Equilibrium and kinetic data were evaluated for formation of the 1 : 1 complexes of NCSâ» with (HâO)âCrChâCl/sup 2 +/ and (HâO)âCrCHClâ/sup 2 +/. Equilibrium is established within less than 100 s, which is unusually rapid for Cr(III)... more
Equilibrium and kinetic data were evaluated for formation of the 1 : 1 complexes of NCSâ» with (HâO)âCrChâCl/sup 2 +/ and (HâO)âCrCHClâ/sup 2 +/. Equilibrium is established within less than 100 s, which is unusually rapid for Cr(III) substitution. This corresponds to replacement of only a single HâO molecule for both NCSâ» and ChâOH as entering groups, verified for NCSâ»
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Equilibrium and kinetic data were evaluated for formation of the 1 : 1 complexes of NCSâ» with (HâO)âCrChâCl/sup 2 +/ and (HâO)âCrCHClâ/sup 2 +/. Equilibrium is established within less than 100 s, which is unusually rapid for Cr(III)... more
Equilibrium and kinetic data were evaluated for formation of the 1 : 1 complexes of NCSâ» with (HâO)âCrChâCl/sup 2 +/ and (HâO)âCrCHClâ/sup 2 +/. Equilibrium is established within less than 100 s, which is unusually rapid for Cr(III) substitution. This corresponds to replacement of only a single HâO molecule for both NCSâ» and ChâOH as entering groups, verified for NCSâ»