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Gay-Lussac's Law

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GAY-LUSSAC’S LAW

• Gay-Lussac's Law states is a gas law


which states that the pressure exerted by
a gas (of a given mass and kept at a
constant volume) varies directly with the
absolute temperature of the gas. In other
words, the pressure exerted by a gas is
proportional to the temperature of the
gas when the mass is fixed and the
volume is constant.
JOSEPH LOUIS GAY-LUSSAC
-FRENCH CHEMIST WHO FORMULATED THE GAY-LUSSAC’S LAW
IN THE 1808.
• The relationship between the pressure and absolute temperature of a
given mass of gas (at constant volume) can be illustrated graphically
as follows.

 It can be understood that the pressure of a gas (kept at constant


volume) reduces constantly as it is cooled until the gas eventually
undergoes condensation and becomes a liquid.
• Formula and Derivation
• Gay-Lussac’s law implies that the ratio of the initial pressure and temperature
is equal to the ratio of the final pressure and temperature for a gas of a fixed
mass kept at a constant volume. This formula can be expressed as follows:
• (P1/T1) = (P2/T2)
• Where:
• P1 is the initial pressure
• T1 is the initial temperature
• P2 is the final pressure
• T2 is the final temperature
• This expression can be derived from the pressure-temperature proportionality
for gas. Since P ∝ T for gases of fixed mass kept at constant volume:
• P1/T1 = k (initial pressure/ initial temperature = constant)
• P2/T2 = k (final pressure/ final temperature = constant)
• Therefore, P1/T1 = P2/T2 = k
• Or, P1T2 = P2T1
Examples of Gay-Lussac’s Law
When a pressurized aerosol can (such as a deodorant can or a spray-paint can) is heated, the resulting
increase in the pressure exerted by the gases on the container (owing to Gay-Lussac’s law) can result in
an explosion. This is the reason why many pressurized containers have warning labels stating that the
container must be kept away from fire and stored in a cool environment.

An illustration describing the increase in pressure which accompanies an increase in


the absolute temperature of a gas kept at a constant volume is provided above.
Another example of Gay-Lussac’s law can be observed in pressure cookers. When the
cooker is heated, the pressure exerted by the steam inside the container increases.
The high temperature and pressure inside the container cause the food to cook faster.
• Solved Exercises on Gay-Lussac’s Law
• Exercise 1
• The pressure of a gas in a cylinder when it is heated to a temperature of 250K is
1.5 atm. What was the initial temperature of the gas if its initial pressure was 1
atm.
• Given,
• Initial pressure, P1 = 1 atm
• Final pressure, P2 = 1.5 atm
• Final temperature, T2 = 250 K
• As per Gay-Lussac’s Law, P1T2 = P2T1
• Therefore, T1 = (P1T2)/P1 = (1*250)/(1.5) = 166.66 Kelvin.
• Exercise 2
• At a temperature of 300 K, the pressure of the gas in a deodorant can is 3 atm.
Calculate the pressure of the gas when it is heated to 900 K.
• Initial pressure, P1 = 3 atm
• Initial temperature, T1 = 300K
• Final temperature, T2 = 900 K
• Therefore, final pressure (P2) = (P1T2)/T1 = (3 atm*900K)/300K = 9 atm.

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