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    11 5 Temperature and Pressure 4th Ed

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    When the Kelvin temperature of a gas is doubled at constant volume and amount of gas, the pressure also doubles. If the pressure (P) increases, then the temperature (K) also increases. All temperatures used in gas law calculations must be converted to Kelvin (K) temperature.

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    11 5 Temperature and Pressure 4th Ed

    Uploaded by

    api-267245178
    222 views18 pages
    When the Kelvin temperature of a gas is doubled at constant volume and amount of gas, the pressure also doubles. If the pressure (P) increases, then the temperature (K) also increases. All temperatures used in gas law calculations must be converted to Kelvin (K) temperature.

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    11 5 temperature and pressure 4th ed

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    When the Kelvin temperature of a gas is doubled at constant volume and amount of gas, the pressure also doubles. If the pressure (P) increases, then the temperature (K) also increases. All temperatures used in gas law calculations must be converted to Kelvin (K) temperature.

    Copyright:

    © All Rights Reserved
    Download as PPT, PDF, TXT or read online from Scribd
    Download as ppt, pdf, or txt
    222 views18 pages

    11 5 Temperature and Pressure 4th Ed

    Uploaded by

    api-267245178
    When the Kelvin temperature of a gas is doubled at constant volume and amount of gas, the pressure also doubles. If the pressure (P) increases, then the temperature (K) also increases. All temperatures used in gas law calculations must be converted to Kelvin (K) temperature.

    Copyright:

    © All Rights Reserved
    Download as PPT, PDF, TXT or read online from Scribd
    Download as ppt, pdf, or txt
    of 18

    Basic Chemistry

    Fourth Edition

    Unit 3 Gases
    Temperature and Pressure
    (Gay-Lussacs Law)
    Learning Goal When the Kelvin
    temperature of a gas is doubled at
    constant volume and amount of
    gas, the pressure also doubles.
    2014 Pearson Education, Inc.

    Gay-Lussacs Law
    Gay-Lussacs law states
    the pressure (P) of a gas is
    directly related to its
    temperature (K) when V and n
    are constant
    if the pressure (P) increases,
    then the temperature (K) also
    increases

    2014 Pearson Education, Inc.

    Figure 11.6 Gay-Lussacs law:


    When the Kelvin temperature of a
    gas is doubled at constant volume
    and amount of gas, the pressure also
    doubles.

    Gay-Lussacs Law
    Gay-Lussacs law is a direct relationship between
    pressure and temperature.

    No change in number of moles and volume.


    All temperatures used in gas law calculations
    must be converted to Kelvin (K) temperature.

    2014 Pearson Education, Inc.

    Gay-Lussacs Law Equation


    The equation for Gay-Lussacs law can be
    rearranged to solve for any factor.

    To obtain P2, multiply both sides by T2.

    2014 Pearson Education, Inc.

    Learning Check
    A gas has a pressure of 2.0 atm at 18 C.
    What is the new pressure when the
    temperature is 62 C (V and n constant)?

    2014 Pearson Education, Inc.

    Solution
    A gas has a pressure of 2.0 atm at 18 C.
    What is the new pressure when the
    temperature is 62 C (V and n constant)?
    Step 1 Organize the data in a table of initial
    and final conditions. We can predict
    that as T increases, P increases.
    Conditions 1

    Conditions 2

    P1 = 2.0 atm

    P2 = ?

    T1 = 18 oC = 291 K

    T2 = 62 oC = 335 K

    2014 Pearson Education, Inc.

    Solution
    A gas has a pressure of 2.0 atm at 18 C.
    What is the new pressure when the
    temperature is 62 C (V and n constant)?
    Step 2 Rearrange the gas law equation to
    solve for the unknown quantity.
    Solve Gay-Lussacs law for P2.

    2014 Pearson Education, Inc.

    Solution
    A gas has a pressure of 2.0 atm at 18 C.
    What is the new pressure when the
    temperature is 62 C (V and n constant)?
    Step 3 Substitute values into gas law
    equation and calculate.

    2014 Pearson Education, Inc.

    Learning Check
    Use the gas laws to complete with: increases or
    decreases.
    A. Pressure ______ when T decreases.
    B. When T decreases, P ______.
    C. Pressure ______ when T changes from 12 L
    to 24 L.
    Pressure _______ when T changes from
    45 C to 15 C.

    2014 Pearson Education, Inc.

    Basic Chemistry

    Copyright 2014 Pearson Education, Inc.

    Solution
    Use the gas laws to complete with: increases or
    decreases.
    A. Pressure decreases when T decreases.
    B. When T decreases, P decreases.
    C. Pressure increases when T changes from 12 L
    to 24 L.
    Pressure decreases when T changes from
    45 C to 15 C.

    2014 Pearson Education, Inc.

    Basic Chemistry

    Copyright 2014 Pearson Education, Inc.

    10

    Learning Check
    A gas has a pressure of 0.750 atm at 128 C.
    What is the temperature in Celsius if the
    pressure increases to 1.50 atm (n and V remain
    constant)?

    2014 Pearson Education, Inc.

    Solution
    A gas has a pressure of 0.750 atm at 128 C.
    What is the temperature in Celsius if the
    pressure increases to 1.50 atm (n and V remain
    constant)?
    Step 1 Organize the data in a table of initial
    and final conditions. We can
    predict
    that as P increases, T
    increases.
    Conditions 1
    Conditions 2
    P1 = 0.750 atm

    P2 = 1.50 atm

    T1 = 128 oC = 401 K

    T2 = ?

    2014 Pearson Education, Inc.

    Solution
    A gas has a pressure of 0.750 atm at 128 C.
    What is the temperature in Celsius if the
    pressure increases to 1.50 atm (n and V remain
    constant)?
    Step 2 Rearrange the gas law equation to
    solve for the unknown quantity.
    Solve Gay-Lussacs law for T2. Increasing temperature
    increases the pressure when moles and volume are
    constant.

    2014 Pearson Education, Inc.

    Solution
    A gas has a pressure of 0.750 atm at 128 C.
    What is the temperature in Celsius if the
    pressure increases to 1.50 atm (n and V remain
    constant)?
    Step 2 Rearrange the gas law equation to
    solve for the unknown quantity.

    2014 Pearson Education, Inc.

    Solution
    A gas has a pressure of 0.750 atm at 128 C.
    What is the temperature in Celsius if the
    pressure increases to 1.50 atm (n and V remain
    constant)?
    Step 3 Substitute values into the gas law
    equation and calculate.
    When T decreases, P also decreases.

    2014 Pearson Education, Inc.

    Vapor Pressure and Boiling Point


    Vapor pressure
    is the pressure above a
    liquid at equilibrium in
    a closed container
    at the boiling point
    vapor pressure
    becomes equal to the
    external pressure

    2014 Pearson Education, Inc.

    Boiling Point of Water


    The boiling point of
    water
    depends on the vapor
    pressure
    is lower at higher
    altitudes

    2014 Pearson Education, Inc.

    Boiling Point of Water


    An autoclave used to
    sterilize equipment
    attains a temperature
    higher than 100 C.
    Increasing the pressure
    increases the
    temperature.

    2014 Pearson Education, Inc.

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