Inorg Chemistry Mar 2018 Module C PDF

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NMAT REVIEW 2018 D. The system absorbs heat while expanding to a

INORGANIC CHEMISTRY vacuum.
MODULE C 10. Fifty four grams of certain metal at 980C was placed in
80mL of water at 297 K. Assuming no heat is lost to the
I. GAS LAWS surrounding, what is the temperature of the water and the
1. If I have 25 mL of a gas at a pressure of 2.1 atm and a metal? (specific heat of metal = 0.085 cal/g-0C)
temperature of 300 K, what will the pressure be if I A. 2800C B. 350C C. 280C D. 250C
increase the temperature to 400 K and compress the gas
to a volume of 10 mL? Figure for #11
A. 14 atm B. 8.6 atm C. 0.028 atm D. 7 atm Activated complex
2. Avogadro’s law states that: y

l
A. The volume of a gas is directly proportional to its A+B
temperature in kelvins. t C+D
B. The volume of a gas is directly proportional to the
number of moles present.
Time of reaction
C. The volume of a gas is directly proportional to the ideal
gas constant. 11. The diagram shows the relative values for the
D. None of these. enthalpies involved in the reaction A+B ---> C+D. Based
on the diagram, which of the following is true?
3. If the Kelvin temperature of a gas is doubled, then
A. The activation energy required for
for the reverse
A. the average molecules move twice as fast.
reaction is lower than that for the forward reaction.
B. every molecule moves twice as fast.
B. A catalyst for the reaction is impossible.
C. every molecule has twice the kinetic energy.
C. The reaction is endothermic.
D. the average molecules has twice the kinetic energy.
D. The reaction is exothermic.
4. Gas A and Gas B contain the same number of molecules
and are at the same temperature. The external pressure III. SOLUTIONS, pH, & HYDROLYSIS
on Gas A is one-half that of Gas B. When compared to Gas 12. What is the [ + ] in a 0.005 M solution of NaOH?
B, the volume of Gas A is A. 5 x 10−3 B. 2  10−3 C. 2  10− D. 5  10 −
A. twice that of Gas B C. four times that of Gas B
B. one-half that of Gas B D. same as that of Gas B 13. If I have 30 grams of lithium hydroxide (MW=24)
dissolved to make 3L of a solution, the molarity of this
5. What is the partial pressure of CH4 in a mixture solution is:
containing 2 moles of CH4, 3 moles of SO2 and 3 moles
A. 0.42 M B. 1.25 M C. 10.0 M D.1.58
CO2? The total pressure is 800 mmHg.
A. 400 mmHg C. 200 mmHg 14. If I dilute 5 mL of 0.15 M NaCl to a final volume of 5 L,
B. 600 mmHg D. 300 mmHg what is the final concentration o f NaCl?
6. A sample of gas has a volume of 80 mL at 45 C. What

A. 0.00015 M C. 15000 M
volume will the sample occupy at 0 C at constant

B. 0.0015 M D. 0.015 M
pressure?
A. 0.69 mL B. 6.9 mL C. 69 mL D. 690 mL 15. The following always form solutions (if they do not
react chemically).
II. THERMODYNAMICS A. a gas in a liquid C. two liquids
7. When 2.0 grams of methane are burned in a bomb B. a solid in a liquid D. two gases
calorimeter containing 2000 grams of water, it causes the
temperature of the water to rise by 13.30 0C. What is the 16. How does buffer work?
molar heat of combustion of methane? A. Being a mixture of either a weak acidacid or base and its
Cp(H2O) = 4.18 J/g0C. conjugate, a buffer stabilizes pH by both accepting and
A. 111 kJ B. 889 kJ C. 13.3 kJ D. 8.89 kJ providing protons for reaction with any added outside acid
8. A certain endothermic reaction occurs with a decrease or base.
in entropy. Therefore, the reaction is B. Being a mixture of a strong acid and a strong base, a
A. nonspontaneous at all temperatures buffer stabilizes pH by neutralizing itself, its environment,
B. spontaneous at low temperatures only and consequently, any added outside acid or base.
C. spontaneous at all temperatures C. Being a mixture of various salts, a buffer can shift the
D. spontaneous at high temperatures only equilibrium of the solution in either the direction of [ H+]
or [OH−] (depending on whether an outside acid or base is
9. Under which condition will the change in internal energy added) and thus lessens the effects of the added
of a system be equal to the change in enthalpy of the chemical.
system? D. Being a mixture of water, acids, and bases, a buffer
A. The system evolves heat at constant
constant pressure. adjusts K w upon addition of an outside acid or base so that
B. The system evolves
evolves heat while its
its volume decreases either K a or K b remains relatively constant. The pH is thus
against an opposing pressure of 1 atm. not affected.
C. The system absorbs heat at constant temperature and
pressure.
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B. 0.2678 N D. 0.1274 N
17. Barium sulfate is used in the form of “barium metal” in 27. Ionic radius is the radius of a cation or an anion as
the radiographic investigation of gastrointestinal tract and measured in an ionic compound. Ionic radius increases as
is opaque to X-rays. Barium compounds are toxic. Despite we move down within a group, and it decreases as we
the low solubility of barium sulfate, some patients are move across a period. Cations are smaller than their
uncommonly allergic to barium ions. You have added solid corresponding atoms, because in the cation there are
barium sulfate to H2O to give a saturated solution but wish more protons than electrons. Therefore, the electrons are
to reduce the barium ion concentration prior to ingestion attracted and they move closer to the nucleus. Anions are
by patient. The reaction shown below is endothermic: larger than their corresponding atoms, because the
BaSO4 ( s ) + H2O Ba+2 ( aq ) + SO4-2 (aq) presence of the extra electrons causes the electrons
Which of the following procedures is used to reduce the causes the electrons to repel each other. As a result, they
concentration of barium ions? try to move as far away from each other, creating bigger
A. heat the mixture clouds.
B. add more solid barium sulfate Which of the following statements is true?
C. remove some of the saturated solution from solid I. The radius of Br - > Br
D. add H2SO4 to give ⌠H+⌡ concentration of 2 M II. The radius of Li < Na
III. The radius of Mg > Cs
18. An ion necessary for the formation of bones and teeth IV. The radius of K + > Cs+
is: A. I & II only C. II & III only
A. HCO3- B. CO3-2 C. Cl-1 D. PO4-3 B. I & III only D. II & IV only
19. The molecular weight of a substance is 128 and its 28. Which of the following compounds will give a pH < 7?
equivalent weight in a particular reaction is 64. A 2.0 M A. CaI2 B. MgSO4 C. KClO D. NH4NO3
solution of this substance will have a normality of:
A. 4.00 N B. 2.00 N C. 0.50 N D. 0.25 N 29. Which of the following compounds will give an alkaline
solution?
For nos. 20-22, consider the following acid solutions: A. CaI2 B. MgSO4 C. NaCN D. NH4F
I. 0.01 M HI III. 0.01 M H2S
II. 0.01M HCℓ IV. 0.01M H3PO4 IV. STOCHIOMETRY
20. Which solution will have equal normality? 30. How many moles of H2 will be produced when 8 moles
A. I, III, and IV B. I and II C. III and IV D. I and III of water is electrolyzed? The reaction is:
2H2O → 2 H2 + O 2
21. Which solutions contain volatile acid? A. 6 moles B. 8 moles C. 4 moles D. 1 mole
A. I, II, and III C. IV only
B. I and III D. II and III 31. How many molecules of oxygen are required for every

molecule of carbon dioxide formed in the combustion of

22. Which solution will have normality twice its molar ethyl alcohol, C2H5OH?
concentration? C2H5OH + 3 O 2 → 2 CO2 + 3 H2O
A. I and II C. IV A. 0.75 B. 1.50 C. 4.65 x 1023 D. 1.2 x 1022
B. III D. III and IV
NH4NO3 N2O + 2H2O
23. How many grams of water must be added to 200 mL
of NaOH solution in order to have a solution with a specific 32. In the equation above, how many grams of
gravity of 1.157 and 13.55% NaOH? (Specific gravity of ammonium nitrate is needed to produce 200g nitrogen (I)
the original solution is 1.32 and 28.83%)
oxide: (N=14, H=1, O=16)
A. 492.85 g C. 285.48 g A. 454 g B. 908 g C. 364 g D. 90.8 g
B. 294.95 g D. 258.45 g
33. If 19.6 g of sulfuric acid are to be used in certain
24. If 40 mL of 0.200 M KMnO 4 (acidified) is diluted with chemical reactions, how many grams of sulfur ato ms
160 mL of water, then the normality of the resulting
would be contained in a sulfuric acid of this size?
solution will be: (S = 32, H2SO4 = 98)
A. 0.0400 N C. 0.0500 N A. 4.4 B. 6.4 C. 8.2 D. 10.6
B. 0.2000 N D. 0.250 N
34. The sum of the coefficients for the combustion of
25. 25 ml. of solution of H2SO4 required exactly 40ml of benzene, C6H6 is?
0.20 N NaOH for titration. Calculate the molarity of H2SO4 A. 35 B. 30 C. 36 D. 10
used:
A. 0.16 M B. 0.86 M C. 1.92 M D. 1.08 M
26. What is the normality of an acid solution if 50 mL of

the solution requires 48.61 mL of 0.1879 N alkali for
neutralization?
A. 0.4000 N C. 0.1827 N

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NMAT REVIEW 2018 D. The system absorbs heat while expanding to a

2. Avogadro’s law states that: y

26. What is the normality of an acid solution if 50 mL of

LEARNFAST REVIEW AND TUTORIAL HUB – NMAT REVIEWER

LEARNFAST REVIEW AND TUTORIAL HUB – NMAT REVIEWER

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