physics 1

1) A gas bubble, from an explosion under water, a) 25 N b) 10 N

oscillates with a period T proportional to pa db c) 20 N d) 15 N
Ec. where ‘P’ is the static pressure, ‘d’ is the 6) The speed of the block at point B immediately
density of the water and ‘E’ is the total energy after it strikes the second incline is –
of the explosion. Find the value of a, b and c. A
a) –2/3, 1/2, 1/3 b) –5/6, 1/2, 1/3
c) –19/6, 1/3, 1/2 d) 1/2, –5/6, 1/3 3m
2) The dimensions of coefficient of viscosity h are B
60º
a) [ML–1T–1] b) [MLT–2] v
c) [MLT–1] d) [ML2T–2] 30º
3) A horizontal uniform rope of the length L, 3m
resting on a friction less horizontal surface, is 30º C
pulled at one end by force F. What is the tention
in the rope of a distance l from the end where 3m 3 3m
the force is applied? a) 60 m / s b) 45 m / s
a) T = F(1–l/L) b) T = F(1–L/l) c) 30 m / s d) 15 m / s
c) T = F(3–l/L) d) T = F(1–l2/L)
7) The speed of the block at point C, immediately
4) Two cars of mass m1 and m2 are moving in
before it leaves the second incline is
circles of radii r1 and r2, respectively. Their
speeds are such that they make complete circles a) 120 m / s b) 105 m / s
in the same time t. The ratio of their centripetal c) 90 m / s d) 75 m / s
acceleration is :
8) If collision between the block and the incline is
a) m1r1 : m2r2 b) m1 : m2
c) r1 : r2 d) 1 : 1 completely elastic, then the vertical (upward)
5) Two blocks of mass 2.9 kg and 1.9 kg are component of the velocity of the block at point B,
suspended from a right support S by two immediately after it strikes the second incline is –
inextensible wires each of length 1 meter, see a) 30 m / s b) 15 m / s
fig. The upper wire has negligible mass and the
c) 0 d) - 15 m / s
lower wire has a uniform mass of 0.2 kg/m. The
9) A cylinder of mass m and radius R rolls down
whole system of blocks wires and support have
an inclined plane of inclination q. Calculate the
an upward acceleration of 0.2 m/s2 . Acceleration
due to gravity is 9.8 m/s2. linear acceleration of the axis of cylinder.
S a) 2 g sin q b) 3/2 g sin q
c) 3 g sin q d) 2/3 g sin q
10) A thin circular disc of radius R is uniformly
2.9 kg
charged with density s > 0 per unit area. The
disc rotates about its axis with a uniform angular
1.9 kg
speed w. The magnetic moment of the disc is
Find the tention at the mid-point of the lower a) pR4sw b) pR4/2 sw
wire c) pR4/4 sw d) 2pR2w
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11) Two satellites S1 and S2 revolve round a planet
in coplanar circular orbits in the same sense.
Their periods of revolution are 1 hour and 8 b R
hours respectively. The radius of the orbit of S1 v
is 104 km. when S2 is closest to S1, find
The speed of S2 relative to S1 ,
a) –p/4 × 104 km/hr b) –p × 104 km/hr
c) –4p × 104 km/hr d) p × 104 km/hr a) 2T/ρv2 b) 3T/ρv2
12) What is the minimum energy required to c) T/ρv2 d) 4T/ρv2
launch a satellite of mass m from the surface 15) When temperature of a gas is 20oC and pressure
of a planet of mass M and radius R in a circular is changed FROM P1 = 1.01 × 105 Pa to p2 =
orbit at an altitude of 2R? 1.165 × 105 Pa then the volume changed by
5GmM 2GmM 10%. The bulk modulus is
a) b)
6R 3R a) 1.55 × 105 Pa b) 0.115 × 105 Pa
5
c) 1.4 × 10 Pa d) 1.01 × 105 Pa
GmM GmM
c) d) 16) A thin tube of uniform cross-section is sealed
2R 5R
at both ends. It lies horizontally the middle 5
13) A large open top container of negligible mass cm containing mercury and the two equal end
and uniform cross-sectional area A has a small containing air at the same pressure P. When the
holes of cross-sectional area A/100 in its side tube is held at an angle of 600 with the vertical
wall near the bottom. The container is kept on direction, the length of the air column above
a smooth horizontal floor and contains a liquid and below the mercury column are 46 cm and
of density ρ and mass m0. Assuming that the 44.5 cm respectively. Calculate the pressure P
liquid starts flowing out horizontally through in centimeters of mercury. (The temperature of
the hole at t = 0, calculate the system is kept at 30oC).
The acceleration of the container and its velocity A) 72.4 b) 73.5
when 75% of the liquid has drained out c) 75.4 d) 74.5
g gm0 2g gm0 17) Einstein’s mass-energy conversion relation E =
a) , b) , mc2 is illustrated by
50 2aρ 3 3aρ
a) nuclear fission b) nuclear fusion
50 gm0 gm0 c) rocket propulsion d) steam engine
c) , d) 5g, 18) A cubical block of co-efficient of linear
g 3aρ 2aρ
expansion αs is submerged partially inside a
14) A bubble having surface tention T and radius R is
liquid of co-efficient of volume expansion gl.
formed on a ring of radius b(b<<R). Air is blown
on increasing the temperature of the system
inside the tube with velocity v as shown. The air by ΔT, the height of the cube inside the liquid
molecules collide perpendicularly with the wall remains unchanged. Find the relation between
of the bubble and stops. Calculate the radius at αs and gl.
which the bubble separates from the ring. a) α = g b) g = 2a
c) a = 2g d) a2 = g
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19) An insulted container containing monoatomic 6× 10–4
kg and charge +0.1 mC moves along
gas of molar mass m is moving with a velocity the -x direction. Its speed at x = + ∞ is V0. Find
vo. If the container is suddenly stopped, find the least value of V0 for which the particle will
the change in temperature cross the origin. Assume that space is gravity
a) mv0 / 2R b) mv0 / 3R free. Given 1/4pe0 = 9 × 109 Nm2/C2.
2
c) mv0 / 2R d) mv02 / 3R a) 3 m/s b) 4 m/s
20) If a gas has ‘n’ degrees of freedom, the ratio of c) 2 m/s d) p/3 m/s
the specific heats g of the gas is 25) A circular ring of radius R with uniform positive
1+ n n charge density l per unit length is located in
a) b) 1 +
2 2 the y-z plane with its centre at the origin O.
1 2 A particle of mass m and positive charge q is
c) 1 + d) 1 +
n n projected from the point P (R 3 , 0, 0) on the
21) A mass M attached to a spring, oscillates with a positive x-axis directly towards O, with an
period of 2 sec. If the mass is increased by 2 kg initial speed v. Find the smallest (non-zero)
the period increases by one sec. Find the initial value of the speed v such that the particle does
mass M assuming that Hook's Law is obeyed. not return to P.
a) 1.6 kg b) 1.1 kg a) 5lq / 2e m b) lq / 2e0 m
0
c) 2.6 kg d) 3.6 kg
22) Two tuning forks with natural frequencies c) lq / 2e0m d) lq / 4e0 m
of 340 Hz each move relative to a stationary 26) Two point charges +8q and –2q are located at
observe, while the other moves towards him x = 0 and x = L respectively. The location of
at the same speed. The observer hears beats of a point on the x axis at which the net electric
frequency 3 Hz. Find the speed of the tuning field due to these two point charges is zero is
fork. a) L/4 b) 2L
a) 1.5 m/s b) 2.5 m/s c) 4L d) 8L
c) 2 m/s d) 2.2 m/s 27) Two points P and Q are maintained at the
23) A whistling train approaches a junction. potentials of 10 V and – 4 V, respectively. The
An observer standing at junction observers work done in moving 100 electrons from P to
the frequency to be 2.2 KHz and 1.8 KHz Q is :
of the approaching and the receding Train a) 9.60 × 10–17 J b) –2.24 × 10–16 J
respectively. Find the speed of the train (speed c) 2.24 × 10–16 J d) –9.60 × 10-17 J
of sound = 300 m/s) 28) Two identical capacitors, have the same
a) 32 m/s b) 31 m/s capacitance C. One of them is charged to
c) 31.5 m/s d) 30 m/s potential V1 and the other V2 .The negative
24) Four point charges +8mC, –1mC, ends of the capacitor are connected together.
–1mC and +8mC are fixed at the points When the positive ends are also connected, the
27 3 3 27 decreases in energy of the combined system is
- m, - m, + m and + m
2 2 2 2
respectively on the y-axis. A particle of mass
1
(
a) C V12 - V22
4
) 1
( 2
b) C V1 + V2
4
2
)
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A B
c)
1
4
2
C ( V1 - V2 )
1
(
d) C V12 - V22
4
)
29) Two concentric spheres of radii R and r have C D
similar charges with equal surface densities (s). a) 1 sec b) 0.1 sec
What is the electric potential at their common c) 2 sec d) 0.2 sec
centre ? 33) A solenoid has an inductance of 10 henry and
a) s/e0 b) s/e0 (R – r) a resistance of 2 ohm. It is connected to a 10
c) s/e0 (R + r) d) None of these volt battery. How long it take for the magnetic
30) Find the emf (V) and internal resistance (r) of a energy to each 1/4 of its maximum value?
single battery which is equivalent to a parallel a) 3.466 sec b) 3.445 sec
combination of two batteries of emfs V1 and V2 c) 3.444 sec d) 3.442 sec
and internal resistance r1 and r2 respectively, 34) The magnetic field due to a current carrying
with polarities are shown in figure. circular loop of radius 3 cm at a point on the
axis at a distance of 4 cm from the current is
r2
V2 54 µT. What will be its value at the center of
+ loop?
A
a) 125 µT b) 150 µT
r1 V1 c) 250 µT d) 75 µT

35) An inductance L and a resistance R are
v r -v r rr v r +v r rr
a) 1 1 2 2 , 1 2 b) 1 1 2 2 , 1 2 connected in series with a battery of emf e. The
r1 + r2 r1 + r2 r1 + r2 r1 + r2 maximum rate at which the energy is stored in
v r +v r rr v r +v r rr the magnetic field is
c) 1 1 2 2 , 1 2 d) 1 1 2 2 , 1 2
r1 + r2 r1 - r2 r1 - r2 r1 + r2 a) e2/4R b) e2/2R
31) A steady current of 1.5 A flows through a copper c) 2R/e d) 4R/e
voltameter for 10 min. If the electrochemical 36) A coil of inductance 300 mH and resistance 2W
equivalent of copper is 30 × 10–5 g C–1, the is connected to a source of voltage 2V. The
mass of copper deposited on the electrode will current reaches half of its steady state value in
be a) 0.05 s b) 0.1 s
a) 0.40 g b) 0.50 g c) 0.15 s b) 0.3 s
c) 0.67 g d) 0.27 g 37) A metal disc of radius 100cm is rotated at a
32) A long horizontal wire AB, which is free to constant angular speed of 60 rads–1 in a plane
move in a vertical plane and carries a steady at right angles to an external field of magnetic
current of 20 A, is in equilibrium at a height induction 0.05 Wbm–2. The emf induced between
of 0.01 m over another parallel long wire CD the centre and a point on the rim will be
which is fixed in a horizontal plane and carries a) 3 V b) 1.5 V
a steady current of 30 A, as shown in figure. c) 6 V d) 9 V
when AB is slightly depressed, it executes 38) Diameter of a plano-convex lens is 6 cm and
simple harmonic motion, find the period of thickness at the center is 3 mm. If the speed of
oscillations. light in material of lens is 2 × 108 m/s, the focal
length of the lens is
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a) 15 cm b) 20 cm 44) Light of frequency v falls on material of
c) 30 cm d) 10 cm threshold frequency v0. Maximum kinetic
39) A thin glass (refractive index 1.5) lens has energy of emitted electron is proportional to:
optical power of –5D in air. Its optical power a) v – v0 b) v
in a liquid medium with refractive index 1.6
will be c) v - v0 d) v0
a) –1D b) 1 D 45) The binding energy per nucleon for the parent
c) –25 D d) 25 D nucleon is E1 and that for the daughter nuclei
40) The refracting angle of a prism is A and the is E2. Then
refractive index is cot(A/2). The angle of a) E2 = 2E1 b) E1 > E2
minimum deviation is c) E2 > E1 d) E1 = 2E2
a) 1800–A b) 1800–2A 46) The speed of daughter nuclei is
c) 1800–3A d) 1800–4A ∆m 2∆m
41) A double-slit apparatus is immersed in a liquid a) c b) c
M + ∆m M
of refractive index 1.33. It has slit separation of
1 mm, and distance between the plane of slits ∆m ∆m
c) c d) c
and screen is 1.33 m. the slits are illuminated M M + ∆m
by a parallel beam of light whose wavelength 47) Hydrogen bomb is based upon
in air is 6300 Å. Calculate the fringe width a) fission b) fusion
a) 1.3 × 10–4m b) 2.3 × 10–4m c) chemical reaction d) transmutation
c) 6.3 × 10–4m d) 3.3 × 10–4m 48) Digital circuit can be made by repetitive use of
42) Highly energetic electrons are bombarded on this gate
a target of an element containing 30 neutrons. a) AND b) OR
The ratio of ratii of nucleus to that of helium
c) NOT d) NAND
nucleus is (14)1/3. Find atomic number of the
49) An alpha nucleus of energy 1/2 mv2 bombards
nucleus and the frequency of Kα line of the
a heavy nuclear target of charge Ze. Then the
x-ray produced. (R = 1.1 × 107 m–1 and c = 3 ×
distance of closest of closest approach for the
108 m/s)
alpha nucleus will be proportional to
a) 56, 1.546 × 1018Hz b) 56, 1.2 × 1018Hz
a) v2 b) 1/m
c) 50, 1.2 × 1018Hz d) 43, 1.436 × 1018Hz
c) 1/v4 d) 1/Ze
43) In hydrogen-like atom (z = 11), nth line of
lyman series has wavelength λ. The de-broglie’s 50) The radius of germanium (Ge) nuclide is
wavelength of electron in the level from which measured to be twice the radius of 94Be. The
it originated is also λ. Find the value of n? number of nucleons in Ge are
a) 23 b) 24 a) 73 b) 74
c) 25 d) 26 c) 75 d) 72

****

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 CHEMISTRY 6
51) X moles of potassium dichromate oxidizes 1 formation of cation is low ionization potential.
mole of ferrous oxalate, in acidic medium. Here b) Co-ordination number of Cs in CsCl is 8.
X is c) Ionic bond is directional.
a) 3 b) 1.5 d) Ionic compounds have high melting and
c) 0.5 d) 1.0 boiling points.
52) The mass of BaCO3 produced when excess 59) The enthalpy change involved in the oxidation of
CO2 is bubbled through a solution of 0.205 mol glucose is –2880 kJ mol–1. Twenty five percent
Ba(OH)2 of this energy is available for muscular work. If
a) 81 g b) 20.25 g 100 kJ of muscular work is needed to walk one
c) 162 g d) 40.5 g kilometer, what is the maximum distance that a
53) A spherical balloon of 21 cm diameter is to be person will be able to walk after eating 120 g of
filled up with hydrogen at N.T.P from a cylinder glucose.
containing the gas at 20 atmosphere at 27ºC. If the a) 5.8 km b) 3.8 km
cylinder can hold 2.82 liters of water, calculate the c) 4.8 km d) 6.8 km
no. of balloons that can be filled up. 60) The value of heat of formation of SO2 and
a) 12 b) 14 SO3 are –298.2 kJ and –98.2 kJ. The heat of
c) 10 d) 11 formation of the reaction
54) The root mean square speeds at STP for the SO2 + (1/2) O2 → SO3 will be
gases H2, N2, O2 and HBr are in the order : a) –200 kJ b) –356.2 kJ
a) H2 < N2 < O2 < HBr c) +200 kJ d) –396.2 kJ
b) HBr < O2 < N2 < H2 61) The polymerization of ethylene to linear
c) H2 < N2 = O2 < HBr polyethylene is represented by the reaction
nCH2 = CH2 → –CH [ 2 – CH2–]n where n has
d) HBr < O2 < H2 < N2
a large integral value. Given that the average
55) The de-broglie wavelength associated with a
enthalpies of bond dissociation for C = C
ball of mass 1 kg having kinetic energy 0.5 J is
and C – C at 298 K are +590 and +331 kJ
a) 6.626 × 10–34 m b) 13.20 × 10–34 m mol–1, respectively, calculate the enthalpy of
c) 10.38 × 10–21 m d) 6.626 × 10–34 Aº polymerisation per mole of ethylene at 298 K.
56) Set of is electronic species is a) –72. kJ /mole b) –75.kJ/mole
a) N2, CO2, CN–, O b) N, H2S, CO c) –78.kJ/mole d) –71.kJ/mole
c) N2, CO, CN–, O+2 2 d) Ca, Mg, Cl 62) Compute the heat of formation of liquid Methyl
57) Specify the co-ordination geometry around alcohol in kilojoules per mole, using the
and hybridization of N and B atoms in a 1 : 1 following data. Heat of vaporization of liquid
complex of BF3 and NH3. methyl alcohol = 38 kJ/mol. Heat of formation
a) N : tetrahedral, sp3 ; B : tetrahedral, sp3 of gaseous atoms from the elements in their
b) N : pyramidal , sp3 ; B : pyramidal, sp3 standard state ; H, 218 kJ mole ; O, 249 kJ/
c) N : pyramidal, sp3 ; B : planar, sp2 mol. Average bond energy : C – H = 415 kJ/
d) N : pyramidal, sp3 ; B : tetrahedral, sp3 mol, C – O = 365 kJ/mol, O – H = 463 kJ/mol
58) Which of the following in not correct? a) –277 kJ/mol b) –266kJ/mol
a) One of the favourable condition for the c) –255kJ/mol d) –275kj/mol
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63) An organic compound CXH2YOY was burnt b) S2O62– < S2O42– < SO32–
with twice the amount of oxygen needed c) S2O42– < SO32– < S2O62–
for complete combustion to CO2 and H2O.
d) SO32– < S2O42– < S2O62–
The hot gases when cooled to 0ºC and 1 atm
68) Which of the following have been arranged
pressure, measured 2.24 liters. The water
in decreasing order of oxidation number of
collected during cooling weighed 0.9 g . The
sulphur ?
vapour pressure of pure water at 20ºC is 17.5
a) Na2S4O6 > H2S2O7 > Na2S2O3 > S8
mm Hg and is lowered by 0.104 mm when 50 g
of the organic compound are dissolved in 1000 b) H2SO4 > SO2 > H2S > H2S2O8
g of water. Give the molecular formula of the c) SO22+ > SO42– > SO32– > HSO4–
organic compound. d) H2SO5 > H2SO3 > SCl2 > H2S
a) (C2H4O)5 or C5H10O5 69) In the Arrhenius equation for a certain reaction,
b) (CH2O)5 or C5H10O5 the value of A&Ea (activation energy) are 4 ×
c) (CH2O)5 or C3H6O5 10–13 sec–1 and 98.6 kJ mol–1 respectively. If
d) (CH2O)5 or C4H8O5 the reaction is of first order, at what temperature
will its half-life period be ten minutes?
64) What is the molarity of H2SO4 solution if 25
a) 312.38 K b) 311.35 K
mL is exactly neutralized with 32.63 mL of
c) 313.35 K d) 310.38 K
0.164 M NaOH ?
70) Given the hypothetical reaction mechanism
a) 0.107 M b) 0.126 M I II III IV
c) 0.214 M d) –0.428 M A  → B  → C → D → E
65) Given : Ag(NH3) 2  
+    Ag+ + 2NH3, Kc = and the date as
6.2 × 10–8 and Ksp of AgCl = 1.8 × 10–10 at Species formed Rate of its formation
298 K. If ammonia is added to a water solution B 0.002 mol/h, per mole of A
containing excess of AgCl(s) only, calculate the C 0.030 mol/h, per mole of B
concentration of the complex in 1.0 M aqueous D 0.011 mol/h, per mole of C
ammonia. E 0.420 mol/h, per mole of D
a) 0.0338 M b) 0.0435 M
The rate determining step is
c) 0.0538 M d) 0.0635 M
a) step I b) step II
66) When two reactants, A & B are mixed to give
c) step III d) step IV
product C & D the reaction quotient Q, at the
71) Select the incorrect statement.
initial stage of the reaction
a) Physical adsorption is reversible while
a) is zero
chemical is irreversible
b) decreases with time
b) High pressure favours physical adsorption
c) is independent of time
while low pressure favours chemical
d) increases with time
adsorption
67) The oxidation states of sulphur in the anions
c) Physical adsorption is not specific while
SO32–, S2O42– and S2O62– follow the order chemical is highly specific.
2– 2–
a) S2O4 < S2O6 < SO3 2– d) High activation energy is involved in chemical
adsorption.
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72) Hardy – schulze rule explain the effect of c) Al3+ d) Si4+
electrolytes on the coagulation of colloidal 79) On dissolving moderate amount of sodium
solution. According to this rule, coagulation metal in liquid NH3 at low temperature, which
power of cations follow the order. one of the following does not occur?
a) Ba+2 > Na+ > Al+3 b) Al+3 > Na+ > Ba+2 a) Blue coloured solution is obtained
c) Al+3 > Ba+2 > Na+ d) Ba+2 > Al+3 > Al+ b) Na+ ions are formed in the solution
73) Which one of the following in the smallest in c) Liquid NH3 becomes good conductor of
the size? electricity
a) N3– b) O2– d) Liquid ammonia remains diamagnetic
c) F– d) Na+ 80) A metal M forms water soluble MSO4 and inert
74) Molybdenum metal is related to which block? MO. MO in aqueous solution forms insoluble
a) s-block b) p-block M(OH)2 soluble in NaOH. metal M is
c) d-block d) none of these a) Be b) Mg
75) Sulphide ores of metals are usually concentrated c) Ca d) Si
by froth floatation process. Which one of the 81) B(OH)3 + NaOH   NaBO2 + Na[B(OH)4]
following sulphide ores offers an exception + H2O. How can this reaction is made to
and is concentrated by chemical leaching proceed in forward direction?
a) Argentite b) Galena a) addition of cis-1, 2-diol
c) Copper pyrite d) Sphalerite b) addition of borax
76) The following reactions take place in the blast c) addition of trans-1, 2-diol
furnace in the preparation of impure iron. d) addition of Na2HPO4
Identify the reaction pertaining to the formation 82) Which one of the following statements about
of the slag. the zeolites is false?
a) Fe2O3(s) + 3CO(g) → 2Fe(l) + 3CO2(g) a) they are used in cation exchangers
b) CaCO3(s) → CaO(s) + CO2(g) b) they have open structure which enables
c) CaO(s) + SiO2(s) → CaSiO3(s) them to take up small molecules
d) 2C(s) + O2(g) → 2CO(g) c) zeolites are aluminosilicates having three
77) In context with the industrial preparation of dimensional network
hydrogen from water gas (CO + H2) which of d) some of the SiO44– unit are replaced by
the following is the correct statement. AlO45– and AlO69– ions in zeolites
a) CO and H2 are fractionally separated using 83) In the process of extraction of gold, Roasted
difference in their densities gold ore + CN– + H2O O 2
→ [X] + OH–
b) CO is removed by adsorption in aqueous
Cu2Cl2 solution [X] + Zn —→ [Y] + Au
c) H2 is removed through occlusion with Pd Identify the complexes [X] and [Y]
d) CO is oxidized to CO2 with steam in the a) X = [Au(CN)2]–, Y = [Zn(CN)4]2–
presence of a catalyst followed by absorption b) X = [Au(CN)4]3–, Y = [Zn(CN)4]2–
of CO2 in alkali c) X = [Au(CN)2]–, Y = [Zn(CN)6]4–
78) Exhausted permutit does not contain...ion.
d) X = [Au(CN)4]–, Y = [Zn(CN)4]2–
a) Na+ b) Mg2+
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84) KMnO4 can be prepared from K2MnO4 as per c) CH3CH==CHCH3
the reaction d) CH3CH2C≡≡CCH2CH3
3MnO42– + 2H2O  
 90) Which one of the following reactions yield 2E-
2MnO42– + MnO2 + 4OH– butene as the major product?
The reaction can go to completion by removing a) CH3—C≡≡C—CH3 + Na/NH3 (liq.)
OH– ions by adding b) CH3—CH==CH—CH3 + Li/NH3 (liq.)
a) KOH b) CO2 c) CH3—C==C—CH3 + Na/NH4OH
c) SO2 d) HCL d) CH3—C≡≡C—CH3 + Pd/BaSO4
85) Which of the following complex ion is not 91) An organic compound E(C5H8) on
expected to absorb visible light? hydrogenation gives compound F(C5H12).
a) [Ni(H2O)6]2+ b) [Ni(CN)4]2– Compound E on ozonolysis gives formaldehyde
c) [Cr(NH3)6]3+ d) [Fe(H2O)6]2+ and 2-ketopropanal. Deduce the structure of
86) Which of the following is considered to be an compound E.
anticancer species? CH3
Cl CH2 Cl Cl a) CH2—C—CH2—CH3
a) Pt CH2 b) Pt CH2
Cl Cl Cl Cl
b) CH3—C—CH—CH2
H3N Cl H3N Cl CH3
c) Pt d) Pt
c) CH3—C—CH2—CH3
H3N Cl Cl NH3
87) Which of the following statement is not true? Br
a) Oxides of sulphur , nitrogen and carban are CH3
the most widespread air pollutant. d) CH3—C—CH—CH2
b) PH of drinking water should be between 92) Which of the following will give yellow
5.5-9.5 precipitate on shaking with an aqueous solution
c) Concentration of DO below 6ppm is good of NaOH followed by acidification with dil.
for growth of fish HNO3 and addition of AgNO3 solution?
d) Clean water would have a BOD value of Cl
less than 5 ppm
88) The brown haze of photochemical smog is a) Br b)
largely attributable to
a) NO b) NO2 CH3
c) CH3COONO2 d) CH2==CHCH==O Cl
I
O c) Br d)
89) The hydrocarbon which can react with sodium 93) Which of the following on reduction with lithium
in liquid ammonia is aluminium hydride yields a secondary amine?
a) CH3CH2CH2C≡≡CCH2CH2CH3 a) Nitroethane b) methylisocyanide
b) CH3CH2C≡≡CH c) acetamide d) methyl cyanide
Space for Rough Work
 10
X H O
94) CH3—CH2C≡≡N → CH3CH2CHO
The compound X is a) –N–C–N–C–NH–C–NH–
a) SnCl2/HCl/H2O, boil
b) H2/Pd—BaSO4 O H
H H
c) LiAlH4/ether
d) NaBH4/ether/H3O+ b) –N–C–C–C–C–N–C–C–C–
95) The correct statement about the following
O
disaccharide is
CH2OH H H H O
O O
H
H H HOH2C
H c) –N–C–C–N–C–C–N–C–C–
(A) (B)
OH H H HO
HO OCH2CH2O CH2OH O O

H OH OH H
a) Ring (A) is pyranose with a – glycosidic link d)
b) Ring (A) is furanose with a – glycosidic link
c) Ring (B) is furanose with a – glycosidic link
d) Ring (B) is pyranose with b – glycosidic link 99) Which of the following is red dye?
OH
96) Which of the following statement is not true ?
a) in vulcanization, the formation of sulphur
a) N N
bridges between different chains make
rubber harder and stronger.
b) natural rubber has the trans-configuration at
every double bond b) N N N(CH3)2
c) buna-S is a copolymer of butadiene and
styrene.
c) N N OH
d) natural rubber is a 1,4-polymer of isoprene
97) If two moles of glucose are oxidized in the
body through respiration , the number of moles d) N N NH2
of ATP produced are 100)The pair in which both species have iron is
a) 19 b) 38 a) nitrogenase, cytochromes
c) 57 d) 76 b) carboxypeptidase, haemoglobin
98) Which of the following structure represents the c) haemocyanin, nitrogenase
peptide chain? d) haemoglobin , cytochromes

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Space for Rough Work

 Mathematics 11
101) The domain of the function a) 45 b) –15
2
f ( x) = exp( 5 x − 3 − 2 x ) is : c) 10 d) 6

a) [3/2, ∞] b) [1, 3/2] 109) If a, b, c are in A.P., a2, b2, c2 are in H.P., then
c) [–∞, 1] d) [1, 5/2] either a = b = c or a, b, –c/2 form a
102) Let {x} and [x] denotes the fractional and a) A.P b) G.P
integral part of a real number x respectively. c) H.P d) not in series
Solve 4{x} = x + [x]. a b (ax + b) / x
a) 5/3, 0, –5/3 b) –5/3, 0, 5/3 110) If b c bx + c = 0,
c) –2/3, 0, 2/3 d) 2/3, 0, –2/3 ax + b bx + c 0
103) Let f (x + y) = f (x) f (y) for all x and y. suppose then a, b, c are in :
f (5) = 2 and f ’(0) = 3. Find f ’(5). a) AP b) GP
a) 5 b) 6 c) HP d) None of these
c) 7 d) 8 111) Let a1, a2, a3, … be in harmonic progression
104) ABC is triangle such that with a1 = 5 and a20 = 25. The least positive
sin (2A + B) = sin (C – A) = –sin (B + 2C) = integer n for which an < 0 is
1/2. If A, B and C are in arithmetic progression, a) 22 b) 23
determine the values of A, B and C. c) 24 d) 25
a) 60º, 45º, 75º b) 75º, 45º, 60º 5
112) The coefficient of x in the expansion of (1 +
c) 45º, 60º, 75º d) 60º, 60º, 60º x2)5 (1 + x)4 is :
105) If cos(x – y), cos x and cos (x + y) are in H.P., a) 30 b) 60
then cos x sec (y/2) = c) 40 d) none of these
a) ± 3 b) − 3 113) Coefficient of x2 in the expansion of (x –
c) 2 d) ± 2 1/2x)8 is equal to :
106) A block weighing w, is supported on an a) 1/7 b) –1/7
inclined surface with the help of a horizontal c) –7 d) 7
force p. The same block can be supported with 114) A student is allowed to select almost n books
the help of another force Q acting parallel to from a collection of (2n + 1) books. If the total
the inclined surface, than the value of 1/p2 + number of ways in which he can select at least
1/w2 is : one book is 63, find the value of n.
a) w sin a b) 1 a) 4 b) 3
c) 1/Q d) 1/Q2 c) 2 d) 1
107) The value of ‘a’ for which one root of the 115) The average marks of boys in a class is 52 and
quadratic equation that of girls is 42. The average marks of the
(a2 – 5a + 3)x2 + (3a – 1)x + 2 = 0 boys and girls combined is 50. The percentage
is twice as large as the other, is of boys in the class is
a) 2/3 b) –2/3 a) 40% b) 20%
c) 1/3 d) –1/3 c) 80% d) 60%
108) If x = 3 + i, then x3 – 3x2 – 8x + 15 is equal to 116) The mean of the number a, b, 8, 5, 10 is 6
: and the variance is 6.80. Then which of the

Space for Rough Work

 12
following is possible value of a and b?
41
a) a = 3, b = 4 b) a = 0, b = 7 124) The value of cot–1 9 + cosec–1 is bgiven
c) a = 5, b = 2 d) a = 1, b = 6 4
by
117) A bag contain n + 1 coins. It is known that a) 0 b) π/4
one of these coins shows heads on both –1
c) tan 2 d) π/2
sides, whereas the other coin are fair. One 125) The points (1, 3) and (5, 1) are two opposite
coin is selected at random and tossed. If the vertices of a rectangle. The other two vertices
probability that toss results in heads is 7/12, lie on the line y = 2x + c. Find c and the
than the value of n is remaining vertices.
a) 3 b) 4 a) C = –3, (3, 3), (1, 0)
c) 5 d) none of these b) C = –2, (4, 4), (2, 0)
a b c c) C = –3, (4, 4), (2, 0)
118) If matrix A = b c a where a, b, c are d) C = –4, (4, 4), (2, 0)
c a b π
126) Let ABC be a triangle such that ∠ACB =
real positive numbers, abc = 1 and ATA = I, 6
then find the value of a3 + b3 + c3. and let a, b and c denote the lengths of the
a) 4 b) 3 side opposite to A, B and C respectively. The
c) 2 d) 1 value(s) of x for which a = x2 + x + 1, b = x2
119) If log3 2, log3 (2 – 5), and log3 [2x – 7/2]
x – 1 and c = 2x + 1 is (are)
are in arithmetic progression, determine the a) −(2 + 3 ) b) 1 + 3
value of x. c) 2 + 3 d) 4 3
a) 4 b) 3 127) The top of a hill observed from the top and
c) 2 d) 1 bottom of a building of height h is at angle of
4 xy elevation p and q respectively. the height of
120) sin 2 q = is true, if and only if
( x + y )2 hill is :
a) x – y ≠ 0 b) x = –y h cos q h cot q
a) b)
c) x + y ≠ 0 d) x ≠ 0, y ≠ 0 cot q − cot p cot p − cot q
121. tan–1(1/4) + tan–1(2/9) is equal to h tan p
a) 1/2 cos–1(3/5) b) 1/2 sin–1(3/5) c) d) none of these
tan p − tan q
c) 1/2 tan–1(3/5) d) tan–1(1/2)
122) If tan α = m/m + 1 and tan β = 1/2m + 1’, 128) If f (x) = x( x − x +1), then-
then α + β is equal to : a) f (x) is continuous but not differentiable at
a) π/3 b) π/4 x=0
c) zero d) π/2 b) f (x) is differentiable at x = 0
123) 2 tan–1(cos x) = tan–1(cosec2x) than x is equal c) f (x) is not differentiable at x = 0
to d) none of these
a) π/2 b) π 1 29) The set of all points where the function
c) π/6 d) π/3 x
f ( x) = is differentiable, is
(1+ | x |)
Space for Rough Work
 13
a) (–∞, ∞) b) [0, ∞) the curve is
c) (–∞, 0) ∪ (0, ∞) d) (0, ∞)  y 1
a) sin   = log x +
1 x 2
50 100 y
 
∫ (1 − x ) dx b) cosec   = log x
130) The value of 5050 01 x
 2y 
c) sec   = log x + 2
50 101
∫ (1 − x ) dx  x 
0  2y  1
d) cos   = log x +
a) 5051 b) 5050  x  2
c) 4848 d) 4850 136) Two equal sides of an isosceles triangle are
131) The area bounded by the curve y = cos x and given by the equations 7x – y + 3 = 0 and x +
y = sin x between the ordinates x = 0 and x = y – 3 = 0 and its third side passes through the
3π/2 is point (1, –10). Determine the equation of the
a) (4 2 − 2) sq unit b) (4 2 + 2) sq unit third side.
a) x – 3y – 31 = 0 b) 3x + y – 31 = 0
c) (4 2 − 1) sq unit d) (4 2 + 1) sq unit
1
c) x + 3y – 31 = 0 d) 3x – y – 7 = 0
x 4 (1 − x) 4 137) The points (0, 8/3), (1, 3) and (82, 30) are
132) The value(s) of ∫ 1 + x2
dx is
vertices of
0
a) An obtuse angled triangle
22 2
a) −π b) b) An acute angled triangle
7 105 c) An isosceles triangle
71 3π d) None of these
c) 0 d) −
15 2 138) The points (1, 3) and (5, 1) are two opposite
133) Find the area of the region bounded by the vertices of a rectangle. The other two vertices
curve C : y = tan x, tangent drawn to C at x = lie on the line y = 2x + c. Find c and the
π/4 and the x-axis. remaining vertices.
a) 1/2[log2 – 1/2] sq. units a) C = –3, (3, 3), (2, 0)
b) 1/2(log2 – 1/2] sq. units b) C = –4, (3, 3), (2, 0)
c) 1/2[log2 – 1/2) sq. units c) C = –3, (3, 3), (3, 0)
d) 1/2(log2 – 1/2) sq. units d) C = –4, (4, 4), (2, 0)
134) To reduce the differential equation 139) The intercept on the line y = x by the circle x2
dy + y2 – 2x = 0 is AB. Equation of the circle is
+ P( x) y = Q( x) ⋅ y n to the linear form,
dx AB as a diameter is
the substitution is: a) x2 + y2 – x – y = 0 b) x2 + y2 – x + y = 0
a) v = 1/yn b) v = 1/yn–1 c) x2 + y2 + x + y = 0 d) x2 + y2 + x – y = 0
c) v = yn d) v = yn–1 140) The two curve x3 – 3xy2 + 2 = 0 and 3x2y – y3 = 2
135) A curve passes through the point (1, π/6). Let a) cut at right angle b) touch each other
the slope of the curve at each point (x, y) be c) cut at angle π/3 d) cut at angle π/4
y/x + sec(y/x), x > 0. Then the equation of 1 41) Find the equations of the circle passing

Space for Rough Work

 14
through (–4, 3) and touching the line x + y = a) x2/4 – y2/4 = (x2 + y2)2/81
2 and x – y = 2. b) x2/9 – y2/4 = (x2 + y2)2/81
2 2 c) x2/4 – y2/4 = (x2 + y2)2/125
a) x + y + 2(10 ± 54 ) x + 55 ± 54 = 0
d) x2/4 – y2/4 = (x2 + y2)3/125
2 2   
b) x + y + 2(10 ± 44 ) x + 55 ± 54 = 0 146) Find 3-dimentional vectors v1 , v2 , v3 satisfying
2 2        
c) x + y + 2(10 ± 54 ) x + 55 ± 44 = 0 v1 ⋅ v1 = 4, v1 ⋅ v2 = −2, v1 ⋅ v3 = 6, v2 ⋅ v2
   
d) 4 x 2 + 4 y 2 + 2(10 ± 54 ) x + 44 ± 44 = 0 = 2, v2 ⋅ v3 = −5, v3 ⋅ v3 = 29

142) Two circles, each of radius 5 units, touch   
a) v1 = 2i, v2 = −i ± j , v3 = 3i ± 2j ± 4
k
each other at (1, 2). If the equation of their   
common tangent is 4x + 3y = 10, find the b) v = 2j , v = −i ± j , v = 3i ± 2j ± 4
1 2 3 k
equation of one of the circle.   
c) v1 = 2j , v2 = −i ± j , v3 = 5i ± 3j ± 4
k
a) x2 + y2 + 6x + 2y – 15 = 0
b) x2 + y2 – 10x + 10y + 10 = 0 d)
c) x2 + y2 + 5x + 7y – 15 = 0
d) x2 + y2 – 5x + 10y + 10 = 0 147) If 
u and 
v are unit vector and q is the acute
143) A straight line L with negative slope passes angle between them, then 2 u × 3 v is a unit
through the point (8, 2) and cuts the positive vector for
coordinate axes at points P and Q. Find the a) exactly two values of q
absolute minimum value of OP + OQ, as L b) more than two values of q
varies, where O is the origin. c) no value of q
a) 20 b) 18 c) 19 d) 17 d) exactly one value of q
144) The locus of the pole of normal chords of an 148) The value of a, for which the points A, B, C
ellipse is given by : with position vectors, 2i − j + 
k ,i − 3j − 5
k
a 6 b6 2 2 2
  
and ai − 3 j + k respectively are the vertices
a) 2 + 2 = (a − b )
x y of a right angled triangle with c = π/2 are
a 3
b 3 a) –2 and –1 b) –2 and 1
b) 2
+ 2
= (a 2 − b 2 )2 c) 2 and –1 d) 2 and 1
x y   
149) Let a , b and c be non-zero vectors such that
a6 b6    1   
c) 2
+ 2
= (a 2 + b 2 )2 (a × b ) × c = | b || c | a. If q is the acute
x y 3
 
a3 b3 angle between the vectors b and c , then sin
d) 2
+ 2
= (a 2 + b 2 )2 q equals
x y
145) Tangents are drawn from any point on the a) 1/3 b) 2 / 3 c) 2/3 d) 2 2 / 3
x2 y 2 150) The area of the parallelogram whose diagonals
hyperbola − = 1 to the circle x2 + y2 3 1
9 4 are i + j −  k and 2i − 6j + 8
k is equal to
= 9. Find the locus of mid-point of the chord 2 2
of contact. a) 5 3 b) 5 2 c) 25 3 d) 25 2
Space for Rough Work
 English and reasoning 15
Directions (Question 151-155) : In each of the best expresses the meaning of the idiom.
following questions, out of the given alternatives, 161) To turn the cover
choose the one which best expresses the meaning a) To take a new way of life
of the given word. b) To work hard
151) DOGMA c) To pass the crises
a) Possibility b) Feeling d) To hide the reality
c) Tenet d) Doubt 162) To hit the nail on the head
152) DILIGENT a) To hit the target
a) Industries b) Intelligent b) To catch someone napping
c) Modest d) Energetic c) To guess right
153) SYCOPHANT d) To settle the old score
a) Suppliant b) Follower 163) To run amuck
c) Flatterer d) Admirer a) To run a race
154) BESIEGED b) To run about in frenzy
a) Encircled b) Skirted c) To feel exhausted
c) Troubled d) Destroyed d) To run to somebody’s help
155) ABROGATION 164) A bull in a china shop
a) Abridgement b) Deprivation a) A person who is very ugly but loves the
c) Annulation d) Dismissal beautiful things of life
b) A person who takes a sadistic delight in
Directions (Question 156-160) : Select the word
harming innocent people
or phrase that is most nearly opposite in meaning to
c) A person who becomes too excited where
the word or phrase in capital letter given below no excitement is warranted
156) CRAVEN d) A person who is rough and clumsy where
a) Direct b) Desirous skill and care are required
c) Bold d) Controlled 165) By fair means or foul
157) ALACRITY a) Without using common sense
a) Courtesy b) Slowness b) Without difficulty
c) Plenty d) Despair c) In any way, honest or dishonest
158) BLAND d) Having been instigated
a) Caustic b) Meagre
Directions (Question 166-170) : In the following
c) Uncooked d) Helpless
items some parts of the sentence have been jumbled
159) JADED
a) Upright b) Stimulated up. You are required to rearrange these parts w hich
c) Void d) Aspiring are labelled P, Q, R and S to produce the correct
160) SPUNK sentence. Choose the proper sequence and mark in
a) Success b) Lack of intelligence your answer sheet accordingly.
c) Timidity d) Loss of prestige 166) Even
Directions (Question 161-165) : In each of the P) the underbelly of the city’s crumbling
following questions, choose the alternative which health infrastructure too

Space for Rough Work

 16
Q)attacks that also reveal 170) Since
R) as the city’s urban infrastructure crumbles P) offer them a means of satisfying their own
S) it is these increasing cases of canine personal goals
The proper sequence should be Q)people tend to follow those who in their
a) QPRS b) RSQP view
c) QSRP d) RPQS R) this understanding in carrying out their
167) Perhaps managerial actions, the more effective
P) that globalization has endorsed is that they are likely to be as leaders
identities of S) the more managers understand what
Q)the most pernicious myth motivates their subordinates, and the more
R) infinitely assimilable, flexible or fractured they reflect
S) people, societies and nations are The proper sequence should be
The proper sequence should be a) QPSR b) RSPQ
a) QPSR b) RPSQ c) QSPR d) RPSQ
c) RSPQ d) QSPR Directions (Questions 171 & 172) : There is a
168) While certain relation between two given words on one
P) in the years to come the salary will be side of : : and one word is given on another side
of: : while another word is to be found from the
adequately filled if not surpassed
given alternatives, having the same relation with
Q)tourism and hospitality sector pales
this word as the given pair has. Select the best
slightly in camparison
alternative.
R) to other service industries like the IT and
171) Tea : Cup : : Tobacco : ?
BPO sectors
a) Leaves b) Hookah
S) when it comes to pay packages, veterans
c) Toxin d) Cheroot
of the field believe that
172) Mature : Regressed : : Varied
The proper sequence should be a) Rhythmic b) Monotonous
a) QPSR b) SRQP c) Decorous d) Obsolete
c) SPQR d) QRSP 173) Sword is related to Slaughter in the same way
169) Hard as Scalpel is related to
P) where producers and consumers sell and a) Murder b) Stab
buy in whatever market takes their fancy c) Surgery d) Chopping
Q)through it is to get economists to agree on 174) Sirius is related to Star in the same way as
anything Cygnus is related to:....
R) and thus an interlocking system of world a) Constellation b) Asteroid
trade c) Galaxy d) Meteor
S) there does seem to be a consensus to Directions (Questions 175-177) : The following
accelerate globalization questions consist of two words each that have a
The proper sequence should be certain relationship to each other9 followed by
a) QPRS b) RSQP four lettered pairs of words.
c) QSRP d) RPQS Select the lettered pair that has the same relationship
Space for Rough Work
 17
as the original pair of words. 181) EGIK is related to WUSQ in the same way
175) Evaporation : Cloud as DFHJ is related to ?.
a) Mountain : Snow a) BDFH b) ECGI
b) Pressure : Atmosphere c) SQOM d) XVTR
c) Book : Pages Direction (Questions 182 & 183) : In each of the
d) Tension : Breakdown following questions, four words have been given,
176) Optimistic : Pessimistic out of which three are alike in some manner and the
a) Difficult : Impossible fourth one is different. Choose out the odd one.
b) Study : Play 182. Choose the odd one
c) Tolerating : Disgusting a) Mermaid b) Sphinx
d) Export : Import c) Unicorn d) Dinosaur
177) Protagonist : Character 183) Choose the odd one
a) Earth : Moon b) Termite : Insect a) Beaches b) Lagoons
c) Lizard : Housefly d) Whale : Fish c) Bars d) Moraines
Directions (Questions 178 & 179) : In each of Directions (Questions 184 & 185) : In each of the
the following questions, there is a certain relation following questions, a number series is given with
between two given numbers on one side of: : and one term missing. Choose the correct alternative
one number is given on another side of:: while that will continue the same pattern and fill in the
another number is to be found from the given blank spaces.
alternatives, having the same relation with this 184) 0, 2, 8, 14, ( ), 34
number as the numbers of the given pair bear. a) 24 b) 22
Choose the best alternative. c) 20 d) 18
178) Given set: (246, 257, 358) 185) 19, 2, 38, 3, 114, 4, ( )
a) (145, 235, 325) b) (143, 253, 246) a) 228 b) 256
c) (273, 365, 367) d) (233, 343, 345) c) 352 d) 456
179) Given set: (63, 49, 35) 186) “saraswati samman” is an award given for
a) (72, 40, 24) b) (72, 48, 24) excellence in the field of
c) (64, 40, 28) d) (81, 63, 45) a) sports b) social service
Directions (Questions 180 & 181) : In each of c) literature d) nuclear power
the following questions, there is some relationship 187) ‘Heavy water’ is used in which of the
between the two terms to the left of:: and the same following fields?
relationship holds between the two terms to its a) Thermal power b) cement
right. Also, in each question, one term either to the c) iron & steel d) nuclear power
right of :: or to the left of it is missing. This term is 188) The world ‘No Tobacco Day’ is observed on
given as one of the alternatives given below each which of the following days?
question. Find out this term. a) 13th may b) 31st may
180) ACFJ is related to ZXUQ in the same way as c) 18th June d) 30th June
EGJN is related to ?. 189) What is cross border exchange?
a) DBYU b) VTQM a) trading of foreign currency in India
c) VTRP d) VUSQ
Space for Rough Work
 18
b) trading of Indian rupee in exchange of a) ionosphere b) mesosphere
other currencies/goods c) stratosphere d) troposphere
c) Hawala transactions in Indian rupee 196) The foreign traveller who visited india during
d) Unauthorized remittance of Indian rupee vijaynagar period was
190) Which of the following is billionth of a a) Megasthenes b) Yuan Chawng
second? c) Fa-hien d) Nicolo Conti
a) Gigabyte b) terabyte 197) Who among the following was the political
c) nanosecond d) microsecond guru of ‘Mahatma Gandhi’?
191) The strait which connect the Arabian sea and a) Bal Gangadhar Tilak
bay of Bengal is known as b) Gopal Krishna Gokhale
a) Bering b) hormuz c) Dadabhai Naoroji
c) palk d) Malacca d) Surendra nath Banerjee
192) The place where the blue nile and white nile 198) which one of the following rulars built the
effect a confluence is ‘Bibi ka Makbara’?
a) Port said b) cairo a) Akbar b) Jahangir
c) Khartoum d) Alexandria c) Shahjahan d) Aurangzeb
193) Which of the following countries was 199) The word “satyameva jayete” in the state
admitted the 189th member of the united emblem adopted by the government of india
nation in September 2000? have been taken from which Upanishad?
a) Nauru b) palau a) Aitareya Upanishad
c) tonga d) Tuvalu b) Mundaka Upanishad
194) which of the following are the form of c) Adhyatma Upanishad
precipitation? d) Prasna Upanishad
1. dew 2. Fog 200) In, India the judges of the high court of a
3. Hail 4. Snow state are appointed by
Select the correct answer using the code a) The President
given below : b) The vice-president
a) 1 and 2 b) 3 and 4 c) The chief justice of India
c) 1 and 3 d) 2 and 4 d) The governor
195) Most of the ozone in the atmosphere is found in

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