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    Chm256 - Experiment 1 - Standardization of HCL With Na2co3 Primary Standard

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    Natra Affaanin
    there might be errors or mistakes in any parts of the reports that was never corrected as the report we never discussed it with the lecturer

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    Chm256 - Experiment 1 - Standardization of HCL With Na2co3 Primary Standard

    Uploaded by

    Natra Affaanin
    781 views6 pages
    there might be errors or mistakes in any parts of the reports that was never corrected as the report we never discussed it with the lecturer

    Original Title

    Chm256 - Experiment 1_standardization of Hcl With Na2co3 Primary Standard

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    there might be errors or mistakes in any parts of the reports that was never corrected as the report we never discussed it with the lecturer

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    781 views6 pages

    Chm256 - Experiment 1 - Standardization of HCL With Na2co3 Primary Standard

    Uploaded by

    Natra Affaanin
    there might be errors or mistakes in any parts of the reports that was never corrected as the report we never discussed it with the lecturer

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
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    The key takeaways are that the experiment aimed to determine the molarity of an HCl solution through titration against a sodium carbonate standard. Sodium carbonate solution was prepared as the primary standard and a dilute HCl solution was standardized against it through titration. The molarity of HCl was then calculated based on the titration results.

    The objective of the experiment was to determine the exact molarity of a hydrochloric acid solution.

    The steps taken to standardize the HCl solution were: 1) Preparing a 0.05M sodium carbonate solution as the primary standard. 2) Preparing a dilute HCl solution. 3) Filling a burette with the HCl solution. 4) Titrating 25.0mL of the sodium carbonate standard with HCl from the burette while monitoring with an indicator. 5) Repeating the titration 3 times and calculating the molarity of HCl based on the results.

    -

    COURSE NAME:
    BASIC ANALYTIC CHEMISTRY (CHM256)

    EXPERIMENT: 1
    STANDARDIZATION OF HCl WITH Na2CO3 PRIMARY STANDARD

    LECTURER’S NAME:
    -

    DATE OF EXPERIMENT:
    - 2020

    STUDENT’S NAME:

    GROUP MEMBERS/LAB PARTNER:

    -
    -
    Objective
    To determine the exact molarity of a hydrochloric acid solution

    Procedure

    a) Preparation of 0.05 M NaCl solution

    1. Na2CO3 were weighed accurately for about 1.33g. And the exact mass was recorded.
    2. Na2Co3 were dissolved in 50ml of water in a 100ml beaker.
    3. The solution was transferred into a 250 ml volumetric flask. The beaker was rinsed with
    distilled water.
    4. Distilled water was added to the mark and the flask were stopper. To make the solution
    homogeneous, the volumetric flask was shaken by turning it upside down a few times.

    b) Preparation of a dilute HCl solution

    1. 2.2 ml of concentrated HCl were transferred into a 250 ml beaker containing a little water.
    2. Acid were diluted to approximately 250ml of diluted water.

    c) Standardization of the dilute HCl solution

    1. Burette were filled with diluted HCl solution that were prepared in (b) above. The initial
    burette reading was recorded.
    2. 25.0 ml of the standard Na2CO3 were pipette into 250 ml conical flask and 2 to 3 drops of
    methyl orange indicator were added.
    3. Na2CO3 in the conical flask were titrated with the HCI from the burette slowly while shaking
    the flask till the indicator colour changed from yellow to red. The burette reading at the end
    point of the titration were recorded.
    4. The titration was repeated 3 times. And all data were recorded.
    5. The exact molarity al the HCl solution were calculated.
    Result
    1. Standardization of HCl with Na2CO3 solution
    1 2 3 Average
    Initial burette 1.20 0.60 1.00 0.93
    reading (mL)
    Final burette reading 28.40 29.20 29.60 29.07
    (mL)
    Volume of HCl used 27.20 28.60 28.60 28.13
    (mL)

    2. Calculate the molarity of the HCl solution


    Trial 1
    Weight of Na2CO3 used = 1.34 g
    Molar mass of Na2CO3 = 105.98 g/mol
    No. Of moles of Na2CO3 = Weight of Na2CO3 used/Molar mass of Na2CO3
    = 1.34 g/105.98 g/mol
    = 0.0126mol
    Molarity of HCl = No. Of moles/volume
    = 0.0126mol/ (27.20/1000) L
    = 0.46M

    Trial 2
    Weight of Na2CO3 used = 1.34 g
    Molar mass of Na2CO3 = 105.98 g/mol
    No. Of moles of Na2CO3 = Weight of Na2CO3 used/Molar mass of Na2CO3
    = 1.34 g/105.98 g/mol
    = 0.0126mol
    Molarity of HCl = No. Of moles/volume
    = 0.0126mol/ (28.60/1000) L
    = 0.44M

    Trial 3
    Weight of Na2CO3 used = 1.34 g
    Molar mass of Na2CO3 = 105.98 g/mol
    No. Of moles of Na2CO3 = Weight of Na2CO3 used/Molar mass of Na2CO3
    = 1.34 g/105.98 g/mol
    = 0.0126mol
    Molarity of HCl = No. Of moles/volume
    = 0.0126mol/ (28.60/1000) L
    = 0.44M
    Question

    1. Calculate the molarity of the HCl solution

    Trial 1
    Weight of Na2CO3 used = 1.34 g
    Molar mass of Na2CO3 = 105.98 g/mol
    No. Of moles of Na2CO3 = Weight of Na2CO3 used/Molar mass of Na2CO3
    = 1.34 g/105.98 g/mol
    = 0.0126mol
    Molarity of HCl = No. Of moles/volume
    = 0.0126mol/ (27.20/1000) L
    = 0.46M

    Trial 2
    Weight of Na2CO3 used = 1.34 g
    Molar mass of Na2CO3 = 105.98 g/mol
    No. Of moles of Na2CO3 = Weight of Na2CO3 used/Molar mass of Na2CO3
    = 1.34 g/105.98 g/mol
    = 0.0126mol
    Molarity of HCl = No. Of moles/volume
    = 0.0126mol/ (28.60/1000) L
    = 0.44M

    Trial 3
    Weight of Na2CO3 used = 1.34 g
    Molar mass of Na2CO3 = 105.98 g/mol
    No. Of moles of Na2CO3 = Weight of Na2CO3 used/Molar mass of Na2CO3
    = 1.34 g/105.98 g/mol
    = 0.0126mol
    Molarity of HCl = No. Of moles/volume
    = 0.0126mol/ (28.60/1000) L
    = 0.44M
    Discussion

    Standardization of HCl solution with Na 2CO3 primary standard were conducted which include
    the preparation of 0.05M Na2CO3 solution as the standard solution by dissolving a known amount of
    the solid Na2CO3 to standardize other acid solution.

    A dilute HCl solution were prepared to be standardize with primary standard solution in order
    to determine its concentration accurately. The reaction between HCl and Na 2CO3 as follow

    2HCl + Na2CO3 → 2NaCl + H2O + CO2

    The burette will be filled with dilute HCl solution prepared and 25.0ml of Na 2CO3 will be
    pipette into conical flask and 2 to 3 drops of methyl orange indicator. The titration will be repeated up
    to 3 times.

    Sometimes there will be errors occurs during conducting this experiment where its from our
    human default for example not recognizing the appearance of the red colour instantly as its appear,
    not shaking the flask properly while HCl were added. These errors could be solved by doing repetition
    up to 3 times to achieve the average for more precise result.

    Conclusion

    A titration is a valid method in finding concentration of a substance within solution by


    repeating it three times.

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