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    Section 3: Naming Ionic Compounds: Chapter 5: Molecules and Compounds

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    DeonLeo Cuenca
    This document discusses naming ionic compounds. It explains that ionic compounds have both systematic and common names. It describes how to name binary ionic compounds containing metals that form only one type of ion or multiple types of ions. It also discusses how to name ionic compounds containing polyatomic ions, including oxyanions. Practice problems are provided for writing names from formulas and formulas from names.

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    Section 3: Naming Ionic Compounds: Chapter 5: Molecules and Compounds

    Uploaded by

    DeonLeo Cuenca
    79 views27 pages
    This document discusses naming ionic compounds. It explains that ionic compounds have both systematic and common names. It describes how to name binary ionic compounds containing metals that form only one type of ion or multiple types of ions. It also discusses how to name ionic compounds containing polyatomic ions, including oxyanions. Practice problems are provided for writing names from formulas and formulas from names.

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    5.3 Naming Ionic Compounds

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    This document discusses naming ionic compounds. It explains that ionic compounds have both systematic and common names. It describes how to name binary ionic compounds containing metals that form only one type of ion or multiple types of ions. It also discusses how to name ionic compounds containing polyatomic ions, including oxyanions. Practice problems are provided for writing names from formulas and formulas from names.

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    79 views27 pages

    Section 3: Naming Ionic Compounds: Chapter 5: Molecules and Compounds

    Uploaded by

    DeonLeo Cuenca
    This document discusses naming ionic compounds. It explains that ionic compounds have both systematic and common names. It describes how to name binary ionic compounds containing metals that form only one type of ion or multiple types of ions. It also discusses how to name ionic compounds containing polyatomic ions, including oxyanions. Practice problems are provided for writing names from formulas and formulas from names.

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    of 27

    Chapter 5: Molecules and Compounds

    Section 3: Naming Ionic


    Compounds
    Learning Goals
    Distinguish between common and systematic
    names for compounds.
    Name binary ionic compounds containing a
    metal that forms only one type of ion.
    Name binary ionic compounds containing a
    metal that forms more than one type of ion.
    Name ionic compounds containing a
    polyatomic ion.
    Naming Compounds
    Chemists have developed systematic ways to
    name compounds.
     If you learn the naming rules, you can examine a
    compound’s formula and determine its name,
    and vice versa.
    Many compounds also have a common name.
     NaCl has the common name salt and the
    systematic name sodium chloride.
    Naming Ionic Compounds
    Identify if the metal cation has more than
    one potential charge.
     Such metals are usually (but not always) found
    in the transition metals section of the periodic
    table.
     Notable Exceptions:
    ▪ Always Zn2+ and Ag+
    ▪ Sn and Pb can have multiple charges
    Binary Ionic Compounds
    Binary compounds are those that
    contain only two different elements.
    The names for binary ionic compounds
    containing a metal that forms only one
    type of ion have the following form:
    Name of Cation + Base Name of Anion + ide
    Binary Ionic Compounds
    Since the charge of the metal is always
    the same for these types of compounds,
    it need not be specified in the
    compound’s name.
     Example: MgF2
    Binary Ionic Compounds
    Practice
    Name these compounds:
     CaO
     Al2O3
     KF
     MgCl2
     Li3N
    Practice
    Write the formula for these ionic
    compounds:
     Potassium bromide

     Sodium oxide

     Zinc nitride
    Binary Ionic Compounds
    If the cation could have more than one
    charge, then the charge must be
    specified in the metal’s name.
     We specify the charge with a Roman
    numeral (in parentheses) following the
    name of the metal.
    Binary Ionic Compounds
    For example, we distinguish between
    Cu+ and Cu2+ by writing a (I) to indicate
    the 1+ ion or a (II) to indicate the 2+ ion:
     Cu+ Copper(I)
     Cu2+ Copper(II)
    Binary Ionic Compounds
    These compounds are named using the
    following form:

    Name of (charge of metal in Base Name of


    Cation
    + roman numerals)
    +
    Anion + ide
    Binary Ionic Compounds
    We can determine the charge of the
    metal from the chemical formula of the
    compound.
     The sum of all the charges must be zero.
    Binary Ionic Compounds
    What is the charge of iron in FeCl3?
     +3
    What is the name for FeCl3?
     Iron (III) Chloride
    Practice
    Name the following compounds:
     PbCl4

     PbO

    Explain why CaO is not named calcium (II)


    oxide.
    Practice
    Write the formula for the following
    compounds:
     Chromium (II) chloride

     Tin (IV) oxide

     Iron (III) oxide


    Polyatomic Ionic Compounds
    Ionic compounds containing polyatomic
    ions are named using the same
    procedure we apply to other ionic
    compounds, except that we use the
    name of the polyatomic ion whenever it
    occurs.
    Polyatomic Ionic Compounds
    For example, we name KNO3 using its
    cation, K+, potassium, and its
    polyatomic anion, NO3-, nitrate.
     KNO3 potassium nitrate
    Practice
    Fe(OH)2

    NH4NO3
    Practice
    Write the formula for the following
    compounds:
     barium nitrate

     ammonium iodide

     iron (III) hydroxide


    Polyatomic Ionic Compounds
    Many polyatomic ions are oxyanions,
    anions containing oxygen.
    When a series of oxyanions contain
    different numbers of oxygen atoms,
    they are named systematically
    according to the number of oxygen
    atoms in the ion.
    Polyatomic Ionic Compounds
    If there are two ions in the series, the one
    with more oxygen atoms is given the
    ending -ate and the one with fewer is
    given the ending -ite.

    NO3− nitrate SO42− sulfate


    NO2− nitrite SO32− sulfite
    Polyatomic Ionic Compounds
    If there are more than two ions in the series,
    then the prefixes hypo-, meaning “less
    than,” and per-, meaning “more than,” are
    used.
     ClO − hypochlorite BrO − hypobromite
    ClO2− chlorite BrO2− bromite
    ClO3− chlorate BrO3− bromate
    ClO4− perchlorate BrO4−perbromate
    Practice
    K2CrO4

    Mn(NO3)2
    Practice
    Write the formula for the following
    compounds:
     sodium perchlorate

     sodium chlorite

     sodium nitrate

     sodium nitrite

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