FMDS0786 - Cellulose Nitrate

FM Global
Property Loss Prevention Data Sheets 7-86

October 1975
Revised May 2000
Page 1 of 4
CELLULOSE NITRATE
Table of Contents
Page
1.0 SCOPE ................................................................................................................................................... 2

1.1 Changes .......................................................................................................................................... 2
2.0 LOSS PREVENTION RECOMMENDATIONS ....................................................................................... 2
2.1 Occupancy ....................................................................................................................................... 2
2.2 Protection ......................................................................................................................................... 2
2.3 Training ............................................................................................................................................ 3
2.4 Contingency Planning ...................................................................................................................... 3
3.0 SUPPORT FOR RECOMMENDATIONS ............................................................................................... 3
3.1 Discussion ....................................................................................................................................... 3
4.0 REFERENCES ....................................................................................................................................... 3
4.1 FM Global ........................................................................................................................................ 3
4.2 NFPA Standards .............................................................................................................................. 3
APPENDIX A GLOSSARY OF TERMS ....................................................................................................... 3
APPENDIX B DOCUMENT REVISION HISTORY ....................................................................................... 4
APPENDIX C HAZARD INFORMATION ..................................................................................................... 4
©2000 Factory Mutual Insurance Company. All rights reserved. No part of this document may be reproduced,
stored in a retrieval system, or transmitted, in whole or in part, in any form or by any means, electronic, mechanical,
photocopying, recording, or otherwise, without written permission of Factory Mutual Insurance Company.
7-86 Cellulose Nitrate
Page 2 FM Global Property Loss Prevention Data Sheets
1.0 SCOPE
This data sheet covers the storage and use of cellulose nitrate as a wetted fiber in drums. Cellulose nitrate
is also known as nitrocellulose or pyroxylin plastic.
1.1 Changes
May 2000. This revision of the document has been reorganized to provide a consistent format.
June 1999. This document was restructured and data sheet and NFPA references were updated.
2.0 LOSS PREVENTION RECOMMENDATIONS
2.1 Occupancy
2.1.1 Cellulose nitrate fibers and powders should only be stored wetted and in metal drums. Drums should
not be opened in storage areas.
2.1.2 Stock should be rotated to ensure that the oldest material is used first.
2.1.3 Handling equipment and personnel practices should be designed to avoid dragging, dropping,
puncturing, or otherwise damaging drums.
2.1.4 Factory Mutual Research Approved (see Appendix A, for definition) safety tools should be used for
opening drums and handling material.
2.1.5 If any material is spilled, it should be immediately wet with water, preferably by placing it in a pail of
water, and safely disposed.
2.1.6 The quantity of cellulose nitrate brought into dispensing or processing areas should be limited to that
required for a shift
2.1.7 Cellulose nitrate should not be permitted to dry out. If a drum is opened but not immediately emptied,
the material should be amply wet with water or solvent, and the drum tightly resealed.
2.1.8 After emptying, drums should be wiped clean, recovered, and sealed. Used rags should be placed in
an Approved waste can, wet down, and disposed of daily.
2.2 Protection
2.2.1 Drums of cellulose nitrate should be stored in separate rooms used only for that purpose. The rooms
should be designed and protected as recommended for flammable liquids with flashpoint under 200°F (93°C)
in Data Sheet 7-29, Flammable Liquid Storage in Portable Containers, with the following modifications:
a) Drums should be stored in an upright position only.
b) If the cellulose nitrate is wetted only with water, natural ventilation is sufficient.
c) For new sprinkler installations, open-head deluge systems actuated by fast acting fire detectors are
preferred.
d) The probability of a flowing flammable liquid fire is slight. Drainage requirements may be reduced
accordingly. Provide drainage to safely dispose of large quantities of water. Refer to Data Sheet 7-83,
Drainage Systems for Flammable Liquids.
2.2.2 Rooms used for dispensing or use of cellulose nitrate should be designed and protected as
recommended in Data Sheet 7-32, Flammable Liquid Operations.
2.2.3 Outdoor storage in drums should be arranged and protected as recommended for outdoor flam-
mable liquid drum storage in Data Sheet 7-29, with the following exceptions:
a) Minimum spacing from important buildings should be 50 ft (15 m).
b) Curbing and drainage is required only as necessary to control large amounts of fire protection water.
©2000 Factory Mutual Insurance Company. All rights reserved.

Cellulose Nitrate 7-86
FM Global Property Loss Prevention Data Sheets Page 3
2.3 Training
2.3.1 As part of the plant property conservation program, employees should be instructed in the fire hazards
and in recommended preventive and protective practices involving the storage and use of cellulose nitrate.
2.4 Contingency Planning

2.4.1 Public and private fire fighters should be fully informed of the hazards of the cellulose nitrate, its
conditions of storage and use, and the protective arrangements provided.
3.0 SUPPORT FOR RECOMMENDATIONS
3.1 Discussion
The storage and use of dry, solid cellulose nitrate (pyroxylin) has been largely discontinued because of the
development of better substitutes. It is likely to be found only in rare instances, such as the storage of old
motion picture film or imported table tennis balls. Since its use is so rare, publication of recommended prac-
tices for this material has been discontinued.
Cellulose nitrate is more commonly present, particularly in lacquer manufacturing plants, as a white fibrous,
pulp-like material or amorphous powder in steel drums. It is wet with 20 to 30% alcohol or other organic
solvent having a flash point not lower than 30°F (-1°C) or wet with 20 to 25% water. For properties and haz-
ards of this material, see Appendix C.
Cellulose nitrate also may be in solution in the form of a lacquer, with low flash point organic solvents. Unless
the cellulose nitrate is more concentrated than in normal commercial lacquers, it may be treated as an ordi-
nary flammable liquid with the hazard based on the flash point. Appropriate safeguards should be provided
as needed for flammable liquid storage and handling. Where lacquers containing cellulose nitrate are used
in spray applications, some special safeguards are needed as specified in Data Sheet 7-27, Spray
Application of Flammable and Combustible Materials.
4.0 REFERENCES
4.1 FM Global
Data Sheet 7-27, Spray Application of Flammable and Combustible Materials.
Data Sheet 7-29, Flammable Liquid Storage in Portable Containers.
Data Sheet 7-32, Flammable Liquid Operations.
Data Sheet 7-83, Drainage Systems for Flammable Liquids.
4.2 NFPA Standards

Cellulose nitrate in dry form (pyroxylin) is covered by NFPA Standard No. 40, Standard for Storage and
Handling of Cellulose Nitrate Motion Picture Film, and 42, Code for the Storage of Pyroxylin Plastic. Wetted
cellulose nitrate in drums (nitrocellulose) is discussed in NFPA No. 35, Organic Coatings. There are no
conflicts with these standards.
APPENDIX A GLOSSARY OF TERMS

Approved: references to ‘‘Approved’’ in this data sheet means the product and services have satisfied the
criteria for Factory Mutual Research Approval. Refer to the Approval Guide for a complete listing of products
and services that are Factory Mutual Research Approved.

7-86 Cellulose Nitrate
Page 4 FM Global Property Loss Prevention Data Sheets
APPENDIX B DOCUMENT REVISION HISTORY

1975 — This document was updated from information provided in the ‘‘Handbook of Industrial Loss
Prevention’’.
1990 — The information in this document was reaffirmed.
APPENDIX C HAZARD INFORMATION

The following hazard information on cellulose nitrate is from NFPA 49 - 1975. NFPA 49 has been with-
drawn by NFPA but the information on cellulose nitrate is accurate.
CELLULOSE NITRATE (not explosive grade) C12H17(ONO2)3O7; C12H16(ONO2)4O6
DESCRIPTION: A white fibrous, pulp-like material or amorphous powder wet with water, alcohol or some other sol-
vent. It may also be in the form of pyroxylin plastic.
FIRE AND EXPLOSION HAZARDS: Presents an unusually severe fire hazard; when dry, ignites readily and burns
explosively. Should never be kept for any appreciable time in any dry fibrous state. Unstabilized product
decomposes gradually at relatively low temperature, with evolution of copious volumes of toxic and flam-
mable gases, and rapid heat generation. In prolonged storage and aging of nitrocellulose plastics, cam-
phor is lost with deterioration and the decomposition temperature may be lowered to 100°F. The resulting
flameless decomposition is self-sustaining and accelerative, presenting the added hazard of dangerous pres-
sures in building structures.
LIFE HAZARD: Formation of large quantities of extremely toxic gases, notably oxides of nitrogen, hydrogen cya-
nide and carbon monoxide is possible, as well as the danger of eruptive combustion and explosion. Avoid
unnecessary exposure; any person exposed to such fumes should receive immediate medical attention.
PERSONAL PROTECTION: In fire conditions wear self-contained breathing apparatus.
FIRE FIGHTING PHASES: Use extreme caution in approaching fires involving this material as it may explode. No
attempt should be made to fight advanced fires, except for remote activation of installed fire extinguishing
equipment and/or with unmanned fixed turrets and hose nozzles. The surrounding area should be evacu-
ated. Fires should be approached from upwind and self-contained breathing apparatus used. Since cellu-
lose nitrate supplies its own oxygen, prompt cooling with a large quantity of water is essential; water applied
through spray nozzles is effective if used quickly and in sufficient volume, in a manner to wet the entire
exposed surface.
USUAL SHIPPING CONTAINERS: Steel drums or barrels, wet with approximately 20% to 35% alcohol, other sol-
vent, or water.
STORAGE: Drums should be protected against damage and not exposed to heating, nor should material be
allowed to dry out. Storage should be segregated, well ventilated, and equipped with both decomposition and
explosion vents, having the maximum amount of free opening. Protect against excessive heat and direct sun-
light, avoid contact with electric light bulbs, steam coils, or other sources of heat; prohibit open flames or
other sources of ignition.
REMARKS: NOTE: While cellulose nitrate is no longer used as a film base in the United States (some foreign
films may still be made with this material), stocks of old film may be encountered in archival storage, and its
use for plastics in the form of lacquers, enamels, playing cards, combs, buttons, fountain pens, eyeglass
frames, and drafting instruments, among sundry other uses, continues in commercial importance. Electrical
equipment should be in accordance with the National Electrical Code (NFPA No. 70, Article 500), with due
consideration given to the material with which the cellulose nitrate is wet and to the possibility of accumula-
tion of nitrate dust.
FM Engr. Comm. October 1975

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FM Global

Property Loss Prevention Data Sheets 7-86

1.0 SCOPE ................................................................................................................................................... 2

2.0 LOSS PREVENTION RECOMMENDATIONS

©2000 Factory Mutual Insurance Company. All rights reserved.

2.4 Contingency Planning

3.0 SUPPORT FOR RECOMMENDATIONS

4.2 NFPA Standards

APPENDIX A GLOSSARY OF TERMS

©2000 Factory Mutual Insurance Company. All rights reserved.

APPENDIX B DOCUMENT REVISION HISTORY

APPENDIX C HAZARD INFORMATION

FM Engr. Comm. October 1975

©2000 Factory Mutual Insurance Company. All rights reserved.

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