Acids: Alkalis
Acids: Alkalis
TITRATIONS
-FINALS
ACIDS – DANGEROUS OR SAFE ???
HOW TO UNDERSTAND WHETHER
WE HAVE AN ACID OR A BASE?
pH Scale
• Ranges from 0-14
• Determines the strength of an acid of a base.
HOW TO MEASURE pH THEN???
(1) Universal Indicators
• It is made of a mixture on indicators.
• Changes color according to pH.
• It can be used as solution or paper.
• Most Common
– FULL RANGE UNIVERSAL INDICATOR
• Changes color from 1-14
But not very accurate
• Later it is checked against a chart to
find pH
(2) pH Meter
• Another method of measuring
the pH of a substance is to use
a pH meter.
• When you place the electrode
into the solution, the
electronic display shows the
pH level.
ACID-ALKALI INDICATORS
• Any substance that changes color according to pH can be used as an
indicator.
• In neutral solutions, color is purple (mixture of red and blue) for litmus.
• Universal indicator is green in neutral solutions.
ACIDS
• All acids have H.
• When acids react, the H gets replaced.
HCl + NaOH NaCl + H2O
H from HCl is replaced by Na.
• But not all H are replaceable.
In CH3COOH, H that is attached to O is
replaceable, but H attached to C is not.
• Acids dissociate in water.
HCl H+ + Cl-
• While measuring pH, we measure the
conc. of H+ ions in solution i.e why H in
pH is written in capital letters.
• Acids can be of two types:
• i. Strong acid. Those which ionizes fully in water.
• ii. Weak acid. Those which ionizes partially/incompletely in water.
BASES
• Bases are substances which neutralize acids by combining with H ions.
• Base usually means metal oxide, metal hydroxide or ammonia.
ALKALI
S
• Bases dissolve in water to form OH- ions.
Thus, they are alkalis.
• Eg: NaOH, KOH etc
• NaOH dissociate in water to form:
NaOH Na+ + OH-
• NH3 solution reacts with water to form:
NH3 + H2O NH4 + OH-
• Metal carbonates like
Na2CO3 + H2O NaOH + NaHCO3
• All these are alkaline and have a pH
greater than 7.
NEUTRALIZATION
REACTIONS
• Neutralization: A Reaction in which Acidity or Alkalinity is removed.
• Alkali + Acid, pH rises as the alkali reacts with acid forming a neutral solution.
• Acid + Alkali, pH falls as the acid reacts with base forming a neutral solution.
REACTION OF ACIDS WITH BASES – NEUTRALIZATION
REACTIONS
• Acid – H2SO4
• Base – CuO or MgO
• The following reaction takes place –
• + +
Copper (II) Oxide Hot Dilute Sulphuric Acid Copper (II) Sulfate (salt) Water
• Cu(II)O is an ionic compound; have O2- ion. H+ from H2SO4 combines with it and forms H2O.
ACIDS WITH ALKALIS – Neutralization
Reactions
• Acid – Dil. HCl
• Alkali – NaOH solution
• Both are ionic compounds and will
be present as ions.
• Na+ and Cl- are there on both sides.
Thus spectator ions are removed and
the ionic equation is obtained.
• All alkalis and acids react in the same
way and form water.
TITRATION
• Method to determine how much acid/alkali reacts with known volume
of alkali/acid.
• Volume of Acid Added = Starting Volume of Acid – Final Volume of Acid