Sodium Adsorption Ratio

A lysimeter study was conducted to assess the impact of some crop rotations and gypsum on amelioration of a calcareous saline-sodic soil (pHs = 8.4, ECe = 8.6 dS m-1, SAR = 37.7, CaCO3 = 81.1 g kg-1) irrigated with marginal-quality water (EC = 1.0 dS m-1, SAR = 4.2, RSC = ...

The salinization process was investigated with hydrogeochemical tools to evaluate the origin of salinity in the Selçuk Plain. Na/Cl and Cl/Br molar ratios of coastal zone that covers an alluvial aquifer, karstic discharges, and a wetland are similar to the local seawater ratio. According to mixing ratios, seawater addition can reach 9–18% in both seasons at the coastal zone especially in karstic springs that are a kind of seawater–freshwater mixing points. A thematic map of the Salinization zone was constructed for the Selçuk Plain using geographical information system tools with different parameters such as major ion ratios, EC values, mixing ratios, and sodium adsorption ratio values. High correlation between Cl and Br, B, Li and Sr explains the salinization process that comes from marine intrusion. The δ 18O and δD composition of water samples varies between −6.7‰ and −2.9‰; −37‰ and −20‰, respectively. The coastal zone waters are plotted on the mixing line due to the effects of the salinization process in the plain.

In a qualitative assessment of mine water from the Raniganj coalfield, 77 mine water samples were analyzed to assess water quality and suitability for domestic, industrial, and irrigation uses. The pH of the mine water ranged from 6.5 to 8.8. Total dissolved solids (TDS) ranged from 171 to 1,626 mg L−1; spatial differences between the TDS values reflect variations in lithology, activities, and prevailing hydrological regime. The anion chemistry was dominated by HCO3− and SO42−. On average, Cl− contributes 10 and 19% of the total anionic balance, respectively, in the Barakar and Raniganj Formation mine water. F− and NO3− contribute <2% to the total anions. The cation chemistry is dominated by Mg2+ and Ca2+ in the mine water of the Barakar Formation and Na+ in the Raniganj Formation mines. Much of the mine water, especially of the Barakar Formation area, has high TDS, total hardness, and SO4 concentrations. Concentrations of some trace metals (i.e. Fe, Cr, Ni) were found to be above the levels recommended for drinking water. However, the mine water can be used for irrigation, except at some sites, especially in the Raniganj Formation area, where high salinity, sodium adsorption ratio, %Na, residual sodium carbonate, and excess Mg restrict its suitability for agricultural uses.

A hydrogeochemical investigation was conducted in a coastal region of Cuddalore district to identify the influence of saltwater intrusion and suitability of groundwater for domestic and agricultural purposes. The geology of the study area comprises of sandstone, clay, alluvium, and laterite soils of Tertiary and Quaternary age. A total of 18 groundwater samples were analyzed for 14 different water quality parameters and the result indicates higher concentrations of ions like Cl (3,509 mg/l), Na (3,123 mg/l), and HCO3 (998 mg/l) when compared with WHO, BIS, and ISI standards. A positive correlation (r 2 = 0.82) was observed between Na and Cl, indicating its sources from salt water intrusion. Three factors were extracted with a total variance of 64% which indicates the sources of salinization, cation exchange, and anthropogenic impact to the groundwater. The Piper trilinear diagram indicates both Na–Cl and mixed Na–HCO3–Cl-type, indicating that groundwater was strongly affected by anthropogenic activities. The plot of (Ca + Mg)/(K + Na) indicates evidences of cation exchange and salt water intrusion. The (Ca–0.33*HCO3)/ SO4 plot indicates salt water intrusion for elevated SO4 levels rather than gypsum dissolution. The spatial distribution of total dissolved solid indicates the saline water encroachment along the SW part of the study area. As per sodium adsorption ratio (SAR), 50% of the samples with <10 SAR are suitable for irrigation and >10 SAR indicates that water is unsuitable for irrigation purposes. The residual sodium carbonate classification indicates that 50% of the samples fall in safe and 50% of the samples fall in bad zones and prolonged usage of this water will affect the crop yield. The Chloro Alkaline Index of water indicates disequilibrium due to a higher ratio of Cl > Na–K, indicating the influence of salt water intrusion. The Permeability Index of the groundwater indicates that the groundwater from the study area is moderate to good for irrigation purposes.

The prolonged irrigation with marginal quality water can cause secondary salinization of soils, which necessitates for better understanding of water management alternatives. Relative performance of sulfuric acid and gypsum is still controversial to counter sodium hazards in soil/water system. As an alternative, sulfurous acid generators (SAG) are also being marketed. But up-till-now, there is not even a single field study published in scientific journals about their efficiency and economical viability for the treatment of saline-sodic water. Therefore, a field study was carried out to compare the effectiveness of SAG and alternate amendments applied on an equivalent basis to grow rice crop. SAG treatment of saline-sodic tube well water decreased only residual sodium carbonate (RSC) from 5.4 to 3.6 mmolc l−1, and had no beneficial effect on its sodium adsorption ratio (SAR) or electrical conductivity (EC). All the treatments kept soil EC and SAR around their respective threshold levels. For paddy yield, SAG, sulfuric acid, and gypsum treatments depicted nonsignificant differences. SAG and sulfuric acid treatments of water were about six times expensive than that of gypsum. It was concluded that soil-applied gypsum, to counter sodic hazards of irrigation water, is economical to sustain irrigated rice in dry regions.

An attempt has been made to understand the hydrogeochemical parameters to develop water quality index in Thirumanimuttar sub-basin. A total of 148 groundwater samples were collected and analyzed for major cations and anions. The domination of cations and anions was in the order of Na>Mg>Ca>K for cations and Cl>HCO3 >SO4 in anions. The hydrogeochemical facies indicate alkalis (Na and K) exceed alkaline earths (Ca and Mg) and strong acids (Cl and SO4) exceed weak acid (HCO3). Water quality index rating was calculated to quantify overall water quality for human consumption. The PRM samples exhibit poor quality in greater percentage when compared with POM due to effective leaching of ions, over exploitation of groundwater, direct discharge of effluents and agricultural impact. The overlay of WQI with chloride and EC correspond to the same locations indicating the poor quality of groundwater in the study area. SAR, Na%, and TH were noted higher during both the seasons indicating most of the groundwater locations not suitable for irrigation purposes.

A hydrogeochemical investigation was conducted in a coastal region of Cuddalore district to identify the influence of saltwater intrusion and suitability of groundwater for domestic and agricultural purposes. The geology of the study area comprises of sandstone, clay, alluvium, and laterite soils of Tertiary and Quaternary age. A total of 18 groundwater samples were analyzed for 14 different water quality parameters and the result indicates higher concentrations of ions like Cl (3,509 mg/l), Na (3,123 mg/l), and HCO3 (998 mg/l) when compared with WHO, BIS, and ISI standards. A positive correlation (r 2 = 0.82) was observed between Na and Cl, indicating its sources from salt water intrusion. Three factors were extracted with a total variance of 64% which indicates the sources of salinization, cation exchange, and anthropogenic impact to the groundwater. The Piper trilinear diagram indicates both Na–Cl and mixed Na–HCO3–Cl-type, indicating that groundwater was strongly affected by anthropogenic activities. The plot of (Ca + Mg)/(K + Na) indicates evidences of cation exchange and salt water intrusion. The (Ca–0.33*HCO3)/ SO4 plot indicates salt water intrusion for elevated SO4 levels rather than gypsum dissolution. The spatial distribution of total dissolved solid indicates the saline water encroachment along the SW part of the study area. As per sodium adsorption ratio (SAR), 50% of the samples with <10 SAR are suitable for irrigation and >10 SAR indicates that water is unsuitable for irrigation purposes. The residual sodium carbonate classification indicates that 50% of the samples fall in safe and 50% of the samples fall in bad zones and prolonged usage of this water will affect the crop yield. The Chloro Alkaline Index of water indicates disequilibrium due to a higher ratio of Cl > Na–K, indicating the influence of salt water intrusion. The Permeability Index of the groundwater indicates that the groundwater from the study area is moderate to good for irrigation purposes.

Groundwater in Palnad sub-basin is alkaline in nature and Na+-Cl−-HCO 3− type around Macherla-Karempudi area in Guntur district, Andhra Pradesh. Total dissolved solids (TDS) show strong positive correlation with Cl−, Na+, Ca2+ and Mg2+, and positive correlation with SO 42−, K+ and HCO 3−. Calcareous Narji Formation is the dominant aquifer lithology, and water-rock interaction controls the groundwater chemistry of the area. Chloro-alkaline indices (CAI) are positive at Miriyala, Adigopula, Mutukuru, Macherla and Durgi suggesting replacement of Na+ and K+ ions from water by Mg++ and Ca++ ions from country rock through base exchange reactions. Negative CAI values are recorded at Terala, Rayavaram and Nehrunagar, which indicate exchange of Na+ and K+ from the rock as cation-anion exchange reaction (chloro-alkaline disequilibrium). TDS range from 91 to 7100 ppm (Avg. 835 ppm) and exceed the prescribed limit of drinking water around Mutukuru, Durgi, Rayavaram, Khambampadu and Ammanizamalmadaka areas. Scanty rainfall and insufficient groundwater recharge are the prime factors responsible for high salinity in the area. Fluoride content ranges from <1 to 3.8 ppm and contaminated areas were identified around Macherla (1 sq km; 3.8ppm), Mandadi (1 sq km, 2.1ppm) and Adigopula (2 sq km, <1 to 3.7 ppm). The % Na+ content varies from 17 to 85 with the mean value of 57, and eighty (80) samples showed higher %Na+ in comparison to the prescribed limit of 60 for irrigation water. Sodium Adsorption Ratio (SAR) and % Na+ in relation to total salt concentration indicate that groundwater (51%) mostly falls under doubtful to poor quality for irrigation purpose. Groundwater of Adigopula village is fluoride contaminated and remedial measures are suggested to improve the water quality.

Currently used soil salinity models do not contain a mechanism for including exchangeable sodium effects on soil pH. A method is needed that allows pH calculation from the sodium adsorption ratio (SAR) or exchangeable sodium percentage (ESP) and electrical conductivity (EC) data. This study developed a simple method for calculating saturated soil paste and aqueous solution pH from SAR (or ESP) and EC data and compared the results with measured values from a number of soils and subsurface waters. The equation pH - A+{B*(SAR) 1/2/(1+CEC)I estimated soil pH from EC and SAR or ESP values. When rewritten as: SAR or ESP = l(pH-A)(1+C&#x27;EC)/13} 2, the SAR or ESP was estimated from pH and EC data. By using shallow bore (well) water and soil extract data from the Murray Basin, values were determined for the scalar terms A, B and C. These values differed among subsurface water and soil types, however, the range of each scalar was reasonably small. It was found that a range of at least 2 . 5 pH units in the calibration data was necessary to obtain reliable regression between predicted and measured pH and SAR or ESP values. When these conditions were met, the predicted results were satisfactory. These relationships provide a method for pH calculation in soil salinity models which takes into account soil EC and sodium effects. They also provide a rapid field method to estimate SAR or ESP from easily obtainable EC and pH data. Further research is needed to define the factors that determine the values of A, B and C.

Despite the increasing prevalence of salinity world-wide, the measurement of exchangeable cation concentrations in saline soil remains problematic. In this situation, it is desirable to determine relationships among indices of soil salinity. Exchangeable Sodium Percentage (ESP) are often determined using laborious and time consuming laboratory tests, but it may be more appropriate and economical to develop a method which uses

Field studies were conducted for a period of ten years (1974 to 1984) on Typic Ustochrept to determine the sustained effects of saline irrigation water electrical conductivity (ECiw ) 3.2 dS/m, sodium adsorption ratio (SAR) 21 (mmol/1)1/2 and residual sodium carbonate (RSC) 4me/1, on the build up of salinity in the soil profile and yield of crops grown under fixed rice-wheat and maize/millet-wheat rotations. Saline waters were continuously used with and without the addition of gypsum (at the rate needed to reduce RSC to zero) applied at each irrigation. In maize/millet-wheat rotation, two additional treatments viz. (i) irrigation with 50% extra water over and above the normal 6 cm irrigation, and (ii) irrigation with good water and saline water alternately, were also kept. The results showed that salinity increased rapidly in the profile during the initial years but after five years (1979–1984) the average soluble salt concentration in 0–90 cm soil profile did not appreciably vary and the mean ECe values under saline water treatment remained almost similar to ECiw , under both the crop rotations. Saline water irrigation increased pH and Na saturation of the soil, reduced water infiltration rate and decreased yields of maize, rice and wheat. The differences in the build up of salinity and ESP of the soil under the two cropping sequences seemed to be related with the differences in leaching that occurred under rice-wheat and maize/millet-wheat rotations. Application of gypsum increased the removal of Na from the profile, appreciably decreased the pH and Na saturation and improved water infiltration rate and raised crop yields. Application of non-saline and saline waters alternately was found to be a useful practice but irrigation with 50% extra water to meet the leaching requirement did not control salinity and hence lowered crop yields.