UNIT - III - MAGNETIC PROPERTIES OF MATERIALS

 Types of magnetic materials

 Domain theory of ferro magnetism
 Hysteresis
 Soft and Hard magnetic materials
 Ferrimagnetism or Ferrites
 Magnetic Hard Disc
 Magnetic Hard Disk Drive (HDD) with GMR sensor

S
1.Types of Magnetic materials

'
S.No Dia-magnetic material Para-magnetic material Ferro magnetic material

H
1 There are equal numbers of There are unequal number of There will be large number of
electron spins which are electron spins and hence there unequal electron spins and

P
randomly oriented and hence exists a permanent magnetic hence there exists enormous

E
the net magnetic moment is moment. amount of permanent magnetic
zero. moment

S
2

. J O
2.33
2 S t
When the external magnetic
field is applied , the electrons
When the external magnetic
field is applied , the electrons
When the external magnetic
field is applied, the electrons
will align perpendicular to the will align parallel to the field which are already aligned
field direction direction parallel will reorient itself
along the field direction
3.4 When the material is placed in When the material is placed in When the material is placed in
the magnetic field, the the magnetic field, the the magnetic field, the
magnetic flux lines are magnetic flux lines passes magnetic flux lines are highly
repelled away from the through the material. attracted towards the centre of
material. the material.
5
4.6 The susceptibility is negative. The susceptibility is positive The susceptibility is positive
(χ = -ve) and small. ( χ = + ve) and large. (χ = +ve)
5.7 The susceptibility is The susceptibility varies The susceptibility depends
independent of temperature. inversely with the absolute upon the temperature.
temperature.
6.8 Permeability is less than 1. Permeability is greater than 1. Permeability is very much
greater than 1.
79 Weak magnets Strong magnets Very strong magnets
8.10 When the temperature is less When the temperature of the When the temperature of the
than the critical temperature, material is less than the curie material is greater than the
the diamagnetism suddenly temperature, para magnetic Curie temperature, the

S
disappears and becomes a material is converted into ferromagnetic material is

'
normal material. diamagnetic material. converted into paramagnetic
material.

H
9.11 Examples: Gold, Antimony, Examples: Platinum, Examples: Iron, Nickel,

P
Bismuth, Water, Silicon, Chromium, Aluminium, Cobalt, Steel, etc.
Hydrogen, Germanium. Copper sulphate, etc.,

2. Domain Theory of Ferromagnetism

S E
According to Weiss hypothesis, a single crystal of

O
ferromagnetic material is divided into large number of well-

J
defined small regions called domains. These domains have

.
spontaneous magnetization due to the parallel alignment of spin

t
magnetic moments in each domain. But the direction of
spontaneous magnetization varies from domain to domain and

S
are oriented in such a way that the net magnetization of the
specimen is zero.
When the magnetic field is applied, the magnetization
occurs in the specimen by two ways,
1. By the movement of domain walls
2. By the rotation of domain walls
By the movement of domain walls
The movement of domain walls takes place in weak magnetic fields. Due to this weak
field applied to the specimen the magnetic moment increases and hence the boundary of
domains are displaced, so that the volume of the domain changes as shown in the figure B.

A B C
By the rotation of domain walls
The rotation of domain walls takes place in strong magnetic fields. When the external
field is high then the magnetization change by means of rotation of the direction of
magnetization towards the direction of the applied field as shown in figure C.
Types of Energy
The domain in ferromagnetic solid is understandable from the thermo dynamical
principle. (i.e.,) in equilibrium the total energy of the system is minimum. For this, first we
consider the total energy of the domain structure and then how it is minimized. The total
energy of the domain comprises the sum of following energies.
i) Exchange energy
The interaction energy which makes the adjacent dipoles to align themselves is known

S
as exchange energy or magnetic field energy. In other words, it is the energy required in

H '
E P
assembling the atomic magnets into a single domain and this work done is stored as potential

S
energy. The magnetic energy can be reduced by dividing the specimen into two domains as
shown in figure.

J O
The process of subdivision may be carried further, until the reduction of magnetic
energy is less than the increase in energy to form another domain and its boundary. This

.
boundary is called as domain wall or Bloch wall.

t
ii) Anisotropy energy

S
In ferromagnetic crystals there are two directions
of magnetization.
a) Easy direction b) Hard direction.
Weak field is applied in easy direction and
strong field along hard direction. For ex: In iron [100] is
easy direction, [110] medium direction and [111] is hard
direction.
The excess of energy required to magnetise the
specimen along hard direction over that required to
magnetise the specimen along the easy direction is
called crystalline anisotropy energy.
iii) Domain wall energy
Bloch wall is a transition layer which separates the
adjacent domain magnetized in different directions.
Based on the spin alignments, two types of Bloch
walls may arises namely i) Thick wall, ii) Thin wall.
When the spins at the boundary are misaligned and
the spin changes gradually, then it leads to thick wall
(misalignment associated with exchange energy). In thin wall, the spins at the boundary
changes abruptly, then the anisotropic energy becomes very less.
iv) Magnetostrictive energy
When a ferromagnetic material is suddenly magnetized it experiences a slight change
in its length, which is due to the rearrangement of domains inside the material. This is called
magnetostriction effect.
The magnetostrictive energy is the energy due the mechanical stresses generated by
domain rotation.

Hysteresis
When ferromagnetic materials like Fe, Co, and Ni are

S
made to undergo through a cycle of magnetization, the variation

'
of magnetic induction (B) with respect to the magnetizing field
(H) can be represented by a closed hysteresis loop or curve. i.e., it

H
refers to the lagging of magnetic induction behind the
magnetizing field.

P
If a magnetizing field H is applied to a ferromagnetic

E
material and if H is increased to Hmax the material acquires the
magnetism. So the magnetic induction also increases, represented

S
by ‘oa’ in the fig. Now if the magnetic field is decreased from
Hmax to zero, the magnetic induction will not fall rapidly to zero,

O
but falls to ‘b’ rather than zero. This shows that even when the

J
applied field is zero (or) removed, the material still acquires some

.
magnetic induction ‘ob’ which is so called residual magnetization (or) retentivity.

t
Now to remove this retentivity the magnetic field strength is reversed and increased to

S
‘-Hmax’ represented as ‘oc’ so called coercivity and hence we get the curve ‘bcd’. Then the
reverse field (-H) is reduced to zero and the curve ‘dc’ is obtained, and by further increasing
H to Hmax, the curve ‘efa’ is obtained.
Explanation of Hysteresis on the basis of domains
We know when the ferromagnetic material is
subjected to external field, there is an increase in the
value of the resultant magnetic moment due to two
process,
(i) The movement of domain walls
(ii) Rotation of domain walls
When a small external field is applied, the
domain walls are displaced slightly in the easy direction
of magnetization. This gives rise to small magnetization
corresponding to the initial portion of the hysteresis
curve OA.
Now, if the applied field is removed, then the
domains returns to its original state, and is known as reversible domains.
When the field is increased, large numbers of domains contribute to the magnetization
and thus the magnetization increase rapidly with H.
 Now, when the field is removed, because of the displacement of domain wall to a
very large distance, the domain boundaries do not come back to their original position.
This process is indicated as AB in fig. and these domains are called irreversible domains.
At point ‘B’ all the domains have got magnetized along the easy direction.
Now, when the field is further increased, the domains start rotating along the filed
direction and the anisotropic energy is stored in the hard direction, represented as BC.
Thus the specimen is said to attain the maximum magnetization. At this position, even
after the removal of external field the material possess maximum magnetization, called
residual magnetism represented by OD.
Actually after the removal of the external field, the specimen will try to attain the
original configuration by the movement of Bloch wall. But this movement is stopped due to

S
the presence of impurities, lattice imperfections etc. therefore to overcome this, a large

'
amount of reverse magnetic field is applied to the specimen. The amount of energy spend to
reduce the magnetization to zero is called as coercivity represented by OE.

3.Soft and hard magnetic materials

P H
E
S.No Soft Hard

S
1. They can be easily magnetized and They cannot be easily magnetized and
demagnetized. demagnetized.

O
2. High susceptibility & permeability. Low susceptibility & permeability.

J
3. Magnetic energy stored is not high. Magnetic energy stored is high.

.
4. Low hysteresis loss, due to small High hysteresis loss, due to large hysteresis

t
hysteresis loop. loop.

S
5. The eddy current loss is small due to its The eddy current loss is high due to its low
high resistivity. resistivity.
6. Coercivity & Retentivity are small. Coercivity & Retentivity are high.
7 They are used to produce temporary They are used to produce permanent magnets
magnets
8 Domain walls are easy to move. The movement of domain wall difficult.

9
4.Ferrimagnetism or Ferrites
Ferrimagnetic materials are also called as Ferrites. Ferrites are the modified structures
of iron with no carbon and are composed of two or more sets of different transition metals.
These materials have anti parallel magnetic moments of different magnitudes, giving rise to
large magnetic moment in the presence of external magnetic field.
The general chemical formula of a ferrite molecule is X2+Fe23+O42-, where X2+
represents a divalent metal ion such as Zn2+, Fe2+, Mg2+, Mn2+, Cd2+ etc., Ferrites crystallize
in the form of a cubic structure. Each corner of a ferrite unit cell consists of a ferrite
molecule.
Therefore, in a ferrite unit cell there are eight molecules. Therefore in a ferrite unit cell,
there are eight divalent metal ions, 16 ferric ions and 32 Oxygen ions. If only the oxygen ions

S
in ferrite crystal are considered, it is found that they constitute a close packed face centered

'
cubic structure.
In these arrangement it is found that for every four O2 ions there are 2 octahedral sites

H
(surrounded by 6 O2 ions) and one tetrahedral site (surrounded by 4 O2 ions).The metal ions

P
are distributed over these tetrahedral sites (A sites) and octahedral sites (B sites). Thus in
ferrites the number of octahedral sites is twice the number of tetrahedral sites. Normally there

E
are two types of structures in ferrites.

S
i) Regular spinel structure
In this type, each divalent metal ion

O
occupies 1 tetrahedral site and each trivalent

J
metal ion occupies 1 octahedral site. Totally
in an unit cell, there will be 8 tetrahedral

.
(8 A) sites and 16 octahedral (16B) sites.

t
Hence, the sites A and B combined to form a

S
regular spinel ferrite structures as shown in
Fig.
The schematic representation of Zinc ferrite molecule as shown in Fig.
ii) Inverse spinel structure
In this type half of the B sites (8 sites) are
occupied by divalent metal ions and the
remaining half of the B sites (8 sites) and all
the A sites are occupied by the trivalent metal
ions, as shown in Fig.
Applications
 Ferrites are used in digital computers
and data processing circuits. Ferrites
are used to produce low frequency ultrasonic waves by magnetostriction principle.
 Ferrites are widely used in non-reciprocal microwave devices. Examples for non-
reciprocal microwave devices are Gyrator, Isolator and Circulator.
 Ferrites are also used in power limiting and harmonic gyration devices.
 Ferrites can also be used in the design of ferromagnetic amplifiers of microwave
signals.
  Ferrite core can be used as a bitable element.
 The rectangular shape ferrite cores can be used as a magnetic shift register.
 Hard ferrites are used to make permanent magnets.
 The permanent magnets (hard ferrites) are used in instruments like galvanometers,
ammeter, voltmeter, flex meters, speedometers, wattmeter, compasses and recorders.
Magnetic moment of a ferrite molecule (Ferrous ferrite)
Saturation magnetization of a ferrite molecule can be calculated from the no. of
unpaired spins of Fe2+ and Fe3+.
Here we have two types of ions Fe2+ and Fe3+.
i) Fe2+ ions has six electrons in 3d shell out of 6 electrons two electrons are paired with
each other and with 4 unpaired electrons.

S
So, Fe2+ gives rise to 4 Bohr magneton

'
ii) Fe3+ has 5 electrons in 3d shell all are unpaired. We have two Fe3+ ions. Totally
trivalent Fe3+ ions gives rise to 10 Bohr magnetons.

H
therefore, the total magnetization of Fe2+ and Fe3+ = 14 Bohr magneton is 14 μB.
Theoretically we get 14 μB but experimentally the total magnetic moment got is only

P
4.08 μB. The reason for this discrepancy is ‘if all the spins are aligned parallel then we will

E
get the total magnetization as 14 μB. But in ferrites half of the magnetic spins of Fe3+ ions are
parallel to one direction and the remaining half of Fe3+ ions are parallel in opposite direction

S
and hence they cancel each other. So the net magnetic moment is only due to Fe2+ ions alone,
i.e., total magnetization as 4 μB.

. J O
Fe3+

S
Magnetic hard disk
t Fe2+

Magnetic Tape
Magnetic tape is one of the most popular storage
medium for data. The tape is a plastic ribbon with metal
oxide material coated on one side which can be
magnetized, in this the informations can be stored.
The electrical signal gives information about the stored
data i.e., logic ‘1’ or logic ‘0’ states on the tape. In this
way, the digital information stored is read out.
Advantages
 Magnetic tape is easy to handle and it is portable
 It is more compact and easier to handle
 Storing data on tapes is considerably cheaper
 Tapes have large storage capacities, ranging from a few hundred kilobytes to several
gigabytes
Disadvantages
 It is a sequential access memory and hence access time is more
Application
 They are generally used only for long term storage and backup.
 Tapes are also used for transporting large amount of data.
Magnetic Disks
Magnetic disks are the most popular direct access storage devices. These Magnetic
disk memories provide large storage capabilities and moderate Operating speeds.
Types of Magnetic Disks
1. Hard disk 2. Floppy disk

S
Magnetic Hard Disc

'
The hard disk is used for storing a large amount of information. This Disk is
available in different size such as 3.5inch, 5.25inch and 8inch.

H
The hard disk is completely sealed and it is protected from the dust Particles.
Construction

P
It is made up of hard aluminium platters. The platter surface is carefully machined

E
until it is flat or plane. The platter surface is coated with magnetic material and is built
into a box. It consists of a number of magnetic disks (2-5) or aluminium platters. All these

S
platters are packed together and they are mounted on a common shaft.
This disk pack is placed in a drive mechanism hard disk drive. The drive

O
mechanism drives the disk pack with the spindle. The data is written or read by R/W

J
heads is the horizontal sensing arms by moving in and out between the platters with the

.
precaution that the R/W head doesn’t touches the surface instead it flyover the disk

t
surface by a fraction of a milli meter.

S
The disk packs, read/write heads and the access mechanism
are sealed in an airtight dust free container.
Advantages
1. It has very large storage capacity and more files
can be permanently stored.
2. Very high speed in retrieving data.
3. The data can be accessed very large number of
times without degradation.
4. This is prevented from dust particles, since they
are sealed in the special chamber.
Disadvantages
1. Hard disks are not easily portable.
2. High cost and heavy loss for data.
Application
Hard disk is common secondary storage device for all types of computers. The
Storage capacity of a hard disk drive may be ranking from 20MB to 4GB.
Magneto resistance
Some metallic materials show a large change in resistance on the application of
magnetic field. This effect is called magneto resistance (MR).
Magnetic Hard Disk Drive (HDD) with Giant Magneto Resistance (GMR) sensor
Principle
In hard disk drives, the binary data in terms of 0’s and 1’s are stored by inducing
magnetic moment in a thin magnetic layer and GMR effect is used as the principle to read
the data in HDD.
Zero represents missing transition and one represents transition in the medium
Construction

S
The HDD consists of recording medium made up of a thin layer of magnetic garnet

'
grown over the substrate. The GMR sensor, which is made up of ferrites and antiferro
magnetic materials is used as reading element. The writing element is made up of inductive

H
magnetic transducer.
Working

P
Writing/Storing

E
1. Initially the current is passed through the writing element and a magnetic field is
induced in between the gap of the inductive magnetic transducer.

S
2. During writing the amplitude current is kept constant, and the direction of the current
is reverse.

O
3. So the magnetization orientation is reversed, from south to north.

J
4. When the induced magnetic field is greater than the coercivity of the recording media,

.
the data is recorded in the form of 1.

t
5. 1 is stored in the recording medium.

S
Reading/Retrieving
6. When the GMR sensor is made to near the recorded medium, the resistance varies,
with respect ot the orientation of the magnetic moments.
7. When the layers are magnetized in parallel manner, the resistance is minimum, so
maximum current flows through the sensor, which represents the data as one.
8. When the layers are magnetized in antiparallel manner, the resistance is maximum
and so minimum current flows through the sensor, which represents the data as zero.
9. Therefore with help of the reading current, zeros and ones can be retrieved from the
HDD.
Advantages
1. It has very large storage capacity.
2. Data can be stored in terms of Terabytes.
3. Non diffusive and very sensitive in reading.
Disadvantages

S
1. HDD has bulkier form factor.

'
2. Consume more power and will damage.
3. HDD may be corrupted sometime due to thermal radiation.

H
Applications
1. Used in coding and signal processing units.

P
2. Many engineering fields such as control systems, nano electronics etc.

S E
. J O
S t