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Ionic Compounds 4.1

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4.

1 Ionic Compounds (Salts)

Page:104-110
https://www.youtube.com/watch?v=kShlfIsvWbQ
Ionic compounds  ionic bond
Ionic bonding is a type of chemical bonding that involves the
electrostatic attraction between oppositely charged ions. It is much
stronger than covalent bonds (which are present in covalent
compounds). That’s why ionic compounds have higher melting and
boiling point.
Formation of an ionic compounds: Following the octet rule!

Ionic crystal structure of NaCl


Ionic compound
• Consists of a cation and an anion.

Ion
One kind of atom two or more kind of atoms

Monoatomic Polyatomic
ions ions
Na+, Cl-, Al3+ SO32-, NO3-, OH-, NH4+
figure 4.3 & 4.4 figure 4.5
Names of the ions
• Cations
Na+ = sodium ion
Exception: Transition metals have more than one charges
Fe2+= iron(II) ion, Fe3+= iron(III) ion
• Anions
Cl-= chloride ion
Exception: Some anions have special names. Figure 4.4
P3-= phosphide ion
Chemical formula of ionic compounds
Question: What is the chemical formula of magnesium chloride?
Answer:
Step 1: Find magnesium and chlorine in the periodic table and write
them as ions.
Mg2+ and Cl-
Step 2: In order to have a neutral ionic compound, find out the ratio
between these ions.
The ratio between Mg2+ and Cl- is 1:2.
The chemical formula of magnesium chloride is MgCl2
Exercises
Magnesium chloride Mg Cl Calcium carbonate
Ions Mg2+ Cl- Ions
Charge 2+ 1- Charge
Ratio 1 2 Ratio
Formula Formula

Aluminium hydroxide Silver nitrate


Ions Ions
Charge Charge
Ratio Ratio
Formula Formula
Rule 1. The cation is written first

Naming ionic compounds in the name; the anion is written


second in the name.

Rule 2. The name of the cation is


the same as the (neutral)
• MgBr2=magnesium bromide element from which it is derived
(e.g., Na+ = "sodium").
• CaO=calcium oxide
• NaNO3=sodium nitrate Rule 3. The anion is named by
adding the suffix -ide to the root
of the element name (e.g., I- =
• FeCl3= ? "iodide").
Formula Name
Rule 4. Some atoms like Fe,Cu…
LiOH Lithium hydroxide
may have more than one charge.
Aluminium sulfide In this case, the charge of this ion
CuI2 is written between brackets in
Roman numeral numbers.
Sodium carbonate (e.g., CuO= Copper(II) oxide
Manganese(IV) oxide Cu+2 O-2

Fe2O3
Binas 66B Polyatomic ions
Binas 40A= Ions with different charges
Summary

• An ionic bond is formed between the ions in an ionic lattice. The ionic bond is
a strong bond, therefore salts have higher boiling and melting points than
molecular substances.
• A single ion is a charged particle that consists of one type of atom. If there are
several electrovalencies of an atom, you use a Roman numeral to indicate the
charge.
• A compound ion is a charged particle that consists of several types of atoms.
• The systematic name of a salt is obtained by taking the name of the positive
ion first, followed by the name of the negative ion.
• The formula of a salt is expressed in a ratio formula, in which the ions occur in
such a ratio that the salt is electrically neutral.
Vragen
Names of the salts

• 16 exercises (name + formula)


• Work with duo
• 16 minutes (1 min for each exercise)
• Ready, raise your hand!
Homework
• Learn 4.1 and make 3,4,6,7,8,11,12,13.

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