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  • Thermodynamics (JEE - Advanced) - 9th Oct. PDF

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    This document provides information about an instructor named Ashwani Tyagi who has over 13 years of teaching experience. Some of their accomplishments include getting AIR ranks between 2-10 in various engineering entrance exams and mentoring over 1 lakh students, with many going on to secure seats in prestigious institutions. The document then advertises live online classes, test series, and doubt clearing sessions offered by the instructor to help students prepare for these exams in a personalized manner.

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    This document provides information about an instructor named Ashwani Tyagi who has over 13 years of teaching experience. Some of their accomplishments include getting AIR ranks between 2-10 in various engineering entrance exams and mentoring over 1 lakh students, with many going on to secure seats in prestigious institutions. The document then advertises live online classes, test series, and doubt clearing sessions offered by the instructor to help students prepare for these exams in a personalized manner.

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    69 views27 pages

    Thermodynamics (JEE - Advanced) - 9th Oct. PDF

    Uploaded by

    Rhythm Bansal
    This document provides information about an instructor named Ashwani Tyagi who has over 13 years of teaching experience. Some of their accomplishments include getting AIR ranks between 2-10 in various engineering entrance exams and mentoring over 1 lakh students, with many going on to secure seats in prestigious institutions. The document then advertises live online classes, test series, and doubt clearing sessions offered by the instructor to help students prepare for these exams in a personalized manner.

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    AIR- 2, 4 , 6 , 9 (NEET)

    Ashwani Tyagi AIR - 3, 4, 9 (AIIMS)


    AIR - 10, 14 (JEE Adv.)
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    Thermodynamics
    (JEE - Advanced)
    Thermodynamic Equations of State

    (∂U/ ∂V)T = T(∂P/ ∂T)V - P

    (∂H/ ∂P)T = V - T(∂V/ ∂T)P


    Example A non-ideal gas obeys the equation PV = RT + BP, where V is the molar
    volume and B is 10 L/mol. If one mole of the gas is expanded isothermally
    and reversibly at 27°C from 20 atm to 2 atm, calculate ΔU and ΔH.
    Theoretical Determination of CV and CP

    U = Et + Er + Ev + Ee
    Principle of Equipartition of Energy
    THERMODYNAMIC TERMS AND BASIC CONCEPTS
    Degrees of freedom(f):
    THERMODYNAMIC TERMS AND BASIC CONCEPTS
    Degrees of freedom(f):
    THERMODYNAMIC TERMS AND BASIC CONCEPTS
    Degrees of freedom(f):
    Determine the values of CV, CP, C𝜸 for the following gases :
    Example (a) He
    (b) H2
    (c) H2 at very low temperature
    (d) H2 at very high temperature
    (e) SO3
    (f) SO2, taking only 20% contribution of vibrational energy
    Example Determine the adiabatic exponent, 𝛄, for a three dimensional N- atomic gas, at
    a. Moderate temperature
    b. Very high temperature
    Example Molecules of a gas have ‘f’ degree of freedom, where degree of freedom
    represents the number of independent methods to express the energy of
    molecules. Determine the adiabatic exponent for the gas.
    Example 4 moles of an ideal gas having 𝛄 = 1.67 are mixed with 2 moles of another
    ideal gas having 𝛄 = 1.40. Find the equivalent values of 𝛄 for the mixture.
    Example An amount Q of heat is added to a monoatomic ideal gas in a process in
    which the gas performs a work Q/2 on its surrounding. Find the molar heat
    capacity for the process.
    Example An ideal gas is taken through a process in which the pressure and the
    volume are changed according to the equation P = KV. Show that the
    molar heat capacity of the gas for the process is given by C= CV + R/2.
    Example One mole of an ideal gas with heat capacity at constant pressure, C P
    undergoes the process: T = To + αV, To and α are constants. Show that the
    heat capacity of the gas as a function of its volume is C = CP + RT/ αV.
    11th Grade
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