(Chem 16) Long Exam 3 Reviewer A

UP Association of Chemistry Majors and Enthusiasts and
UP Chemical Society
In partnership with the College of Science Student Council
CHEM 16 3rd LONG EXAM SAMPLE EXAM
I. MODIFIED TRUE OR FALSE. Write TRUE if the statement is true. Otherwise, change the
underlined word/phrase.
1. The law of effusion states that the rate of effusion of a specific gas is proportional to the square
root of its molar mas.
2. Henry’s Law states that the increase in solubility of a gas in a liquid solvent is in indirect
proportion to that of its partial pressure above the solution.
3. CH3CH2CH2CH3 exhibits weaker intermolecular forces of attraction than CH3CH2CH3.
4. For a system to be non-ideal, high P and low T should be observed.
5. Water is always pH 7.
6. In a saturated solution, the rate of dissolution of solvent is equal to the rate of crystallization.
7. Adhesive forces are the intermolecular forces that hold similar molecules together.
8. Charles’s Law states that the volume of gas is inversely proportional to the absolute temperature
at constant pressure and number of moles.
9. The standard molar volume is 24.2 L at STP.
10. According to Le Châtelier’s Principle, when heat is added to an exothermic reaction, it shifts
forward. When heat is removed, it shifts in reverse.
11. The crystal lattice energy is the energy needed to separate an ionic solute into gaseous ions.
12. For ternary acids having the same central atom, the lowest oxidation state of the central atom is
usually the strongest acid.
II. MULTIPLE CHOICE. Choose the letter of the best answer.

1. Acetylene gas can be produced by slowly reacting calcium carbide with water, given by the
equation 𝐶𝑎𝐶2 + 2𝐻2 𝑂 → 𝐶2 𝐻2 + 𝐶𝑎(𝑂𝐻)2 . If 35.0 g of calcium carbide were allowed to fully
react with excess amounts of water, what will be the volume (in mL) of the acetylene gas
produced under 1 atm of pressure at 25 °C?
a. 19 mL
b. 28 mL
c. 30 mL
d. 13 mL
2. It took 6.4 minutes for 25 mL of argon to reach the end of an effusion tube that has a porous
barrier. How long will it take for 25 ml of CHCl3 to effuse through the tube under the same
conditions?
a. 663.80 seconds
b. 384.58 seconds
c. 907.1 seconds
d. 215.0 seconds
3. Nitrogen dioxide is a brown gas used to produce nitric acid and is one of the main air pollutants
known. What is the density of nitrogen dioxide gas (MM = 46.00 g/mol) if it occupies 150 L of
volume at 28 °C and 86.126 kPa? (101.325 kPa = 1 atm)
a. 5.157 g/L
b. 1.723 g/L
c. 1.580 g/L
d. 0.158 g/L
4. Which of the following is not part of the Kinetic Molecular Theorem?
a. Gasses consist of minute particles. Although small, the volume they occupy is not negligible
compared to the volume of container.
b. The interaction between particles, either attractive or repulsive, is negligible.
c. As the average kinetic energy decreases, the absolute temperature also decreases.
d. The gas particles are at constant motion at a very fast rate such that they collide with each
other and the container.
5. Which of the following is stated in the Brønsted-Lowry Theory?
a. Acid is a proton donor; thus, any hydrogen-containing molecule is capable of releasing a
proton.
b. Acidic H are bonded to an electronegative atom in most acids.
c. Acids produce hydrogen in aqueous solutions.
d. The reaction between acids and bases occurs through a proton-transfer process.
6. In the Van der Waals Equation correction on the Ideal Gas Law, what equation is the correction
factor for the volume taken up by the gas molecules?
a. 𝑛𝑏
𝑎𝑛2
b. 𝑉2
𝑛𝑅𝑇
c.
𝑉−𝑛𝑏
𝑎𝑛2
d. − 𝑉2
7. In the reaction below, what kind of acid-base neutralization is observed?
a. Lewis
b. Arrhenius
c. Brønsted-Lowry
d. None of the above
8. Based on the reaction, what is the conjugate acid?
a. Bisulfate ion
b. Water
c. Hydroxide
d. Sulfurous acid
9. Compound X has density equal to 0.789 g/mL. What is the %w/v concentration of the solution
formed when 10.00 mL of compound X is dissolved in 100 mL water, if the molar mass of
compound X is 16.08 g/mol?
a. 10.0%
b. 7.89%
c. 2.81%
d. 0.49%
10. How many atoms are contained in a unit cell of a body-centered cubic crystal lattice structure?
a. 1
b. 2
c. 3
d. 4
11. Calculate the standard free energy change at room temperature (27 °C) when N2 reacts with O2 to
form NO if ΔH°=180.7 kJ and ΔS°=24.7 J/K.
a. 7179.90 kJ
b. -7179.90 kJ
c. 173.34 kJ
d. -173.34 kJ
12. Which if the following have a direct relationship with each other?
I. Pressure and volume III. Temperature and volume
II. Pressure and no. of moles IV. Volume and no. of moles
a. I and II only
b. I, II, and III only
c. II, III, and IV only
d. I, II, III, and IV
13. A 27.6 mL sample of PH3(g) (FW: 34.0 g/mol) is obtained at STP (1 atm). What is the mass of
this gas?
a. 41.9 g
b. 41.0 mg
c. 4.19 mg
d. 0.419 g
14. Rank the following in order of increasing surface tension (at room temperature):
I. CH3OH
II. CCl4
III. CH3CH2OCH2CH3
a. I < II < III
b. II < I < III
c. II < III < I
d. I < III < II
15. What is the pH of an aqueous solution that is 3.00% KOH, by mass, and has a density of
1.0242 g/mL?
a. 0.3
b. 12.6
c. 1.02
d. 13.7
16. Which of the following incorrectly describes the critical point in a phase diagram?
a. It is the point wherein all phases are in equilibrium
b. It is the pressure and temperature at which a liquid and its vapor are identical
c. It is the highest temperature point on a vapor pressure curve
d. None of the above
17. In the Brønsted-Lowry definition of acids and bases, the acid is a/an _______ and the base is
a/an _______.
a. Electron acceptor, electron donor
b. Proton acceptor, proton donor
c. Electron donor, electron acceptor
d. Proton donor, proton acceptor
18. The Kinetic Molecular Theory is the model that accounts for macroscopic gas behavior at the
level of individual particles. It is based on the following postulates except:
a. The particles in a gas are in constant, random, straight-line motion, except when they collide
with the container walls or with each other.
b. The movement of a gas into a vacuum governs its rate of effusion, which is inversely
proportional to the square root of its molar mass.
c. The collisions of the particles are elastic, having a constant total kinetic energy. Between
collisions, the molecules do not influence each other by attractive or repulsive forces.
d. A gas consists of a large collection of individual particles with empty space between
them. The volume of each particle is so small compared with the volume of the whole
sample that it is assumed to be zero.
For numbers 19-21, refer to the following compounds:
a. C8H18 b. (CH3)3CH c. C6H5CHO d. CH3CH2CH2CH3
19. Which compound has the highest boiling point?
20. Which compound has the lowest boiling point?
21. What are the forces of attraction present in compound D?
I. dipole-dipole III. hydrogen bonds
II. London dispersion IV. ionic
a. I, II, and IV
b. II only
c. II and III
d. I and II
22. How much heat is required to vaporize a 2.35 g sample of diethyl ether (FW = 74.12 g/mol; ΔHvap
= 29.1 kJ/mol) at 298 K?
a. 92.3 kJ
b. -92.3 kJ
c. 0.923 kJ
d. -0.923 kJ
23. This refers to how easily the electron cloud of an atom can be distorted
a. Effective nuclear charge
b. Polarizability
c. Le Châtelier’s Principle
d. Polarity
24. Which of the following is not true regarding the properties of aqueous solutions of acids and
bases?
a. Basic aqueous solutions conduct electricity.
b. Bases turn bromothymol blue from blue to yellow.
c. Acids react with metals to generate hydrogen, H2 (g).
d. Aqueous acidic solutions react with salts of weaker acids to form the weaker acid and salt of
stronger acid.
III. PROBLEM SOLVING

1. An unknown, nonvolatile and non-electrolyte sample weighing 25.99 grams is dissolved in 1.26 ×
104 g of water under standard atmospheric conditions at 25 °C. The solution was placed in a
container that measures a solution’s osmotic pressure. The device reads 2.75 atm of pressure.
(Density of water at 25°C = 1.00 g/ml)
a. What is the molecular mass of the solute?
b. The Kb of water is 0.520 °C·kg/mol. What would be the new boiling point of the solution?
2. The production of ammonia follows the chemical reaction:
𝑁2 + 𝐻2 → 𝑁𝐻3
a. Suppose that 3.00 kg N2 is reacted with excess H2 in a 250.0 L chamber to produce NH3.
Assuming ideal conditions, what is the pressure inside the chamber at 450 °C?
b. When the temperature inside the chamber is controlled to 235 °C, the reaction only goes to
58.02% completion. What would be the new pressure at the new conditions?
c. To confirm if the gas produced is NH3, the rate of effusion was compared with unlabeled gas
X that is 81.68% C and 18.32% H. The effusion time for X in a 0.050 m orifice was 0.62
times the effusion time needed for NH3 to effuse through the same orifice. What is the
identity of gas X?
3. A 28.5 g sample of a nonelectrolyte compound was dissolved in 0.180 × 103 g of water. The
solution froze at -3.34 °C. What is the molecular weight of the compound? (Kf = 1.75 °C/m; P =
1 atm)

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UP Association of Chemistry Majors and Enthusiasts and

CHEM 16 3rd LONG EXAM SAMPLE EXAM

II. MULTIPLE CHOICE. Choose the letter of the best answer.

III. PROBLEM SOLVING

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