Preparation For Loading LNG Cargo
Preparation For Loading LNG Cargo
Preparation For Loading LNG Cargo
These very flexible tankers are able to carry many cargoes in a fully
refrigerated condition at atmospheric pressure or at temperatures
corresponding to carriage pressure of between five and nine bar.
The movement of liquefied gases by waterways is now a mature
industry, served by a fleet of many tankers, a network of export and
import terminals and a wealth of knowledge and experience on the
part of various people involved.
Gas carriers have certain features common with other tankers used
for the carriage of bulk liquids such as oil and chemical tankers.
A feature almost unique to the gas carrier is that the cargo is kept
under positive pressure to prevent air entering the cargo system.
This means that only cargo liquid and cargo vapour are present in
the cargo tank and flammable atmospheres cannot develop.
All gas cargoes are transported in liquid form (ie they are not
carried as a gas in its vapour form) and, because of their physical
and chemical properties, they are carried either at:
i) Fully Pressurised
LNG is mainly methane and ethane. LNG ships carry their cargo at
-161°C, at a relative density of approximately 0.600 with a volume
contraction ratio of 1 in 600. LNG cargo is carried at ambient
pressure.
LPG is mainly propane and butane. LPG ships carry their cargo at
-42°C, at a relative density of approximately 0.500 with a volume
contraction ratio of 1 in 300. LPG cargo may be carried under
pressure.
The cargo tank construction of LNG and LPG ships can be of (a)
prismatic design (b) membrane design or (c) spherical design.
Materials used for these cargo tanks can be aluminium, balsa wood,
plywood, invar or nickel steel, stainless steel, with pearlite and
polyurethane foam.
Gas carriers must comply with the standards set by the Gas Codes
or national rules, and with all safety and pollution requirements
common to other tankers.
The safety features inherent in the tanker design requirements have
helped considerably in the safety of these tankers. Equipment
requirements for gas carriers include temperature and pressure
monitoring, gas detection and cargo tank liquid level indicators, all
of which are provided with alarms and ancillary instrumentation.
The variation of equipment as fitted can make the gas carrier one of
the most sophisticated tankers afloat today.
LNG carriers in service are fitted with independent cargo tanks and
with membrane tanks. LNG carriers are generally specialised ships
transporting LNG at its atmospheric pressure boiling point of
approximately -162 degree C, depending on the cargo grade. These
ships are usually dedicated vessels, but some smaller examples
may also carry basic LPG cargoes. If an LNG ship is capable of
carrying basic LPG cargoes, a reliquefaction plant is installed to
handle the boil-off LPG cargo vapours.
Construction
The basic cargo tank types utilized on board gas carriers are in
accordance with the list below:-
Membrane: Integral
Independent Tanks
The material used for Type ‘A’ tanks is not crack propagation
resistant. Therefore, in order to ensure safety, in the unlikely event
of cargo tank leakage, a secondary containment system is required.
This secondary containment system is known as a secondary barrier
and is a feature of all ships with Type ‘A’ tanks capable of carrying
cargoes below -10 degree C.
For a fully refrigerated LPG carrier (which will not carry cargoes
below –55 degree C) the secondary barrier must be a complete
barrier capable of containing the whole tank volume at a defined
angle of heel and may form part of the ship’s full, as shown in the
figure.
In general, it is this design approach which is adopted. By this
means appropriate parts of the ship’s hull are constructed of special
steel capable of withstanding low temperatures. The alternative is to
build a separate secondary barrier around each cargo tank.
There are Type ‘B’ tanks of prismatic shape in LNG service. The
prismatic Type ‘B’ tank has the benefit of maximizing ship-deck.
Where the prismatic shape is used, the maximum design vapour
space pressure is, as for Type ‘A’ tanks, limited to 0.7 barg.
Fig:LNG carrier moss tanks
Integral Tanks
Integral tanks form a structural part of the ship’s hull and are
influenced by the same loads which stress the hull structure.
Integral tanks are not normally allowed for the carriage of liquefied
gas if the cargo temperature is below -10 degree C. Certain tanks
on a limited number of Japanese-built LPG carriers are of the
integral type for the dedicated carriage of full refrigerated butane.
There are two basic types of cargo containment systems which are
generally referred to as incorporating either membrane or Moss
Rosenberg technology. In both cases, the containment system is
designed to serve two purposes:
The materials used for the hull structure are designed to withstand
varying degrees of temperature. At temperatures below their
specified limits, these steels will crystallise and become brittle. The
materials used for the containment system are required to reduce
the heat transfer from the hull structure to minimise boil-off gas
from the cargo, as well as to protect the hull structure from the
effects of cryogenic temperatures.
Membrane cargo containment
The cargo tanks are separated from other compartments, and from
each other, by transverse cofferdams which are dry compartments.
1. The heat flow into the tank is limited to such an extent that
the evaporation, or boil-off rate, is about 0.15% per day based
on sea surface temperature of 32 degrees and air temperature
45 degrees Celsius.
2. The inner hull steel does not attain a temperature below its
minimum design value, even in the case of failure of the
primary barrier.
2. Condition of anodes.
3. Condition of paintwork - a reference sheet is provided for this.
Moss Tanks
Hull.
Fig:LNG carrier moss tanks cross section
The tanks are encased within void spaces and situated in-line from
forward to aft within the hull. The spaces between the inner hull and
outer hull are used for ballast and also provide protection to the
cargo tanks in the event of an emergency situation, such as a
collision or grounding.
Fig:Moss Rosenberg LNG technology
The tanks are each supported by a metal skirt from the equatorial
ring, which transmits the weight of the tank and the cargo to the
lower hull. The skirt is stiffened in the upper part by horizontal rings
and the lower part by vertical corrugated stiffeners.
Leak detection
The basis of the design philosophy is the ‘leak before failure’
concept. This presumes that the primary barrier will fail
progressively, not suddenly and catastrophically.
Any leakage of LNG liquid will drain by gravity from between the
tank plating and the insulation to the southern hemisphere and will
collect in the drain tube at the bursting disc, then to the drip pan.
The drain tube at the bottom of the insulation space is sealed in
normal service by a bursting disc which is designed to fail at
cryogenic temperatures.
During dry dock all the compartments of an LNG carrier are kept
gas free. After leaving the dry dock the vessel has to be prepared to
load cargo, for that the following points to be considered with
priority.
i) Before delivering dry air into a hold space, completely dry up the
bottom section of the hold space, particularly the bilge well.
ii) When drying a hold space after completing the inerting operation
of a cargo tank, purge relevant equipments and inerting/aerating
lines with dry air to prevent the ingress of inert gas into the hold
space. This is because the hold space holding dry air sent into it is
kept almost sealed till the next dry docking and, in addition, about
15% CO2 gas is present in the inert gas, which may corrode
aluminum cargo tanks and destroy insulation materials.
iii) During drying operation, measure the atmosphere at different
levels at regular intervals. When the dew point of the hold space
drops below than the planned temperature, finish the drying
operation.
Before introducing the cargo into the tanks, the moisture content
and oxygen content in the tanks shall be reduced simultaneously.
Cargo tanks filled with air shall be dried and inerted with inert gas
supplied from the inert gas generator on board. Inert gas shall be
led into the bottom of the cargo tank through the liquid filling line
and displaced air shall be vented to the atmosphere through the
vapour line and the vent mast. Drying and inerting shall be finished
when the dew point and also the oxygen content in the cargo tank
are less than the planned level.
Gassing-up
After lay-up or dry dock, the cargo tanks are filled with inert gas or
nitrogen. If the purging has been done with inert gas, the cargo
tanks have to be gassed up and cooled down when the vessel
arrives at the loading terminal. This is because, inert gas contains
about 14% carbon-dioxide, which will freeze at around -60ºC and
produces a white powder which can block valves, filters and nozzles.
During gassing up, the inert gas in the cargo tanks is replaced with
warm LNG vapor. This is done to remove carbon dioxide and to
complete drying of the tanks.
LNG liquid is supplied from the terminal to the liquid manifold where
it passes to the stripping/spray header via the appropriate ESDS
liquid valve. It is then fed to the main vaporizer and the LNG vapour
produced is passed at a temperature warmer than the dew point
temperature existing within the cargo tanks through the vapor
header and into each tank via the vapor suction fitted in the upper
part of the tank. This method of gassing up is called “Piston Flow
Method”. In this the lighter specific gravity LNG vapor is injected
from top and the heavier IG is displaced from bottom.
At the start of the operation, the piping system and main vaporizer
contain inert gas. Consequently to avoid the formation of water
condensate or solid CO2, the supply line to the vaporizer from the
manifold has to be first purged with Nitrogen either by using the
ships or shore supplying.
After lay-up or dry dock, the cargo tanks are filled with inert gas or
nitrogen. If the purging has been done with inert gas, the cargo
tanks have to be gassed up and cooled down when the vessel
arrives at the loading terminal. This is because, inert gas contains
about 14% carbon-dioxide, which will freeze at around -60ºC and
produces a white powder which can block valves, filters and nozzles.
During gassing up, the inert gas in the cargo tanks is replaced with
warm LNG vapor. This is done to remove carbon dioxide and to
complete drying of the tanks. The LNG vapour is lighter than the
inert gas, which allows the inert gases in the cargo tank to be
exhausted up the tank filling line to the liquid header. The inert gas
then vents to the atmosphere via the vent mast.
LNG liquid is supplied from the terminal to the liquid manifold where
it passes to the stripping/spray header via the appropriate ESDS
liquid valve. It is then fed to the main vaporizer and the LNG vapour
produced is passed at a temperature warmer than the dew point
temperature existing within the cargo tanks through the vapor
header and into each tank via the vapor suction fitted in the upper
part of the tank. This method of gassing up is called “Piston Flow
Method”. In this the lighter specific gravity LNG vapor is injected
from top and the heavier IG is displaced from bottom.
Fig:Gassing up with venting from vent mast
At the start of the operation, the piping system and main vaporizer
contain inert gas. Consequently to avoid the formation of water
condensate or solid CO2, the supply line to the vaporizer from the
manifold has to be first purged with Nitrogen either by using the
ships or shore supplying.
Completion criteria
Vapor generation
If LNG is introduced directly into warm tanks, the LNG will almost
immediately turn into vapour. LNG has a liquid to gas expansion
ratio 1: 600. Therefore, to enable the liquid to be loaded into the
tank at a reasonable loading rate, necessity of large compressors
would be required to remove the vapour generated in the process.
Vapor generation
If LNG is introduced directly into warm tanks, the LNG will almost
immediately turn into vapour. LNG has a liquid to gas expansion
ratio 1: 600. Therefore, to enable the liquid to be loaded into the
tank at a reasonable loading rate, necessity of large compressors
would be required to remove the vapour generated in the process.
After the cargo system has been gassed up the headers and tanks
must be cooled down before loading can commence. The cool down
operation follows immediately after the completion of gassing up
using the LNG supplied from the terminal.
The rate of cool down is limited for the following reasons, note that
although many of the reasons remain similar between Membrane
and Moss vessels the Moss vessels have additional requirements
that must be complied with.
LNG is supplied from the terminal to the manifold cool down line
and from there directly to the spray header. The various spray
valves are operated in order to produce a temperature profile in line
with, but not exceeding, the manufacturers’ instructions. Some
tanks may require a minimum equatorial temperature before bulk
loading may commence; this temperature is to be strictly adhered
to.
During the cool down Nitrogen flow to the primary and secondary
barriers (particularly on Membrane vessels) will significantly
increase. It is essential that the rate of cool down is controlled in
order to maintain the pressure in the primary and secondary
barriers at the pressure determined by the manufacturer.
LNG is liquefied natural gas, which is the very cold liquid form of
natural gas.LNG carriers are generally specialised ships transporting
LNG at its atmospheric pressure boiling point of approximately -162
degree C, depending on the cargo grade.LNG carriers were typically
in the range 80-135,000 m3 up until 2006.
Note !
In order to avoid the possibility of pipe sections hogging,
(contracting at the bottom more than at the top and thus causing
flanges and long pipe sections to be stressed) the liquid header and
crossovers must be cooled down and filled as quickly as possible.
iii) To avoid the formation of vapor locks in the pipelines when cargo
is introduced. If LNG is introduced into a warm pipeline the initial
cargo will vaporize, create a large pressure that can ‘block’ the
loading of the liquid. It is then possible that this vapour will then
condense very rapidly as the temperature reduces below the
condensation point, allowing the liquid to surge along the pipeline
possibly resulting in damage to the pipelines, valves or connections.
After the connection of loading arms, air should be purged from the
loading arms and the tips of manifold pipes. N2 gas is lead into the
loading arms from injection lines connected to the arms, and then
pressurize up to about 4 to 6 kg/cm2G.
After pressurization, the ship’s liquid manifold vent valve and vapor
manifold vent/drain valve are opened to release air and N2 gas into
the atmosphere. While this operation is repeated two or three
times, a leak test (with soap solution) is conducted at the same
time. Air purge comes to an end when the oxygen content of the
purged gas has dropped below 2%.
The cool down of the loading arms is performed from shore side by
use of a small capacity pump. At a discharge port, the arms are
cooled down by sending in LNG by ship’s spray pump.
Loading Operation
LNG is loaded via the loading manifolds to the liquid header and
then to each tank filling line. The boil-off and displaced vapour leave
each tank via the vapour suction to the vapour header. The vapour
is initially free-flowed to shore via vapour crossover manifold and,
as tank pressure rises, one compressor is brought into operation to
increase the gas flow to shore and limit the vapour main and cargo
tank pressure.
Bulk loading
When all lines and valves are fully cooled the vessel can commence
ramping up the loading rate in the sequence agreed with the
terminal. Deballasting should be commenced in accordance with the
cargo plan. The cargo should be evenly distributed during the
loading.
Topping off
Deballasting
The ballast should be adjusted to keep a small stern trim to aid with
the stripping of the ballast tanks. The flow rate of the ballast should
be adjusted to keep the ship within 1 meter of the arrival draft or as
specified by the terminal. Deballasting should normally be
completed before the start of the topping off of the cargo tanks.
When loaded in the cargo tanks, the pressure of the vapour phase is
maintained substantially constant, slightly above atmospheric
pressure.
The properties of the LNG, i.e. the boiling point, density and heating
value, have a tendency to increase during the voyage.
Pressure Surge
Pressurized Systems
Reciprocating Compressors
Sloshing
Within a range of tank filling levels, the pitching and rolling of the
ship and the liquid free surface can create high impact pressure on
the tank surface. This effect is called “sloshing” and can cause
structural damage. Filling levels within this range must therefore be
avoided.
How to maintain tank pressure for a gas carrier carrying liquefied gases
A liquefied gas is the liquid form of a substance which, at ambient temperature and at atmospheric
pressure, would be a gas.
Most liquefied gases are hydrocarbons and the key property that makes hydrocarbons the world’s
primary energy source – combustibility – also makes them inherently hazardous. Because these gases
are handled in large quantities, it is imperative that all practical steps are taken to minimize leakage and
to limit all sources of ignition.
Whilst the hydrocarbon gases methane, ethane, propane and butane may be regarded principally as
fuels, the LPGs are also important as feedstock in the production of the chemical gases.
(3) Intermediate temperatures and pressures (semi-pressurized ship, often referred to as semi-
refrigerated).
Particularly hazardous cargoes such as ethylene oxide and propylene oxide may be carried below their
boiling points to reduce boil-off and increase safety. In such cases the tank pressure is maintained above
atmospheric with nitrogen padding.
Any heat input to the cargo will vaporize some of the liquid and gradually increase the tank pressure.
Pressure vessels are designed to accommodate this increase, but on fully or semi-refrigerated ships the
boil-off is condensed by the reliquefaction system and returned to the cargo tanks as a boiling liquid. On
LNG vessels cargo tank pressure is almost always controlled by burning the boil-off in the main
propulsion system or in rare cases (e.g. emergency) by venting it to atmosphere. If the pressure above a
boiling liquid is increased, vaporization from the surface is reduced, and vice versa.
Pressures above or below the design range can damage a system, and operating personnel should be
fully aware of any pressure limitation for each part of the cargo system; pressures should always be kept
between the specified maximum and minimum.
Pressure Surge
High surge pressures (shock pressures or “liquid hammers”) can be created if valves are opened or shut
too quickly, and the pressure may be sufficient to cause hose or pipeline failure.
Pressurized Systems
In pressurized systems, with the cargo at ambient temperature, there is normally no external frosting to
indicate the presence of liquid or vapour anywhere in the system. Checks should be made for the
presence of high pressure vapour of liquid by gauges and test cocks before opening valves etc.
Reciprocating Compressors
If vapour trapped in a reciprocating compressor condenses, it can dilute the lubricating oil in the
crankcase which could cause bearing failure, overheating or possibly an explosion. The crankcase
heating equipment, if fitted, should be used to reduce the possibility of cargo condensing and should be
operated before the compressor is started. Liquid condensed in the compressor may also cause
mechanical damage.
Cargo operations such as cooldown, warm-up, loading and discharge may affect pressures in hood or
inter-barrier spaces. Pressures can also be affected by climatic changes and the variation in temperature
between day and night.
Pressure in cargo tanks and hold or inter-barrier spaces should be closely monitored, especially during
cargo operations, and the equipment provided should be used to make the necessary adjustments.
Particular care is necessary with membrane or semi-membrane systems which are vulnerable to damage
from vacuum or incorrect differential pressures because of the thin barrier material.
Pressures in cargo tanks may be maintained above atmospheric by: (1) Equalizing pressures between
tanks which contain the same cargo, or (2) Circulating cargo liquid or vapour, or both, between tanks
containing the same cargo, or (3) Circulating cargo within a tank by use of the cargo pumps, or (4)
Allowing the cargo to warm up.
Liquid gas samples should not be placed in containers which cannot withstand the pressure created by
the sample at the highest ambient temperature expected. Sufficient ullage should be left in the
container to ensure that it does not become liquid full at the highest temperature anticipated. Liquid gas
samples should be stored within the cargo area.
Sloshing
Within a range of tank filling levels, the pitching and rolling of the ship and the liquid free surface can
create high impact pressure on the tank surface. This effect is called “sloshing” and can cause structural
damage. Filling levels within this range must therefore be avoided.
However, some cargoes may be carried safely within the range specified for a particular system if the
sloshing forces are permissible; guidance should be sought from the Ship-owner, the designer and
Classification Society.
Pressure relief valves depend on accurate setting of opening and closing pressures for effective
operation.
Cargo Heat Exchangers
Heat exchangers should be pressure tested prior to use. This is especially important after a long period
of idleness and before a ship is delivered on time charter. In addition to testing the tubes for tightness,
the seawater low temperature cut-out must be tested to ensure that the cargo inlet valve to the heater
closes, thereby avoiding damage to the tubes from freezing should the outlet temperature of the
seawater fall below 5 degree C
Prior to cargo pump start, confirm that all liquid branch valves are
closed and all filling valves are opened. Also notify the engine room
to verify that sufficient generator capacity is available. Start the
cargo pumps as per established guidelines. It is important that the
shore is made aware of when pumps will be coming on line and the
consequent changes in their tank pressures then can expect.
Request the receiving terminal to stop the return gas blower to keep
adequate tank pressure. After discharging, at least one filling valve
is kept open to avoid pressurization of the liquid line. Liquid draining
and vapour purging of the arms is performed after completion of
cargo discharging. After completing of draining and purging, the
following operations are carried out.
Cargo heel
(Note: When the liquid level reaches 1 metre or less, avoid stopping
the pump if at all possible until the cargo has been fully discharged.
If the shore facility is unable to accept the liquid for intermittent
periods it is better to keep the pump going and recirculate back into
the tanks until discharge can be resumed and completed.)
All LNG remaining in the downward leg of the loading arms and
manifold connection is to be drained to the tanks through the liquid
line assisted by nitrogen pressure from ashore. The LNG and vapour
manifolds are then purged with nitrogen until an acceptable
hydrocarbon content is reached.
Draining / purging
On completion the manifold ESD valves are closed and the spray
line is lined up from the manifold to all tanks via the spray return
valves. The cool down valve on each manifold is kept closed. Then
the terminal raises the pressure within the arms to a certain level
(normally around 4 kgs/cm2). Then the spray cool down valve are
opened up and LNG liquid and vapour in the liquid arm is fed to the
cargo tanks through the spray line by Nitrogen (N2) pressure.
Vapour in the vapour arm is fed to the cargo tanks through the
vapour header by N2 gas supplied from the terminal. Draining is
normally carried out by pressuring the arms one by one.
(2) Cargo tank pressures are kept within design limits; and
If the system is used only to keep cargo tank pressure just below
the relief valve set point, the cargo will warm up to a new
temperature and it may be too hot for discharge at the terminal. If
it is necessary to cool down the liquid on passage, the loading
temperature and system capacity should be assessed to ensure that
the necessary operations can be completed during the voyage.
(6) The lubricants used for all machines should be compatible with
the cargo and suitable for the temperatures and pressures
experienced both in operation and when stopped. Oil levels should
be checked and crankcase heaters started if necessary before the
plant is activated.
Boil-off from LNG cargo may be burnt as fuel in the main propulsion
system. Two factors influence the sanctioning of this practice:
LNG boil-off may be either vented or burnt (or both) to keep tank
pressures at the required level. The decision whether to vent or
burn the boil-off depends on many factors, some economic, some
the result of regulations. Regulations may, for instance, either
prohibit venting or the use of cargo as fuel in certain places. Such
regulations should always be observed.
On the high sea, cargo vapour may provide the main fuel, though
oil pilot burners are also required. In the case of steam plants,
cargo vapour may also be burnt when propulsion machinery is not
in operation provided that means for steam-dumping are installed.
(2) Ventilation fans for the machinery space and the fuel supply line
trunking should be operated before and during gas burning
operations. Attention should be paid to the ventilation of any areas
near untrunked gas piping.
(4) Supply lines should be purged with inert gas immediately before
and after burning operations.
(6) If the gas flame goes out, the reason should be established
before it is relit. If both oil and gas flames are lost all combustion
spaces should be ventilated of flammable vapour before the flame is
relit, otherwise an explosion could occur. Attention should be paid to
flame failure sensors; low sensitivity will result in failure to shut
down and high sensitivity will cause unnecessary shutdowns.
(9) The gas supply lines should be checked regularly for leaks. If a
leak does occur, the fuel supply should be isolated immediately and
not reconnected until the leak has been repaired.
(11) All joints in the supply line should be pressure tested after
maintenance before the system is re-commissioned.
(12) Water should be drained from carbon steel fuel lines to prevent
corrosion.
(13) Flame screens may be fitted in the supply line or within each
burner: they have very small holes which are easily blocked, and
should be cleaned regularly.
The BVG management system is a total gas flow control from cargo
tanks to main boilers. The total gas flow consists of the following
two kind of gas.
The natural BOG is sent to the main boilers by low duty compressor
(L/D compressor) through the low duty heater and the flow rate is
controlled by L/D compressor speed & inlet guide vane (IGV). If
natural BOG does not meet boiler demand, the forcing vaporizer will
generate forcing BOG and add it to natural BOG for full speed range
of ship.
Absolute Vapour Density – The mass of a unit volume of gas under stated conditions of temperature
and pressure.
Administration – The government of the country in which the ship is registered (Flag Administration).
Approved Equipment – Equipment of a design that has been tested and approved by an appropriate
authority such as an Administration or Classification Society.
BOG – Boil off gas, vapour produced above a cargo liquid surface due to evaporation caused by heat
ingress.
Asphyxia – When a person is deprived of an adequate supply of oxygen a loss of consciousness will
follow.
Asphyxiant – A gas or vapour which has no toxic properties but when present in sufficient concentration
excludes oxygen and will cause asphyxia.
Auto-ignition Temperature – The lowest temperature to which a solid liquid or gas requires to be raised
to cause self-sustained combustion without initiation by spark or flame. Bar Gauge – Pressure in bar.
Boil Off – Vapour produced above a cargo liquid surface due to evaporation caused by heat ingress.
Boiling Point – The temperature at which the vapour pressure of a liquid equals that of the atmosphere
above its surface. This temperature varies with pressure.
Bonding (Electrical) – The connecting together of electrically conducting metal parts to ensure electrical
continuity.
Brittle Fracture – Fracture of a material caused by a lack of ductility in the crystal structure resulting
from low temperature.
Cargo Area – That part of the ship, which contains the cargo containment system, cargo pumps and
compressor rooms.
Cargo Containment System Independent Tanks – Independent tanks are self-supporting. They do not
form part of the ship’s hull and are not essential to the hull’s strength.
Type A – Are tanks, which are designed primarily using “Recognized Standards” of classical ship
structural analysis procedures.
Type B – Are tanks which are designed using model tests, refined analytical tools and analysis methods
to determine stress levels, fatigue life and crack propagation characteristics.
Type C – Referred to as pressure vessels are tanks meeting pressure vessel criteria.
Cargo Operations – Any operation on board a gas carrier involving the handling of cargo liquid or vapour
including cargo transfer, reliquefaction, venting etc.
Certified Gas Free – Means that a tank, compartment or container has been tested using an approved
instrument and proved to be sufficiently free at the time of the test of toxic or explosive or inert gas for
a specified purpose, such as hotwork by an authorized person. E.g. shore chemist and that a certificate
to this effect has been issued.
Chemical Absorption Detector – (e.g. Draeger Tubes) – Used for the detection and determining the
concentration of gases or vapours based on the principle of a reaction between the gas and a chemical
agent, the gas discolours the agent.
Closed Gauging System – A system whereby the contents of a tank can be measured by means of a
device which penetrates the tank but is part of a closed system e.g. float system, electronic probe,
magnetic probe.
Critical Temperature – The temperature above which a gas cannot be liquefied by pressure alone.
Explosion Proof Enclosure – One, which will withstand, without injury, any explosion of the prescribed
flammable gas that may occur within it under practical conditions of operation within the rating of the
apparatus and will prevent the transmission of flame such as will ignite the prescribed flammable gas,
which may be present in the surrounding atmosphere.
Filling Limit (or Ratio) – The volume of a tank expressed as a percentage of the total volume, which can
be safely filled, having due regard to the possible expansion (and change in density) of the liquid.
Flame Arrestor – A device used in gas vent lines to arrest the passage of flame into enclosed spaces.
Flammable – Capable of being ignited and burning in air. The term “flammable gas” is used to mean a
vapour air mixture within the flammable range.
Flammable Range – The flammable (explosive) range, lies between the minimum and maximum
concentrations of vapour in air, which form flammable (explosive) mixtures. This is usually abbreviated
to LFL (Lower Flammable Limit) and UFL (Upper Flammable Limit). These are synonymous with “Lower
Explosive Limit” (LEL) and Upper Explosive Limit” (UEL).
Flash Point – The lowest temperature at which a liquid gives off sufficient vapour to form a flammable
mixture with air near the surface of the liquid or within the apparatus used. This is determined by
laboratory testing in a prescribed apparatus.
Gas-Dangerous Space or Zone – A space or zone within the cargo area which is designated as likely to
contain flammable vapours and which is not equipped with approved arrangements to ensure that its
atmosphere is maintained in a safe condition at all times.
Gas Free – Gas free means that a tank, compartment or container has been tested using appropriate gas
detection equipment and found to be sufficiently free, at the time of the test, of toxic or explosive or
inert gases for a specific purpose.
Gas-Freeing – The introduction of fresh air into a tank, compartment or container to remove toxic,
flammable or inert gas to such a level as is required for a specified purpose (e.g. tank entry, hot work).
Gas-Safe Space or Zone – A space or zone not designated as a gas-dangerous space or zone.
Gauze Screen (sometimes called Flame Screen) – A portable or fixed device incorporating one or more
corrosion resistant wire meshes used for preventing sparks from entering an open deck hole, or for a
SHORT PERIOD OF TIME preventing the passage of flame, yet permitting the passage of gas.
Hot Space – The space enclosed by the ship’s structure in which a cargo containment system is situated
(see Cargo Containment System).
Hot Work – Hot work is any work involving welding or burning, and other work including drilling,
grinding, electrical work and the use of non-intrinsically safe electrical equipment, which might produce
an incendiary spark.
Hot Work Permit – A document issued by an authorized person permitting specific work for specified
time to be done in a defined area employing tools and equipment which could cause ignition of
flammable gases.
Hydrates – The compounds formed at certain pressures and temperatures by the interaction between
water and hydrocarbons.
IMO – International Maritime Organization: this is the United Nations specialized agency dealing with
maritime affairs.
IMO Codes – The IMO Codes for the Design, Construction and Equipment of Ships carrying Liquefied
Gases in Bulk.
IGC Code – The International Code for the Construction and Equipment of Ships carrying Liquefied Gases
in Bulk.
Inert Gas – A gas or vapour, which will not support combustion and will not react with the cargo.
Inerting – This is the introduction of inert gas into a space to reduce and maintain the oxygen content to
a level at which combustion cannot be supported.
Insulating Flange – An insulating device placed between metallic flanges, bolts and washers, to prevent
electrical continuity between pipelines, sections of pipelines, hose strings and loading arms or
equipment/apparatus.
Intrinsically Safe – Intrinsically safe equipment, instruments, or wiring are such equipment, instruments
or wiring that are capable of releasing sufficient electrical or thermal energy under normal or abnormal
conditions to cause ignition of a specific hazardous atmosphere mixture in its most easily ignited
concentration.
Liquefied Gas – A liquid, which has an absolute vapour pressure exceeding 2.8kp/cm2 at 37.8° C, and
certain other substances specified in the IMO Codes.
LPG – Liquefied Petroleum Gases – these are mainly propane and butane, shipped either separately or in
mixtures. They may be refinery by product gases or may be produced in conjunction with crude oil or
natural gas.
Peroxide – A compound, formed by the chemical combination of cargo liquid or vapour with
atmospheric oxygen, or oxygen from another source. These compounds may, in some cases, be highly
reactive or unstable and constitute a potential hazard.
Polymerization – The phenomenon whereby the molecules or a particular compound can be made to
link together into a larger unit containing anything from two to thousands of molecules, the new unit
being called a polymer. A compound may thereby change from a free flowing liquid to a viscous one or
even a solid. A great deal of heat may be evolved when this occurs. Polymerization may occur
spontaneously with no outside influence, or it may occur if the compound is heated, or if a catalyst or
impurity is added. Polymerization may, under some circumstances be dangerous.
Relative Liquid Density – The mass of a liquid at a given temperature compared with the mass of an
equal volume of fresh water at the same temperature or at a different given temperature. Term Specific
Gravity being discontinued in general.
Relative Vapour Density – The weight of the vapour compared with the weight of an equal volume of
air, both at standard conditions of temperature and pressure. Thus vapour density of 2.9 means that the
vapour is 2.9 times heavier then an equal volume of air under the same physical conditions.
Responsible Officer – The Master or any officer to whom the Master may relegate responsibility for any
operation or duty.
Responsible Terminal Representative – The shore supervisor in change of all operators and operations
at the terminal associated with the handling of products, or his responsible delegate.
Restricted Gauging System – A system employing a device, which penetrates the tank and which, when
in use, permits a small quantity of cargo vapour or liquid to be exposed to the atmosphere. When not in
use the device is completely closed.
RPT – Rapid Phase Transition - When LNG contacts water under specific conditions, it transforms
explosively from the liquid to vapour state.
Secondary Barrier – The liquid resisting outer element of a cargo containment system designed to afford
temporary containment of any envisaged leakage of liquid cargo through the primary barrier and to
prevent the lowering of the temperature of the ship’s structure to an unsafe level.
Self-Reaction – The tendency of a chemical to react with itself, usually resulting in polymerization or
decomposition.
Sloshing – Wave formations which may arise at the liquid surface in a cargo tank from the effects of ship
motions.
Span Gas – A vapour sample of known composition and concentration and concentration used to
calibrate (or “span”) a ship’s gas detection equipment.
Static Electricity – The electrification of dissimilar materials through physical contact and separation.
Threshold Limit Value (TLV) – The TLVs refer to the maximum concentration of gases, vapours, mists or
sprays to which it is believed that nearly all persons on board may be repeatedly exposed, day after day,
without adverse effect assuming an 8 hours per day, 40 hours per week exposure. Because of the wide
variation in individual susceptibility, exposure of an occasional individual at, or even below, the TLV may
not prevent discomfort or aggravation of a pre-existing condition.
Vapour Pressures – The pressure exerted by the vapour above the liquid at a given temperature.
Venting – The release of cargo vapour or inert gas from cargo tanks and associated systems.
Void Space – The enclosed space in the cargo area external to a cargo containment system, not being a
hold space, ballast space, fuel oil tank, cargo pump or compressor room, or any space in normal use by
personnel.
CTS – Custody Transfer System, this is the cargo measurement and level gauging instrumentation