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PROCESS - NH3 Process Block Diagram

Feed Desulphurization Steam / Secondary


(Natural Gas) Steam/Carbon Reforming CO Conversion
① Hydrogenation
=2.7
CH4 : 91.04 % : Organic S → H2S
C2H6 : 6.48 % CH4, CnHm + H2O CO + H2O → CO2, H2
C3~C6 : 0.03% ②Desulphurization
N2 : 0.59 % : ZnO + H2S → → CO, CO2, H2
MP Steam
CO2 : 1.86 % ZnS + H2O
AIR(N2) HP Steam BFW
To Fuel system 4 CO2 to
(Incl. excess N2 & CH4) stage
Urea Unit
Ammonia Recycle Purge Gas
Recovery Regen. Gas
Methanation & Dryer
Ammonia Synthesis CO2 Removal
NH3 ① Methanation
Purge Gas N2+3H2 → 2NH3 BASF’s
Purifier : CO, CO2 + H2
→ CH4 + H2O OASE Process
Refrigeration Ammonia Converter 2 Maintain
: Residual CO,CO2
: Three thermodynamic stages stage H2/N2 = 2.988 : Residual CO2
< 5 ppm
with inter-cooling < 500 ppm
②Dryer
: Residual H2O, CO2 & NH3
BFW HP Steam < 1 ppm
Liquid
NH3 < Source of H2, N2 >
- H2 from Natural Gas and H2O
- N2 from Air
PROCESS – Simplified PFD
Cryogenic Purifier
Utility & Off Site

Tie in (at Battery limit) Natural Gas Laboratory & Workshop


- River water - Process Gas / Fuel Gas - New Lab. Building and Equipment
- Natural Gas from Existing NG - PSVs
Transfer Pipe - Metering & Distribution

Raw Water Treatment Demineralized Water System Potable Water System


- River water (17 km apart from site) - N+1 train - RO package
- Intake system - Anion/Cation Beds / Mixed Bed - Chlorination unit
- Clarifier, MF, Chemical dosing - Online Analyzer - UV sterillisation unit
- Resin Regeneration

Cooling Water System Steam System Power Generation


- Cooling Tower (No spare cell) - Auxiliary Boilers (50% x 2) - Steam Turbine Generator (25MW)
- C.W. Pumping Station - Boiler Feed Water - EDG (5.6MW); Considering start-up
- Chemical Dosing Unit - Steam System power
- Emergency Cooling Water for Critical - Black Start (No External Power Grid)
Items in case of Power Failure
Utility & Off Site

Instrument & Plant Air Inert Gas Waste Water & Effluents
- One Standby Motor Driven Air - High Purity Nitrogen obtained from - Centralized Effluent Treatment
Compressor ASU package - Oily Water Separation
- Air Dryer (Oxygen Content 0.1% v/v) - NH3 & Urea Off Spec. Condensate
- IA Reservoir - Rain Water

Ammonia Storage

- 6,000 MT Anhydrous Ammonia Storage (DWT)


- Surplus Ammonia to be sent to Ammonia Tank
- Boil-Off Ammonia Vapors to Process Refrigeration
- Product Ammonia Transfer from Storage to Urea
- Anhydrous Ammonia Export by Truck Loading Facility

Urea Handling & Storage

- 42,000 MT Urea Bulk Storage Warehouse


- Bagging storage: 7000 MT
- Bagging system : 1000kg X 2 train,
- 125 MT/hr Reclaimer
- Conveyor Belt from Granulation Unit to Warehouse

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