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Liquefied Petroleum Gas

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Liquefied Petroleum Gas

What is LPG or LP Gas?


LPG or LP Gas is the abbreviation of Liquefied Petroleum Gas. This group of products
includes saturated Hydrocarbons - Propane (C3H8) and Butane (C4H10), which can be
stored/transported separately or as a mixture. They exist as gases at normal room
temperature and atmospheric pressure.

Why is it called Liquefied Petroleum Gas?


This is because these gases liquefy under moderate pressure. They liquefy at moderate
pressures, readily vaporizing upon release of pressure. It is this property that permits
transportation of and storage of LP Gas in concentrated liquid form.

Where does LPG come from?


LPG comes from two sources. It can be obtained from the refining of crude oil. When
produced this way it is generally in pressurized form. LPG is also extracted from natural gas
or crude oil streams coming from underground reservoirs. 60% of LPG in the world today is
produced this way whereas 40% of LPG is extracted from refining of crude oil.

What is commercial Propane & Butane?


Ideally products referred to as "propane" and "butane" consist very largely of these
saturated hydrocarbons; but during the process of extraction/production certain allowable
unsaturated hydrocarbons like ethylene, propylene, butylenes etc. may be included in the
mixture along with pure propane and butane. The presence of these in moderate amounts
would not affect LPG in terms of combustion but may affect other properties slightly (such
as corrosiveness or gum formation).

How is LPG seen & felt?


• It is colorless and cannot be seen
• It is odorless. Hence LPG is odorized by adding an odorant prior to supply to the
user, to aid the detection of any leaks.
• It is slightly heavier than air and hence if there is a leak it flows to lower lying areas.
• In liquid form, its density is half that of water and hence it floats initially before it is
vaporized.
• It is non-toxic but can cause asphyxiation in very high concentrations in air.

LPG expands upon release and 1 liter of liquid will form approximately 250 liters of vapor

What is LPG used for?


LPG is used as a fuel for domestic (cooking), industrial, horticultural, agricultural, heating
and drying processes. LPG can be used as an automotive fuel or as a propellant for
aerosols, in addition to other specialist applications. LPG can also be used to provide
lighting through the use of pressure lanterns.
Why are Butane and Propane used in combination?
While butane and propane are different chemical compounds, their properties are similar
enough to be useful in mixtures. Butane and Propane are both saturated hydrocarbons.
They do not react with other. Butane is less volatile and boils at 0.6 deg C. Propane is more
volatile and boils at - 42 deg C. Both products are liquids at atmospheric pressure when
cooled to temperatures lower than their boiling points. Vaporization is rapid at temperatures
above the boiling points. The calorific (heat) values of both are almost equal. Both are thus
mixed together to attain the vapor pressure that is required by the end user and depending
on the ambient conditions. If the ambient temperature is very low propane is preferred to
achieve higher vapor pressure at the given temperature.

What are the advantages of LPG?


The advantages of LPG are as follows

• Because of its relatively fewer components, it is easy to achieve the correct fuel to
air mix ratio that allows the complete combustion of the product. This gives LPG its
clean burning characteristics.
• Both Propane and Butane are easily liquefied and stored in pressure containers.
These properties make the fuel highly portable, and hence, can be easily transported
in cylinders or tanks to end-users.
• LPG is a good substitute for petrol in spark ignition engines. Its clean burning
properties, in a properly tuned engine, give reduced exhaust emissions, extended
lubricant and spark plug life.
• As a replacement for aerosol propellants and refrigerants, LPG provides alternatives
to fluorocarbons, which are known to cause deterioration of the earth's ozone layer.

The clean burning properties and portability of LPG provide a substitute for traditional fuels
such as wood, coal, and other organic matter. This provides a solution to de-forestation and
the reduction of particulate matter in the atmosphere (haze), caused by burning the
traditional fuels.

What are LPG properties?


Commercial Commercial Mixture 50%
Property Units
Propane Butane each
Specific gravity of Liquid
0.504 0.582 0.543
at 15 deg C (Water=1)
Specific gravity of Vapor
1.5 2.01 1.75
at 15 deg C(Air=1)
Vapor pressure at 38 Kg/sq.cm
13.8 2.6 8.0
deg C
Boiling point at atm Deg C
- 42 9 + 9 to - 42
pressure
Ignition temperature in air Deg C 495-605 480-535 480-605
Latent Heat of Btu/lb
184 167 175
Vaporization

http://www.e-lpg.com/lp_gas.asp

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