MS CLASS XII CHEMISTRY 2019-20

Q.No. Value points Marks

SECTION:A
1. Reaction taking place at cathode when the battery is in use:

PbO2 (s)  SO42 (aq)  4H  (aq)  2e   PbSO4 (s)  2H 2O(l ) 1

2. 2 F = 2  96500  193000 coulombs 1

3. 38 1.294 1000 1
Molarity   5.02M
98 100
4. Mass of solution after discharge= 3500 mL 1.139 g mL1  3986.5 g ½
20
Mass of H2SO4 present in the solution  3986.5 g  797.3 g ½
100

5. At anode: O2 (g) ½
At cathode: H2 (g) ½

6. Sodium cyanide. 1
7. Nucleotide 1
OR
Laevorotatory / Gets inverted 1
8. Zwitterion / dipolar ion 1
9. Condensation 1
10. Benzaldehyde 1
11. (c) 1
12. (b) 1
13. (c) 1
14. (a) 1
15. (a) 1
OR
(b) 1
16. (c) 1
17. (a) 1
18. (d) 1
19. (d) 1
20. (d) 1
SECTION:B
21. Lone pairs : 2 1
Geometry : Square planar 1
22. Ea 1
Slope  
(i) 2.303 R

(ii) k 1 > k2
1
23. When there is dissociation of solute into ions, in dilute solutions (ignoring 1
interionic attractions) the number of particles increases. As the value of
 colligative properties depends on the number of particles of the solute , the
experimentally observed value of colligative property will be higher than
the true value, therefore the experimentally determined (observed) molar
mass is always lower than the true value.

For KCl (electrolyte) the experimentally determined molar mass is always ½

lower than the true value when water is used as solvent.
Glucose (non-electrolyte) does not show a large variation from the true ½
value.

24.
(a) CH3-CH(Cl)-COOH 1

(b) C6H5CHO 1

25. 1

IUPAC Name of the entity:

Dichloridobis(ethane-1,2-diamine)platinum(IV) ion
1
OR
3
Bonding in [CO( NH 3 ) 6 ]
d2sp3 hybridisation ½

½
Geometry: Octahedral
½
Diamagnetic
26. Vapour phase refining: It is a refining method in which the metal is 1
converted into its volatile compound and collected elsewhere. It is then
decomposed to give pure metal.
Example: Mond’s Process for refining of Nickel / van Arkel method for ½
refining of Zirconium

Equations involved:

Ni  4CO 330  Ni(CO) 4
350 K

½

Ni(CO) 4 450  Ni  4CO
470 K

OR ½
Extraction of gold involves leaching the metal with CN -
Oxidation reaction: ½
4 Au (s) + 8 CN- (aq.) + 2H2O (aq.) + O2 (g) →4[Au(CN)2]-(aq.) + 4 OH-
(aq.)
The metal is recovered by displacement method: ½
2[Au(CN)2]- (aq.) + Zn (s) → 2 Au (s) + [Zn(CN)4]2- (aq.)
½
Zinc acts as a reducing agent.
27. The following compound will undergo SN1 faster:
CH2Cl
½

Greater the stability of the carbocation, greater will be its ease of formation
from the corresponding halide and faster will be the rate of reaction. ½
The benzylic carbocation formed gets stabilised through resonance.

CH3CH2CH2Cl forms a 10 carbocation, which is less stable than benzylic

carbocation.
½

SECTION :C
28. KCl → K+ + Cl-
n=2 ½
i 1    n
i  1  ½
½
T f  iK f m
0.5 x 1000 ½
 (1  0.92) x1.86x
74.5 x100
½
T f  0.24
T f  T f0  T f'
½
T f'   0.24 0C

OR
 A  0.6
 B  0.4
pA   A pA
0

 0.4 x 105.2
 42.08 kPa
½
pB   B pB
0

 0.6 x 46.8
 28.08 kPa ½
PT  p A  pB
½
 42.08  28.08
 70.16 kPa ½
Composition of A and B in the vapour phase:
p A  y A PT

42.08
yA   0.599 ½
70.16
pB  y B PT

28.08
yB   0.400 ½
70.16

29. rate  k [ A]x [ B] y

0.05  k [0.1]x [0.1] y ......(i )
0.10  k[0.2] [0.1] x y
.......(ii )
0.05  k[0.1] [0.2]x y
......(iii )
(ii )  (i )
0.10
 (2) x
0.05
x 1 ½
 (iii )  (i )
0.05
 ( 2) y
0.05
½
y 0
rate  k [ A]1[ B]0 ½
It is a first order reaction.

rate
k  o.5 s 1 ½
[ A]
0.693 0.693
t1   ½
2 k 0.5
t 1 1.386 s
2
½
OR
0.693
t1  ½
2 k
0.693 ½
k2  350 K
25
0.693
k1  300 K ½
50
k2
 2
k1
k2 Ea  1 1
log     ½
k1 2.303 R  T1 T2 
Ea  350  300  ½
log 2 
2.303 x 8.314  350 x300 
½
Ea = 12.104 kJ / mol.

30.

(a) K4[Fe(CN)6] 1

(b) Fe(OH)3 is converted into colloidal state by preferential adsorption of Fe 3+ 1

ions.

(c) Proteins 1

31.
(a) Moist sulphur dioxide behaves as a reducing agent, reduces MnO 4- to Mn2+. 1

(b) X –X’ bond in interhalogens is weaker than X-X bond in halogens except 1
 F-F bond.
(c) Due to the ease with which it liberates atoms of nascent oxygen. 1

OR 1
(a) It is due to low enthalpy of dissociation of F-F bond and high hydration
enthalpy of Fluorine.
(b) Nitrogen oxides emitted from the exhaust systems of supersonic jet 1
airplanes combine rapidly with ozone, forming NO2 and O2, thus leading to
ozone layer depletion.
(c) When Neil Bartlett prepared a compound O2 PtF6 , he realised that the first 1
ionisation enthalpy of molecular oxygen and xenon were identical. So he
made an effort and mixed PtF6 and Xe to prepare a similar compound
Xe  PtF6 .

32. 1-Propoxypropane is formed. 1

Mechanism involved:
Step 1 :Formation of protonated alcohol
½

½
33. Experiment Ethanal Propanone
(a) 1.Tollens Test:
(i) Warm the organic A bright silver mirror No silver mirror is
compound with is produced formed.
freshly prepared
ammonical silver
nitrate
solution(Tollen’s
reagent).
2. Fehlings Test:
Heat the organic A reddish bown No precipitate is
compound with precipitate is obtained
Fehling’s reagent. obtained. 1
Any one test

Experiment Pentan-2-one Pentan-3-one

Iodoform Test:
(ii) The organic A yellow precipitate No yellow precipitate
compound is heated is obtained. is obtained.
with iodine in
presence of sodium 1
hydroxide solution.

Or any other suitable test.

1
(b) 4- Methoxybenzoic acid < Benzoic acid < 4- Nitrobenzoic acid <
3,4-Dinitrobenzoic acid
OR
The carbon atom of the carbonyl group of benzaldehyde is less
electrophilic than carbon atom of the carbonyl group present in ethanal. 1
The polarity of the carbonyl group is reduced in benzaldehyde due to
resonance hence less reactive than ethanal. 1

CHO CH = CH - CHO
1
OH-
+ CH3CHO
293 K

34.
(a) Broad spectrum antibiotics: 1
Antibiotics which kill or inhibit a wide range of Gram-positive and Gram-
negative bacteria.
e.g. Chloramphenicol. ½
any other suitable example.
(b) Analgesics:
Reduce or abolish pain without causing impairement of consciousness,
mental confusion, incoordination or paralysis or some other disturbances of 1
 nervous system.
e.g. Aspirin / paracetamol etc. ½
any other suitable example.
SECTION:D
35.
(a) Fe  2H   H 2  Fe2
2.303RT Fe2
Ecell  Ecell
0
 log  2 1
nF [H ]
0
Ecell  EH0  / H  EFe2 / Fe
0
2

 0  (0.44)  0.44 V
1
0.0591 [0.1]
0.1745  0.44  log
2 [ x]2 ½
Log x = -5
Log[H+] = -5
pH = 5 ½

(b) The mass of copper and silver deposited at the cathode will be different. 1
The amount of different substances deposited by the same quantity of
electricity passing through the electrolytic solution are directly proportional 1
to their chemical equivalents.

OR

(a) o (CH 3COOH )  oH   oCH COO  ½

3

½
= 349.6 + 40.9 = 390.5 S cm2 mol-1
 1000
m  ½
c
4.95 10 5 S cm 1 1000 cm3 L1 ½
m  1
 48.15S cm 2 mol 1
0.001028 mol L

  om ½
m
48.15S cm 2 mol 1
  0.1233 ½
390.5 S cm 2 mol 1
(b) 1
Electrolyte B is a strong electrolyte.
Limiting molar conductivity increases only to a smaller extent for a strong
½
electrolyte, as on dilution the interionic interactions are overcome.
Limiting molar conductivity increases to a larger extent for a weak
electrolyte, as on dilution the degree of dissociation increases, therefore the
½
number of ions in total volume of solution increases.
36. (A) (B) (C)

(E) (D)

(1/2 x 5 marks for structure and ½ x 5 for writing equations)

OR

(a)

(i) 1

(ii)
1

(iii)
C2H5Cl H C2H5Cl
CH3CH2NH2 C2H5-N-C2H5 C2H5-N-C2H5 1

C2H5

(b)

½
A : CH3CH2CONH2
(i) ½
B : CH3CH2NH2
½
A: CH3CH2CH2NH2
(ii) ½
B:CH3CH2CH2OH
3 7.
(1/2x
(a) A = FeCr2O4 B = Na2CrO4 C = Na2Cr2O7 2)
D = K2Cr2O7

(b)

(i) 5f, 6d and 7s levels in actinoids are of comparable energies. 1

(ii) This is due to poorer shielding by 5f electrons in actinoids as compared to 1

shielding by 4f electrons in lanthanoids.

(iii) In actinoids, 5f electrons are more effectively shielded from the nuclear 1
charge than the 4f electrons of the corresponding lanthanoids. Since the
outer electrons are less firmly held, they are available for bonding in the
actinoids.

OR

(a)

(i) MnO42 ions disproportionate in acidic medium to give Permanganate ions ½

and Manganese(IV) oxide.

3MnO42  4H   2MnO4  MnO2  2H 2O ½

(ii) Lanthanum sulphide if formed. ½

2 La  3S  La2 S 3
heat ½
(Deduct overall ½ mark if equation not balanced/ statements not written)
(b)

(i)
Copper has high enthalpy of atomisation and low enthalpy of hydration.
1
Since the high energy to transform Cu(s) to Cu2+(aq) is not balanced by
hydration enthalpy, therefore E o ( M 2 / M ) value for copper is
positive(+0.34 V).

(ii) Cr2+ is reducing as its configuration changes from d4 to d3, the latter having 1
more stable half filled t2g level. On the other hand, the change from Mn3+ to
Mn2+ results in extra stable d5 configuration.
 This is due to the increasing stability of the species of lower oxidation state
to which they are reduced.
(iii) 1