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03 MA2003 - Forms of Energy

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FORMS OF ENERGY, TEMPERATURE

SCALES

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3.1 FORMS OF ENERGY
Total Energy, E = Macroscopic Forms + Microscopic Forms

possessed by system related to molecular


as a whole w.r.t. an structure and degree of
external ref frame molecular activity


E  KE  PE  U
dV  1
M F E  mV  mgz  U
2
dt
2
E  KE  PE  U
For stationary closed system, E  U
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FORMS OF ENERGY
Internal Energy, U
• is the sum of energies of molecules
• is a property - includes

U = Usensible + Ulatent

states-of-matter_en.jar

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3.2 ZEROTH LAW OF THERMODYNAMICS AND TEMPERATURE

• if objects A and B are each in thermal


equilibrium with object C, then A and B are in
thermal equilibrium with each other.

‘A’ is in thermal ‘B’ is in thermal


equilibrium with equilibrium with
‘C’ . ‘C’.
‘A’ and ‘B’ must be in
thermal equilibrium
with each other.
Courtesy To: Prof. KT Ooi [MAE]
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3.3 TEMPERATURE SCALES
• All temperature scales are based on some easily
reproducible states such as the freezing and boiling
points of water: the ice point and the steam point.
• Two-point scale
• Ice point: A mixture of ice and water that
is in equilibrium with air saturated with 100 ºC
vapor at 1 atm pressure (0°C or 32°F).
0 ºC
• Steam point: A mixture of liquid water
and water vapor (with no air) in
equilibrium at 1 atm pressure (100°C or 0˚C
100˚C
212°F).

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TEMPERATURE SCALES
• Two-point Temperature Scale
Xo = Value of thermometric property at 0 oC
X100 = Value of thermometric property at 100 oC
Xθ = Value of thermometric property at T oC

T  0 
 X  X 0  100 oC
100  0 X 100  X 0 

T
 X  X 0 
100
X 100  X 0 
0 oC
X0 Xθ X100 X
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CONSTANT VOLUME GAS THERMOMETER
P100=Patm+ h100 ρg Patm
PV=mRT

P=mRT/ V
Po=Patm+ ho ρg Patm
P∞T
P h
h 100
o

Liquid
temperature to
be measured
Flexible hose
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Variation of temperature with pressure of a constant volume
gas thermometer

T
100ºC
T
0ºC
P P

• T = a P + b,
-
273.15ºC where
T is temperature in Celsius,
P = pressure, a =constant.
b = -273.150C
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COMPARISON OF TEMPERATURE SCALES.

Comparison of magnitudes of various


temperature units.
ΔT

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SEE YOU AGAIN IN THE NEXT LECTURE

That’s all, folks!


Bye now

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