Material Safety Data Sheet: Elan Chemical Company, Inc

MATERIAL SAFETY DATA SHEET
ELAN CHEMICAL COMPANY, INC
Date Printed: October 23, 2007

Date Updated: January 18, 2007
1. Product /Company Identification

Product Name: DIACETYL
Manufacturer: Elan Chemical Co. Inc.

268 Doremus Ave.
Newark, NJ 07105
U.S.A.
Phone: (973)344-8014
Fax: (973)344-5880
Emergency: 800-424-9300 (Chemtrec)
2. Composition/Information on Ingredient
Synonyms: 2,3-Butanedione, Biacetyl
CAS Number: 431-03-8
FEMA: 2370
Molecular Formula: C4 H6 O2 Molecular Weight: 86.09
3. Hazards Identification
Emergency Overview
Flammable (USA). Highly Flammable (EU). Harmful.
Harmful by inhalation and if swallowed. Irritating to eyes, respiratory system and skin.
Risk of serious damage to eyes. Stench.
HMIS NFPA
Health 2 2
Flammability 3 3
Reactivity 0 0
4. First Aid Measures

Oral Exposure: If swallowed, wash out mouth with water provided person is conscious.
Call a physician.
Inhalation Exposure: If inhaled, move to fresh air. If not breathing give artificial respiration. IF
breathing is difficult, give oxygen.
Skin Exposure: In case of contact, immediately wash skin with soap and copious amounts
of water.
Eye Exposure: In case of contact, immediately flush eyes with copious amounts of water
for at least 15 minutes
Diacetyl 1
5. Fire Fighting Measures
Flammable Hazards: YES
Flash Point: 7ºC (44.6°F)
Extinguishing Material: Carbon Dioxide

Dry Chemical Powder
Foam
Protective Equipment: Wear self-contained breathing apparatus and protective clothing to

prevent contact with skin and eyes.
Specific Fire Fighting Hazards: Emits toxic fumes under fire conditions. Flammable liquid.
Emits toxic fumes under fire conditions.
Exposure Hazards: Harmful Liquid. Irritant.
6. Accidental Release Measures
Procedure to be followed in case of leak or spill:

Evacuate Area. Shut off all sources of ignition. Use nonsparking tools.
Personal Protection: Wear respirator, chemical safety goggles, rubber boots, and heavy rubber
gloves.
Clean up Methods: Cover area with an activated carbon adsorbent, take up and place in a
closed container, and hold for waste disposal. Ventilate area and wash
spill site after clean up is complete.
7. Handling and Storage Procedures
Handling: Do not breathe vapor. Do not get in eyes, skin and clothing. Avoid
prolonged or repeated exposure.
Storage: Keep container tightly closed. Keep away from heat and open flame.
Store in a cool, dry place.
Diacetyl 2
8. Exposure Controls/ PPE
Respiratory: In addition to local exhaust ventilation, workers should use respiratory

protection whenever they handle diacetyl. At a minimum, workers who
handle diacetyl on a regular basis should wear a NIOSH-approved full-
face air-purifying respirator with organic vapor cartridges and particulate
filters. Employers must comply with the OSHA Respiratory Protection
Standard including getting medical clearance for employees wearing
respirators and providing fit testing annually.
Eyes: Chemical Safety goggles
Skin: Chemical resistant gloves.
Ventilation: Local exhaust ventilation should be used to reduce levels of diacetyl in air
as much as possible. There is no known safe level of diacetyl in air.
General Hygiene Measures: Wash contaminated clothing before reuse. Wash thoroughly after
handling.
9. Physical/Chemical Properties
Appearance: Yellow liquid

Odor: Pronounced butter odor.
Boiling Point: 88-89º C
Melting Point: -2°C
Flash Point: 7ºC (44.6º F)
Vapor Density: 3 g/1
Specific Gravity: 0.985
Refractive Index: 1.394
10. Stability and Reactivity
Stability: Stable
Materials to Avoid: Strong oxidizing agents. Strong bases, Reducing Agents, Metals.
Hazardous Decomposition Products: Carbon Monoxide, Carbon Dioxide, Nitrogen Oxides.
11. Toxicological Information
Exposure Effects:
Skin Contact: Causes skin irritation.
Skin Absorption: May be harmful if absorbed through skin.
Eye Contact: Causes eye irritation.
Inhalation: May be harmful if inhaled. Material is irritating to mucous
membranes and upper respiratory tract. Prolonged exposure to this
material may cause bronchiolitis obliterans (a severe narrowing or
complete obstruction of the small airways) or lung disease.
Ingestion: Harmful if swallowed.
Diacetyl 3
Exposure to diacetyl can cause a serious lung disease (called bronchiolitis obliterans). The
damage to the lungs can be permanent, severe, and can lead to death.
Individuals exposed to diacetyl who have persistent cough and/or shortness of breath should see
a physician immediately and be evaluated for lung disease.
Employers should provide exposed employees with lung function tests and respiratory health
questionnaires before beginning to work with diacetyl and at least every six months thereafter. A
licensed physician should review the tests to look for decreases in lung function over time.
To the best of our knowledge, the chemical, physical and toxicological properties have not been
thoroughly investigated.
12. Ecological Information
No Data Available.
13. Disposal Considerations
Disposal: This combustible material may be burned in a chemical incinerator

equipped with an afterburner and scrubber. Dispose of in accordance with
local, state, and federal regulations.
14. Transportation Information
Ground (DOT) & Air (IATA)

Proper shipping Name: Butanedione
UN# 2346
Class: 3
Packing Group: II
Hazard Label: Flammable
15. Regulatory Information
EU Classifications:
Symbol of Danger:F Xn
Indication of Danger: Highly Flammable. Harmful
R: 11 20/22 38 41
Risk Statements: Highly Flammable. Harmful by inhalation and if swallowed. Irritating to skin.
Risk of serious damage to eyes.
S: 16 26 39
Safety Statements: Keep away from sources of ignition – no smoking. In case of contact with
eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection.
Diacetyl 4
US Classifications:
Indication of Danger: Flammable(USA) HighlyFlammable (EU). Harmful.
Risk Statements: Flammable. Harmful by inhalation and if swallowed. Irritating to eyes,
respiratory system and skin. Risk of serious damage to eyes.
Safety Statements: Keep away from sources of ignition – no smoking. In case of contact with
eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection.
United States Regulatory Information

SARA Listed: No
TSCA Inventory Item: Yes
Canada:
DSL: Yes
NDSL: No
16. Additional Information

This material safety data sheet is intended to meet the specific requirements of 29 CFR
1910.1200 and should be used accordingly. While the information has been obtained from
sources believed to be accurate and reliable, no warranty, expressed or implied, can be made
with regard to its completeness, correctness or accuracy. Any users or handlers of this product
who are not under the direct control of Elan Chemical Co., Inc. are responsible for evaluating
this information in light of their particular situation and are responsible for all losses, damages
or expenses that result while this material is under their control. It is also the responsibility of
the users and handlers to observe any and all laws and regulations (Federal, State and Local)
concerning the transportation, use, handling, storage and disposal of this product.
Diacetyl 5

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MATERIAL SAFETY DATA SHEET

ELAN CHEMICAL COMPANY, INC

Date Printed: October 23, 2007

1. Product /Company Identification

Manufacturer: Elan Chemical Co. Inc.

4. First Aid Measures

Flammable Hazards: YES

Flash Point: 7ºC (44.6°F)

Extinguishing Material: Carbon Dioxide

Protective Equipment: Wear self-contained breathing apparatus and protective clothing to

Exposure Hazards: Harmful Liquid. Irritant.

6. Accidental Release Measures

Procedure to be followed in case of leak or spill:

7. Handling and Storage Procedures

Respiratory: In addition to local exhaust ventilation, workers should use respiratory

Appearance: Yellow liquid

10. Stability and Reactivity

11. Toxicological Information

12. Ecological Information

13. Disposal Considerations

Disposal: This combustible material may be burned in a chemical incinerator

14. Transportation Information

Ground (DOT) & Air (IATA)

15. Regulatory Information

United States Regulatory Information

16. Additional Information

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