifies whether the ignition operation is normally executed.
ECD FREQUENCY
Verifies whether the frequency of the pulse voltage applied to the ECD is below the limit.
CARRIER GAS ROM, DETECTOR GAS ROM, APC ROM, AMC ROM
Verifies whether the data saved in the ROM on the flow controller PCB can be read correctly.
CARRIER GAS AD CONVERTER, DETECTOR AD CONVERTER,
APC AD CONVERTER, AMC AD CONVERTER
Verifies whether the contents of the A/D converter on the flow controller PCB can be read
correctly.
GAS CONTROL
Checks if carrier gas, detector gas, AUX APC, and AUX AMC are normally controlled.
OVER TEMP PROTECTION
Ensure that the overheat protection circuit is normal.
CPU PERIPHERAL
RESET IC
Verifies that the reset circuit works normally.
WATCH DOG TIMER
Ensures that the IC which checks for software problems is functioning normally.
ROM
Checks that the ROM is intact.
RAM
Verifies whether the RAM can be correctly written and read.
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14.1.5 Starting the diagnosis
Press [Start Diag] (PF menu) from the standard diagnosis main screen shown in Fig. 14.1.1
to start diagnosis and to display the screen shown in Fig. 14.1.3.
14.1.6 PF menu
Fig. 14.1.3 Starting the Diagnosis
PF menu Description
Reference
section
Stop Diag
Stops the diagnosis.
If the program is stopped, items not yet executed are canceled.
14.1.7
Reset
Before stariting the IC diagnosis, the message Reset IC will be checked.
Press PF2 key. appears. Press [Reset] (PF menu) to check whether reset
IC is functioning normally.

Reset IC
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14.1.7 Stopping/exiting the diagnosis
Press [Stop Diag] (PF menu) during diagnosis to display the diagnosis stop screen shown in
Fig. 14.1.4.
When the diagnostics are allowed to complete, the total diagnosis results (Test Result) and
the number of abnormalities (Number of NG) are displayed.
14.1.8 PF menu
Fig. 14.1.4Diagnosis stops
PF menu Description
Reference
section
Details
When the diagnosis is stopped, diagnosis results up to that time are dis-
played.
When the diagnosis ends, the diagnosis results of all items are displayed.
Press [Print] (PF menu) to print out the displayed diagnosis results.
14.1.9
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14.1.9 Diagnosis results
Press [Details] (PF menu) from the screen shown in Fig. 14.1.4 once the standard diagnosis
is have stopped or ended; the Test Result screen shown in Fig. 14.1.5 appears.
Press [Details] (PF menu) from the standard diagnosis screen shown in Fig. 14.1.4 to
display the results of the last test since the power was turned on. Once the power is turned
off, the diagnosis results are cleared.
14.1.10 PF menu
Fig. 14.1.5 Diagnosis results
PF menu Description
Reference
section
Print Prints out the results of the diagnosis to a Chromatopac.

14 Diagnosis
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Q diagnosis results
Good : Displayed when the diagnosis result satisfies the requirements.
Not Good : Displayed when the diagnosis result does not satisfy the require-
ments.
N/T (= Not Tested) : Displayed when the diagnostic test was stopped or when an item
is excluded from the test.
N/A (= Not Applicable) : Displayed when diagnostic test is disabled for the item (ignition
test for a TCD, for example).
N/S (= Not Selected) : Displayed when the diagnosis were not perfomed on an item
because it has not been configured in an analytical line.
Certain diagnosis items can be performed for components which
have not been configured. For example, for a detector not
configured in any line, Make Up Gas Control is not checked, but
its detector ROM check can be executed.
N/I (= Not Installed) : Displayed when the diagnosis item is not installed.
Q Troubleshooting items which are Not Good
Diagnosis item Countermeasures
SEPTUM COUNTER
Replace the septum. (Refer to 4.4 Septum in the
operation manual.)
INSERT COUNTER
Replace the glass insert. (Refer to 4.6 Glass
Insert in the operation manual.)
ROOM TEMPERATURE Check the operation range.
ATMOSPHERIC PRESS Check the operation range.
GAS PRIMARY PRESS
Increase supply pressure from the gas cylinder.
For example, adjust the regulator.
DETECTOR IGNITION Refer to 5.1 Troubleshooting operation manual.
ANY OTHER ITEM Contact your Shimadzu representative.
181
14 Diagnosis
14.2 14.
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14.2Log Reading Menu
Select 2. LOG READING MENU from the [DIAG] key main screen to display the Log Read-
ing Menu screen shown in Fig. 14.2.1.
GC OPERATION LOG
Displays the power On/Off log and the system On/Off log.
ANALYSIS LOG
Displays the analysis log. This log records whether analyses were finished and whether con-
trols deviated from their target valves.
PARAMETER LOG
Displays the key operation log and the parameter change log.
ERROR LOG
Displays the log of displayed error messages.
DIAGNOSTIC LOG
Displays the diagnosis log.
Fig. 14.2.1 Log reading menu main screen
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14.2.3 GC Operation log
Select 1. GC OPERATION LOG to display the system On/Off log and the heater On/Off
log.
(1) Screen description
Select 2. LOG READING MENU from the [DIAG] key main screen, then select 1. GC
OPERATION LOG. The screen shown in Fig. 14.2.2 appears.
Up to 50 logs are stored. If the number of logs exceeds 50, existing logs are deleted
starting with the oldest.
If there are more items than can be displayed on one screen, scroll through the screen using the left
and right arrow keys.
(2) PF menu
Fig. 14.2.2 Operation log screen
PF menu Description
Reference
section
Clear Log
Deletes all displayed logs.
When [Clear Log] (PF menu) is pressed, the screen changes and the
message Clear log with PF2 appears. Press [Clear Log] (PF menu) to
clear the log.

Print Prints the the operation log to a Chromatopac.

NOTE
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14.2.4 Analysis log
When 2. ANALYSIS LOG is selected, the analysis log is displayed. This log records
whether analyses were allowed to finish and whether monitored valves exceeded their set
valves.
Select 2. LOG READING MENU from the [DIAG] key main screen, then select 2.
ANALYSIS LOG to display the screen shown in Fig. 14.2.3.
25545 logs are saved. The number of saved logs depends on the size of each log. If
the number of logs exceeds the capacity, existing logs are deleted starting from the
oldest.
During a temperature program, if the rate of temperature increase is too great, the GC may not be
within the Ready range. When this occurs, the analysis log shows Fail.
(2) PF menu
Fig. 14.2.3 Analysis log screen
PF menu Description
Reference
section
Clear Log
clear the log.

Print Prints the analysis log to a Chromatopac.

NOTE
NOTE
14 Diagnosis
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(3) Analysis log details
On the analysis log main screen, use the cursor to select a log item with on the right
and press the [ENTER] key to display the screen shown in Fig. 14.2.4.
The screen provides details about each error when the monitored value deviated from
the set value, and for which an alarm or warning was issued during the analysis.
Fig. 14.2.4 Details screen
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14.2.5 Parameter log
When 3. PARAMETER LOG is selected, parameter names and new values are
displayed when parameters are changed. In addition, the direct operation of valves, etc.
are also displayed.
Select 2. LOG READING MENU from the [DIAG] key main screen, then select 3.
PARAMETER LOG. The screen shown in Fig. 14.2.5 appears.
Up to 50 logs are saved. If the number of logs exceeds 50, existing logs are deleted
starting from the oldest.
(2) PF menu
Fig. 14.2.5 Parameter log screen
PF menu Description
Reference
section
Clear Log
clear the log.

Print Prints the parameter log to a Chromatopac.

NOTE
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14.2.6 Error log
When 4. ERROR LOG is selected, the log of all errors which have been displayed is
shown.
Select 2. LOG READING MENU from of the [DIAG] key main screen, then select 4.
ERROR to display the screen shown in Fig. 14.2.6.
(2) PF menut
Fig. 14.2.6 Error log screen
PF menu Description
Reference
section
Clear Log
clear the log.

Print Prints the error log to a Chromatopac.

NOTE
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14.2.7 Diagnostic log
When 5. DIAGNOSTIC LOG is selected, the resulst of the standard diagnosis are
displayed. The results of the last diagnosis are shown in the [Details] (PF menu) screen
described in 14.1 Standard Diagnosis.
Select 2. LOG READING MENU from of the [DIAG] key main screen, then select 5.
DIAGNOSTIC LOG. The screen shown in Fig. 14.2.7 appears.
If there are more items than items than can be displayed on one screen, scroll through the screen
using the left and right arrow keys.
(2) PF menu
Fig. 14.2.7 Diagnosis log screen
PF menu Description
Reference
section
Clear Log
clear the log.

Print Prints the diagnosis log to a Chromatopac.

NOTE
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14.3Analysis Counter
Use the analysis counter to set the replacement timing of the septum, and the glass insert, when
the counter exeeds the limit, an error message is displayed.
Select 3. ANALYSIS COUNTER from the [DIAG] key main screen to display the screen
When the dual INJ (DINJ) is used, the number of analyses is indicated as follows:
Dual mode: The value counted on the L (left) inlet is indicated when the signal polarity of the detector
(DFID, DTCD) is +. The value counted on the R (right) inlet is indicated when the signal polarity is -.
Single mode: The value counted on the selected inlet (L or R) is indicated.
(a) Dual INJ (b) SPL
Fig. 14.3.1 Analysis counter screen
Computer for
Septum
Computer for
Insert
NOTE
14 Diagnosis
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AOC WAIT
Selection: Yes/No, Default: No
When the threshold is exceeded during batch processing, select Yes to temporarily pause,
the AOC operation when the analysis counter has exeed the limit.
USE COUNTER
ANALYSIS COUNTER
Selection: 0
SETTING TO WARN
Range: 09999, Default: 100
The septum/glass insert replacement interval depends on the type of analysis. Periodically replace the
septum and the glass insert even if the warning message is not displayed.
14.3.3 PF menu
PF menu Description
Reference
section
Reset Resets analysis number counter of the current item.

Next Displays the setup screen of the analysis counter of another injection port.

NOTE
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14.4Coolant Consumption Counter
The coolant consumption display allows you to confirm the total time that the CRG has been On
(The CRG is an optional accessory.)
If the coolant consumption exceeds the time limit specified (setting to warn), a warning message
is displayed. Replace the gas supply.
Select 4. COOLANT CONSUMPTION from the [DIAG] key main screen to display the
Coolant consumption screen shown in Fig. 14.4.1.
Fig. 14.4.1 Coolant consumption sets screen screen
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USE COUNTER
Selection: Yes/No, Default : Yes
CONSUMPTION
Default: 0 min
The total time that the CRG is On is displayed.
Refer to 15.5 Setting the CRG Parameters.
SETTING TO WARN
Range: 09999 min, Default : 100 min
The coolant consumption time depends on the gas cylinder volume and the number of analyses which
requier CRG. Set the warning time according to the analysis conditions.
14.4.3 PF menu
PF menu Description
Reference
section
Reset Resets the Use counter.

NOTE
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14.5Standard Installation Test
After the system has been installed by your Shimadzu representative, the standard installation
test is performed to check whether the system is functioning properly.
Select 5. STANDARD INSTALLATION from the [DIAG] key screen to display the Standard
installation screen shown in Fig. 14.5.1.
The installation test can be performed at any time to check for proper functioning. From this
screen, load the analytical conditions of the standard installation test.
14.5.2 PF menu
Fig. 14.5.1 Standard installation test main screen
PF menu Description
Reference
section
Load
Automatically sets the analytical conditions of the standard installation test.
When [Load] (PF menu) is pressed, TEST is displayed for the used file
name.

Unload Returns analytical conditions to their former status.

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14.5.3 Test procedure
(1) Specify the analytical conditions file of the standard installation test.
Example: Load File 1 using [File] (PF menu) of the [SET] key.
(2) Configure the injection port and the detector used to execute the standard installation
test in an analytical here.
However, if two or more analytical lines have been configured, the lowest No. analytical
line is set with the test conditions.
In the standard installation test, only one detector can be set per analytical line. If two or
more detectors are set, an error message appears.
(3) Set the dimensions of the column installed.
Example: Set the dimensions of the column using [Column] of the [FLOW] key.
(4) Press [Load] (PF menu) to load the analytical conditions of the standard installation test.
(5) If the analytical condition need to be changed for the installation test, change the
parameters.
(6) Make an injection, then verify whether the data has been acquired correctly.
(7) When analysis finishes, press [Unload] (PF menu) to return the analytical conditions to
their former status.
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14.6Peak Generator
Select 6. PEAK GENERATOR to generate electronic peaks to confirm of the operation of the
data processing unit.
Select 6. PEAK GENERATOR from the [DIAG] key screen to display the Peak generator
PEAK GENERATOR
Range: On/Off, Default: Off
MODE
Range: Noise/No Noise/Trunc, Default: Noise
Ch1Ch4 STANDARD SIGNAL
14.6.3 PF menu
Fig. 14.6.1 Peak generator setup screen
PF menu Description
Reference
section
Peak Info
Specify the parameters (retention time, full width at half height and peak
height) of the peaks to be generated.

15.1 15.
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15 Optional Devices
15.1Auto Injector Parameters
From the gas chromatograph, specify the parameters of the Shimadzu AOC-20i Auto Injector and the
AOC-20s Auto Sampler Carousel, which automatically inject liquid samples into the gas chromatograph.
For detailed setting procedures, refer to AOC-20 users manual.
After installing the auto injector on the GC, access the line configuration screen from the
[SET] key, and then select AOC 1 for the analytical line. (Refer to 8.3 Specifying the
Analytical Flow Line Components ([Line Config])) Then, press the [OPTION] key. If the
screen shown in Fig. 15.1.1 does not appear, press the [OPTION] key again or [NEXT] (PF
menu) to display it.
The screen toggles among AOC parameters AUX temperature AUX APC AUX AMC
CRG screens in this order.
Q AOC STATUS
The AOC status can be monitored.
Fig. 15.1.1 AOC setup screen
Screen display Description
Inactive AOC is not operating.
Taking vial A vial is being picked up from the tray.
Preparation AOC is operating (before injection).
Rinse AOC is operating (after injection).
Putting vial A vial is being returned to the tray.
Wait AOC is waiting for analysis.
The AOC status is displayed.
15 Optional Devices
15.1 Auto Injector Parameters
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SAMPLE WASH
Set the number of times to rinse the syringe with sample before injection.
NUMBER OF INJECTION
Set the number of times the sample should be injected.
SAMPLE SIZE
Range: 0.18.0 l, Default: 1.0 l
Set the sample injection amount.
PRE SOLVENT WASH
Set the number of times to rinse the syringe with solvent before injection.
This item is valid only when the injection mode is set to 0 (normal).
SOLVENT WASH
Set the number of times to rinse the syringe with solvent after injection.
PUMPING
Set the number of times to raise and lower the plunger with the needle inside the sample to
eleminate syringe air bubbles.
VISCOSITY
Range: 0.099.9 sec, Default: 0.2 sec
During rinsing with sample and pumping, the system waits for the specified period of time.
When aspirating sample before injection, the system waits for either the valve set here or 4
seconds, which ever is longer.
The wait time during rinsing with solvent is always 0.2 seconds.
DWELL TIME
Range: 0.099.9 sec, Default: 0.0 sec
Set the length of time for the syringe to remain in the injection port after injection.
INJ. SPEED (PLUNGER)
Selecton: Slow/Middle/Fast, Default: Fast
Specifies the plunger speed during injection.
AOC POWER
Turns the AOC power on and off (built-in GC-2014 power supply).
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15.1.3 PF menu
PF menu Description
Reference
section
Start Starts AOC. The GC also starts when AOC injects a sample.

Stop
Temporarily stops the AOC.
If [Start] (PF menu) is pressed in stop status, the AOC resumes the opera-
tion before [Stop] (PF menu) was pressed.

Priority Sets up a Priority analysis. 15.1.4
Other Para Sets AOC options and customization. 15.1.7
Sampler Sets the auto sampler, sub injector and bar code reader. 15.1.10
Reset Resets AOC to the status before control was started.

Upload
Loads parameters from the AOC to the AOC setup screen of the gas
chromatograph.

Print Prints the parameters on the Chromatopac.

Next
Toggles the screen among AOC parameters AUX temperature AUX
APC AUX AMC CRG screens in this order.

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15.1.4 AOC priority analysis
Select [Priority] (PF menu) from the AOC main screen to display the AOC priority sample
The batch can only be interrupted when the AOC is operating.
Enter the sample injection No., and press [Set] (PF menu).
INJECTION SAMPLE
INJECTION SAMPLE NUMBER
Enter the sample vial No. designated for priority analysis.
When an auto sampler carousel is not in use,
Short rack No. 16
Long rack No. 112
When an auto sampler corousel is installed, No. 1150 (maximum)
When an auto sampler carousel, the allowable vial No. range depends on the vial rack type
and the number of racks. A valve of 0 (default) indicates no priority sample.
Fig. 15.1.2 Priority analysis setup screen
NOTE
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15.1.6 PF menu
15.1.7 Other AOC parameters
Select [OtherPara] (PF menu) from the AOC main screen to display the other parameters
Specify options and AOC custom parameters.
PF menu Description
Reference
section
Set
Analyzes the vial No. specified after the analysis of the current sample is
finished.

Fig. 15.1.3Additional AOC parameter setup
15 Optional Devices
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15.1.8 Other AOC Parameter
INJ. SPEED (SYRINGE)
Selection: Slow/Fast, Default: Fast
Set the syringe injection speed.
USING 3 SOLVENT VIALS
Specifies whether three solvent vials are present and the autosampler carousel is not in use.
This item is only available when USE OF THE SAMPLER in [Sampler] (PF menu) is set to
Not Use.
SOLVENT SELECT
Selection: All/A only/B only/C only, Default: All
This item is available when USING 3 SOLVENT VIALS is set to Yes or USE OF THE
SAMPLER in [Sampler] (PF menu) is set to Use.
All: Three solvent types are used.
A only: Only the solvent in the vial A is used.
B only: Only the solvent in the vial B is used.
C only: Only the solvent in the vial C is used.
For the details, refer to Fig. 3.4.1 in 3.4 Auto Sampler in the AOC-20 Users Manual.
AIR SUCTION
Set whether or not 1 l of air is aspirated into the siringe after aspirating sample.
This type of injection is useful for samples with a wide boiling point range when compound
discrimination problems can occur.
PLUNGER SUCTION SPEED
Selection: Slow/Middle/Fast, Default: Fast
Set the plunger speed during sample injection.
SPEED OF PLUNGER
Selection: Slow/Middle/Fast, Default: Fast
Set the plunger speed during rinsing with sample or pumping.
SYRINGE HEIGHT ( )
Range: 020 mm, Default: 0 mm
Set the syringe height when it moves down to a sample vial (moves syringe up from default).
SYRINGE HEIGHT ( )
Range: 02 mm (1.5 ml vial)/010 mm (4 ml vial), Default: 0 mm
Set the syringe height when it moves down to a sample vial (moves syringe down from
default).
SYRINGE HEIGHT (INJ)
Range: 022 mm, Default: 0 mm
Set the syringe height when it moves down during sample injection (moves syringe up from
default).
CAUTION
When the column initial temperature is high or when a PEG-based,
polar column is used, the column life may be shortened by injecting
air.
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MULTI-INJ
Set the number of times to inject each sample.
KINDS OF VIALS
Selection: 1.5 ml/4 ml, Default: 1.5 ml
Specyfy the vial type.
RACK
Selection: Short/Long, Default: Short
Set the rack type.
KINDS OF THE SYRINGE
Selection: 10 l/50 l/250 l, Default: 10 l
Set the syringe type.
SUCTION VOLUME FOR WASHING
Selection: 80 %/60 %, Default: 80 %
Set the aspiration volume during sample wash and pumping.
RACK POSITION
Set the rack position while sampler is used.
15.1.9 PF menu
PF menu Description
Reference
section
Inj Mode For details, refer to 3.3.3 Injection mode in AOC-20 Users Manual.

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15.1.10 Auto-sampler carousel and other optional parameters
Select [Sampler] (PF menu) from the AOC main screen to display the sampler screen shown
in Fig. 15.1.4.
Specify the options installed on the AOC, such as sampler carousel.
When AOC1 and AOC2 are selected for the analytical line in Line configuration of the
[SET] key, both USE OF THE SAMPLER and USE OF THE SUB AOC are automatically
set to Use.
USE OF THE SAMPLER
Selection: Use/Not Use, Default: Not Use
USE OF THE SUB AOC
Selection: Use/Not Use, Default: Not Use(Set to Not Use because it is not used by GC-2014.)
BAR CODE READER
Selection: Use/Not Use, Default: Not Use
Select Use when the Bar Code reader is installed.
Fig. 15.1.4Sampler carousel and other options setup
203
15 Optional Devices
15.2 15.
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15.2Setting AUX Temperature
Temperature controller used for parts other than the column oven, injection port, and detector
can be set.
When an optional device such as heater is installed, press the [OPTION] key to display the
screen shown in Fig. 15.2.1. If a different screen appears, press the [OPTION] key again or
[NEXT] (PF menu) to display the correct screen.
TEMPERATURE SETTING VALUE
15.2.3 PF menu
Fig. 15.2.1 Main screen to set AUX temperature
PF menu Description
Reference
section
Print Prints each temperature through a Chromatopac. 17.1
NEXT

On/Off Displays a sub screen to set a used unit to On. 15.2.4
15 Optional Devices
15.2 Setting AUX Temperature
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15.2.4 On/Off setting
When On/Off (PF menu) is pressed on the main screen to set AUX temperature, the
screen to set On/Off appears.
15.2.5 On/Off parameter list
TEMPERATURE CONTROL
Temperature is controlled when On is selected.
Fig. 15.2.2 Screen to set On/Off of AUX temperature
205
15 Optional Devices
15.3 15.
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15.3Setting the AUX APC Parameters
The pressure, the flow rate and the gas type can be set for the AUX APC.
When the optional AUX APC is installed, press the [OPTION] key to display the screen
shown in Fig. 15.3.1. If a different screen appears, press the [OPTION] key again or [NEXT]
(PF menu) to display the correct screen.
Fig. 15.3.1 AUX APC main screen
15 Optional Devices
15.3 Setting the AUX APC Parameters
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PRESS
Range: 0.0400.0 kPa, Default: 100 kPa
Set the pressure when the control mode is set to PRESS.
GAS TYPE
Set the type of gas supplied to the APC. If the gas type is set incorrectly, the flow rate can
not be set as specified in FLOW mode. This is because a restrictor is used to calculate the
flow rate.
15.3.3 PF menu
PF menu Description
Reference
section
Offset
Performs offset calibration of APC sensor to improve the reproducibility of
results.
3.6
Next
Toggles among AOC parameters AUX temperature AUX APC AUX AMC
CRG screens

On/Off Set APC to be used to On. Default value is On.

207
15 Optional Devices
15.4 15.
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15.4Setting the AUX AMC Parameters
Flow rate and gas type can be set for the AUX AMC.
When the DAFC unit on other configurations is set to "AMC, LR" and/or the optional AUX
AMC is installed, press the [OPTION] key to display the screen shown in Fig. 15.4.1. If a dif-
ferent screen appears, press the [OPTION] key again or [NEXT] (PF menu) to display the
correct screen.
Fig. 15.4.1 AUX AMC main screen
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15.4 Setting the AUX AMC Parameters
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FLOW RATE
Set the flow rate when the control mode is set to FLOW.
GAS TYPE
Set the type of gas supplied to the AMC. This parameter is used to calculate the flow rate.
15.4.3 PF menu
PF menu Description
Reference
section
Offset
Performs offset calibration of AMC sensor to improve the reproducibility of
results.

Next
3.6
On/Off Set the AMC to be used to On. Default is On.
209
15 Optional Devices
15.5 15.
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15.5Setting the CRG Parameters
The CRG (option) allows temperatures below room temperature to be set. The CRG can be
connected to the column oven or the INJ2.
Press the [OPTION] key from the [OPTION] key main screen, or press [NEXT] (PF menu)
until the CRG screen, shown in Fig.15.3.1, appears.
The screen toggles among AOC parameters setting AUX temperature AUX APC
AUX AMC CRG screens in this order.
If the CRG is turned off after a negative temperature valve has been set, the temperature cannot be
achieved, and the GC cannnot become ready. When turning off the CRG, ensure that the temperature
valve is set properly.
Fig. 15.5.1CRG main screen
NOTE
15 Optional Devices
15.5 Setting the CRG Parameters
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COLUMN OVEN
VALVE Selection: On/Off, Default: Off
CRG Selection: Use/Not Use, Default: Not Use
When the CRG is connected to the column oven, the column oven temperature
control range is extended to -99.0 +400.0 C from (room temperature + 4 C)
+400.0 C.
When using the CRG, set VALVE to On and CRG to Use.
When using valve control only, set VALVE to On and set CRG to Not Use.
INJ 2
VALVE Selection: On/Off, Default: Off
CRG Selection: Use/ Not Use, Default: Not Use
When the PTV is installed on INJ2, the injection port temperature control range is
extended to -99.0+400.0 C from 0.0400.0 C
When using the CRG, set VALVE to On and CRG to Use.
When using valve control only, set VALVE to On and set CRG to Not Use.
15.5.3 PF menu
PF menu Description
Reference
section
Next

16.1 16.
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16.1Time Scheduler
Use the Time scheduler to establish a weekly or daily schedule of automated GC operations.
16.1.1 description Screen
Select 1. TIME SCHEDULER from the [FUNC] key main screen to display the Time sched-
uler menu shown in Fig. 16.1.1.
MODE
Select whether the same schedule will be executed every day or a different schedule will be
executed on each day of the week.
EDIT
Edit the schedule.
START/STOP
Set the schedule start/stop procedure.
COPY
Copy the contents of a schedule to a specified schedule.
DELETE
Delete the contents of a specified schedule.
Fig. 16.1.1Time scheduler menu
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16.1.3 Setting the mode
Select 1. MODE from the time scheduler menu to display the mode setup screen shown in
Fig. 16.1.2.
Select whether to use the same schedule every day or to use a different schedule on each
day of the week. Up to 8 schedules can be set with the time scheduler.
When the time scheduler is operating, the mode cannot be changed.
Q Schedule number and day of the week
The table below shows the relationship between the schedule number and the day of the
week.
Fig. 16.1.2 Mode setup screen
Mode 1
(schedule number)
Mode 2
(day)
No. 0 Sun.
No. 1 Mon.
No. 2 Tue.
No. 3 Wed.
No. 4 Thu.
No. 5 Fri.
No. 6 Sat.
No. 7

NOTE
The schedule number can
be set only when in Number
mode.
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16.1.4 Editing a time schedule
Select 2. EDIT from the time scheduler menu to display the schedule number or the day of
the week setup screen shown in Fig. 16.1.3. Before editing a schedule, select the schedule
number or the day of the week, and press [Edit] (PF menu). Then, the schedule edit screen
shown in Fig. 16.1.4 appears.
You do not have to set schedules in the order of execution time. After editing time schedules,
they are automatically sorted. More than one schedule can be set to the same time. These
schedules will be executed at the same time.
16.1.5 PF menu
Fig. 16.1.3Schedule number selection screen Fig. 16.1.4 Schedule edit screen
PF menu Description
Reference
section
New Creates a new time schedule. 16.1.6
Del Line Deletes a schedule line at the current cursor position.
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16.1.6 Creating a new time schedule
Select [New] (PF menu) from the time schedule screen to display the Time Schedule screen
Set an item using the [] and [] keys and [ENTER] key. When [Finish] (PF menu) appears
after you have set items, press [Finish] to validate the schedule.
In the upper half of the screen, the contents of the set schedule are displayed. In the lower
half of the screen, the schedule edit screen is displayed.
Up to 100 lines are available per schedule.
The schedule execution time range is from 00:00 to 23:59. The unit is 1 minute.
16.1.7 PF menu
Fig. 16.1.5 Creating a new schedule
PF menu Description
Reference
section
Finish Validates the time schedule.

Prev Page Returns to previous setup screen.

Next Page
Moves to next item.
The cursor can also be moved to next item by pressing [ENTER] key.

Cancel Cancels the time schedule currently being created.

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16.1.8 Parameters available in the time scheduler
16.1.9 Changing schedule parameters
To change the contents of an existing time schedule, move the cursor using the [ ] and [ ]
keys to select the schedule to be changed, and press the [ENTER] key.
To change the time:
When the Time Schedule select screen appears, enter new numeric values and press
[Finish] (PF menu), if you would like to change only the time.
To change the parameters:
Move the cursor, change the parameter, and then press [Finish] (PF menu) to complete
the change.
To cancel any changes:
If you have changed the schedule but would like to return to the former schedule, press
[Cancel] (PF menu) before pressing [Finish] (PF menu). The schedule returns to its former
status.
Parameter Description
Stop
NUMBER
OF
TIMES
OF RUN
Time
scheduler
stop
Specifies the number of times the program can execute before
the schedule stops or switches to another file. If greater than 2,
The choices are Continuous or Pause at each run. For an
AOC, select Continuous. When Pause at each run is
chosen, the program executes at set intervals continuously at
set intervals.
If another program (such as a temperature program) is running
when time schedule execution time expires, priority is given to
the running program. When the current program finishes, the
time schedule stops or file is changed to another file.
Schedule
0-9 Load
GC Start/Stop Sets start/stop of gas chromatograph.
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16.1.10 Time schedule example
Example:7:00 System starts.
19:00 System stops.
First program Screen display
1. Time: 7:00
2. Start/stop
3. Start
Second program
4. Time: 19:00
5. Start/stop
6. Stop
7. Setting is completed.
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16.1.11 Starting/stopping a time schedule
Select 3. START/STOP from the time scheduler menu when no time schedule is executing
to display the screen shown in Fig. 16.1.6.
Select 3. START/STOP while a time schedule is executing to display the screen shown in
Fig. 16.1.7.
16.1.12 PF menu
Fig. 16.1.6 Schedule start screen Fig. 16.1.7 Schedule stop screen
PF menu Description
Reference
section
Start
Starts a time schedule.
This item is displayed when no time schedule is running.
If mode is set to number, the same schedule will be executed on
following day and beyond when schedule finishes.
If mode is set to day, the schedule for the current day is executed, and
the schedule for each day will be executed on the following day and
beyond.
Next
Runs the selected schedule on the following day.
If mode is set to day, the schedule for the next day is executed.

Stop
Stops the current schedule.
This item is displayed when a time schedule is running.

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16.1.13 Copying and deleting a time schedule
Select 4. COPY or 5. DELETE from the time scheduler menu screen to display the time
schedule copy screen or the time schedule delete screen shown in Fig. 16.1.8 or Fig. 16.1.9.
To copy, specify the copy source schedule and the copy destination schedule, then press
[Copy] (PF menu).
To delete, specify a schedule number to be deleted, then press [Delete] (PF menu).
A currently running schedule cannot be copied or deleted.
Fig. 16.1.8 Schedule copy screen Fig. 16.1.9 Schedule delete screen
NOTE
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16.2 16.
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16.2Batch Schedule
Use the batch schedule to continuously and automatically perform analyses.
A batch is useful for switching methods automatically during the analyses.
Select 2. BATCH from the [FUNC] key screen, the Batch screen shown in Fig. 16.2.1
appears.
Q AOC status
The AOC status is displayed on the Batch screen..
Fig. 16.2.1 Batch schedule screen
Screen display Description
Inactive AOC is not operating.
Taking vial Auto sampler arm is picking up a vial.
Preparation AOC is operating (before injection).
Rinse AOC is operating (after injection).
Putting vial Auto sampler arm is returning a vial to the
tray.
Wait AOC is waiting for analysis.
The AOC status is
displayed.
16.2 Batch Schedule
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Vial Initial No. and final vial No.
Example: 1-9 (Analysis starts from vial No. 1 and ends at vial No. 9.)
GC GC method file for analyses
DP Channel No. of chromatopac and file No.
Example: 1-5 (Channel 1 and data processing file No. 5 are used.)
This setting is ignored when using GC solution software.
#INJ Number of times to inject
Mk U is displayed when SAMPLE TYPE is set to Unknown.
S is displayed when SAMPLE TYPE is set to Standard.
CMD S is displayed when SLOPE TEST is set to On.
C is displayed when CLEAN UP is set to On.
16.2.3 PF menu
PF menu Description
Reference
section
Start Starts the batch schedule.

Stop Stops the batch schedule.

New Creates a new batch schedule.
16.2.4
16.2.7
Del line Deletes the line at the current cursor position.

Print Prints the schedule to a Chromatopac.

16.2 Batch Schedule
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16.2.4 Creating a new batch schedule
Select [New] (PF menu) from the batch schedule screen to display the new batch schedule
Set an item using the [ ] and [ ] keys and [ENTER] key. When [Finish] (PF menu)
becomes available and the items have been set, press [Finish] to validate the schedule.
At the top of the screen, the contents of the set schedule are displayed. At the bottom of the
screen, the schedule can be edited.
Up to 100 lines are available per schedule.
Fig. 16.2.2 New batch schedule screen
16.2 Batch Schedule
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START VIAL NO.
Range:
1
Default: 0
FINAL VIAL NO.
Range:
1
Default: 0
1: With no auto sampler
Short rack ... 16
Long rack ... 112
With auto sampler 1150 (maximum)
When the auto sampler is used, the possible depends on the vial rack type and the number
of racks.
The default, 0, indicates that the setting is not given.
SAMPLE
Inject sample
The specified sample vial No. is analysed.
Without sample
Vials are not used for samples. Instead samples are introduced from a gas sampler with a
valve.
GC FILE NO.
Range: FILE 09, Default: FILE0
Set the file No. of the GC method to be used.
CHANNEL NO.
Range: Ch1/Ch2, Default: Ch 1
Set the channel No. connecting the GC to the Chromatopac. This setting is ignored when
using GC solution software.
DATA PROCESSOR FILE NO.
Range: FILE 09, Default: FILE0
Specify a date processor (Chromatopac) date integration file. This setting is ignored when
using GC solution software.
NUMBER OF INJECTION
Set the number of times to inject each sample.
SAMPLE TYPE
Unknown Select this item to analyze a sample of unknown concentration.
Analyze a standard and create a calibration curve before analyzing an unknown
sample.
Standard Select this item to analyze a standard of known concentration.
SLOPE TEST
When On is selected, the slope test is performed before running the batch schedule.
CLEAN UP
When On is selected, clean up is performed before running the batch schedule.
16.2 Batch Schedule
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16.2.6 PF menu
16.2.7 Editing a batch schedule
To change an existing batch processing schedule, move the cursor using the [ ] and [ ]
keys to the schedule to be edited and press the [ENTER] key. The schedule to be edited
appears on the edit screen.
To change the vial number, enter the new number from the edit screen and press [Finish]
(PFmenu).
To change the other parameters, move the cursor and make the change from the edit
screen, and then press [Finish] (PFmenu).
To cancel the edits and restore the original batch schedule, press [Cancel] (PFmenu) before
pressing [Finish](PFmenu).
PF menu Description
Reference
section
Finish Validates the schedule.


Next Page Moves to setup screen for next item.

Cancel Cancels the schedule being created.

16.2 Batch Schedule
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16.2.8 Batch processing Setup example
Example Sample vials No. 1 to 3 are analyzed. The GC method file No. 2 is used. The
Chromatopac data processing file No. 0 is set to Ch 1.
A standard of known concentration is injected once.
Clean up is performed, but the slope test is not performed.
Screen display
1. Start vial No.: 1
Final vial No.: 3
2. GC file No.: FILE2
3. Data processing file No.:
Ch 1, FILE0
4. Number of injections: 1
Sample type: Standard
5. Slope test: Off
Clean up: On
6. The batch is set up.
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16.3Time Program
Use a time program to execute zero point adjustment and relay control during analysis.
Select 3. TIME PROGRAM from the [FUNC] key screen to display the time program
A time program starts as soon as analysis starts.
Time programs do not need to be set up in order. After you finish editing time programs, they
are automatically sorted.
More than one step can be set for the same time. The specified actions are executed at the
same time.
16.3.2 PF menu
Fig. 16.3.1 Time program main screen
PF menu Description
Reference
section
New Creates a new time program. 16.3.3
Del Line Deletes the time program line at the current cursor position.

Chng Line Moves the cursor to the next line.

Print Prints the program to the Chromatopac.

16.3 Time Program
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16.3.3 Creating a new time program
Select [New] (PF menu) from the time program screen to display the time program edit
Set an item using the [ ] and [ ] keys and the [ENTER] key. When [Finish] (PF menu)
becomes available and the items have been set, press [Finish] to validate the program.
At the top of the screen, the contents of the set program are displayed. At the bottom of the
screen, the program edit screen is displayed.
Up to 100 lines are available for one program.
The possible program execution time ranges from 0.00 to 9999.00 minutes.
16.3.4 PF menu
Fig. 16.3.2Time program edit screen
PF menu Description
Reference
section
Finish Validates the time program.


Next Page Moves to next item.

Cancel Cancels the time program being created.

16.3 Time Program
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16.3.5 Time Program parameters
NOTE 1) Relay description
AC On/Off: Turns the power supplied to the AC connector on the power controller PCB on/off.
Event of On/Off point: Turns the relay contact on the PRG PCB (option) on/off.
Event91 and Event92: Switches a-contact and b-contact of each relay on the CPU PCB
(standard).
Event of PRG: Switches a-contact and b-contact of each relay on the PRG PCB (option).
Blower, Cooling Fan, CRG INJ and CRG Column: Turns the power of each option on/off.
Relay
NOTE 1)
Detector
Range
Sets range or attenuation for the detector configured in the
analytical line.
Polarity
Changes the polarity between + and - for TCD configured in the
analytical line.
Current Sets current for the detector configured in the analytical line.
NOTE 2)
Zero Adj
Turns on/off zero adjustment for the detector configured in the
analytical line.
Flame Ignites / Extinguishes the flame.
FTD
Turns on/off voltage feedback to make current constant for FTD
configured in the analytical line.
Detector controller
Turns on/off control of detector configured in the analytical line
during analysis program.
Flow
controller
Refer to
NOTE 3).
Splitter Ctrl Opens/closes splitter.
Flow controller On/Off
Turn carrier gas, septum purge, detector gas, APC, and AMC (AUX
AMC and AMC. LR) on/off.
High press inj mode Turns high pressure injection mode on/off.
Gas saver Turns gas saver function on/off.
Temperature
INJ1, INJ2, DET1, DET2,
AUX3, AUX4, AUX5
Use a time program to change temperature of heated zones, which
cannot be programmed.
Stop
NUMBER
OF TIMES
OF RUN
End of
program

Specify the number of times to execute the GC program. Then,
either the program stops or the next file is executed. If greater than
2, the choices are continuous or pause at each run. For an
AOC, select continuous. When pause at each run is selected,
the program executes continuously at set intervals.
If another program (such as a temperature program) is running
when time program execution time expires, priority is given to
running the program. When the current program finishes, the time
program stops or file is changed to another file.
0: FILE
09 Load
Other Set the parameter to input event No..(Refer to 17.4 Event No..)
Relay
Relay
Switch point
Event 91,92 V9192 Point A or B
PRG V9394 Point A or B
On/Off point Event 116 On or Off
AC On/Off
Oven Exhaust Fan On or Off
Cooling Fan On or Off
CRG INJ On or Off
CRG Colum On or Off
16.3 Time Program
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NOTE 2) Current range
NOTE 3) When the dual AFC is used
1. There is no settings for splitter ctrl, high press inj mode, and gas saver.
2. Septum purge cannot be selected on flow controller On/Off.
16.3.6 Editing a time program
To change the contents of an existing time program, move the cursor using the [ ] and [ ]
keys to the program line to be edited changed and press the [ENTER] key.
To change only the time, enter the new time from the edit screen and press [Finish] (PF
menu).
To change the other parameters, move the cursor and make the changes from the edit
screen, and then press [Finish] (PF menu).
To cancel the edits and restore the original time program, press [Cancel] (PF menu) before
pressing [Finish] (PF menu).
Detector type Current
FTD 0.0010.00 (pA)
ECD 0.002.00 (nA)
TCD 0200 (mA)
16.3 Time Program
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16.3.7 Time program setup example
Example 1: When both positive and negative peaks appear on the chromatogram
Four minutes after the program execution starts, the polarity of the detector DET
1 (TCD) is switched from plus to minus. Two minutes later (six minutes after the
program execution starts), the polarity is switched back to plus.
First program Screen display
1. Time: 4.0 min
2. Detector
3. Polarity
4. DET 1
5. - (minus)
Second program
6. Time: 6.0 min
Steps 24 are repeated.
7. + (plus)
8. The time program is set up.
16.3 Time Program
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Example 2: Two AOC analyses use File No.0, then file No.1 is used.
(The execution time is set to 30 min.)
Screen display
1. Time: 30 min
2. Stop
3. Run: 2 times
4. File 1 is loaded.
5. Pause at each run(AOC)
6. The time program is set up.
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16.4Pre-Run Program
The Pre-Run program controls flow controllers and relays before the analysis starts.
Select 4. PRE-RUN from the [FUNC] key screen to display the Pre-Run screen shown in
Fig. 16.4.1. A Pre-Run program is executed after the [START] key is pressed, but before an
analysis.
While the Pre-Run program is running, the elapsed time is displayed in the Time field on
the [MONIT] key screen.
Program steps do not need to be entered in order. After you finish editing the Pre-Run
program, programs are automatically sorted.
More than one step can be set for the same time. The specified actions are executed at the
same time.
16.4.2 PF menu
Fig. 16.4.1 Pre-Run program main screen
PF menu Description
Reference
section
New Creates a new Pre-Run program. 16.4.3
Del Line Deletes the program at the current cursor position.

Chng Line Changes over the screen of Pre-Run program every line.

Print Prints the program to the Chromatopac.

16.4 Pre-Run Program
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16.4.3 Creating a new Pre-Run program
Create a Pre-Run program following the same procedure described in 16.3.3. Creating a
new time program in 16.3 Time Program.
The parameters are equivalent to those shown in 16.3.5. Time Program Parameters
except for STOP. The STOP parameter is described below.
Up to 100 lines are available for the Pre-Run program.
The possible Pre-Run program execution time ranges from 0.00 to 9999.00 minutes.
In the following case, AUTO of the STOP parameter is carried out when the pre-run program is fin-
ished.
There is no STOP parameter in the pre-run program.
Running the Batch Schedule.
16.4.4 Editing a Pre-Run program
To change the contents of the existing Pre-Run program, move the cursor using the [ ] and
[ ] keys to the program line to be edited and press the [ENTER] key.
To change only the time, enter the new time from the edit screen and press [Finish] (PF
menu).
To change the other parameters, move the cursor and make the changes from the edit
screen, and then press [Finish] (PF menu).
To cancel the edits and restore the original time program, press [Cancel] (PF menu) before
pressing [Finish] (PF menu).
16.4.5 After Pre-Run program is finished
When the Pre-Run program is finished, certain events automatically return to their pre-
programs status.
These events are listed below..
For details about the event No., refer to 17.4 Event No..
End of
program
Auto
The AOC starts after the Pre-Run program is finished.
If there is no AOC, the GC starts.
Manual (Stop program)
After the Pre-Run program is finished, the system becomes
ready.
GC starts
After the Pre-Run program is finished, the GC starts.
For example, select this item to activate a gas sampler, switch the
valve and introduce the gas sample in to the GC as soon as the
program stops.
AOC/HSS starts
After the Pre-Run program is finished, the AOC/HSS starts.
After sample is injected, GC starts.
Clean up
After the Pre-Run program stops, clean up starts.
After clean up finishes, the system becomes ready.
Event No. Description
131134 Turn detector controller on/off.
141146 Turn carrier gas and septum purge on/off.
147158 Turn detector gas on/off.
171 Turns high pressure injection on/off.
181198 Turn AUX APC on/off.
201-210 Turn AUX AMC on/off.
NOTE
16.4 Pre-Run Program
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16.4.6 Pre-Run Program set up example
Example: Switches B-contact of Event 91 four minutes in to the program.
Screen display
1. Time : 4.0 min
2. Relay
3. Relay
4. Switch point
5. Event 91, 92
6. Event 91
7. Point B
8. Setting is completed
16.5 16.
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16.5Direct Operation
Select 5. DIRECT OPERATION from the [FUNC] key screen to display the screen shown
in Fig. 16.5.1.
Input the event No. and press the [Execute] key to execute the specified event.
For a description of the event No., refer to 17.4 Event No..
EVENT
Range: -500+500, Default: ---
Runs the operation assigned to the event No.
Refer to 17.4 Event No..
16.5.3 PF menu
Fig. 16.5.1 Direct operation setup screen
PF menu Description
Reference
section
Execute
Runs the specified operation.
Input event No. to be run, and press [Execute] (PF menu).

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16.6GC Configuration
Select 6. GC CONFIGURATION from the [FUNC] key screen to display the GC
configuration screen shown in Fig. 16.6.1.
DATE/TIME SETTING
Set the date and the time.
MAX. TEMPERATURE
Set the maximum temperature limit for each headed zone.
TRANSMISSION PARAMETER
Set the parameters related to transmission.
READY CHECK
Indicate the conditions, which should be satisfied in order for the system to be ready and the
STATUS light to illuminate.
SIGNAL SETTING
Set the signals which can be output from the gas chromatograph.
PORT NAME CUSTOMIZATION
Customize the names of various GC items.
LINK DEVICE CODE
Set the link device code the GC is linked to a Chromatopac.
Fig. 16.6.1 GC Configuration setup screen
16.6 GC Configuration
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TEMPERATURE OFFSET
Set the temperature offset for each heated zone.
OTHER CONFIGURATIONS
Specify the configuration of miscellaneous setup items.
16.6.3 Setting the date and time
Select 6. GC CONFIGURATION from the [FUNC] key screen, and then select 1.
DATE/TIME SETTING, to display the Date/Time setting screen shown in Fig. 16.6.2.
The date and the time can be set. This setting is automatically saved, even when the
GC power is off.
DATE
Range: 2000.01.012099.12.31
TIME
Range: 00:00:0023:59:59
Fig. 16.6.2 Date/time setup screen
The current date and time
are displayed.
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16.6.4 Setting the maximum temperature limits
Select 6. GC CONFIGURATION from the [FUNC] key screen, and then select 2. MAX
TEMPERATURE to display the Max. Temperature screen shown in Fig. 16.6.3.
Set the maximum temperature limits of 8 heated zones.
COLUMN
In order to protect the column, do not allow the maximum oven temperature to exceed
the maximum column temperature.
INJ1/DET1/DET2
Range: 10.0420.0 C, Default: 420.0 C
INJ2
AUX3/AUX4/AUX5
Range: 10.0420.0 C, Default: 420.0 C
AUX3, AUX4 and AUX5 are available optionally.
If the are installed, the AUX temperature control unit (P/N 221-48458-91) is required.
16.6.4.3 PF menu list
When Yes is selected, the Detector temperature setting value must be bigger than or
equal to the Oven temperature setting value.
When No is selected, the Detector temperature setting value may be smaller than the
Oven temperature setting value.
Fig. 16.6.3 Maximum temperature setup screen
PF menu Description
Reference
chapter
Protect Protection against contamination

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16.6.5 Setting transmission parameters
TRANSMISSION PARAMETER, to display the Transmission Parameter screen shown
in Fig.16.6.4.
PROTOCOL
Selection: None/LEVEL1/LEVEL2/LEVEL3, Default: LEVEL2
BAUD RATE
Selection: 2400/4800/9600/19200/38400/57600/115200 bps, Default: 9600 bps
Set the communication speed.
STOP BIT
Selection: 1 bit/ 2 bit, Default: 1 bit
PARITY
Selection: NONE/EVEN/ODD, Default: NONE
STOP BIT and PARITY can be set when PROTOCOL is set to None or LEVEL1
or LEVEL2.
Set to EVEN in case of connecting a Chromatopac.
Refer to 2.3 Outputting Digital Signals to a Personal Computer and 2.4 Connecting a RS-232C
Cable to the Chromatopac C-R8A.
16.6.5.3 PF menu
Fig. 16.6.4Transmission parameter setup screen
PF menu Description
Reference
section
Apply Down loads the parameters immediately.

NOTE
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16.6.6 Setting the Ready Check Parameters
The Ready Check verifies whether the preset analytical conditions have been met.
When the selected items reach the specified settings, the STATUS light illuminates.
READY CHECK, to display the ready check screen shown in Fig.16.6.5.
Set each parameter to yes or no. All parameters with yes must reach their initial
parameter starts in order for the GC to be ready and the STATUS light to turn green.
HEATER PORT
TEMP
Indicate which headed zones should be included in the ready check.
CARRIER GAS
SEPTUM PURGE
Indicate which injection port septum purge flow lines should included in the check.
The displayed items depend on the injection port type.
DET FLOW GAS
MAKE UP
HYDROGEN
Fig. 16.6.5 Ready Check setup screen
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AIR
Indicate which detector APC zones should be included in the check.
The displayed items depend on the detector type.
AUX APC
APC1APC15 PRESS
This item is available only when optional APC units are installed.
AUX AMC
AMC1AMC10 FLOW
This item is available only when optional AMC units are installed.
DETECTOR
CONTROLLER
This item is available only when the FID is installed.
DRIFT
This item compares the baseline drift to the drift limit for 10 minutes.
Once the GC becomes ready, the GC re-evaluates of the ready status 10 minutes later.
WAIT SIGNAL
The wait signal applies to all detectors configured in analytical lines.
User-specified names are used in this screen.
16.6.6.3 PF menu
PF menu Description
Reference
section
Drift Set the baseline drift limit.

NOTE
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16.6.7 Parameter Configuration
Signals are output from four gas chromatograph channels.
To assign detector channels, see 13 Detector.
This section describes the detector signal configuration as well as the configuration of
various other parameters which can be monitored on the screen.
SIGNAL SETTING, to display the signal settings screen shown in Fig. 16.6.6.
This screen allows you to adjust the GC signal parameters.
16.6.7.2 PF menu
Fig. 16.6.6 Signal setup screen
PF menu Description
Reference
section
Gain etc. Sets the signal gain and offset for each detector. 16.6.7.6
Data File
Sets the format of digital signals.
When GC is linked to a personal computer, this item is automatically set to
PC. When link is ended, this item automatically reverts to Chromatopac.

Det Sig
Sets signal output channels for all detectors.
The signal out put channels can also be specified for installed detectors
which have not been configured in an analytical line.
If two or more detectors are set to one channel, data can be output to
either channel without switching the output signal cable simply by changing
the analytical line configuration.
Use the cursor to select the

desired channel.
Press [ENTER] to open that
channels setup screen.
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16.6.7.3 Selecting the detector signals
Select the signal type from the main screen, and then press DET SIG to display the
Select the type of signal to output. For a description of the settings, refer to 13
Detector.
16.6.7.4 Selecting the temperature control signal
Select the signal type from the main screen, and then press TEMP to display the
Select the temperature control signal to be output.
Fig. 16.6.7 Detector signal setup screen
Fig. 16.6.8 Temperature control signal setup screen
For detector signal subtraction,
also specify the channels (1-4)
for the subtraction.
For background signal com-
pensation, also specify the
background signal No.(1 or 2).
The currently set channel
No. is displayed.
The currently set channel No.
is displayed.
When saving the background
signal, specify which signal (1
or 2) should be saved.
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16.6.7.5 Selecting the flow signal
Select the signal type from the main screen and then press FLOW to display the
Select the flow signal to be output.
Select the carrier gas, detector gas and APC gas items. The APC gas can be set when
the APC is installed as an option in any location other than the flow controller or the
detector gas.
Q Carrier gas
If you select the carrier gas for the flow signal selection, the screen shown in Fig. 16.6.9 appears.
Q Detector gas
If you select the detector gas for the flow signal selection, the screen shown in Fig. 16.6.10
appears.
Fig. 16.6.9 Carrier gas signal setup screen
Fig. 16.6.10Detector gas signal setup screen
Select an item to be output
from each area.
is displayed.
from each area.
is displayed.
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Q APC gas
If you select the APC gas for the flow signal selection to display the screen shown in Fig. 16.6.11.
AMC gas
If you select the AMC gas for the flow signal selection, the screen shown in Fig. 16.6.12
appears.
Fig. 16.6.11 APC gas signal setup screen
Fig. 16.6.12 AMC gas signal setup screen
is displayed.
from each area.
is displayed.
from each area.
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16.6.7.6 Signal offset
When you select [Gain etc.] (PF menu) from the signal setup main screen, the Gain and
offset screen shown in Fig. 16.6.12 appears. Set the offset and the the detector signal
gain here.
Select [Sig. Ch] (PF menu), to set the gain and the offset for any signal other than
defector signals (such as temperature or pressure). In addition, you can set the time
constant and the zero adjustment of the signal for each channel.
Fig. 16.6.13 Detector signal gain and offset screen
Range Default
Gain offset
0.00-100.00
-999999-9999999
1.00
0
Time constant
4 ms, 5 ms, 10 ms, 20 ms, 50 ms,
100 ms, 200 ms, 500 ms, 1 s, 2 s
50 ms
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16.6.8 Customizing Component Names
Select 6. GC CONFIGURATION from the [FUNC] key screen, amd then select 6.
PORT NAME CUSTOMIZATION, the Name customization screen shown in Fig.
16.6.13 appears.
Specify the names of GC components (8 characters, alphanumeric and symbols).
To customize the name, refer to 6.3.5 Changing item names in 5.3 Basic Key
Operations.
16.6.8.2 Customization example
If the Heater Name and Carrier Name are customized, the Line Configuration
screen changes as shown in Fig. 16.6.15.
Fig. 16.6.14 Name setup screen
Fig. 16.6.15 Name customization example
The port name was changed
using Carrier Name Customiz.
There is no injection port in
INJ2, and there is only a
carrier flow controller.
The INJ2 and DET1 names
were changed from Heater
Name Customiz.
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16.6.8.3 Heater Name Customization
Select 6. GC CONFIGURATION from, the [FUNC] key screen, and then 6. PORT
NAME CUSTOMIZATION, and finally, select 1. HEATER NAME CUSTOMIZ, to open
the screen shown in Fig. 16.6.16.
16.6.8.4 Carrier Name Customization
Select 6. GC CONFIGURATION from the [FUNC] key screen, and then 6. PORT
NAME CUSTOMIZATION, and finally select CARRIER NAME CUSTOMIZ, to open
the screen shown in Fig. 16.6.17.
Fig. 16.6.16 Heater port name setup screen
Fig. 16.6.17Carrier name setup screen
Only listed heated zone names
can be changed.
To change the names, refer to
in 6.3 Basic Key Operations.
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16.6.8.5 AUX APC Name Customization
NAME CUSTOMIZATION, and finally 3. AUX APC NAME CUSTOMIZ, to open the
16.6.8.6 AUX AMC Name Customization
NAME CUSTOMIZATION, and finally 4. AUX AMC NAME CUSTOMIZ, to open the
Fig. 16.6.18 AUX APC name setup screen
Fig. 16.6.19AUX AMC name setup screen
Only listed APC options can
be named.
Only listed AMC options can
be named.
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16.6.8.7 Relay Name Customization
NAME CUSTOMIZATION, and finally RELAY NAME CUSTOMIZ, to open the screen
Fig. 16.6.20 Relay name setup screen
Only listed relays can be
named.
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16.6.9 Setting the link device code
When the gas chromatograph is linked to a Chromatopac, the link device code must be set.
The link device code specifies which GC channel should start when the GC [START] key is
pressed.
Select 6. GC CONFIGURATION from the [FUNC] key screen, and then select 7. LINK
DEVICE CODE, to open the screen shown in Fig. 16.6.21.
CHANNEL TO START
Ch1Ch4 Selection: On/Off, Default: On
Set On or Off for the start signal of each channel.
Fig. 16.6.21 Link device code setup screen
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16.6.10 Temperature offset
If the actual temperature of the various heated zones (as measured by a thermocouple)
differs flow the set temperature, set a temperature offset value to compensate.
Select 6. GC CONFIGURATION from the [FUNC] key and select 8. TEMPERATURE
OFFSET to display the temperature offset screen shown in Fig. 16.6.22.
COLUMN/INJ1/INJ2/DET1/DET2/AUX3/AUX4/AUX5
Range: -10.00+10.00, Default: 0.00
The temperature of each heated zone can be offset, Uninstalled ports are not displayed.
For example, when -1 C is obtained by subtracting the column oven temperature
measured by thermocouple from the gas chromatograph value with an offset value of
0, input -1 as the offset value.
Fig. 16.6.22Offset set up screen
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16.6.11 Other Settings
OTHER CONFIGURATIONS to open the configurations screen shown in Fig. 16.6.23.
Fig. 16.6.23 Setup screen of other configuration
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LANGUAGE
Selection: Alt./English, Default: English
Switch between Japanese (Alt.) and English screen languages.
BACK LIGHT AUTO OFF
Range: 09999 (sec)., Default: 0 (sec)
Set the period of time when the backlight LCD display automatically turns off.
PRESSURE UNIT
Selection: kPa/bar/psi., Default: kPa
Set the pressure units for display.
In the case that the presssure unit of bar or psi are used, pay attention to the following.
The range of the primary pressure is not displayed in the value of bar, psi. Set up it
with the value that consults the following table and transformed into kPa.
The pressure axis on the screen after pressing [MONIT] key is displayed in the value of
kPa regardless of the pressure unit sets.
The setting value, measured value of the primary pressure of the diagnosis result of the
standard diagnosis is displayed in the value of kPa regardless of the pressure unit
sets.
The display, printing of each log file is displayed in the value of kPa regardless of the
pressure unit sets.
BEEP VOLUME
Selection: Off/Low/Mid/Hig, Default: Low
BEEP TONE
Selection: Lo/Hi, Default: Hi
Use a different tone for different GCs to be able to discern which GC has a problem.
ATMOSPHERIC COMPENSATION
Select On to compensate for higher altitudes when in linear velocity mode.
ZERO AT READY
Set On for, the gas chromatograph to automatically perform zero adjustment when the
GC is ready.
POLARITY IN READY
Selection: Open/Close, Default: Open
Set the polarity of GC ready signal.
INJ1/INJ2 PRIMARY PRESS
Selection: 300500 kPa/500900 kPa/900980 kPa, Default: 500900 kPa
Select the pressure range of the carrier gas cylinder.
If the wrong range is selected, error messages are not displayed correctly.
Example: If the gas cylinder pressure supplied to the GC-2014 is 700 kPa, select 500
900 kPa. This is not displayed when the carrier gas flow controller is DAFC.
Range (kPa = 1) Increase quantity
kPa 1 0.1
bar 1/100 0.01
psi 1/6.895 0.1
kPa bar psi
300 - 500 3.00 - 5.00 43.5 - 72.5
500 - 900 5.00 - 9.00 72.5 - 130.5
900 - 980 9.00 - 9.80 130.5 - 142.1
NOTE
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DAFC UNIT
Selection: DAFC/AMC. LR, Default: DAFC
When using the dual AFC as an AMC for detector makeup gas, set to AMC. LR. If AMC.
LR is set, the injection port connected to the dual AFC becomes off from the flow line
and is not displayed on the flow line configuration screen (8.3.1)
Set the DAFC unit prior to starting GCsolution.
DTCD PREAMPLIFIER
Selection: x1/x10, Default: x1
When it is set to x10, TCD output is amplified ten times.
GC START
Selection: SYSTEM Key Screen/ SET Key Screen/ MONIT Key Screen/,
Default: SYSTEM Key Screen
Select the screen, which is displayed automatically after pressing the "Start GC" key
(PF1 key of the [SYSTEM] key main screen).
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16.7 16.
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16.7Service and Maintenance
Select 7. SERVICE/MAINTENANCE from the [FUNC] key screen to display the Service/
Maintenance screen shown in Fig. 16.7.1.
INSTALLATION (POSITION)
Specify the heated zone locations for installed components.
INSTALLATION (PIPING)
Set the installation status of the carrier gas and the detector gas flow controllers.
INITIALIZE
Initialize the RAM, configuration, and installation settings.
POWER CONSUMPTION
Displays the power consumption of all heated zones.
SERVICE
Reserved for the use of shimadzu service personnel during maintenance or inspections.
Fig. 16.7.1 Service/maintenance menu screen
16.7 Service and Maintenance
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16.7.3 INSTALLATION (POSITION)
16.7.3.1 Screen Description
Select 7. SERVICE/MAINTENANCE from the [FUNC] key screen, and then select 1.
INSTALLATION (POSITION), to open the GC installation screen shown in Fig. 16.7.2
appears.
After installing injection ports and detectors, specify the location of installed components
by entering the headed zone number while. referring to Fig. 16.7.3.
Set the left installation position for units with two column installation positions such as DINJ and DFID.
Fig. 16.7.2 GC installation setup screen
NOTE
Enter the heated zone number
to specify the unit installation
position in a number. (Refer
to Fig. 16.7.3.)
The component type of installed
injectors and detectors is
automatically determined.
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INSTALLATION POSITION
Specify the component installation location by entering a numeric value from 1 to 8 as
Set 0 when a unit is not installed.
Set 15 when a unit is installed in a position not shown in Fig. 16.7.3.
Fig. 16.7.3 Component installation location
Changes are not in effect until the GC has been turned off and on. NOTE
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16.7.4 INSTALLATION (PIPING)
INSTALLATION (PIPING), to open the Installation (Piping) Screen shown in Fig.
16.7.4.
In the carrier gas, flow controller fields, specify where the flow controller injection port
tubing is connected.
In the detector gas flow controller fields, specify the detector configuration including
detector type and flow control unit.
Q Carrier gas flow controller settings
The names CAR1, CAR2 and CAR3 are automatically assigned in ascending order of
the slot No. for each installed AFC.
Specify the flow controller carrier gas settings for each CAR.
UNIT TYPE
For, display only.
When an AFC is installed, this is automatically displayed.
If a manual flow controller is installed, specify the installation Slot No.(See below.)
SPLITTER is automatically displayed for the Unit Type.
SLOT NO.
Selection: NON/MSLOT17, Default: NON
This item can be set only when a manual flow controller is installed.
Select the Slot No. where the manual flow controller is installed.
Slot No. which have already been set cannot be selected.
When an AFC is installed, its SLOT no. 26 is automatically recognized and displayed.
Fig. 16.7.4 Installation status setup screen
Detector gas
flow controller
settings
Carrier gas
flow controller
settings
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TEMP. PORT
Selection: NON/INJ1/ INJ2/DET1/DET2/AUX3/AUX4/AUX5, Default: NON
Specify the injection port heated zone where the flow controller tubing is connected.
This assosiates the flow controller to an injection port.
Q Detector gas flow controller settings
When installing detector flow control units, the names DET#1 to DET#4 are
automatically assigned starting with the one nearest to the GC.
Specify the to flow controller detector gas settings for each detector No. (DET#1 to
DET#4).
CONT. TYPE
For display only.
The type of each installed detector control unit is automatically recognized and displayed.
DET APC No.
For display only.
When the slot No. is selected for each installed detector gas flow controller, the name
DET APC 1 to DET APC 4 is automatically assigned to each flow controller.
UNIT TYPE
For display only.
When an APC is installed, the APC type is displayed for the Slot No. selected.
APC (1ch) indicates an APC for ECD/TCD. APC (2ch) indicates an APC for FPD.
APC (3ch) indicates an APC for FID/FTD.
When manual flow controllers are selected, DET GAS is automatically displayed.
SLOT NO.
Selection: NON/SLOT26/MSLOT17, Default: NON
When a manual flow controller is installed, specify the installation location slot no. from
among MSLOT17.
When a APC is installed, select an available Slot No..
Slot No. which have already been set cannot be selected.
When CONT. TYPE is WDFID (for dual FID) or TCD-L (for packed TCD), two DET APC
numbers and slots are displayed. Only the upper lines can be set. When a manual flow
controller is used, enter the smaller slot no. among the pair (2 slots). (Example: If
MSLOT4 and MSLOT 5 are available, specify MSLOT4.)
Two units of the same type of APCs need to be installed on slots next to each other
because piping for two units is set. An APC for the L side is installed on the slot with the
smaller number so set the slot no. on the L side to the upper line. An APC installed on
the next slot is automatically set on the R side. For example, when the L side is set on
SLOT4, the R side is set on SLOT5.
Setting slots for TCD-L detector gas is unnecessary because makeup gas is usually not
used for packed TCD.
HEATER PORT
Selection: NON/INJ1/INJ2/DET1/DET2/AUX3/AUX4/AUX5, Default: NON
Specify the detector heated zone where the flows controller tubing is connected.
This assosiates the flow controller to a detector.
When CONT. TYPE is WDFID, only heater ports that the DFID is connected to can be
set for piping.
When CONT. TYPE is TCD-L, piping of two units of heater ports need to be set. The
upper line is for the pre heater and the lower line is for the TCD cell. A port that the DFID
(or a pre heater unit without the FID cell) is connected to can be set for the pre heater
and a port that the DTCD is connected to can be set for the TCD cell.
Only heater port that the DFID is connected to is shared for temperature regulation of
the DFID and TCD-L pre heater (set for both).
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Changes are not in effect until the GC has been turned off and on.
Manual flow controller slot numbers are MSLOT1 to 7 from the left viewed from the back of the unit.
AFC and APC slot numbers are SLOT2 to 6 from the left viewed from the back of the unit. (SLOT1 is
not available.)
Manual flow controller APC
Fig. 16.7.5 Setup for detector gas flow controller
NOTE
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16.7.5 INITIALIZATION
INITIALIZE, to display the Initialization screen shown in Fig. 16.7.6.
When you move the arrow cursor and press the [ENTER] key, the initialization
confirmation screen (Fig. 16.7.7) appears. On this screen, press the [INIT] (PF menu)
key to initialize the selected item.
INITIALIZE CONFIGURATION
This item initializes configuration settings such as heated zone temperature limits and
ready check parameters. However the column temperature limit is saved in the analysis
file and is not reset. Analysis files 09 cannot be initializend.
INITIALIZE INSTALLATION
This item initializes the installation settings of injection ports, flow controllers, etc.
INITIALIZE RAM
This item initializes the RAM, erasing all data, including analysis files 09, configuration
and installation settings.
Initialize the RAM when there is a RAM problem.
INITIALIZE ALL
This item initializes all settings including.
Analysis files 09
Fig. 16.7.6Initialization menu screen Fig. 16.7.7 Initialization confirmation screen
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16.7.6 Power consumption
POWER CONSUMPTION, to open the Power consumption screen shown in Fig
16.7.8.
APPROX. POWER CONSUMPTION
Approximate total power consumption of all working heaters is displayed.
Fig. 16.7.8 Power consumption monitoring screen
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16.8 16.
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16.8Stopwatch
Select 8. STOP WATCH from the [FUNC] key screen to display the stopwatch screen
The stopwatch can display elapsed time up to 99 : 99 : 99.9 in units of 0.1 second. When the
counted time exceeds 99 : 99 : 99.9, the stopwatch is reset and the time restants at 0.0
seconds.
The stopwatch can function even when other keys are pressed. However, once the stop key
is pressed, the stopwatch is reset to 0.0 seconds if another key is pressed.
16.8.2 PF menu
16.8.3 Timing with inverse measurement
When using a bubble film flow meter of V ml, obtain the flow rate using the reciprocal
number.
Fig. 16.8.1 Stop watch screen
PF menu Description
Reference
section
Start Starts timing.
If Start is pressed again when the timing has stopped, the stopwatch is
reset to 0.0 seconds.
Stop Stops counting.

V x (Reciprocal number of measurement time) ml/min
16.9 16.
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16.9Key Lock and Parameter Lock
Select 9. LOCK from the [FUNC] key screen to display the Lock screen shown in Fig.
16.9.1.
If either key lock or parameter lock has already been activated, the Unlock screen appeares
instead.
Fig. 16.9.1 Lock menu screen
16.9 Key Lock and Parameter Lock
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16.9.2 Key locking
Select 9. LOCK from the [FUNC] key screen, and then select 1. KEY LOCKING to display
the Key locking screen shown in Fig. 16.9.2. This screen indicates that the current status is
not locked.
When keys are locked, key operations are disabled. This function is useful to prevent analy-
sis mistakes because no key operation is accepted. When the keys are locked, an icon
indicating the lock status is displayed at the lower left corner of the screen.
When the keys are locked, analyses can still be started and stopped, and parameters can be
monitored.
Q Unlocking keys
Press the [FUNC] key when the keys are locked, to open the screen shown in Fig. 16.9.3.
Once the keys are unlocked, the screen shown in Fig. 16.9.1 appears.
Fig. 16.9.2 Key Locking main screen
Fig. 16.9.3 Key unlock screen
This screen is displayed when
the current status is locked.
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16.9.3 Parameter locking
Select 9. LOCK from the [FUNC] key screen, and then select 2. PARAMETER LOCKING
to display the screen shown in Fig. 16.9.4.
The parameter lock function prevents unauthorized parameter changes (for analytical
conditions such as temperature, pressure and flow rate). Setup values can be monitored,
but cannot be changed.
Fig. 16.9.4 Parameter locking main screen
Press [Password] (PF menu)
to display the password
setup screen.
The parameter lock function
is also available without
password.
When the password is to
be required, set Use
Password to USE, enter
a password, then press
[Lock] (PF menu).
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Q Setting a password
Select [Password] (PF menu) from the screen shown in Fig. 16.9.4 to display the password
screen shown in Fig. 16.9.5. The password is a number ranging from 1 to 9999. The factory
set password is 2014.
Setting a password
Enter each requierd password, and press [Set] (PF menu).
Enter the new password twice to confirm it.
If the Old Password or Confirm new password is incorrect, an error message appears.
Confirm the password to be input, entering it correctly.
Only the system supervisor should have password access. Change the factory-set password promptly.
Do not forget your password, and keep it secure.
Fig. 16.9.5Password setup screen
NOTE
NOTE
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Q Unlocking the parameters (without password)
If parameters are locked and no password is required, when you select 9. LOCK from the
[FUNC] key screen, the screen shown in Fig. 16.9.6 appears.
When the parameter are unlocked, the screen shown in Fig. 16.9.4 appears.
Q Unlocking parameters (with password)
If parameters are locked and a password is set, when you select 9. LOCK from the
[FUNC] key screen, the screen shown in Fig. 16.9.7 appears.
When you input the correct password and press the [Unlock] (PF menu) key, the parameters
are unlocked and the screen shown in Fig. 16.9.4 appears.
Fig. 16.9.6Parameter unlock screen (without password)
Fig. 16.9.7 Parameter unlock screen (when a password is set)
This screen is displayed
when parameters are locked.
This screen is displayed
when parameters are locked.
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16.10 16.
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16.10ROM Version No.
The system ROM version No. can be displayed.
Press [Version] (PF menu) from the [FUNC] key screen to display the version screen shown
in Fig. 16.10.1.
VERSION
BUILD NO.
The ROM version may be required during system maintenance.
Fig. 16.10.1 ROM version No. screen
16.10 ROM Version No.
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271
17.1 17. 17.
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17 Printing
17.1Printing
17.1.1 Connection to Chromatopac
Connect the gas chromatograph to the Chromatopac, then press [Print] (PF menu) from the
GC screen to print to the Chromatopac.
For the GC and Chromatopac connection, refer to 2.4 Connecting a RS-232C Cable to the
Chromatopac C-R8A.
17.1.2 Parameters to be printed
17.1.2.1 Program
The current file program can be printed.
This includes the following screens: temperature program (COL, INJ1, INJ2), pressure
program (CAR1, CAR2, CAR3), flow rate program (CAR1, CAR2, CAR3) and split ratio
program (CAR1, CAR2.)
Press [Print] (PF menu) from any screen to print the same parameters for a saved pro-
gram.
Fig. 17.1.1
- COLUMN OVEN TEMP PROGRAM -
RATE TEMP TIME
0 ------- 100.0 1.00
1 6.00 220.0 25.00
- INJ1 TEMP PROGRAM -
RATE TEMP TIME
0 ------- 25.0 0.00
- INJ1 PRESSURE PROGRAM -
RATE TEMP TIME
0 ------- 100.0 0.00
- INJ1 SPRIT RATIO -
TIME RATE
0 ------- -1.0
- END -
17 Printing
17.1 Printing
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17.1.2.2 AOC parameters
The current files AOC parameters and the parameters of AOC settings can be printed.
The AOC2 parameters can be printed when an AOC2 is configured in the analytical line.
All printed items are listed by command name. To match command names to screen
items, refer to 17.2 AOC commands.
Fig. 17.1.2
17.1.2.3 Main parameters
Press [Print] (PF menu) from the [SET] key to print the temperature valves for all heated
zones, the CAR1/2 pressure value, and the total flow rate value from the current file.
Fig. 17.1.3
- AOC PARAMETER -
AOC1 AOC2
WRPT 2 2
WMOD 1 1
REPT 1 1
IVOL 1.0 1.0
WPRS 0 0
PUMP 5 5
WTPP 0.2 0.2
WAIT 0.0 0.0
ISPD 2 2
SSPD 1 1
SAND 0 0
SOLV 0 0
SINT 0 0
SSNO 0 0
SNO2 0 0
AAIR 0 0
USPD 2 2
DSPD 2 2
HIGH 0 0
LOWS 0 0
- GC PARAMETER 0:FILE0 -
COLUMN OVEN TEMP 25.0
INJ1 TEMP 25.0
DET1 TEMP 25.0
INJ1 PRESS 100.0
INJ1 FLOW 50.0
- END -
17 Printing
17.1 Printing
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17.1.2.4 Time program and Pre-Run program
The time programs and Pre-Run programs can be printed as Event No. or parameter
names. To match Event No. and parameter names to screen items, refer to 17.3
Program Parameters and 17.4 Event No.
For all functions treated as events in the printout, the line No. is displayed as 0 regardless of the line
number.
Fig. 17.1.4
17.1.2.5 Batch schedule
Press [Print] (PF menu) to print the bach schedule as shown below.
Fig. 17.1.5
- GC TIME PROGRAM -
TIME FUNC VALUE LINE
0.0 EVNT 91.0 0
2.0 D1RG 1.0 1
3.0 D1RG 0.0 1
200.0 STOP 1990.0 0
- END -
- GC SAMPLE SCHEDULER -
START FINAL GC-FILE DP-FILE #INJ MK COMNAD
1 5 0 Ch.1-2 1 STANDARD STEST
6 15 0 Ch.1-2 3 UNKNOWN
- END -
NOTE
17 Printing
17.1 Printing
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17.1.2.6 Log
From each screen of the GC operation log, the analysis log, the parameter log, the error
log and the diagnostic log, press [Print] (PF menu) to print the parameters displayed on
the screen.
For the analysis log, only the list screen is printed. The contents of the detailed analysis
screen are not printed.
For example, press [Print] (PF menu) from the error log screen, to obtain the following
printed results.
The log items are printed in chronological order, starting from the oldest.
Fig. 17.1.6
- GC ERROT LOG -
TIMEOCCURED CODE ERROR MESSAGE (VALUE)
200.05.16 14:21 [E1020] DET1 sensor down error (530.00)
200.05.16 14:27 [E0031] INJ-DET2 A/D error
200.05.16 14:27 [E0032] AUX1-AUX3 A/D error
200.05.16 14:27 [E0011] CAR1 AFC PCB error (7.00)
200.05.16 14:27 [E0030] COL A/D error
200.05.16 14:27 [E0001] DC 5 V range error (8.43)
200.05.16 14:27 [E0002] DC 24 V range error (20.34)
200.05.16 14:27 [E0034] Battery voltage error (0.26)
200.05.16 14:27 [E0005] Room temp range error (84.27)
200.05.16 14:27 [E1019] INJ1 sensor down error (530.00)
200.05.16 14:27 [E1018] COL sensor down error (530.00)
200.05.16 14:27 [E1020] DET1 sensor down error (530.00)
200.05.16 14:28 [E0031] INJ1-DET2 A/D error
200.05.16 14:28 [E0032] AUX1-AUX3 A/D error
200.05.16 14:28 [E0011] CAR1 AFC PCB error (7.00)
NOTE
275
17 Printing
17.2 17.
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17.2AOC commands
When you press [Print] from the AOC, all items are printed as command names. The list
below shows correspondence of command names to item names.
The setup values, such as Fast and Yes/No are printed as numbers. Correspondence of
setup values to numbers is shown in the range and default columns in the list below.
Q Command list
Command
name
Item Range Default
WRPT Sample Wash 099 2
WMOD Solvent Wash 099 1
REPT Number of Injection 199 1
IVOL Sample Size 0.18.0 1.0
WPRS Pre solvent Wash 099 0
PUMP Pumping 099 5
WTPP Viscosity 0.099.9 0.2
WAIT Dwell Time 0.099.9 0
ISPD Inj. Speed (Plunger) Slow: 0, Fast: 2 Fast: 2
SSPD Inj. Speed (Syringe) Slow: 0, Fast: 1 Fast: 1
SAND Inj. Mode 04 0
SOLV Solvent selection
All: 0, only A: 1,
only B: 2, only C: 3
All: 0
SINT Priority Sample No. 1 0
*SSNO
Injected sample No. (Only this sample is
analyzed.)
1 0
*SNO2 Injected sample No. (for sub AOC) 1 0
AAIR Air Aspiration No: 0, Yes: 1 No: 0
USPD Plunger Aspiration Speed Slow: 0, Middle : 1, Fast: 2 Fast: 2
DSPD Speed of Plunger Slow: 0, Middle : 1, Fast: 2 Fast: 2
HIGH
Syringe Height ( )
020 0
LOWS
Syringe Height ( )
1.5 ml vial: 02
4 ml vial: 010
0
INJH Syringe Height (Inj) 022 0
STRI Multi - Inj 199 1
*FSAM
Final sample No. (Samples after that are not
analyzed.)
1 0
*WKEY
Washing with solvent before injection in
solvent flush mode
0, 1 0
*UVOL Aspiration volume during pumping 8 l: 0, 6 l: 1 8 l: 0
SLMD Using 3 Solvent Vials No: 0, Yes: 1 No: 0
VIAL Vial size 1.5 ml:0, 4 ml:1 1.5 ml:0
*CKTR With/without tray check With: 0, Without: 1 Without: 0
*TANL Analysis time 0655 0
*TSTR Analysis start time 0.099.9 0.0
LSYR Syringe Volume
10 l: 0, 50 l: 1,
250 l: 2
10 l: 0
17 Printing
17.2 AOC commands
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GC-2014
1: Without autosampler, short rack: 16
Without autosampler, long rack: 112
With autosampler: 1150
Command names marked with * cannot be set on the GC screen.
SAMU Use of the sampler Not use: 0, Use: 1 Not use: 0
SUBU Use of the sub AOC Not use: 0, Use: 1 Not use: 0
BARC Bar Code Reader Not use: 0, Use: 1 Not use: 0
SPMD Distribution of sample for dual AOC 08 0
PAR1 Use of Same Param No: 0, Yes: 1 No: 0
*GLPM Setting of validation mode 0, 1 0
*GRPT Number of times of GLP sample discharge 199 50
*GVOL GLP sample discharge volume 180 20
*GPMP
Number of times of pumping after second
GLP
05 1
*ATSP Automatic stop function Off: 0, On: 1 On: 1
*ARSG Ready signal polarity Open: 0, Close: 1 Open: 0
TLET Rack Short: 0, Long: 1 Short: 0
TSEL Rack position while sampler is used 02 1
Command
name
Item Range Default
NOTE
277
17 Printing
17.3 17.
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17.3Program Parameters
Press [Print] from a time program or Pre-Run program to print the program as event No. or
parameter names.
This paragraph describes the parameter names and the display when a program stops.
Q Event No. (EVNT)
Refer to 17.4 Event No..
Q Temperature
Heated zone names from a temperature program are printed with the parameter names
shown below.
Column temperature : CITP
INJ1 : INJT
INJ2 : AITP
DET1 : DETT
DET2 : AUXT
AUX3 : TCDT
AUX4 : AX4T
AUX5 : AX5T
Q Detector range, polarity and current value
Detector range, polarity and the current value from a program are printed with the parameter
names shown below.
Range of DET #1 : D1RG
Polarity of DET #1 : D1PL
Current value of DET #1 : D1CR
17 Printing
17.3 Program Parameters
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Q Time program STOP and repetitions
When a time program STOP value is specified, it is printed with the four digits described
below.
[1] [2] [3] [4]
Digit [1] value
0: Continuous
When a program finishes, the next program automatically starts without waiting
for the start command.
1: Pause at each run (AOC)
When a program finishes, the GC waits for the start command.
Digit [2] and [3] valves
Number of times of run (0099)
00 indicates 1 repetition.
When both digits [2] and [3] are set to 0, nothing is printed but the number of
repetition times is set to 1.
Digit [4] value
File No. to switch to after repetitious run is finished (09)
In order to stop the program, input the current file No.
Q Pre-Run program (START)
Pre-Run program values are printed with numbers 04, described below.
0: Auto
1: Manual (Stop program)
2: GC start
3: AOC/HSS start
4: Clean up
279
17 Printing
17.4 17.
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17.4Event No.
Many parameters are printed with event No. The list below shows the correspondence of event
No. to functions.
Q Event No. list
No. Meaning of Event xx (Example: Event 1) Meaning of Event-xx (Example: Event -1)
0
Reverses contact status of Events 1 to 16 and
Events 91 to 96.
Opens contact of Events 1 to 16 and switches
contact of events 91 to 96 to N/C type (normal).
1
Turns on contact of one contact in one circuit
(option PRG).
Turns off contact of one contact in one circuit
(option PRG).
2
(option PRG).
(option PRG).
3
(option PRG).
(option PRG).
4
(option PRG).
(option PRG).
5
(option PRG).
(option PRG).
6
(option PRG).
(option PRG).
7
(option PRG).
(option PRG).
8
(option PRG).
(option PRG).
9
(option PRG).
(option PRG).
10
(option PRG).
(option PRG).
11
(option PRG).
(option PRG).
12
(option PRG).
(option PRG).
13
(option PRG).
(option PRG).
14
(option PRG).
(option PRG).
15
(option PRG).
(option PRG).
16
(option PRG).
(option PRG).
51 Performs zero adjustment of DET #1. Frees zero adjustment of DET #1.
61
Turns on CAR1 gas saver.
Sets split ratio to value of CAR1 gas saver split
ratio 1.
Turns off CAR1 gas saver.
Returns split ratio to value of analysis
parameter.
17 Printing
17.4 Event No.
280
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62
ratio 2.
parameter.
63
ratio 1.
parameter.
64
ratio 2.
parameter.
71 Ignites frame. Extinguishes frame.
81 Turns on feedback of FTD 1. Turns off feedback of FTD 1.
91 N/O contact between two contacts in one circuit N/C contact between two contacts in one circuit
92 N/O contact between two contacts in one circuit N/C contact between two contacts in one circuit
93
N/O contact between two contacts in one circuit
(option PRG)
N/C contact between two contacts in one circuit
(option PRG)
94
N/O contact between two contacts in one circuit
(option PRG)
N/C contact between two contacts in one circuit
(option PRG)
103 Closes CAR1 splitter control. Opens CAR1 splitter control.
104 Closes CAR2 splitter control. Opens CAR2 splitter control.
105 Turns On AC blower. Turns Off AC blower.
106 Closes air (solenoid valve). Opens air (solenoid valve).
109 Turns On AC CRG INJ. Turns Off AC CRG INJ.
110 Turns On AC CRG Column. Turns Off AC CRG Column.
111 Turns On AC Cooling fan. Turns Off AC Cooling fan.
131 Turns On DET #1 detector controller. Turns Off DET #1 detector controller.
141 Turns On CAR1* carrier gas. Turns Off CAR1* carrier gas.
142 Turns On CAR1 septum purge Turns Off CAR1 septum purge.
143 Turns On CAR2** carrier gas. Turns Off CAR2** carrier gas.
144 Turns On CAR2 septum purge. Turns Off CAR2 septum purge.
145 Turns On CAR3*** carrier gas. Turns Off CAR3*** carrier gas.
146 Turns On CAR3 septum purge. Turns Off CAR3 septum purge.
147 Turns On DET #1 makeup gas. Turns Off DET #1 makeup gas.
148 Turns On DET #1 H2. Turns Off DET #1 H2.
149 Turns On DET #1 Air. Turns Off DET #1 Air.
When the dual AFC (DAFC) is used as flow controller, the following carrier gas is turned On/Off.
* CAR1 L side ** CAR2 L side
*** When CAR1 is DAFC: CAR1 R side, When CAR1 is AFC and CAR2 is DAFC: CAR2 R side.
17 Printing
17.4 Event No.
281
GC-2014
161
Turns On CAR1 gas saver.
ratio 1.
When GC becomes ready, split ratio returns to
value of analysis parameter.
Turns Off CAR1 gas saver.
parameter.
162
ratio 2.
parameter.
163
ratio 1.
parameter.
164
ratio 2.
parameter.
171
Turns On CAR1/CAR2/CAR3 high pressure
injection mode.
Turns Off CAR1/CAR2/CAR3 high pressure
injection mode.
Returns column input pressure to value of
analysis parameter.
181 Turns On APC1 flow controller. Turns Off APC1 flow controller.
201 Turns On AMC1 flow controller. Turns Off AMC1 flow controller.
17 Printing
17.4 Event No.
282
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For dual AFC, there are no gas saver, splitter, septum purge, or high pressure injection modes.
283
18.1 18. 18.
GC-2014
18 Error Messages
18.1Error Messages
This system is programmed to self-diagnose certain errors. When an error is detected, an
alarm sounds and one of the error messages shown below is displayed. The detected errors
are recorded in the Error Log.
For errors of which the CS column in the table below shows Yes, a screen to confirm about
resetting them appears. When the confirmation screen appears, select one of the following
actions:
Codes shown in the tables below identify errors. Provide the code when calling service
representative about an error. These codes are also recorded in the error log.
18.1.1 System errors
Power supply failure
If the above error messages appear, the hardware has failed. The GC system cannot be
used in this condition. Turn off the system and contact your Shimadzu representative.
Room temperature sensor/atmospheric pressure sensor error
The room temperature or atmospheric pressure is out of the performance range. If this error
occurs even though the actual room temperature/atmospheric pressure is within the range,
the sensors may have failed. The system cannot be used in this condition. Turn off the
system and contact your Shimadzu representative.
Reset Error Resets the system parameters, restoring the conditions prior to the error.
System control resumes. If the cause of the error has been corrected, the
error does not occur any more.
Ignore Error Select this to keep the system as it is for a while for some reason, for
example, in order to remove the cause of the error.
Code Message CS
0001 DC 5 V is out of range No
0002 DC 24 V is out of range No
0003 DC -15 V is out of range No
Code Message CS
0005 Room temperature is out of range No
0006 Atm. pressure is out of range No
18 Error Messages
18.1 Error Messages
284
GC-2014
PCB failure
Clock reset
The built-in clock has been reset. As a result, other saved parameters may have changed.
Check the configuration, installation, and flow rate settings. Initialize the parameters or reset
them if necessary. If the same message is displayed repeatedly, the hardware has failed.
The GC system cannot be used in this condition. Turn off the system and contact your
Shimadzu representative.
A/D converter failure, feedback loop communication error
Low voltage of CPU board battery
The battery on CPU board is dead. It must be replaced. Turn off the system and contact your
Shimadzu representative.
Code Message CS
0007 DET#1 PCB error No
0011 CAR1 AFC PCB error No
0012 CAR2 AFC PCB error No
0013 Det APC1 PCB error No
0023 APC 1-3 PCB error No
Code Message CS
0029 Clock is initialized No
Code Message CS
0030 COL A/D conv. error No
0031 INJ1-DET2 A/D error No
0032 AUX3-AUX5 A/D error No
0033 Loop back test error No
Code Message CS
0034 Battery voltage error No
18 Error Messages
18.1 Error Messages
285
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Cooling fan error
The GC cooling fan is out of order. The system cannot perform fully in this condition. Turn off
the system and contact your Shimadzu representative.
Damaged in electronics
A repair is necessary. Contact your Shimadzu representative.
Abnormal PRG current
Electric current in the optional PRG board is abnormal. The system cannot be used in this
condition. Turn off the system and contact your Shimadzu representative.
Flow controller AMC board failure
Code Message CS
0035 Cooling fan error No
Code Message CS
0036 ROM error No
0037 RAM error No
0038 CPU register error No
Code Message CS
0039 PRG current error Yes
Code Message CS
0040 CAR1 DAFC PCB error No
0041 CAR2 DAFC PCB error No
0042 AMC 1-2 PCB error No
0047 CAR1 SAFC PCB error No
0048 CAR2 SAFC PCB error No
18 Error Messages
18.1 Error Messages
286
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18.1.2 Temperature control errors
Heat loss
This message appears when heat loss is substantial. The oven door may be open or the
insulation has a hole. If the column oven door is open, close it and select Reset Error. If the
insulation has a hole in it, turn off the power of the unit, repair the hole, and then restart the
system.
This error may not occur even when the door is open when the column oven temperature is
set at a certain range or the temperature around the unit is a certain level.
Temperature increase limit over
These messages appear when the maximum temperature limit has been exceeded. Press
Ignore Error and change the maximum limit temperature. If the confirmation screen to reset
the error appears again, press Reset Error.
Code Message CS
1001 Heat is escaping Yes
Code Message CS
1002 COL temp exceed the limit Yes
1003 INJ1 temp exceed the limit Yes
1004 DET1 temp exceed the limit Yes
1005 INJ2 temp exceed the limit Yes
1006 DET2 temp exceed the limit Yes
1007 AUX3 temp exceed the limit Yes
18 Error Messages
18.1 Error Messages
287
GC-2014
Temperature sensor errors
When one of these messages appears, the temperature sensor may have failed. The sensor
cannot be used in this condition and replacement or repair is required. Turn off the system
and contact your Shimadzu representative.
Unstable temperature with CRG
This message appears when cooling is impossible because of insufficient coolant, etc.
If there is no coolant, turn off the system, replace the coolant, and then restart the system.
This message may appear when cooling is impossible because the oven door is open. In
this case, close the door and press Reset Error.
Code Message CS
1010 COL sensor is short circuit Yes
1011 INJ1 sensor is short circuit Yes
1012 DET1 sensor is short circuit Yes
1013 INJ2 sensor is short circuit Yes
1014 DET2 sensor is short circuit Yes
1015 AUX3 sensor is short circuit Yes
1018 COL sensor is down Yes
1019 INJ1 sensor is down Yes
1020 DET1 sensor is down Yes
1021 INJ2 sensor is down Yes
1022 DET2 sensor is down Yes
1023 AUX3 sensor is down Yes
1026 COL sensor is error Yes
1027 INJ1 sensor is error Yes
1028 DET1 sensor is error Yes
1029 INJ2 sensor is error Yes
1030 DET2 sensor is error Yes
1031 AUX3 sensor is error Yes
Code Message CS
1034 COL CRG cannot be controlled Yes
18 Error Messages
18.1 Error Messages
288
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Overheat
An error may have occurred in the temperature control circuit.
Turn off the system and contact your Shimadzu representative.
Relay/heater control circuit errors
An error may have occurred in the control circuit.
Turn off the system and contact your Shimadzu representative.
Detector temperature setting error
These messages appear when the Detector temperature setting value is smaller than that of
the Oven. Increase the Detector temperature.
To have the Detector temperature lower than the column oven temperature, set No on
Protection against contamination (PF menu) on the screen to set the maximum temperature
on configuration setting.
Code Message CS
1036 Overheat is sensed Yes
1037 COL temp controller broken No
1038 INJ1 temp controller broken No
1039 DET1 temp controller broken No
1040 INJ2 temp controller broken No
1041 DET2 temp controller broken No
1042 AUX3 temp controller broken No
Code Message CS
1045 COL relay error No
1046 INJ1-DET2 relay error No
1047 AUX3-AUX5 relay error No
1048 Heater controller error No
Code Message CS
1049 DET#1 set temp is low No
18 Error Messages
18.1 Error Messages
289
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18.1.3 Pressure/flow rate errors
Leaks
The pressure cannot reach the set value. Check whether gas is supplied and whether gas is
leaking from connections.
Gas may be leaking in locations other than the ones displayed.
(Example) If the purge flow rate is too low because of the leakage of carrier gas line, the message
Purge leaks appears in stead of the indication of ESC or TFC leakage.
Code Message CS
2005 CAR1 purge leaks Yes
2014 DetAPC1 makeup gas leaks Yes
2015 DetAPC1 hydrogen leaks Yes
2016 DetAPC1 air leaks Yes
2026 APC1 leaks Yes
2027 APC2 leaks Yes
2028 APC3 leaks Yes
2029 APC4 leaks Yes
2030 APC5 leaks Yes
2031 APC6 leaks Yes
2032 APC7 leaks Yes
2033 APC8 leaks Yes
2034 APC9 leaks Yes
2035 APC10 leaks Yes
NOTE
18 Error Messages
18.1 Error Messages
290
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Valve leak errors
Gas is flowing even if the pressure is set at 0 kPa or the flow rate is set at 0 ml/min. If there
is no problem with the gas supply, an AFC/APC value error may have occurred. Turn off the
system and contact your Shimadzu representative.
Code Message CS
2048 CAR1 purge valve leaks Yes
2057 DetAPC1 makeup valve leaks Yes
2058 DetAPC1 hydrogen valve leaks Yes
2059 DetAPC1 air valve leaks Yes
2069 APC1 valve leaks Yes
18 Error Messages
18.1 Error Messages
291
GC-2014
Abnormal component operation
Verify whether gas is supplied stably at the required pressure. If there is no problem with the
gas supply, the control system, such as the APC, may have failed. Turn off the system and
contact your Shimadzu representative.
Code Message CS
2091 CAR1 purge is out of control Yes
2100 DetAPC1 makeup gas is out of ctrl Yes
2101 DetAPC1 hydrogen is out of control Yes
2102 DetAPC1 air is out of control Yes
2112 APC1 is out of control Yes
18 Error Messages
18.1 Error Messages
292
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AFC leaks
The pressure cannot reach the set value. Check whether gas is supplied and whether gas is
leaking from connections.
Gas may be leaking in locations other than the ones displayed.
AFC valve leak errors
Gas is flowing even if the pressure is set at 0 kPa or the flow rate is set at 0 ml/min. If there
is no problem in the gas supply, an AFC value error may have occurred. Turn off the system
and contact your Shimadzu representative.
Verify whether gas is supplied stably at the required pressure. If there is no problem in the
When errors 2138-2140 occur, carrier gas is not properly supplied. Check the gas remaining
in the gas cylinder and piping connections.
Control setting errors
These messages appear when the temperature control starts without carrier gas control. Set
the setting of the flow controller to On or remove unused carrier gas line from the line
configuration.
Code Message CS
2130 CAR1 AFC leaks Yes
2131 CAR2 AFC leaks Yes
Code Message CS
2132 CAR1 AFC valve leaks Yes
2133 CAR2 AFC valve leaks Yes
Code Message CS
2134 CAR1 AFC is out of control Yes
2138 CAR1 prim is out of range No
Code Message CS
2141 CAR1 is not controlled No
NOTE
18 Error Messages
18.1 Error Messages
293
GC-2014
Verify whether gas is supplied stably at the required pressure. If there is no problem in the
18.1.4 Communication errors
External device communication errors (i.e., Chromatopac)
One of these messages appears during a link failure or communication failure. (When a
communication error occurs, the link is automatically disconnected.)
When one of these messages appears, check the connection status, and reset the link.
Code Message CS
2144 CAR1. L DAFC is out of control Yes
2145 CAR1. R DAFC is out of control Yes
2146 CAR2. L DAFC is out of control Yes
2147 CAR2. R DAFC is out of control Yes
2148 AMC.L is out of control Yes
2149 AMC.L is out of control Yes
2150 AMC.R is out of control Yes
2151 AMC1 is out of control Yes
2161 CAR1 SAFC is out of control Yes
2162 CAR2 SAFC is out of control Yes
Code Message CS
4001 Time out No
4002 Parity error No
4003 Message is not accepted No
4004 Data is invalid No
4005 Command is invalid No
4006 Data is out of range No
4007 TRS port is shut down No
4008 TRS file error No
18 Error Messages
18.1 Error Messages
294
GC-2014
AOC communication errors
One of these messages appears during a link failure or communication failure. (When a
communication error occurs, the link is automatically disconnected.)
When one of these messages appears, check the connection status, and reset the link.
18.1.5 Detector errors
Over current
Current of the detector is abnormal. If the resistance of the filament becomes abnormally
high when the TCD or the FTD is in use, the protection circuit is actuated to prevent damage
to the filament, and an alarm sounds.
If either error has occurred, turn off the system.
Possible reasons for the protection circuit to be activated are described below.
The set current value exceeds the maximum operating current.
Gas is not flowing.
Gas is leaking.
A significant amount of air is present in the flow line (for TCD).
Correct the error then turn on the system. If the system does not recover after several
resets, or the reason for the error cannot be located, contact your Shimadzu representative.
Code Message CS
4009 AOC command is invalid No
4010 AOC data is out of range No
4011 AOC time out No
4012 AOC2 TRS error No
4013 AOC link error No
Code Message CS
4101 DET#1 TCD cell error Yes
4105 DET#1 FTD current error Yes
18 Error Messages
18.1 Error Messages
295
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Detector flame error
The detector flame (FID, FPD) has been extinguished. Check the gas supply, and ignite the
detector again. If the flame error occurs repeatedly, the hardware has failed. The system
cannot be used in this condition. Turn off the system and contact your Shimadzu
representative.
FPD errors
There is a problem with the FPD detector. Refer to FPD Users Manual.
Errors 4125-4128, that are related to abnormal current, cannot be recovered without turning
off the system once.
TCD errors
The difference in filament resistance is high between the TCD cells, and the detector cannot
be zeroed. If the zero point cannot be adjusted even by turning the adjuster on the right side
of the unit, the detector control unit may have failed. The system cannot be used in this
condition. Turn off the system and contact your Shimadzu representative.
Code Message CS
4109 DET#1 flame is out No
Code Message CS
4113 DET#1 FPD battery error Yes
4117 DET#1 FPD temperature error Yes
4121 DET#1 FPD cooling fan error Yes
4125 DET#1 FPD current error Yes
Code Message CS
4201 TCD signal is out of range No
4202 TCD signal zero error No
18 Error Messages
18.1 Error Messages
296
GC-2014
Detector ignition errors
These messages appear when the FID or FPD do not ignite within a certain time after the
key is pressed.
Even when one of these messages appears, hydrogen gas keeps flowing when a manual
flow controller is used. Shut off the hydrogen gas for safety then check the following items.
(1) The column is connected
(2) Hydrogen is supplied at proper flow rate
(3) Air is supplied at proper flow rate
(4) Filament of the igniter is intact
(5) The jet of the FID is not clogged
(6) Unused FID is not set to On
This message appears when the APC (used to control detector gas) for hydrogen or air is
not Ready at the time of ignition. Check that the gas supply pressure is stable and whether
or not gas is leaking. If there is no problem with the gas supply, the hardware has failed. The
system cannot be used in this condition. Turn off the system and contact your Shimadzu
representative.
18.1.6 Program errors
Set value change
This message appears when a set value was changed while the program is running. If the
parameter or event has not yet been executed, the new value is used for the analysis.

Time over errors
These messages appear when the program execution time exceeds the maximum allowable
value (9999.99 min). Change the program so that its total execution time does not exceed
9999.99 min. Although the program can be executed even after this error occurs, it is
discontinued at 9999.99 min.
Code Message CS
4203 DET#1 ignition failed No
Code Message CS
4207 H2, AIR APC are not ready No
Code Message CS
4301 Settings were changed No
Code Message CS
4302 Program time is over No
4303 Clean up time is over No
4304 Pre-run prog. time is over No
18 Error Messages
18.1 Error Messages
297
GC-2014
18.1.7 Operations errors
Value outside of range was entered
When the numeric value entered is out of the valid range, this message or valid setting
range is displayed. Enter a valid number.
File operation errors
These massages appear when an incorrect file operation was attempted.
Press another key, and continue operation.
Overflow of calculated pressure value
The carrier gas pressure is calculated from the linear velocity, flow rate, or the split ratio. The
value you have input is outside the set range. Change the conditions so that the pressure is
within the set range, and enter a new value.
Overflow of calculated flow rate value
The carrier gas total flow rate is calculated from the split ratio or the pressure. The value you
have input is outside the set range. Change the conditions and enter a new value.
Code Message CS
5001 Input parameter out of range No
Code Message CS
5002 Invalid file no. No
5003 This file is now used No
Code Message CS
5006 CAR1 calc. prss out of range No
Code Message CS
5009 CAR1 calc. flow out of range No
18 Error Messages
18.1 Error Messages
298
GC-2014
Overflow of calculated APC pressure value MUP=makeup, HGN=hydrogen, AIR=air,
PUR=purge
Code Message CS
5012 MUP1 calc. prss out of range No
5013 HGN1 calc. prss out of range No
5014 AIR1 calc. prss out of range No
5024 APC1 calc. prss out of range No
5042 PUR1 calc. prss out of range No
18 Error Messages
18.1 Error Messages
299
GC-2014
The pressure calculated from the flow rate you have input is outside the set range. Change
the conditions and enter a new value.
Overflow of calculated pressure value during a linear velocity program
The carrier gas pressure calculated from the linear velocity you have input is outside the set
range. Change the conditions and enter a new value.
Overflow of calculated flow rate value in programs
The carrier gas total flow rate calculated from the split ratio program you have input is
outside the set range. Change the conditions and enter a new value.
Code Message CS
Code Message CS
5075 CAR1 calc. ratio out of range No
5076 CAR2 calc. ratio out of range No
Code Message CS
18 Error Messages
18.1 Error Messages
300
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18.1.8 Optional device error (AOC-20i/s)
One of these messages appears when an error has occurred in the AOC-20i auto injector or
AOC-20s auto sampler.
For details, refer to the AOC-20i/s Users Manual.
Code Message CS
6001 AOC1 rack error No
6002 AOC1 syringe error No
6003 AOC1 plunger error No
6004 AOC1 can not start No
6005 AOC1 RAM initialized No
6006 AOC1 ROM error No
6007 AOC1 CH2 command error No
6008 AOC1 sample vial is not set No
6009 AOC1 RAM error No
6010 AOC1 installation error No
6011 AOC1 CH1 error No
6013 AOC1 waste vial is not set No
6014 AOC-20s rotating error No
6015 AOC-20s exp. and ctrl. error No
6016 AOC-20s up/down error No
6017 AOC-20s can not start No
6018 AOC-20s vial setting error No
6019 AOC-20s vial returning error No
6020 AOC-20s holding error No
6021 AOC-20s sample vial removed No
6022 AOC-20s vial is not set No
6023 AOC2 rack error No
6024 AOC2 syringe error No
6025 AOC2 plunger error No
6026 AOC2 can not start No
6027 AOC2 RAM initialized No
6028 AOC2 ROM error No
6029 AOC2 CH2 command error No
6030 AOC2 sample vial is not set No
6031 AOC2 RAM error No
6032 AOC2 installation error No
6035 AOC2 waste vial is not set No
18 Error Messages
18.1 Error Messages
301
GC-2014
18.1.9 Warning messages
These messages appear when the time or the count exceeds the set value. Replace the
subject component and reset the count on the menu of the DIAG key screen.
Code 9002 warning requires component replacement and counter reset by a serviceperson.
Contact your Shimadzu representative.
This message appears when the system was started before it was ready. Normally, do not
start analysis until the system is ready.
If this message appears when all the parameters including temperature and flow rate are
ready, check the ready setting for unused components and check the equilibration time.
This message appears when ignition sequence was re-attempted because the ignition
failed. This does not stop the execution of analysis. If this message appears frequently,
check DETECTOR IGNITE and DETECTOR IGNITION by the standard diagnosis
procedure. Also check for gas leaks and verify the gas flow rates. If set values are correct,
These messages appear when the sensor use time exceeds the preset value. Component
replacement and reset by a serviceperson are required. Contact your Shimadzu representative.
Code Message CS
9000 COL CRG use time is over Yes
9001 INJ2 CRG use time is over Yes
9002 Fan use time is over Yes
9004 CAR1 septum counter is over No
9007 CAR1 insert counter is over No
Code Message CS
9010 System is not ready No
Code Message CS
9011 Ignition finished (retried) No
Code Message CS
9012 COL sensor use time is over Yes
9013 INJ1 sensor use time is over Yes
9014 DET1 sensor use time is over Yes
9015 INJ2 sensor use time is over Yes
9016 DET2 sensor use time is over Yes
9017 AUX3 sensor use time is over Yes
18 Error Messages
18.1 Error Messages
302
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These messages appear when the detector (FID, FPD) cannot be ignited. Check the
detectors line configuration and set detector control and temperature control to On before
ignition.
Code Message CS
9020 Temperature is not controlled No
9021 Detector is not controlled No
9022 FID/FPD is not installed No
303
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19 Index
A
Actual (current) values 69
AD CONVERTER 176
AFC 129
analysis counter 188
ANALOG SIGNAL TYPE 155, 167
Analysis counter 188
Analysis log 183
AOC 195
AOC commands 275
APC 159
ATMOSPHERIC COMPENSATION 253
ATMOSPHERIC PRESS 175
AUTO IGNIT 80
Auto Injector 195
automatic ignition 156
automatic re-ignition 156
AUX AMC 207
AUX APC 205
B
BACK LIGHT AUTO OFF 253
BACKGROUND SIG COMP. 155, 167
BACKGROUND SIG. SAVE 155, 167
batch schedule 219
BAUD RATE 238
BEEP 253
C
CARRIER GAS TYPE 131, 148
CE key 67, 68
Changing item names 75
Checking 15
Chng Graph 105
chromatogram 103
CLEAN UP 80
Clean up 82
Clear key 68
COL key 68, 113
COLUMN FLOW RATE 92, 122, 129, 147
Column inner diameter (I.D.) 133
COLUMN LENGTH 133
COLUMN OVEN 92, 114
Computer for Insert 188
Computer for Septum 188
CONTROL MODE 93, 122, 130, 148
Coolant Consumption Counter 190
COUNTER FOR INSERT 175
COUNTER FOR SEPTUM 175
CPU 176
CPU REGISTOR 175
CRG 190, 207
CRG USE TIME 175
CURRENT 166
CURRENT FILE 80
cursor 73
Cursor key 68
Cursor keys 67
D
DATE 236
day 212
DC VOLTAGE 175
DET key 68, 154, 165
DET SIG SUBTRACTION 155, 167
DETECTOR 80
DETECTOR ADC REGISTER 175
DETECTOR CONTROLLER 154, 165
Detector Gas 157, 159
DETECTOR HV SOURCE 175
DETECTOR IGNITE 176
DETECTOR IGNITION 176
DETECTOR ROM 175
detector signals 242
DETECTOR TEMP 93
DIAG key 67, 68, 173
Diagnostic log 187
DRIFT 240
drying-out 6
dual AFC 122
Dual FID 154
E
ECD FREQUENCY 176
ENTER 67
ENTER key 68
Entering numeric values 74
EQUILIBRATION TIME 114
Error log 186
Event No. 279
F
Fan Off 114
Fan On 114
FAN USE TIME 175
FID 153
File 95
file copy 96
file initialization 97
FILE LOAD 87
FILM THICKNESS 124, 133
FILTER TIME CONSTANT 155, 167, 170
FLOW CONTROL 80
FLOW key 68, 129

304
GC-2014
FLOW lamp 67
FLOW lights 70
FLOW OFF TIME 80
Flow Rate 122
Flow rate program 137
flow signal 243
FUNC key 67, 68, 211
Fuse 6
G
GAS CONTROL 176
gas filter 13
Gas saver 134
GC CONFIGURATION 235
GC OPERATION LOG 182
H
Heating energy generation 5
Help 77
HELP key 67, 68, 77
HETP 150
High Pressure Injection 143
Hydrogen flame ionization detector 153
hydrogen gas 10
I
INITIALIZATION 261
INJ key 68
INLET PRESS 92, 129, 147
Inlet pressures 122
INSTALLATION (PIPING) 258
INSTALLATION (POSITION) 256
isothermal analysis 115
K
Key locking 265
L
LANGUAGE 253
LCD USE TIME 175
leaks 15
LINEAR VELOCITY 92, 129, 147
link device code 250
Load 95
LONGEST PROGRAM TIME 105
M
Maint INJ 81
MAKE UP 160
MONIT key 67, 68, 103
monitor injection screen 109
Monitoring the Flow Rate 107
Monitoring the Temperature 106
N
N/A 180
N/I 180
N/S 180
N/T 180
O
Offset 123, 132, 148, 160
OPTION key 68
Optional Devices 195
Oven Temperature 113
OVER TEMP PROTECTION 176
P
Parameter locking 266
Parameter log 185
PARITY 238
password 267
Peak Genarator 194
PF key 67, 68, 72
PF menu 72
power cable 4
Power consumption 262
power supply 4
Pre-Run program 231
Pressure program 135
PRESSURE UNIT 253
PRIMARY PRESS 175, 253
primary pressure 253
Printing 271
Programmed analysis 115
PROTOCOL 238
PURGE FLOW RATE 93
purge flow rate 148
R
RAM 176
Ready Check 239
REAL TIME CLOCK REGISTOR 175
REMAIN TIME 105
Index
F-O
305
GC-2014
RESET IC 176, 177
RESTART GC 80
RETENTION TIME (Rt) 105
ROM 176
ROOM TEMPERATURE 175
S
SAMPLING TIME 93, 130
Schedule number 212
Screen 67, 69
Septum purge flow rate 93
septum purge flow rate 93, 141
SET key 68, 91
set values 69
SIGNAL ATTENUATION 155, 167
SIGNAL OUTPUT PORT 155, 167
SIGNAL POLARITY 155, 166
SIGNAL RANGE 155, 167
SLEEP TIME 80
Split injection system 126
SPLIT MODE 93, 130
SPLIT RATIO 92, 130
Split ratio program 139
Splitless injection system 126
Splitter Fix 143
Standard Diagnosis 173
Standard Installation Test 192
START key 67, 68, 111, 112
start procedure 86
START TEMP/DET 80
START TIME 80
Starting an Analysis 109
STATUS 70
STATUS lamp 67
STOP BIT 238
STOP key 67, 68, 112
stop procedure 88
STOP TIME 80
Stopping Analysis 112
Stopwatch 263
SYSTEM key 67, 68
T
TCD 164
TEMP 70, 114, 154, 165
TEMP lamp 67
TEMP SENSOR DIAG 175
TEMP SENSOR USE TIME 175
temperature control signal 242
Temperature offset 251
temperature program 115
Thermal Conductivity Detector 164
TIME 236
Time Program 225
Time Scheduler 211
Toggle key 68, 72
TOTAL FLOW RATE 92, 130, 148
U
UNIT key 67
V
VALVE 210
VLV Off 156
VLV On 156, 157
W
WATCH DOG TIMER 176
Z
Zero Adj 105, 108
Zero Free 105, 108
Zero free 108
Symbol
68, 72
67, 68

306
GC-2014

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What are the two manuals that make up the GC-2014 user's manual?

What safety precautions are included in the operation manual?

221-40609A

GC-2014 Gas Chromatograph

PF1 PF2 PF3

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6 Basic Key Operation

6 Basic Key Operation

6 Basic Key Operation

8 Setting the Analytical Parameters and File Management

8 Setting the Analytical Parameters and File Management

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Stop Stops counting.

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