Water 100 BATCH COLUMN DESIGN(BINARY SYSTEM)

FEED/DAY(L): 1000
20% EXCESS(L) 900

FEED B.P M.W FEED

COMPONENTS (°C) (Kg/Kg mol) (w/w%) (mol%)
water 100 18 1 2.25
Acetonitrile 82 41.05 99 97.75

Time Parameter 1.7 hrs

Feed 755 Kg Reflux Ratio
Time Taken 4.59 hrs Intercept
Number of Stages
INTERCEPT 0.0439
Minimum Reflux 5.17

CALCULATION OF VAPOUR MASS FLOW RATE:

Composition of Boil up (w/w%)
Acetone 14
Water 86
Reflux Ratio 8
L/G 0.8889
Average temperature of gas 84.52 °C
Density of Liquid 859.5400 Kg/m3
Moles of Distillate/100 g Distillate 2.8728 moles
Operating Pressure 760 mm Hg
Average MW of Distillate 34.81 Kg/Kmol
Density of Gas 1.187 Kg/m3
X Intercept 0.0331
Ordinate 0.3000
1" Ceramic Intallox Saddles 98
Viscosity of Liquid 0.4833 cp
0.0005 Kg/m sec
Gas Flow rate at Flooding-G' 2.5874 Kg/m2-sec
at 70% flooding 1.8112 Kg/m2-sec

STRUCTURED PACKINGS
 MELLAPAK 250Y MELLAPAK 500Y
Flow Parameter 0.033 Flow Parameter 0.033
Cg, max 0.125 Cg, max 0.125
Cg 0.100 Cg 0.100
Correction Factor 1 Correction Factor 0.7
g 3.192 Kg/m2.s g 2.235
Boil up Rate G 147.990 Kg/hr Boil up Rate G 147.990
0.041 Kg/sec 0.041
4.251 Kgmol/hr 4.251
Area of Column 0.013 m2 Area of Column 0.018
Column Diameter 128.076 mm Column Diameter 153.080
Temperature 357.52 °K Temperature 357.52
Pressure 1013 m bar Pressure 1013
F Factor 2.9313 F Factor 2.052
NTSM 2.6 NTSM 4
Height 13.5 m Height 8.78
Pressure Drop 3.5 mbar/m Pressure Drop 2.5
Total Pressure Drop 47.25 mbar Total Pressure Drop 21.94
35.439 mm Hg 16.45
SIGN(BINARY SYSTEM)

DISTILLATE BOTTOMS Density

(w/w%) (mol%) (w/w%) (mol%) (g/cc)
14 27.07 0.5 1.13 0.998
86 72.93 99.5 98.87 0.837
0.83861

8 10 15
0.0301 0.0246 0.017
27 25 14

COLUMN DIAMETER CALCULATION (RANDOM PACKINGS)

Maximum Distillate Rate 16.4 Kg/hr
0.5 Kgmol/hr
Boil up rate 148.0 Kg/hr
0.0 Kg/sec
4.3 Kgmol/hr
Latent Heat of Vapourisation 160.4 Kcal/Kg
Heat Load 23735.7 Kcal/hr
Area of Column 0.0227 m2
Diameter of Column 170 mm

CONDENSER AREA
Heat Load 23735.7 Kcal/hr
Temperature at the top 84.5 °C
Cooling Water Inlet Temp. 32.0 °C
Cooling Water Outlet Temp. 37.0 °C
LMTD 50.0 °C
Overall Heat Transfer Coefficient (U) 500.0 kcal/hr-m2-c
Main Condenser Area 0.9 m2
Vent Condenser Area 0.1 m2
Cooling Water Req. for Main Condenser 4.7 m3/hr
Cooling Water Req. for Vent Condenser 0.5 m3/hr
Total Cooling Water Requirement 5 m3/hr
 MELLAPAK 750Y
Flow Parameter 0.033
Cg, max 0.125
Cg 0.100
Correction Factor 0.63
Kg/m2.s g 2.011 Kg/m2.s
Kg/hr Boil up Rate G 147.990 Kg/hr
Kg/sec 0.041 Kg/sec
Kgmol/hr 4.251 Kgmol/hr
m2 Area of Column 0.020 m2
mm Column Diameter 161.361 mm
°K Temperature 357.52 °K
m bar Pressure 1013 m bar
F Factor 1.85
NTSM 5.3
m Height 6.62 m
mbar/m Pressure Drop 6 mbar/m
mbar Total Pressure Drop 39.74 mbar
mm Hg 29.80 mm Hg
 Latent Heat Viscosity
(Kcal/Kg) (cp)
540.00 0.897
98.59 0.416
160.3874 0.48334

I fr II fr III fr
Starting Bottoms 2.25 1.6 1.32
Distillate 27.07 27.07 27.07
Ending Bottoms 1.6 1.32 0.095
R 8 10 15
Mi 18.62 18.1 17.95
Mf 18.15 17.9 17.13
T(hr) 1.01 0.5 3.07
Qty Rem. 738.17 731.3 702.93
Qty Eva. 16.58 6.9 28.37

Distillation Time 4.59 hrs

Quantity Remained 0.00 Kg

REBOILER
Reboiler Load 23735.7 Kcal/hr
Temperature 82.09 °C
Steam Pressure 3 Kg/cm2-g
Steam Temperature 133.54 °C
Latent Heat of Steam 516.68 Kcal/Kg
Overall Heat Transfer Coeff(U) 488 kcal/hr-m2-c
Reboiler Area 0.95
Steam Required 45.93894 Kg/hr
Total Steam Required 55.1 Kg/hr
 BATCH COLUMN DESIGN(BINARY SYSTEM)

CLIENT: M/s Talli Godavari, Hyderabad

SYSTEM: THF Recovery from THF Water system.

FEED/DAY(L): 1000
20% EXCESS(L) 1200

FEED B.P M.W FEED

COMPONENTS (°C) (Kg/Kg mol) (w/w%) (mol%)
water 100 18 1 2.25
Acetonitrile 82 41.05 99 97.75

Time Parameter 1.8 hrs

Feed 1006 Kg Reflux Ratio
Time Taken 4.86 hrs Intercept
Number of Stages
INTERCEPT 0.0439
Minimum Reflux 5.17

CALCULATION OF VAPOUR MASS FLOW RATE:

Composition of Boil up (w/w%)
Acetone 14
Water 86
Reflux Ratio 8
L/G 0.8889
Average temperature of gas 84.52 °C
Density of Liquid 859.5400 Kg/m3
Moles of Distillate/100 g Distillate 2.8728 moles
Operating Pressure 760 mm Hg
Average MW of Distillate 34.81 Kg/Kmol
Density of Gas 1.187 Kg/m3
X Intercept 0.0331
Ordinate 0.3000
1" Ceramic Intallox Saddles 98
Viscosity of Liquid 0.4833 cp
0.0005 Kg/m sec
Gas Flow rate at Flooding-G' 2.5874 Kg/m2-sec
at 70% flooding 1.8112 Kg/m2-sec

STRUCTURED PACKINGS
 MELLAPAK 250Y MELLAPAK 500Y
Flow Parameter 0.033 Flow Parameter 0.033
Cg, max 0.125 Cg, max 0.125
Cg 0.100 Cg 0.100
Correction Factor 1 Correction Factor 0.7
g 3.192 Kg/m2.s g 2.235
Boil up Rate G 186.358 Kg/hr Boil up Rate G 186.358
0.052 Kg/sec 0.052
5.354 Kgmol/hr 5.354
Area of Column 0.016 m2 Area of Column 0.023
Column Diameter 143.723 mm Column Diameter 171.782
Temperature 357.52 °K Temperature 357.52
Pressure 1013 m bar Pressure 1013
F Factor 2.9313 F Factor 2.052
NTSM 2.6 NTSM 4
Height 13.5 m Height 8.78
Pressure Drop 3.5 mbar/m Pressure Drop 2.5
Total Pressure Drop 47.25 mbar Total Pressure Drop 21.94
35.439 mm Hg 16.45
SIGN(BINARY SYSTEM)

DATE 22/3/2012
PREPARED BY: Devayani
CHECKED BY: Santhosh
APPROVED BY: NSW

DISTILLATE BOTTOMS Density

(w/w%) (mol%) (w/w%) (mol%) (g/cc)
14 27.07 0.5 1.13 0.998
86 72.93 99.5 98.87 0.837
0.83861

8 10 15
0.0301 0.0246 0.017
27 25 14

COLUMN DIAMETER CALCULATION (RANDOM PACKINGS)

Maximum Distillate Rate 20.7 Kg/hr
0.6 Kgmol/hr
Boil up rate 186.4 Kg/hr
0.1 Kg/sec
5.4 Kgmol/hr
Latent Heat of Vapourisation 160.4 Kcal/Kg
Heat Load 29889.4 Kcal/hr
Area of Column 0.0286 m2
Diameter of Column 191 mm

CONDENSER AREA
Heat Load 29889.4 Kcal/hr
Temperature at the top 84.5 °C
Cooling Water Inlet Temp. 32.0 °C
Cooling Water Outlet Temp. 37.0 °C
LMTD 50.0 °C
Overall Heat Transfer Coefficient (U) 500.0 kcal/hr-m2-c
Main Condenser Area 1.2 m2
Vent Condenser Area 0.1 m2
Cooling Water Req. for Main Condenser 6.0 m3/hr
Cooling Water Req. for Vent Condenser 0.6 m3/hr
Total Cooling Water Requirement 7 m3/hr
 MELLAPAK 750Y
Flow Parameter 0.033
Cg, max 0.125
Cg 0.100
Correction Factor 0.63
Kg/m2.s g 2.011 Kg/m2.s
Kg/hr Boil up Rate G 186.358 Kg/hr
Kg/sec 0.052 Kg/sec
Kgmol/hr 5.354 Kgmol/hr
m2 Area of Column 0.026 m2
mm Column Diameter 181.074 mm
°K Temperature 357.52 °K
m bar Pressure 1013 m bar
F Factor 1.85
NTSM 5.3
m Height 6.62 m
mbar/m Pressure Drop 6 mbar/m
mbar Total Pressure Drop 39.74 mbar
mm Hg 29.80 mm Hg
 Latent Heat Viscosity
(Kcal/Kg) (cp)
540.00 0.897
98.59 0.416
160.3874 0.48334

I fr II fr III fr
Starting Bottoms 2.25 1.6 1.32
Distillate 27.07 27.07 27.07
Ending Bottoms 1.6 1.32 0.095
R 8 10 15
Mi 24.83 24.2 23.93
Mf 24.19 23.9 22.84
T(hr) 1.07 0.5 3.25
Qty Rem. 984.22 975.1 937.24
Qty Eva. 22.11 9.2 37.82

Distillation Time 4.86 hrs

Quantity Remained 0.00 Kg

REBOILER
Reboiler Load 29889.4 Kcal/hr
Temperature 82.09 °C
Steam Pressure 3 Kg/cm2-g
Steam Temperature 133.54 °C
Latent Heat of Steam 516.68 Kcal/Kg
Overall Heat Transfer Coeff(U) 488 kcal/hr-m2-c
Reboiler Area 1.19
Steam Required 57.849035 Kg/hr
Total Steam Required 69.4 Kg/hr
PRESSURE PRESSURE °C Kcal/Kg FP Cg max
1 Kg/cm2-g Temp Latent heat 0.01 0.15
1.5 0.02 17.51 587.61 0.0125 0.15
2 0.03 24.1 583.89 0.015 0.14
2.5 0.04 28.98 581.14 0.0175 0.14
3 0.05 32.9 578.92 0.02 0.135
3.5 0.06 36.18 577.05 0.025 0.13
4 0.07 39.02 575.44 0.03 0.125
4.5 0.08 41.53 574.01 0.035 0.12
5 0.09 43.79 572.72 0.04 0.115
0.1 45.83 571.54 0.045 0.11
0.2 60.09 563.3 0.05 0.105
0.3 69.13 557.97 0.06 0.1
0.4 75.89 553.94 0.07 0.095
0.5 81.35 550.64 0.08 0.09
0.6 85.95 547.83 0.09 0.085
0.7 89.96 545.36 0.1 0.085
0.8 93.51 543.15
0.9 96.71 541.14
1 99.63 539.3 MELLAPAK 500Y
1.1 102.32 537.59 F Factor NTSM
1.2 104.81 535.99 0.6 4.4
1.3 107.13 534.49 0.7 4.4
1.4 109.32 533.07 0.8 4.4
1.5 111.37 531.73 0.9 4.3
1.5 111.37 531.73 1 4.3
1.6 113.32 530.45 1.1 4.2
1.7 115.17 529.22 1.2 4.2
1.8 116.93 528.05 1.3 4.2
1.9 118.62 526.92 1.4 4.2
2 120.23 525.84 1.5 4.2
2.2 123.27 523.78 1.6 4.2
2.4 126.09 521.86 1.7 4.2
2.6 128.73 520.04 1.8 4.1
2.8 131.2 518.32 1.9 4.1
3 133.54 516.68 2 4
3.5 138.87 512.89
4 143.63 509.45 MELLAPAK 750Y
4.5 147.92 506.29 F Factor NTSM
5 151.85 503.35 0.6 5.7
5.5 155.47 500.6 0.7 5.7
6 158.84 498 0.8 5.7
6.5 161.99 495.54 0.9 5.7
7 164.96 493.2 1 5.7
7.5 167.76 490.96 1.2 5.6
 8 170.42 488.8 1.4 5.6
8.5 172.94 486.73 1.6 5.6
9 175.36 484.74 1.8 5.3
9.5 177.67 482.8 2 5
10 179.88 480.93 2.25 4.8
11 184.06 477.35
12 187.96 473.94
13 191.6 470.7
14 195.04 467.6
15 198.28 464.61
16 201.37 461.74
17 204.3 458.95
18 207.11 456.26
19 209.79 453.64
20 212.37 451.1
21 214.85 448.61
22 217.24 446.19
23 219.55 443.82
24 221.78 441.5
25 223.94 439.23
26 226.03 437.01
27 228.06 434.82
28 230.04 432.67
29 231.96 430.56
30 233.84 428.48
 X axis Ordinate
PACKINGS Correction Factor 0.02 0.32
MELLAPAK 125X 1.5 0.025 0.31
MELLAPAK 125Y 1.25 0.03 0.3
MELLAPAK 170X 1.51 0.035 0.3
MELLAPAK 170Y 1.1 0.04 0.28
MELLAPAK M2X 1.41 0.045 0.28
MELLAPAK M2Y 1.09 0.05 0.27
MELLAPAK 250X 1.25 0.055 0.27
MELLAPAK 250Y 1 0.06 0.26
MELLAPAK 350Y 0.85 0.065 0.26
MELLAPAK 500X 1 0.07 0.25
MELLAPAK 500Y 0.7 0.075 0.24
MELLAPAK 750Y 0.63 0.08 0.23
SULZER BX 1 0.085 0.23
PACKING CY 0.65 0.09 0.22
PACKING KERAPAK 0.8 0.095 0.22
0.1 0.21
0.125 0.19
MELLAPAK 250Y 0.15 0.17
F Factor NTSM 0.175 0.15
0.6 3.2 0.2 0.14
0.7 3.15 0.25 0.125
0.8 3.1 0.3 0.1
0.9 3.05 0.35 0.09
1 3 0.4 0.08
1.2 3 0.5 0.065
1.4 2.9 0.6 0.055
1.6 2.85 0.7 0.045
1.8 2.8 0.8 0.04
2 2.75 0.9 0.036
2.25 2.7 1 0.033
2.5 2.6 1.25 0.025
2.75 2.6 1.5 0.02
3 2.5 1.75 0.0175
3.25 2.4 2 0.0145
3.5 2.2 2.5 0.012
3.75 2 3 0.008
4 1.8 3.5 0.007
4.5 1.3 4 0.0058
5 0.0042
6 0.0032
7 0.0026
8 0.002
9 0.00175
10 0.0015