In the indoor environment people are exposed to several fungal species. Evident dampness is associated with increased respiratory symptoms. To examine immune responses associated with fungal exposure mice are often exposed to one species... more
In the indoor environment people are exposed to several fungal species. Evident dampness is associated with increased respiratory symptoms. To examine immune responses associated with fungal exposure mice are often exposed to one species grown on an agar medium. The aim of this study was to develop an inhalation exposure system to be able to examine responses in mice to exposure to mixed fungal species aerosolised from fungal-infested building materials. Indoor airborne fungi were sampled and cultivated on gypsum boards. Aerosols were characterised and compared with aerosols in homes.Aerosols containing 10(7)cfu of fungi/m(3) air were generated repeatedly from fungal-infested gypsum boards in a mouse exposure chamber. Aerosols contained: Aspergillus nidulans, A.niger, A.ustus, A.versicolor, Chaetomium globosum, Cladosporium herbarum, Penicillium brevicompactum, P.camemberti, P.chrysogenum, P.commune, P.glabrum, P.olsonii, P.rugulosum, Stachybotrys chartarum and Wallemia sebi. They w...
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Number size distributions of submicron atmospheric aerosol were measured between February 1, 1996 and January 31, 1997 at a forest site in Southern Finland. Over 50,000 10-min spectra in the size range 3–500nm were obtained by two... more
Number size distributions of submicron atmospheric aerosol were measured between February 1, 1996 and January 31, 1997 at a forest site in Southern Finland. Over 50,000 10-min spectra in the size range 3–500nm were obtained by two parallel DMPSs. The spectra were fitted with two or three lognormal distributions. The occurrence and evolution of different size modes are described, and
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Interpretation of ice-core records in terms of changes in atmospheric concentrations requires understanding of the various parameters within air–snow transfer functions. the dry-deposition velocity is one of these parameters, dependent on... more
Interpretation of ice-core records in terms of changes in atmospheric concentrations requires understanding of the various parameters within air–snow transfer functions. the dry-deposition velocity is one of these parameters, dependent on local meteorological conditions and thereby also affected by climate changes. We have determined aerosol dry-deposition velocities by measurements of aerosol particle-number concentration and the vertical wind component with an eddy-covariance system close to the Swedish and Finnish research stations Wasa and Aboa in Dronning Maud Land, Antarctica. Measurements were performed over a smooth, snow-covered area and over moderately rough, rocky ground during 4 and 19 days, respectively, in January 2000. the median dry-deposition velocity determined 5.25 mabove the surface was 0.33 and 0.80 cm s–1, respectively. the large difference between the two sites was mainly due to the stratification of the surface boundary layer, the surface albedo and the surfa...
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Apportionment of primary and secondary pollutants during a July 2001 intensive study at the National Energy Technology Laboratory is reported. PM2.5 was apportioned into primary and secondary contributions using PMF2, and results were... more
Apportionment of primary and secondary pollutants during a July 2001 intensive study at the National Energy Technology Laboratory is reported. PM2.5 was apportioned into primary and secondary contributions using PMF2, and results were compared with apportionment based on UNMIX 2.3. Input to PMF2 included PM2.5 mass data from four per 24 hour PC-BOSS filters and TEOM, NOx, NO2, O3, non-volatile,
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This work provides thermodynamic data, in particular, liquid-state saturation vapor pressures of three common slightly water soluble secondary organic aerosol components, namely, malonic, succinic, and glutaric acids. A modified tandem... more
This work provides thermodynamic data, in particular, liquid-state saturation vapor pressures of three common slightly water soluble secondary organic aerosol components, namely, malonic, succinic, and glutaric acids. A modified tandem differential mobility analyzer system was used to measure evaporation rates of nanometer sized aqueous malonic, succinic, and glutaric acid droplets at relative humidities and temperatures relevant in the lower troposphere. Liquid phase saturation vapor pressures and other thermodynamic properties were derived from the measurements using a binary condensation model. The obtained expressions for liquid phase saturation vapor pressures compare well with extrapolated literature data. The importance of the choice of method for calculating activity coefficients is discussed.
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Total particle number concentrations and particle size distributions in the diameter range 3–800 nm were measured in continental Antarctica during the austral summers 2000 and 2001. Observed total particle number concentrations varied... more
Total particle number concentrations and particle size distributions in the diameter range 3–800 nm were measured in continental Antarctica during the austral summers 2000 and 2001. Observed total particle number concentrations varied between about 200 and 2000 cm−3, with on average higher concentrations in marine/coastal air masses than in continental air masses. Concentrations in excess of about 300–400 cm−3 were
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This work provides thermodynamic data, in particular, liquid-state saturation vapor pressures of three common slightly water soluble secondary organic aerosol components, namely, malonic, succinic, and glutaric acids. A modified tandem... more
This work provides thermodynamic data, in particular, liquid-state saturation vapor pressures of three common slightly water soluble secondary organic aerosol components, namely, malonic, succinic, and glutaric acids. A modified tandem differential mobility analyzer system was used to measure evaporation rates of nanometer sized aqueous malonic, succinic, and glutaric acid droplets at relative humidities and temperatures relevant in the lower troposphere. Liquid phase saturation vapor pressures and other thermodynamic properties were derived from the measurements using a binary condensation model. The obtained expressions for liquid phase saturation vapor pressures compare well with extrapolated literature data. The importance of the choice of method for calculating activity coefficients is discussed.
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The bacterium Bacillus thuringiensis (Bt) is the active organism in a variety of commercially available products used worldwide as biopesticides. Bt products are applied in large outdoor areas as well as in indoor environments. Even... more
The bacterium Bacillus thuringiensis (Bt) is the active organism in a variety of commercially available products used worldwide as biopesticides. Bt products are applied in large outdoor areas as well as in indoor environments. Even though it has been sold for decades, not much is known about the occupational exposure to Bt. The aim of this study was to obtain knowledge about the exposure to Bt subspecies israelensis (Bti) in a propagation section in a greenhouse, where Bti is applied hourly by a spray boom, and to test a preventive measure to reduce the exposure to airborne Bti. Furthermore, we wanted to study the exposure during work with potted plants treated earlier with Bti. Exposure to aerosols with Bti was measured repeatedly by personal and stationary samplers before and after the intervention. Bti was identified by polymerase chain reaction in air and soil samples. Personal exposure to inhalable Bti in the propagation section was 3×10(5) cfu m(-3) (median level, n = 22); th...
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Gaseous and particulate pollutant concentrations associated with five samples per day collected during a July 2001 summer intensive study at the Pittsburgh Carnegie Mellon University (CMU) Supersite were used to apportion fine particulate... more
Gaseous and particulate pollutant concentrations associated with five samples per day collected during a July 2001 summer intensive study at the Pittsburgh Carnegie Mellon University (CMU) Supersite were used to apportion fine particulate matter (PM2.5) into primary and secondary contributions using PMF2. Input to the PMF2 analysis included the concentrations of PM2.5 nonvolatile and semivolatile organic material, elemental carbon (EC), ammonium sulfate, trace element components, gas-phase organic material, and NO(x), NO2, and O3 concentrations. A total of 10 factors were identified. These factors are associated with emissions from various sources and facilities including crustal material, gasoline combustion, diesel combustion, and three nearby sources high in trace metals. In addition, four secondary sources were identified, three of which were associated with secondary products of local emissions and were dominated by organic material and one of which was dominated by secondary ammonium sulfate transported to the CMU site from the west and southwest. The three largest contributors to PM2.5 were secondary transported material (dominated by ammonium sulfate) from the west and southwest (49%), secondary material formed during midday photochemical processes (24%), and gasoline combustion emissions (11%). The other seven sources accounted for the remaining 16% of the PM2.5. Results obtained at the CMU site were comparable to results previously reported at the National Energy Technology Laboratory (NETL), located approximately 18 km south of downtown Pittsburgh. The major contributor at both sites was material transported from the west and southwest. Some difference in nearby sources could be attributed to meteorology as evaluated by HYSPLIT model back-trajectory calculations. These findings are consistent with the majority of the secondary ammonium sulfate in the Pittsburgh area being the result of contributions from distant transport, and thus decoupled from local activity involving organic pollutants in the metropolitan area. In contrast, the major local secondary sources were dominated by organic material.
Research Interests: Engineering, Carbon, Trace Metals, Power Plant, Environmental Sciences, and 16 moreFossil Fuels, Nitrates, Zinc, Iron, Pennsylvania, Particle Size, Steel Industry, Particulate Matter, Trace element, Ammonium Sulfate, Air Pollutants, Sulfates, Elemental Carbon, Secondary production, Fine Particulate Matter, and Urban Area
As part of the Gasoline/Diesel PM Split Study, relatively large fleets of gasoline vehicles and diesel vehicles were tested on a chassis dynamometer to develop chemical source profiles for source attribution of atmospheric particulate... more
As part of the Gasoline/Diesel PM Split Study, relatively large fleets of gasoline vehicles and diesel vehicles were tested on a chassis dynamometer to develop chemical source profiles for source attribution of atmospheric particulate matter in California's South Coast Air Basin. Gasoline vehicles were tested in cold-start and warm-start conditions, and diesel vehicles were tested through several driving cycles. Tailpipe emissions of particulate matter were analyzed for organic tracer compounds, including hopanes, steranes, and polycyclic aromatic hydrocarbons. Large intervehicle variation was seen in emission rate and composition, and results were averaged to examine the impacts of vehicle ages, weight classes, and driving cycles on the variation. Average profiles, weighted by mass emission rate, had much lower uncertainty than that associated with intervehicle variation. Mass emission rates and elemental carbon/organic carbon (EC/OC) ratios for gasoline vehicle age classes were influenced most by use of cold-start or warm-start driving cycle (factor of 2-7). Individual smoker vehicles had a large range of mass and EC/OC (factors of 40 and 625, respectively). Gasoline vehicle age averages, data on vehicle ages and miles traveled in the area, and several assumptions about smoker contributions were used to create emissions profiles representative of on-road vehicle fleets in the Los Angeles area in 2001. In the representative gasoline fleet profiles, variation was further reduced, with cold-start or warm-start and the representation of smoker vehicles making a difference of approximately a factor of two in mass emission rate and EC/OC. Diesel vehicle profiles were created on the basis of vehicle age, weight class, and driving cycle. Mass emission rate and EC/OC for diesel averages were influenced by vehicle age (factor of 2-5), weight class (factor of 2-7), and driving cycle (factor of 10-20). Absolute and relative emissions of molecular marker compounds showed levels of variation similar to those of mass and EC/OC.
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A survey of monthly average concentrations of sulfur dioxide (SO2) and hydrogen sulfide (H2S) at rural locations in western Canada (provinces of Alberta, British Columbia, and Saskatchewan) was conducted in 2001-2002, as part of an... more
A survey of monthly average concentrations of sulfur dioxide (SO2) and hydrogen sulfide (H2S) at rural locations in western Canada (provinces of Alberta, British Columbia, and Saskatchewan) was conducted in 2001-2002, as part of an epidemiological study of the effects of oil and gas industry emissions on the health of cattle. Repeated measurements were obtained at some months and locations. We aimed to develop statistical models of the effect of oil and gas infrastructure on air concentrations. The regulatory authorities supplied the information on location of the different oil and gas facilities during the study period and, for Alberta, provided data on H2S content of wells and flaring volumes. Linear mixed effects models were used to relate observed concentrations to proximity and type of oil and gas infrastructure. Low concentrations were recorded; the monthly geometric mean was 0.1-0.2 ppb for H2S, and 0.3-1.3 ppb for SO2. Substantial variability between repeated measurements was observed. The precision of the measurement method was 0.005 ppb for both contaminants. There were seasonal trends in the concentrations, but the spatial variability was greater. This was explained, in part, by proximity to oil/gas/bitumen wells and (for SO2) gas plants. Wells within 2 km of monitoring stations had the greatest impact on measured concentrations. For H2S, 8% of between-location variability was explained by proximity to industrial sources of emissions; for SO2 this proportion was 18%. In Alberta, proximity to sour gas wells and flares was associated with elevated H2S concentrations; however, the estimate of the effect of sour gas wells in the immediate vicinity of monitoring stations was unstable. Our study was unable to control for all possible sources of the contaminants. However, the results suggest that oil and gas extraction activities contribute to air pollution in rural areas of western Canada.
Research Interests: Engineering, Environmental Monitoring, Air pollution, Oil and gas, Seasonality, and 14 moreEnvironmental Sciences, Industry, British Columbia, Spatial Variability, Repeated Measures, Alberta, Hydrogen Sulfide, Rural Area, Statistical Model, Saskatchewan, Epidemiologic Studies, Sulfur Dioxide, Oil and Gas Industry, and Air Pollutants
A methodology for estimating vehicular emissions comprising a car simulator, a basic traffic model, and a geographical information system is capable of estimating vehicle emissions with high time and space resolution. Because of the... more
A methodology for estimating vehicular emissions comprising a car simulator, a basic traffic model, and a geographical information system is capable of estimating vehicle emissions with high time and space resolution. Because of the extent of the work conducted, this article comprises two sections: In Part 1 of this work, we describe the system and its components and use examples for testing it. In Part 2 we will study in more detail the emissions of the sample fleet using the system and will make comparisons with another emission model. The experimental data for the car simulator is obtained using on-board measuring equipment and laboratory Fourier transform IR (FTIR) measurements with a dynamometer following typical driving cycles. The car simulator uses this data to generate emission factors every second. These emission factors, together with information on car activity and velocity profiles of highways and residential and arterial roads in Mexico City in conjunction with a basic traffic model, provide emissions per second of a sample fleet. A geographical information system is used to localize these road emissions.
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In this paper, the deterioration of catalysts in small, four-stroke, spark-ignition engines is described. The laboratory testing performed followed a proven test method that mimics the lifetime of a small air-cooled utility engine... more
In this paper, the deterioration of catalysts in small, four-stroke, spark-ignition engines is described. The laboratory testing performed followed a proven test method that mimics the lifetime of a small air-cooled utility engine operating under normal field conditions. The engines used were single-cylinder, 6.5-hp, side-valve engines. These engines have a nominal 125-hr lifetime. The effectiveness of the catalysts was determined by testing exhaust emissions before and after the catalyst to determine the catalyst's efficiency. This was done several times during the lifetime of the engines to determine the deterioration in the performance of the catalysts at lowering pollutant emissions. Additional testing was performed on the catalysts to determine wear patterns, contamination, and recoverable activity. The results indicate that considerable catalyst deterioration is occurring over the lifetime of the engine. The results reveal that soot buildup, poisons, and active surface loss appear to be the contributing factors to the deterioration. These results were determined after analyzing the exhaust emissions data, scanning electron microscope results analysis, and the impact of regeneration attempts. An ANOVA statistical analysis was performed, and it was determined that the emissions are also impacted, to some degree, by time and the engine itself.
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A sensitivity analysis was conducted to characterize sources of uncertainty in results of a molecular marker source apportionment model of ambient particulate matter using mobile source emissions profiles obtained as part of the... more
A sensitivity analysis was conducted to characterize sources of uncertainty in results of a molecular marker source apportionment model of ambient particulate matter using mobile source emissions profiles obtained as part of the Gasoline/Diesel PM Split Study. A chemical mass balance (CMB) model was used to determine source contributions to samples of fine particulate matter (PM2.5) collected over 3 weeks at two sites in the Los Angeles area in July 2001. The ambient samples were composited for organic compound analysis by the day of the week to investigate weekly trends in source contributions. The sensitivity analysis specifically examined the impact of the uncertainty in mobile source emissions profiles on the CMB model results. The key parameter impacting model sensitivity was the source profile for gasoline smoker vehicles. High-emitting gasoline smoker vehicles with visible plumes were seen to be a significant source of PM in the area, but use of different measured profiles for smoker vehicles in the model gave very different results for apportionment of gasoline, diesel, and smoker vehicle tailpipe emissions. In addition, the contributions of gasoline and diesel emissions to total ambient PM varied as a function of the site and the day of the week.
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Alkylphenol polyethoxylates (APEOs) have been widely used as nonionic surfactants in a variety of industrial and commercial products. Typical compounds are nonylphenol polyethoxylates (NPEOs) and octylphenol polyethoxylates (OPEOs), which... more
Alkylphenol polyethoxylates (APEOs) have been widely used as nonionic surfactants in a variety of industrial and commercial products. Typical compounds are nonylphenol polyethoxylates (NPEOs) and octylphenol polyethoxylates (OPEOs), which serve as precursors to nonylphenol (NP) and octylphenol (OP), respectively. NP and 4-t-OP are known to have endocrine disrupting effects on fish (medaka, Oryzias latipes), so it is important to know the concentrations of APEOs in the environment. Because the analytical characteristics of these compounds depend on the length of the ethoxy chain, it is necessary to use appropriate compounds as internal standards or surrogates. We synthesized two 13C-labeled surrogate compounds and used these compounds as internal standards to determine NPEOs and OPEOs by high-performance liquid chromatography (LC)-mass spectrometry. Method detection limits were 0.015 microg/L for NP (2)EO to 0.037 microg/L for NP(12)EO, and 0.011 microg/L for OP(3,6)EO to 0.024 microg/L for OP (4)EO. NPEO concentrations in water from a sewage treatment plant were less than 0.05-0.52 microg/L for final effluent and 1.2-15 microg/L for influent. OPEO concentrations were less than 0.05-0.15 microg/L for the final effluent and less than 0.05-1.1 microg/L for influent.