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SAFETY DATA SHEET

PENTACIP 130
Page: 1
Revision date: 01/06/2015
Revision No: 2

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: PENTACIP 130

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: Detergent for professional use.

1.3. Details of the supplier of the safety data sheet

Company name: CCL Pentasol Limited


Hall Wood Avenue
Haydock
St. Helens
WA11 9WA
UK
Tel: +44 (0) 1942 722000
Fax: +44 (0) 1942 722111
Email: info@cclpentasol.co.uk

1.4. Emergency telephone number

Emergency tel: +44 (0) 1942 722000

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: Skin Corr. 1A: H314; Met. Corr. 1: H290
Most important adverse effects: Causes severe skin burns and eye damage.

2.2. Label elements

Label elements:
Hazard statements: H314: Causes severe skin burns and eye damage.
Signal words: Danger
Hazard pictograms: GHS05: Corrosion

Precautionary statements: P260: Do not breathe dust/fumes/gas/mist/vapours/spray.


P264: Wash with plenty of water and soap thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+330+331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+361+353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse

[cont...]
SAFETY DATA SHEET
PENTACIP 130
Page: 2
skin with water/shower.
P304+340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER/doctor/.
P321: Specific treatment (see instructions on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to hazardous or special waste collection point.

2.3. Other hazards

PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients:

SODIUM HYDROXIDE

EINECS CAS PBT / WEL CLP Classification Percent


215-185-5 1310-73-2 - Skin Corr. 1A: H314 30-50%

Section 4: First aid measures

4.1. Description of first aid measures

Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the
affected skin with running water for 10 minutes or longer if substance is still on skin. Transfer
to hospital if there are burns or symptoms of poisoning.
Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist
examination.
Ingestion: Wash out mouth with water. Do not induce vomiting. Give 1 cup of water to drink every 10
minutes. If unconscious, check for breathing and apply artificial respiration if necessary. If
unconscious and breathing is OK, place in the recovery position. Transfer to hospital as soon
as possible.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. If unconscious
and breathing is OK, place in the recovery position. If conscious, ensure the casualty sits or
lies down. If breathing becomes bubbly, have the casualty sit and provide oxygen if available.
Transfer to hospital as soon as possible.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate.
Eye contact: Corneal burns may occur. May cause permanent damage.
Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding
from the mouth or nose.
[cont...]
SAFETY DATA SHEET
PENTACIP 130
Page: 3
Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may
cause coughing or wheezing.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

4.3. Indication of any immediate medical attention and special treatment needed

Immediate / special treatment: Eye bathing equipment should be available on the premises.

Section 5: Fire-fighting measures

5.1. Extinguishing media

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool
containers.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: Corrosive. In combustion emits toxic fumes.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with
skin and eyes.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions: Notify the police and fire brigade immediately. If outside keep bystanders upwind and away
from danger point. Mark out the contaminated area with signs and prevent access to
unauthorised personnel. Do not attempt to take action without suitable protective clothing -
see section 8 of SDS. Turn leaking containers leak-side up to prevent the escape of liquid.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Clean-up should be dealt with only by qualified personnel familiar with the specific substance.
Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal
by an appropriate method.

6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS.

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do
not handle in a confined space. Avoid the formation or spread of mists in the air.

[cont...]
SAFETY DATA SHEET
PENTACIP 130
Page: 4

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions: Do not store at extreme temperatures. Store in a well ventilated area. Keep container tightly
closed.
Suitable packaging: Must only be kept in original packaging. Polyethylene.

7.3. Specific end use(s)

Section 8: Exposure controls/personal protection

8.1. Control parameters

Hazardous ingredients:

SODIUM HYDROXIDE

Workplace exposure limits: Respirable dust

State 8 hour TWA 15 min. STEL 8 hour TWA 15 min. STEL


UK - 2 mg/m3 - -

DNEL/PNEC Values

DNEL / PNEC No data available.

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area.


Respiratory protection: Respiratory protection not required. Self-contained breathing apparatus must be available in
case of emergency.
Hand protection: Gloves (alkali-resistant).
Eye protection: Tightly fitting safety goggles. Ensure eye bath is to hand.
Skin protection: Alkali resistant protective clothing.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Liquid
Colour: Colourless
Odour: Barely perceptible odour
Solubility in water: Miscible in all proportions
Relative density: 1.38 typical pH: 14.0

9.2. Other information

Other information: No data available.

Section 10: Stability and reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

[cont...]
SAFETY DATA SHEET
PENTACIP 130
Page: 5

10.2. Chemical stability

Chemical stability: Stable under normal conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
Decomposition may occur on exposure to conditions or materials listed below.

10.4. Conditions to avoid

Conditions to avoid: Direct sunlight. Heat.

10.5. Incompatible materials

Materials to avoid: Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

Hazardous ingredients:

SODIUM HYDROXIDE

IPR MUS LD50 40 mg/kg


ORL RBT LDLO 500 mg/kg

Relevant hazards for substance:

Hazard Route Basis


Skin corrosion/irritation DRM Hazardous: calculated
Serious eye damage/irritation OPT Hazardous: calculated

Symptoms / routes of exposure

Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate.
Eye contact: Corneal burns may occur. May cause permanent damage.
Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding
from the mouth or nose.
Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may
cause coughing or wheezing.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

Section 12: Ecological information

12.1. Toxicity

Ecotoxicity values: No data available.

[cont...]
SAFETY DATA SHEET
PENTACIP 130
Page: 6

12.2. Persistence and degradability

Persistence and degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobility in soil

Mobility: Readily absorbed into soil.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Negligible ecotoxicity.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.
Disposal of packaging: Arrange for collection by specialised disposal company.
NB: The user's attention is drawn to the possible existence of regional or national regulations
regarding disposal.

Section 14: Transport information

14.1. UN number

UN number: UN3266

14.2. UN proper shipping name

Shipping name: CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.


(SODIUM HYDROXIDE)

14.3. Transport hazard class(es)

Transport class: 8

14.4. Packing group

Packing group: II

14.5. Environmental hazards

Environmentally hazardous: No Marine pollutant: No

14.6. Special precautions for user

Special precautions: No special precautions.


Tunnel code: E
Transport category: 2

[cont...]
SAFETY DATA SHEET
PENTACIP 130
Page: 7

Section 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.2. Chemical Safety Assessment

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No
453/2010.

Phrases used in s.2 and s.3: H314: Causes severe skin burns and eye damage.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. This company shall not be held liable for any damage resulting
from handling or from contact with the above product.

[final page]
SAFETY DATA SHEET
PENTASAN 451
Page: 1
Revision date: 01/06/2015
Revision No: 2

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: PENTASAN 451

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: Detergent for professional use.

1.3. Details of the supplier of the safety data sheet

Company name: CCL Pentasol Limited


Hall Wood Avenue
Haydock
St. Helens
WA11 9WA
UK
Tel: +44 (0) 1942 722000
Fax: +44 (0) 1942 722111
Email: info@cclpentasol.co.uk

1.4. Emergency telephone number

Emergency tel: +44 (0) 1942 722000

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: Skin Corr. 1A: H314; -: EUH031


Most important adverse effects: Contact with acids liberates toxic gas. Causes severe skin burns and eye damage.

2.2. Label elements

Label elements:
Hazard statements: EUH031: Contact with acids liberates toxic gas.
H314: Causes severe skin burns and eye damage.
Signal words: Danger
Hazard pictograms: GHS05: Corrosion

Precautionary statements: P260: Do not breathe dust/fumes/gas/mist/vapours/spray.


P264: Wash with plenty of water and soap thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+330+331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

[cont...]
SAFETY DATA SHEET
PENTASAN 451
Page: 2
P303+361+353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower.
P304+340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER/doctor/.
P321: Specific treatment (see instructions on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to hazardous or special waste collection point.

2.3. Other hazards

PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients:

SODIUM HYDROXIDE

EINECS CAS PBT / WEL CLP Classification Percent


215-185-5 1310-73-2 - Skin Corr. 1A: H314 1-10%

SODIUM HYPOCHLORITE SOLUTION CL ACTIVE

231-668-3 7681-52-9 - Skin Corr. 1B: H314; Aquatic Acute 1: 1-10%


H400; -: EUH031

Section 4: First aid measures

4.1. Description of first aid measures

Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the
affected skin with running water for 10 minutes or longer if substance is still on skin. Transfer
to hospital if there are burns or symptoms of poisoning.
Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist
examination.
Ingestion: Wash out mouth with water. Do not induce vomiting. Give 1 cup of water to drink every 10
minutes. If unconscious, check for breathing and apply artificial respiration if necessary. If
unconscious and breathing is OK, place in the recovery position. Transfer to hospital as soon
as possible.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. If unconscious
and breathing is OK, place in the recovery position. If conscious, ensure the casualty sits or
lies down. If breathing becomes bubbly, have the casualty sit and provide oxygen if available.
Transfer to hospital as soon as possible.

[cont...]
SAFETY DATA SHEET
PENTASAN 451
Page: 3

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate.
Eye contact: Corneal burns may occur. May cause permanent damage.
Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding
from the mouth or nose.
Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may
cause coughing or wheezing.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

4.3. Indication of any immediate medical attention and special treatment needed

Immediate / special treatment: Eye bathing equipment should be available on the premises.

Section 5: Fire-fighting measures

5.1. Extinguishing media

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool
containers.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: Corrosive. In combustion emits toxic fumes.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with
skin and eyes.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions: Notify the police and fire brigade immediately. If outside keep bystanders upwind and away
from danger point. Mark out the contaminated area with signs and prevent access to
unauthorised personnel. Do not attempt to take action without suitable protective clothing -
see section 8 of SDS. Turn leaking containers leak-side up to prevent the escape of liquid.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Clean-up should be dealt with only by qualified personnel familiar with the specific substance.
Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal
by an appropriate method.

6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS.

[cont...]
SAFETY DATA SHEET
PENTASAN 451
Page: 4

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do
not handle in a confined space. Avoid the formation or spread of mists in the air.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions: Do not store at extreme temperatures. Store in a well ventilated area. Keep container tightly
closed.
Suitable packaging: Must only be kept in original packaging. Polyethylene.

7.3. Specific end use(s)

Section 8: Exposure controls/personal protection

8.1. Control parameters

Hazardous ingredients:

SODIUM HYDROXIDE

Workplace exposure limits: Respirable dust

State 8 hour TWA 15 min. STEL 8 hour TWA 15 min. STEL


UK - 2 mg/m3 - -

DNEL/PNEC Values

DNEL / PNEC No data available.

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area.


Respiratory protection: Respiratory protection not required. Self-contained breathing apparatus must be available in
case of emergency.
Hand protection: Gloves (alkali-resistant).
Eye protection: Tightly fitting safety goggles. Ensure eye bath is to hand.
Skin protection: Alkali resistant protective clothing.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Liquid
Colour: Yellow-green
Odour: Perceptible odour
Solubility in water: Miscible in all proportions
Relative density: 1.142 typical pH: > 12.0

[cont...]
SAFETY DATA SHEET
PENTASAN 451
Page: 5

9.2. Other information

Other information: No data available.

Section 10: Stability and reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
Decomposition may occur on exposure to conditions or materials listed below.

10.4. Conditions to avoid

Conditions to avoid: Direct sunlight. Heat.

10.5. Incompatible materials

Materials to avoid: Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

Hazardous ingredients:

SODIUM HYDROXIDE

IPR MUS LD50 40 mg/kg


ORL RBT LDLO 500 mg/kg

SODIUM HYPOCHLORITE SOLUTION...100% CL ACTIVE

ORL MUS LD50 5800 mg/kg

Relevant hazards for substance:

Hazard Route Basis


Skin corrosion/irritation DRM Hazardous: calculated
Serious eye damage/irritation OPT Hazardous: calculated

Symptoms / routes of exposure

Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate.
Eye contact: Corneal burns may occur. May cause permanent damage.
Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding
from the mouth or nose.
[cont...]
SAFETY DATA SHEET
PENTASAN 451
Page: 6
Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may
cause coughing or wheezing.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

Section 12: Ecological information

12.1. Toxicity

Ecotoxicity values: No data available.

12.2. Persistence and degradability

Persistence and degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobility in soil

Mobility: Readily absorbed into soil.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Negligible ecotoxicity.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.
NB: The user's attention is drawn to the possible existence of regional or national regulations
regarding disposal.

Section 14: Transport information

14.1. UN number

UN number: UN1760

14.2. UN proper shipping name

Shipping name: CORROSIVE LIQUID, N.O.S.


(SODIUM HYDROXIDE; SODIUM HYPOCHLORITE SOLUTION)

14.3. Transport hazard class(es)

Transport class: 8

14.4. Packing group

Packing group: III

[cont...]
SAFETY DATA SHEET
PENTASAN 451
Page: 7

14.5. Environmental hazards

Environmentally hazardous: No Marine pollutant: No

14.6. Special precautions for user

Special precautions: No special precautions.


Tunnel code: E
Transport category: 3

Section 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.2. Chemical Safety Assessment

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No
453/2010.
* indicates text in the SDS which has changed since the last revision.
Phrases used in s.2 and s.3: EUH031: Contact with acids liberates toxic gas.
H314: Causes severe skin burns and eye damage.
H400: Very toxic to aquatic life.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. This company shall not be held liable for any damage resulting
from handling or from contact with the above product.

[final page]
SAFETY DATA SHEET
PENTACID 250
Page: 1
Revision date: 01/06/2015
Revision No: 2

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: PENTACID 250

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: Detergent for professional use.

1.3. Details of the supplier of the safety data sheet

Company name: CCL Pentasol Limited


Hall Wood Avenue
Haydock
St. Helens
WA11 9WA
UK
Tel: +44 (0) 1942 722000
Fax: +44 (0) 1942 722111
Email: info@cclpentasol.co.uk

1.4. Emergency telephone number

Emergency tel: +44 (0) 1942 722000

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: Skin Corr. 1A: H314


Most important adverse effects: Causes severe skin burns and eye damage.

2.2. Label elements

Label elements:
Hazard statements: H314: Causes severe skin burns and eye damage.
Signal words: Danger
Hazard pictograms: GHS05: Corrosion

Precautionary statements: P260: Do not breathe dust/fumes/gas/mist/vapours/spray.


P264: Wash with plenty of water and soap thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+330+331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+361+353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse

[cont...]
SAFETY DATA SHEET
PENTACID 250
Page: 2
skin with water/shower.
P304+340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER/doctor/.
P321: Specific treatment (see instructions on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to hazardous or special waste collection point.

2.3. Other hazards

PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients:

NITRIC ACID

EINECS CAS PBT / WEL CLP Classification Percent


231-714-2 7697-37-2 - Ox. Liq. 3: H272; Skin Corr. 1A: H314 30-50%

ORTHOPHOSPHORIC ACID

231-633-2 7664-38-2 - Skin Corr. 1B: H314 1-10%

Section 4: First aid measures

4.1. Description of first aid measures

Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the
affected skin with running water for 10 minutes or longer if substance is still on skin. Transfer
to hospital if there are burns or symptoms of poisoning.
Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist
examination.
Ingestion: Wash out mouth with water. Do not induce vomiting. Give 1 cup of water to drink every 10
minutes. If unconscious, check for breathing and apply artificial respiration if necessary. If
unconscious and breathing is OK, place in the recovery position. Transfer to hospital as soon
as possible.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. If unconscious
and breathing is OK, place in the recovery position. If conscious, ensure the casualty sits or
lies down. If breathing becomes bubbly, have the casualty sit and provide oxygen if available.
Transfer to hospital as soon as possible.

[cont...]
SAFETY DATA SHEET
PENTACID 250
Page: 3

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate.
Eye contact: Corneal burns may occur. May cause permanent damage.
Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding
from the mouth or nose.
Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may
cause coughing or wheezing.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

4.3. Indication of any immediate medical attention and special treatment needed

Immediate / special treatment: Eye bathing equipment should be available on the premises.

Section 5: Fire-fighting measures

5.1. Extinguishing media

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool
containers.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: Corrosive. In combustion emits toxic fumes.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with
skin and eyes.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions: Notify the police and fire brigade immediately. If outside keep bystanders upwind and away
from danger point. Mark out the contaminated area with signs and prevent access to
unauthorised personnel. Do not attempt to take action without suitable protective clothing -
see section 8 of SDS. Turn leaking containers leak-side up to prevent the escape of liquid.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Clean-up should be dealt with only by qualified personnel familiar with the specific substance.
Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal
by an appropriate method.

6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS.

[cont...]
SAFETY DATA SHEET
PENTACID 250
Page: 4

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do
not handle in a confined space. Avoid the formation or spread of mists in the air.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions: Do not store at extreme temperatures. Store in a well ventilated area. Keep container tightly
closed.
Suitable packaging: Must only be kept in original packaging. Polyethylene.

7.3. Specific end use(s)

Section 8: Exposure controls/personal protection

8.1. Control parameters

Hazardous ingredients:

NITRIC ACID...100%

Workplace exposure limits: Respirable dust

State 8 hour TWA 15 min. STEL 8 hour TWA 15 min. STEL


UK - 2.6 mg/m3 - -

ORTHOPHOSPHORIC ACID...100%

UK 1 mg/m3 2 mg/m3 - -

DNEL/PNEC Values

DNEL / PNEC No data available.

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area.


Respiratory protection: Respiratory protection not required. Self-contained breathing apparatus must be available in
case of emergency.
Hand protection: Gloves (acid resistant).
Eye protection: Tightly fitting safety goggles. Ensure eye bath is to hand.
Skin protection: Acid-resistant protective clothing.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Liquid
Colour: Colourless
Odour: Irritating odour
Solubility in water: Miscible in all proportions
Viscosity: Non-viscous
[cont...]
SAFETY DATA SHEET
PENTACID 250
Page: 5
Relative density: 1.235 typical pH: <2.0

9.2. Other information

Other information: No data available.

Section 10: Stability and reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
Decomposition may occur on exposure to conditions or materials listed below.

10.4. Conditions to avoid

Conditions to avoid: Direct sunlight. Heat.

10.5. Incompatible materials

Materials to avoid: Strong bases. Strong reducing agents.

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

Hazardous ingredients:

ORTHOPHOSPHORIC ACID...100%

ORL RAT LD50 1530 mg/kg

Relevant hazards for substance:

Hazard Route Basis


Skin corrosion/irritation DRM Hazardous: calculated
Serious eye damage/irritation OPT Hazardous: calculated

Symptoms / routes of exposure

Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate.
Eye contact: Corneal burns may occur. May cause permanent damage.
Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding
from the mouth or nose.
Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may
cause coughing or wheezing.

[cont...]
SAFETY DATA SHEET
PENTACID 250
Page: 6
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

Section 12: Ecological information

12.1. Toxicity

Ecotoxicity values: No data available.

12.2. Persistence and degradability

Persistence and degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobility in soil

Mobility: Readily absorbed into soil.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Negligible ecotoxicity.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.
Disposal of packaging: Arrange for collection by specialised disposal company.
NB: The user's attention is drawn to the possible existence of regional or national regulations
regarding disposal.

Section 14: Transport information

14.1. UN number

UN number: UN3264

14.2. UN proper shipping name

Shipping name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.


(NITRIC ACID; ORTHOPHOSPHORIC ACID)

14.3. Transport hazard class(es)

Transport class: 8

14.4. Packing group

Packing group: II

14.5. Environmental hazards

Environmentally hazardous: No Marine pollutant: No

[cont...]
SAFETY DATA SHEET
PENTACID 250
Page: 7

14.6. Special precautions for user

Special precautions: No special precautions.


Tunnel code: E
Transport category: 2

Section 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.2. Chemical Safety Assessment

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No
453/2010.

Phrases used in s.2 and s.3: H272: May intensify fire; oxidiser.
H314: Causes severe skin burns and eye damage.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. This company shall not be held liable for any damage resulting
from handling or from contact with the above product.

[final page]
SAFETY DATA SHEET
PENTASOL BOOSTER
Page: 1
Revision date: 01/06/2015
Revision No: 2

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: PENTASOL BOOSTER


CAS number: 7722-84-1
EINECS number: 231-765-0

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: Detergent for professional use.

1.3. Details of the supplier of the safety data sheet

Company name: CCL Pentasol Limited


Hall Wood Avenue
Haydock
St. Helens
WA11 9WA
UK
Tel: +44 (0) 1942 722000
Fax: +44 (0) 1942 722111
Email: info@cclpentasol.co.uk

1.4. Emergency telephone number

Emergency tel: +44 (0) 1942 722000

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: Acute Tox. 4: H302; STOT SE 3: H335; Eye Dam. 1: H318; Skin Irrit. 2: H315
Most important adverse effects: Harmful if swallowed. Causes skin irritation. Causes serious eye damage. May cause
respiratory irritation.

2.2. Label elements

Label elements:
Hazard statements: H302: Harmful if swallowed.
H315: Causes skin irritation.
H318: Causes serious eye damage.
H335: May cause respiratory irritation.
Signal words: Danger
Hazard pictograms: GHS05: Corrosion
GHS07: Exclamation mark

[cont...]
SAFETY DATA SHEET
PENTASOL BOOSTER
Page: 2
Precautionary statements: P261: Avoid breathing dust/fumes/gas/mist/vapours/spray.
P264: Wash with plenty of water and soap thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER/doctor/.
P302+352: IF ON SKIN: Wash with plenty of water/.
P304+340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER/doctor//if you feel unwell.
P321: Specific treatment (see instructions on this label).
P330: Rinse mouth.
P332+313: If skin irritation occurs: Get medical advice/attention.
P362: Take off contaminated clothing.
P403+233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to hazardous or special waste collection point.

2.3. Other hazards

PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients:

HYDROGEN PEROXIDE SOLUTION

EINECS CAS PBT / WEL CLP Classification Percent


231-765-0 7722-84-1 - Ox. Liq. 1: H271; Acute Tox. 4: H332; 30-50%
Acute Tox. 4: H302; Skin Corr. 1A: H314

Section 4: First aid measures

4.1. Description of first aid measures

Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the
affected skin with running water for 10 minutes or longer if substance is still on skin. Transfer
to hospital if there are burns or symptoms of poisoning.
Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist
examination.
Ingestion: Wash out mouth with water. Do not induce vomiting. Give 1 cup of water to drink every 10
minutes. If unconscious, check for breathing and apply artificial respiration if necessary. If
unconscious and breathing is OK, place in the recovery position. Transfer to hospital as soon
as possible. [cont...]
SAFETY DATA SHEET
PENTASOL BOOSTER
Page: 3
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. If unconscious
and breathing is OK, place in the recovery position. If conscious, ensure the casualty sits or
lies down. If breathing becomes bubbly, have the casualty sit and provide oxygen if available.
Transfer to hospital as soon as possible.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate.
Eye contact: Corneal burns may occur. May cause permanent damage.
Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding
from the mouth or nose.
Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may
cause coughing or wheezing.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

4.3. Indication of any immediate medical attention and special treatment needed

Immediate / special treatment: Eye bathing equipment should be available on the premises.

Section 5: Fire-fighting measures

5.1. Extinguishing media

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool
containers.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: Corrosive. In combustion emits toxic fumes.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with
skin and eyes.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions: Notify the police and fire brigade immediately. If outside keep bystanders upwind and away
from danger point. Mark out the contaminated area with signs and prevent access to
unauthorised personnel. Do not attempt to take action without suitable protective clothing -
see section 8 of SDS. Turn leaking containers leak-side up to prevent the escape of liquid.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Clean-up should be dealt with only by qualified personnel familiar with the specific substance.
Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal
by an appropriate method.

[cont...]
SAFETY DATA SHEET
PENTASOL BOOSTER
Page: 4

6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS.

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do
not handle in a confined space. Avoid the formation or spread of mists in the air.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions: Do not store at extreme temperatures. Store in a well ventilated area. Keep container tightly
closed.
Suitable packaging: Must only be kept in original packaging. Polyethylene.

7.3. Specific end use(s)

Section 8: Exposure controls/personal protection

8.1. Control parameters

Hazardous ingredients:

HYDROGEN PEROXIDE SOLUTION...100%

Workplace exposure limits: Respirable dust

State 8 hour TWA 15 min. STEL 8 hour TWA 15 min. STEL


UK 1.4 mg/m3 2.8 mg/m3 - -

DNEL/PNEC Values

DNEL / PNEC No data available.

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area.


Respiratory protection: Respiratory protection not required. Self-contained breathing apparatus must be available in
case of emergency.
Hand protection: Gloves (acid resistant).
Eye protection: Tightly fitting safety goggles. Ensure eye bath is to hand.
Skin protection: Acid-resistant protective clothing.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Liquid
Colour: Colourless
Odour: Odourless
Solubility in water: Miscible in all proportions

[cont...]
SAFETY DATA SHEET
PENTASOL BOOSTER
Page: 5
Boiling point/range°C: 100 - 120 Vapour pressure: 12 mbar 20ºC
Relative density: 1.13 typical pH: 1

9.2. Other information

Other information: No data available.

Section 10: Stability and reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
Decomposition may occur on exposure to conditions or materials listed below.

10.4. Conditions to avoid

Conditions to avoid: Direct sunlight. Heat.

10.5. Incompatible materials

Materials to avoid: Strong bases. Strong reducing agents.

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

Hazardous ingredients:

HYDROGEN PEROXIDE SOLUTION...100%

ORL MUS LD50 2 gm/kg


ORL RAT LD50 376 mg/kg
SKN RAT LD50 4060 mg/kg

Relevant hazards for substance:

Hazard Route Basis


Acute toxicity (ac. tox. 4) ING Hazardous: calculated
Skin corrosion/irritation DRM Hazardous: calculated
Serious eye damage/irritation OPT Hazardous: calculated
STOT-single exposure INH Hazardous: calculated

[cont...]
SAFETY DATA SHEET
PENTASOL BOOSTER
Page: 6

Symptoms / routes of exposure

Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate.
Eye contact: Corneal burns may occur. May cause permanent damage.
Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding
from the mouth or nose.
Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may
cause coughing or wheezing.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

Section 12: Ecological information

12.1. Toxicity

Ecotoxicity values: No data available.

12.2. Persistence and degradability

Persistence and degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobility in soil

Mobility: Readily absorbed into soil.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Negligible ecotoxicity.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.
Disposal of packaging: Arrange for collection by specialised disposal company.
NB: The user's attention is drawn to the possible existence of regional or national regulations
regarding disposal.

Section 14: Transport information

14.1. UN number

UN number: UN2014

14.2. UN proper shipping name

Shipping name: HYDROGEN PEROXIDE, AQUEOUS SOLUTION

[cont...]
SAFETY DATA SHEET
PENTASOL BOOSTER
Page: 7

14.3. Transport hazard class(es)

Transport class: 5.1 (8)

14.4. Packing group

Packing group: II

14.5. Environmental hazards

Environmentally hazardous: No Marine pollutant: No

14.6. Special precautions for user

Special precautions: No special precautions.


Tunnel code: E
Transport category: 2

Section 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.2. Chemical Safety Assessment

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No
453/2010.

Phrases used in s.2 and s.3: H271: May cause fire or explosion; strong oxidiser.
H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H315: Causes skin irritation.
H318: Causes serious eye damage.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. This company shall not be held liable for any damage resulting
from handling or from contact with the above product.

[final page]
SAFETY DATA SHEET
PENTASOL H15 Page 1
Issued: 21/06/2012
Revision No: 2

1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING

Product name: PENTASOL H15


Use of substance / preparation: Disinfectant for professional use.
Company name: CCL Pentasol Limited
Hall Wood Avenue
Haydock
St. Helens
WA11 9WA
UK
Tel: +44 (0) 1942 722000
Fax: +44 (0) 1942 722111
2. HAZARDS IDENTIFICATION

Main hazards: Contact with acids liberates toxic gas. Causes burns. Very toxic to aquatic organisms.
3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous ingredients: SODIUM HYPOCHLORITE SOLUTION CL ACTIVE 10-30%


EINECS: 231-668-3 CAS: 7681-52-9
[-] R31; [C] R34; [N] R50
4. FIRST AID MEASURES (SYMPTOMS)

Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate.
Eye contact: Corneal burns may occur. May cause permanent damage.
Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding from the mouth or
nose.
Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may cause coughing or
wheezing.
4. FIRST AID MEASURES (ACTION)

Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the affected skin
with running water for 10 minutes or longer if substance is still on skin. Transfer to hospital if there are burns or
symptoms of poisoning.
Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist examination.
Ingestion: Wash out mouth with water. Do not induce vomiting. Give 1 cup of water to drink every 10 minutes. If
unconscious, check for breathing and apply artificial respiration if necessary. If unconscious and breathing is
OK, place in the recovery position. Transfer to hospital as soon as possible.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. If unconscious and breathing is
OK, place in the recovery position. If conscious, ensure the casualty sits or lies down. If breathing becomes
bubbly, have the casualty sit and provide oxygen if available. Transfer to hospital as soon as possible.
5. FIRE-FIGHTING MEASURES

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.
Exposure hazards: Corrosive. In combustion emits toxic fumes.
Protection of fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.
6. ACCIDENTAL RELEASE MEASURES

Personal precautions: Notify the police and fire brigade immediately. If outside keep bystanders upwind and away from danger point.
Mark out the contaminated area with signs and prevent access to unauthorised personnel. Do not attempt to
take action without suitable protective clothing - see section 8 of SDS. Turn leaking containers leak-side up to
prevent the escape of liquid.
Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.
Clean-up procedures: Clean-up should be dealt with only by qualified personnel familiar with the specific substance. Absorb into dry
earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method.
7. HANDLING AND STORAGE

Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do not handle in a
confined space. Avoid the formation or spread of mists in the air.
Storage conditions: Do not store at extreme temperatures. Store in a well ventilated area. Keep container tightly closed.
Suitable packaging: Must only be kept in original packaging. Polyethylene.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering measures: Ensure there is sufficient ventilation of the area.


Respiratory protection: Respiratory protection not required. Self-contained breathing apparatus must be available in case of
emergency.
Hand protection: Gloves (alkali-resistant).
Eye protection: Tightly fitting safety goggles. Ensure eye bath is to hand.
[cont...]
Issued: 21/06/2012 SAFETY DATA SHEET
PENTASOL H15 Page 2

Skin protection: Alkali resistant protective clothing.


9. PHYSICAL AND CHEMICAL PROPERTIES

State: Liquid
Colour: Yellow-green
Odour: Irritating odour
Solubility in water: Miscible in all proportions
Viscosity: Non-viscous
Boiling point/range°C: 107
Melting point/range°C: -25
Relative density: 1.26 typical
pH: >12
10. STABILITY AND REACTIVITY

Stability: Stable under normal conditions.


Conditions to avoid: Direct sunlight. Heat.
Materials to avoid: Strong oxidising agents. Acids.
Haz. decomp. products: In combustion emits toxic fumes.
11. TOXICOLOGICAL INFORMATION

Hazardous ingredients: SODIUM HYPOCHLORITE SOLUTION...100% CL ACTIVE


ORL MUS LD50 5800 mg/kg
Routes of exposure: Refer to section 4 of SDS for routes of exposure and corresponding symptoms.
12. ECOLOGICAL INFORMATION

Mobility: Readily absorbed into soil.


Persistence and degradability: Biodegradable.
Bioaccumulative potential: No bioaccumulation potential.
Other adverse effects: Negligible ecotoxicity.
13. DISPOSAL CONSIDERATIONS

Disposal of packaging: Arrange for collection by specialised disposal company.


NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.
14. TRANSPORT INFORMATION

ADR / RID

UN no: 1791 ADR Class: 8


Packing group: III Classification code: C9
Shipping name: HYPOCHLORITE SOLUTION
Labelling: 8 Hazard ID no: 80

IMDG / IMO

UN no: 1791 Class: 8


Packing group: III EmS: 8-08
Marine pollutant: NO
Labelling: 8
IATA / ICAO

UN no: 1791 Class: 8


Packing group: III
Packing instructions: 809(P&CA); 821(PAO)
Labelling: 8
15. REGULATORY INFORMATION

Hazard symbols: Corrosive.


Dangerous for the environment.

[cont...]
Issued: 21/06/2012 SAFETY DATA SHEET
PENTASOL H15 Page 3

Risk phrases: R31: Contact with acids liberates toxic gas.


R34: Causes burns.
R50: Very toxic to aquatic organisms.
Safety phrases: S7: Keep container tightly closed.
S14: Keep away from acids.
S24/25: Avoid contact with skin and eyes.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28: After contact with skin, wash immediately with plenty of water.
S36/37/39: Wear suitable protective clothing, gloves and eye / face protection.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
S60: This material and its container must be disposed of as hazardous waste.
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.
Precautionary phrases: Warning! Do not use with other products. May release dangerous gases (chlorine).
Note: The regulatory information given above only indicates the principal regulations specifically applicable to the
product described in the safety data sheet. The user's attention is drawn to the possible existence of additional
provisions which complete these regulations. Refer to all applicable national, international and local regulations
or provisions.
16. OTHER INFORMATION

Other information: This safety data sheet is prepared in accordance with Regulation (EC) No 1907/2006.
Risk phrases used in s.3: R31: Contact with acids liberates toxic gas.
R34: Causes burns.
R50: Very toxic to aquatic organisms.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only
as a guide. This company shall not be held liable for any damage resulting from handling or from contact with
the above product.

[final page]
SAFETY DATA SHEET
PENTAFOAM 300
Page: 1
Revision date: 01/06/2015
Revision No: 2

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: PENTAFOAM 300

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: Detergent for professional use.

1.3. Details of the supplier of the safety data sheet

Company name: CCL Pentasol Limited


Hall Wood Avenue
Haydock
St. Helens
WA11 9WA
UK
Tel: +44 (0) 1942 722000
Fax: +44 (0) 1942 722111
Email: info@cclpentasol.co.uk

1.4. Emergency telephone number

Emergency tel: +44 (0) 1942 722000

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: Eye Irrit. 2: H319; Skin Irrit. 2: H315


Most important adverse effects: Causes skin irritation. Causes serious eye irritation.

2.2. Label elements

Label elements:
Hazard statements: H315: Causes skin irritation.
H319: Causes serious eye irritation.
Signal words: Warning
Hazard pictograms: GHS07: Exclamation mark

Precautionary statements: P264: Wash with plenty of water and soap thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+352: IF ON SKIN: Wash with plenty of water/.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove

[cont...]
SAFETY DATA SHEET
PENTAFOAM 300
Page: 2
contact lenses, if present and easy to do. Continue rinsing.
P321: Specific treatment (see instructions on this label).
P332+313: If skin irritation occurs: Get medical advice/attention.
P337+313: If eye irritation persists: Get medical advice/attention.
P362: Take off contaminated clothing.
P501: Dispose of contents/container to hazardous or special waste collection point.

2.3. Other hazards

PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients:

ORTHOPHOSPHORIC ACID

EINECS CAS PBT / WEL CLP Classification Percent


231-633-2 7664-38-2 - Skin Corr. 1B: H314 10-30%

SODIUM ALKYLAMINE DICARBOXYLATE

290-476-8 90170-43-7 - Eye Irrit. 2: H319 1-10%

Section 4: First aid measures

4.1. Description of first aid measures

Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Wash
immediately with plenty of soap and water.
Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor.
Ingestion: Wash out mouth with water. Consult a doctor.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Consult a doctor.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be irritation and redness. The eyes may water profusely.
Ingestion: There may be soreness and redness of the mouth and throat.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Exposure may
cause coughing or wheezing.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

4.3. Indication of any immediate medical attention and special treatment needed

Immediate / special treatment: Eye bathing equipment should be available on the premises.

Section 5: Fire-fighting measures

[cont...]
SAFETY DATA SHEET
PENTAFOAM 300
Page: 3

5.1. Extinguishing media

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool
containers.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: In combustion emits toxic fumes.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with
skin and eyes.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions: Refer to section 8 of SDS for personal protection details. If outside do not approach from
downwind. If outside keep bystanders upwind and away from danger point. Mark out the
contaminated area with signs and prevent access to unauthorised personnel. Turn leaking
containers leak-side up to prevent the escape of liquid.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal
by an appropriate method.

6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS.

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do
not handle in a confined space. Avoid the formation or spread of mists in the air.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions: Do not store at extreme temperatures. Store in a well ventilated area. Keep container tightly
closed.
Suitable packaging: Must only be kept in original packaging. Polyethylene.

7.3. Specific end use(s)

Section 8: Exposure controls/personal protection

8.1. Control parameters

[cont...]
SAFETY DATA SHEET
PENTAFOAM 300
Page: 4

Hazardous ingredients:

ORTHOPHOSPHORIC ACID...100%

Workplace exposure limits: Respirable dust

State 8 hour TWA 15 min. STEL 8 hour TWA 15 min. STEL


UK 1 mg/m3 2 mg/m3 - -

DNEL/PNEC Values

DNEL / PNEC No data available.

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area.


Respiratory protection: Respiratory protection not required. Self-contained breathing apparatus must be available in
case of emergency.
Hand protection: Gloves (acid resistant).
Eye protection: Safety glasses. Ensure eye bath is to hand.
Skin protection: Acid-resistant protective clothing.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Liquid
Colour: Pale yellow
Odour: Barely perceptible odour
Solubility in water: Miscible in all proportions
Viscosity: Non-viscous
Relative density: 1.118 typical pH: < 2.00

9.2. Other information

Other information: No data available.

Section 10: Stability and reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
Decomposition may occur on exposure to conditions or materials listed below.

[cont...]
SAFETY DATA SHEET
PENTAFOAM 300
Page: 5

10.4. Conditions to avoid

Conditions to avoid: Direct sunlight. Heat.

10.5. Incompatible materials

Materials to avoid: Strong reducing agents. Strong bases.

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

Hazardous ingredients:

ORTHOPHOSPHORIC ACID...100%

ORL RAT LD50 1530 mg/kg

SODIUM ALKYLAMINE DICARBOXYLATE

ORAL RAT LD50 >2000 mg/kg

Relevant hazards for substance:

Hazard Route Basis


Skin corrosion/irritation DRM Hazardous: calculated
Serious eye damage/irritation OPT Hazardous: calculated

Symptoms / routes of exposure

Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be irritation and redness. The eyes may water profusely.
Ingestion: There may be soreness and redness of the mouth and throat.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Exposure may
cause coughing or wheezing.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

Section 12: Ecological information

12.1. Toxicity

Hazardous ingredients:

SODIUM ALKYLAMINE DICARBOXYLATE

RAINBOW TROUT (Oncorhynchus mykiss) 48H EC50 10.7 mg/l

12.2. Persistence and degradability

Persistence and degradability: Biodegradable.

[cont...]
SAFETY DATA SHEET
PENTAFOAM 300
Page: 6

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobility in soil

Mobility: Readily absorbed into soil.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Negligible ecotoxicity.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.
Disposal of packaging: Arrange for collection by specialised disposal company.
NB: The user's attention is drawn to the possible existence of regional or national regulations
regarding disposal.

Section 14: Transport information

14.1. UN number

UN number: UN3264

14.2. UN proper shipping name

Shipping name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.


(ORTHOPHOSPHORIC ACID)

14.3. Transport hazard class(es)

Transport class: 8

14.4. Packing group

Packing group: III

14.5. Environmental hazards

Environmentally hazardous: No Marine pollutant: No

14.6. Special precautions for user

Special precautions: No special precautions.


Tunnel code: E
Transport category: 3

Section 15: Regulatory information

[cont...]
SAFETY DATA SHEET
PENTAFOAM 300
Page: 7

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.2. Chemical Safety Assessment

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No
453/2010.

Phrases used in s.2 and s.3: H314: Causes severe skin burns and eye damage.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. This company shall not be held liable for any damage resulting
from handling or from contact with the above product.

[final page]
SAFETY DATA SHEET
PENTASOL AM3 PLUS
Page: 1
Revision date: 01/06/2015
Revision No: 2

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: PENTASOL AM3 PLUS

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.3. Details of the supplier of the safety data sheet

Company name: CCL Pentasol Limited


Hall Wood Avenue
Haydock
St. Helens
WA11 9WA
UK
Tel: +44 (0) 1942 722000
Fax: +44 (0) 1942 722111
Email: info@cclpentasol.co.uk

1.4. Emergency telephone number

Emergency tel: +44 (0) 1942 722000

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: Eye Dam. 1: H318; Skin Irrit. 2: H315


Most important adverse effects: Causes skin irritation. Causes serious eye damage.

2.2. Label elements

Label elements:
Hazard statements: H315: Causes skin irritation.
H318: Causes serious eye damage.
Signal words: Danger
Hazard pictograms: GHS05: Corrosion

Precautionary statements: P264: Wash with plenty of water and soap thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+352: IF ON SKIN: Wash with plenty of water/.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.

[cont...]
SAFETY DATA SHEET
PENTASOL AM3 PLUS
Page: 2
P310: Immediately call a POISON CENTER/doctor/.
P321: Specific treatment (see instructions on this label).
P332+313: If skin irritation occurs: Get medical advice/attention.
P362: Take off contaminated clothing.
P501: Dispose of contents/container to hazardous or special waste collection point.

2.3. Other hazards

PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients:

N-(3-AMINOPROPYL)-N-DODECYLPROPANE-1,3-DIAMINE

EINECS CAS PBT / WEL CLP Classification Percent


219-145-8 2372-82-9 - Acute Tox. 3: H301; Skin Corr. 1B: H314; 1-10%
STOT RE 2: H373; Aquatic Acute 1:
H400

ALCOHOLS, C13-15-BRANCHED AND LINEAR, ETHOXYLATED

- - - Acute Tox. 4: H302; Eye Dam. 1: H318 1-10%

Section 4: First aid measures

4.1. Description of first aid measures

Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Wash
immediately with plenty of soap and water.
Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist
examination.
Ingestion: Wash out mouth with water. Do not induce vomiting. If conscious, give half a litre of water to
drink immediately. Consult a doctor.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be pain and redness. The eyes may water profusely. There may be severe pain.
The vision may become blurred. May cause permanent damage.
Ingestion: There may be soreness and redness of the mouth and throat. Nausea and stomach pain
may occur.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

[cont...]
SAFETY DATA SHEET
PENTASOL AM3 PLUS
Page: 3

4.3. Indication of any immediate medical attention and special treatment needed

Immediate / special treatment: Eye bathing equipment should be available on the premises.

Section 5: Fire-fighting measures

5.1. Extinguishing media

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool
containers.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: In combustion emits toxic fumes.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with
skin and eyes.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions: Mark out the contaminated area with signs and prevent access to unauthorised personnel.
Do not attempt to take action without suitable protective clothing - see section 8 of SDS. Turn
leaking containers leak-side up to prevent the escape of liquid.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal
by an appropriate method.

6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS.

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area.
Avoid the formation or spread of mists in the air.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions: Do not store at extreme temperatures. Store in a well ventilated area. Keep container tightly
closed.
Suitable packaging: Must only be kept in original packaging. Polyethylene.

7.3. Specific end use(s)

[cont...]
SAFETY DATA SHEET
PENTASOL AM3 PLUS
Page: 4

Section 8: Exposure controls/personal protection

8.1. Control parameters

Workplace exposure limits: No data available.

DNEL/PNEC Values

DNEL / PNEC No data available.

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area.


Respiratory protection: Respiratory protection not required. Self-contained breathing apparatus must be available in
case of emergency.
Hand protection: Gloves (alkali-resistant).
Eye protection: Tightly fitting safety goggles. Ensure eye bath is to hand.
Skin protection: Alkali resistant protective clothing.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Liquid
Colour: Blue
Odour: Barely perceptible odour
Solubility in water: Miscible in all proportions
Relative density: 1.007 typical pH: 9.0-9.5

9.2. Other information

Other information: No data available.

Section 10: Stability and reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
Decomposition may occur on exposure to conditions or materials listed below.

10.4. Conditions to avoid

Conditions to avoid: Direct sunlight. Heat.

10.5. Incompatible materials

Materials to avoid: Strong oxidising agents. Strong acids.

[cont...]
SAFETY DATA SHEET
PENTASOL AM3 PLUS
Page: 5

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

Hazardous ingredients:

N-(3-AMINOPROPYL)-N-DODECYLPROPANE-1,3-DIAMINE

ORL RAT LD50 50-300 mg/kg


SKN RAT LD50 >2000 mg/kg

ALCOHOLS, C13-15-BRANCHED AND LINEAR, ETHOXYLATED

ORL RAT LD50 >2000 mg/kg

Relevant hazards for substance:

Hazard Route Basis


Skin corrosion/irritation DRM Hazardous: calculated
Serious eye damage/irritation OPT Hazardous: calculated

Symptoms / routes of exposure

Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be pain and redness. The eyes may water profusely. There may be severe pain.
The vision may become blurred. May cause permanent damage.
Ingestion: There may be soreness and redness of the mouth and throat. Nausea and stomach pain
may occur.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

Section 12: Ecological information

12.1. Toxicity

Hazardous ingredients:

N-(3-AMINOPROPYL)-N-DODECYLPROPANE-1,3-DIAMINE

DAPHNIA 48H EC50 0.1-1 mg/l


FISH 96H LC50 0.1-1 mg/l

ALCOHOLS, C13-15-BRANCHED AND LINEAR, ETHOXYLATED

Activated sludge 48H EC50 >1000 mg/l

[cont...]
SAFETY DATA SHEET
PENTASOL AM3 PLUS
Page: 6

ZEBRAFISH (Brachydanio rerio) 96H LC50 1-10 mg/l


Daphnia magna 48H EC50 1-10 mg/l
SCENEDESMUS SUBSPICA 72H IC50 1-10 mg/l

12.2. Persistence and degradability

Persistence and degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobility in soil

Mobility: Readily absorbed into soil.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Negligible ecotoxicity.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.
NB: The user's attention is drawn to the possible existence of regional or national regulations
regarding disposal.

Section 14: Transport information

Transport class: This product does not require a classification for transport.

Section 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.2. Chemical Safety Assessment

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No
453/2010.
* indicates text in the SDS which has changed since the last revision.
Phrases used in s.2 and s.3: H301: Toxic if swallowed.
H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H315: Causes skin irritation.
H318: Causes serious eye damage.

[cont...]
SAFETY DATA SHEET
PENTASOL AM3 PLUS
Page: 7
H373: May cause damage to organs <or state all organs affected, if known> through
prolonged or repeated exposure <state route of exposure if it is conclusively proven that no
other routes of exposure cause the hazard>.
H400: Very toxic to aquatic life.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. This company shall not be held liable for any damage resulting
from handling or from contact with the above product.

[final page]
SAFETY DATA SHEET
PENTALK 579
Page: 1
Revision date: 01/06/2015
Revision No: 2

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: PENTALK 579

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: Detergent for professional use.

1.3. Details of the supplier of the safety data sheet

Company name: CCL Pentasol Limited


Hall Wood Avenue
Haydock
St. Helens
WA11 9WA
UK
Tel: +44 (0) 1942 722000
Fax: +44 (0) 1942 722111
Email: info@cclpentasol.co.uk

1.4. Emergency telephone number

Emergency tel: +44 (0) 1942 722000

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: Eye Dam. 1: H318; Skin Irrit. 2: H315


Most important adverse effects: Causes skin irritation. Causes serious eye damage.

2.2. Label elements

Label elements:
Hazard statements: H315: Causes skin irritation.
H318: Causes serious eye damage.
Signal words: Danger
Hazard pictograms: GHS05: Corrosion

Precautionary statements: P264: Wash with plenty of water and soap thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+352: IF ON SKIN: Wash with plenty of water/.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove

[cont...]
SAFETY DATA SHEET
PENTALK 579
Page: 2
contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER/doctor/.
P332+313: If skin irritation occurs: Get medical.
P362: Take off contaminated clothing.
P501: Dispose of contents/container to hazardous or special waste collection point.

2.3. Other hazards

PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients:

2-(2-BUTOXYETHOXY)ETHANOL

EINECS CAS PBT / WEL CLP Classification Percent


203-961-6 112-34-5 - Eye Irrit. 2: H319 1-10%

TRISODIUM NITRILOTRIACETATE

225-768-6 5064-31-3 - Carc. 2: H351; Acute Tox. 4: H302; Eye 1-10%


Irrit. 2: H319

TETRASODIUM ETHYLENE DIAMINE TETRAACETATE

200-573-9 64-02-8 - Acute Tox. 4: H302; Eye Dam. 1: H318 1-10%

ALCOHOLS, C13-15-BRANCHED AND LINEAR, ETHOXYLATED

- - - Acute Tox. 4: H302; Eye Dam. 1: H318 1-10%

SODIUM HYDROXIDE

215-185-5 1310-73-2 - Skin Corr. 1A: H314 <1%

Section 4: First aid measures

4.1. Description of first aid measures

Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Wash
immediately with plenty of soap and water.
Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist
examination.
Ingestion: Wash out mouth with water. Do not induce vomiting. If conscious, give half a litre of water to
drink immediately. Consult a doctor.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be pain and redness. The eyes may water profusely. There may be severe pain.
The vision may become blurred. May cause permanent damage.

[cont...]
SAFETY DATA SHEET
PENTALK 579
Page: 3
Ingestion: There may be soreness and redness of the mouth and throat. Nausea and stomach pain
may occur.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

4.3. Indication of any immediate medical attention and special treatment needed

Immediate / special treatment: Eye bathing equipment should be available on the premises.

Section 5: Fire-fighting measures

5.1. Extinguishing media

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool
containers.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: In combustion emits toxic fumes.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with
skin and eyes.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions: Mark out the contaminated area with signs and prevent access to unauthorised personnel.
Do not attempt to take action without suitable protective clothing - see section 8 of SDS. Turn
leaking containers leak-side up to prevent the escape of liquid.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal
by an appropriate method.

6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS.

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area.
Avoid the formation or spread of mists in the air.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions: Do not store at extreme temperatures. Store in a well ventilated area. Keep container tightly
closed.

[cont...]
SAFETY DATA SHEET
PENTALK 579
Page: 4

7.3. Specific end use(s)

Section 8: Exposure controls/personal protection

8.1. Control parameters

Hazardous ingredients:

2-(2-BUTOXYETHOXY)ETHANOL

Workplace exposure limits: Respirable dust

State 8 hour TWA 15 min. STEL 8 hour TWA 15 min. STEL


UK 67.5 mg/m3 101.2 mg/m3 - -

SODIUM HYDROXIDE

UK - 2 mg/m3 - -

DNEL/PNEC Values

DNEL / PNEC No data available.

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area.


Respiratory protection: Respiratory protection not required. Self-contained breathing apparatus must be available in
case of emergency.
Hand protection: Gloves (alkali-resistant).
Eye protection: Tightly fitting safety goggles. Ensure eye bath is to hand.
Skin protection: Alkali resistant protective clothing.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Liquid
Colour: Colourless
Odour: Barely perceptible odour
Solubility in water: Miscible in all proportions
Relative density: 1.05 typical pH: > 11.0

9.2. Other information

Other information: No data available.

Section 10: Stability and reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions.

[cont...]
SAFETY DATA SHEET
PENTALK 579
Page: 5

10.3. Possibility of hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
Decomposition may occur on exposure to conditions or materials listed below.

10.4. Conditions to avoid

Conditions to avoid: Direct sunlight. Heat.

10.5. Incompatible materials

Materials to avoid: Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

Hazardous ingredients:

2-(2-BUTOXYETHOXY)ETHANOL

ORL MUS LD50 6050 mg/kg


ORL RAT LD50 4500 mg/kg

ALCOHOLS, C13-15-BRANCHED AND LINEAR, ETHOXYLATED

ORL RAT LD50 >2000 mg/kg

SODIUM HYDROXIDE

IPR MUS LD50 40 mg/kg


ORL RBT LDLO 500 mg/kg

Relevant hazards for substance:

Hazard Route Basis


Skin corrosion/irritation DRM Hazardous: calculated
Serious eye damage/irritation OPT Hazardous: calculated

Symptoms / routes of exposure

Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be pain and redness. The eyes may water profusely. There may be severe pain.
The vision may become blurred. May cause permanent damage.
Ingestion: There may be soreness and redness of the mouth and throat. Nausea and stomach pain
may occur.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

[cont...]
SAFETY DATA SHEET
PENTALK 579
Page: 6

Section 12: Ecological information

12.1. Toxicity

Hazardous ingredients:

TRISODIUM NITRILOTRIACETATE

- 72H IC50 > 100 -


- 48H EC50 > 100 -
- 96H LC50 > 100 -

ALCOHOLS, C13-15-BRANCHED AND LINEAR, ETHOXYLATED

Activated sludge 48H EC50 >1000 mg/l


ZEBRAFISH (Brachydanio rerio) 96H LC50 1-10 mg/l
Daphnia magna 48H EC50 1-10 mg/l
SCENEDESMUS SUBSPICA 72H IC50 1-10 mg/l

12.2. Persistence and degradability

Persistence and degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobility in soil

Mobility: Readily absorbed into soil.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Negligible ecotoxicity.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.
NB: The user's attention is drawn to the possible existence of regional or national regulations
regarding disposal.

Section 14: Transport information

Transport class: This product does not require a classification for transport.

Section 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

[cont...]
SAFETY DATA SHEET
PENTALK 579
Page: 7

15.2. Chemical Safety Assessment

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No
453/2010.
* indicates text in the SDS which has changed since the last revision.
Phrases used in s.2 and s.3: H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H315: Causes skin irritation.
H318: Causes serious eye damage.
H319: Causes serious eye irritation.
H351: Suspected of causing cancer <state route of exposure if it is conclusively proven that
no other routes of exposure cause the hazard>.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. This company shall not be held liable for any damage resulting
from handling or from contact with the above product.

[final page]
SAFETY DATA SHEET
PEROSAN 5
Page: 1
Revision date: 01/06/2015
Revision No: 6

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: PEROSAN 5


CAS number: 79-21-0
EINECS number: 201-186-8

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: Disinfectant for professional use.

1.3. Details of the supplier of the safety data sheet

Company name: CCL Pentasol Limited


Hall Wood Avenue
Haydock
St. Helens
WA11 9WA
UK
Tel: +44 (0) 1942 722000
Fax: +44 (0) 1942 722111
Email: info@cclpentasol.co.uk

1.4. Emergency telephone number

Emergency tel: +44 (0) 1942 722000

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: Org. Perox. EF: H242; Met. Corr. 1: H290; Acute Tox. 4: H302; Skin Corr. 1A: H314; Eye Dam.
1: H318; STOT SE 3: H335; Aquatic Chronic 1: H410; Acute Tox. 4: H312; Acute Tox. 4: H332;
-: EUH071
Most important adverse effects: Heating may cause a fire. May be corrosive to metals. Harmful if swallowed. Harmful in
contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage.
Harmful if inhaled. May cause respiratory irritation. Very toxic to aquatic life with long lasting
effects. Corrosive to the respiratory tract.

2.2. Label elements

Label elements:
Hazard statements: H242: Heating may cause a fire.
H290: May be corrosive to metals.
H302: Harmful if swallowed.
H312: Harmful in contact with skin.

[cont...]
SAFETY DATA SHEET
PEROSAN 5
Page: 2
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
H410: Very toxic to aquatic life with long lasting effects.
EUH071: Corrosive to the respiratory tract.
Signal words: Danger
Hazard pictograms: GHS02: Flame
GHS05: Corrosion
GHS07: Exclamation mark
GHS09: Environmental

Precautionary statements: P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.
No smoking.
P234: Keep only in original container.
P260: Do not breathe dust/fumes/gas/mist/vapours/spray.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+352: IF ON SKIN: Wash with plenty of water/soap.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P307+311: IF exposed or concerned: Call a POISON CENTER/doctor/.
P501: Dispose of contents/container to hazardous or special waste collection point.

2.3. Other hazards

PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients:

HYDROGEN PEROXIDE SOLUTION

EINECS CAS PBT / WEL CLP Classification Percent


231-765-0 7722-84-1 - Ox. Liq. 1: H271; Acute Tox. 4: H332; 10-30%
Acute Tox. 4: H302; Skin Corr. 1A: H314

[cont...]
SAFETY DATA SHEET
PEROSAN 5
Page: 3

ACETIC ACID

200-580-7 64-19-7 - Flam. Liq. 3: H226; Skin Corr. 1A: H314 1-10%

PERACETIC ACID

201-186-8 79-21-0 - Flam. Liq. 3: H226; Org. Perox. CD: 1-10%


H242; Acute Tox. 4: H332; Acute Tox. 4:
H312; Acute Tox. 4: H302; Skin Corr. 1A:
H314; Aquatic Acute 1: H400

Section 4: First aid measures

4.1. Description of first aid measures

Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the
affected skin with running water for 10 minutes or longer if substance is still on skin. Transfer
to hospital if there are burns or symptoms of poisoning.
Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist
examination.
Ingestion: Wash out mouth with water. Do not induce vomiting. Give 1 cup of water to drink every 10
minutes. If unconscious, check for breathing and apply artificial respiration if necessary. If
unconscious and breathing is OK, place in the recovery position. Transfer to hospital as soon
as possible.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. If unconscious
and breathing is OK, place in the recovery position. If conscious, ensure the casualty sits or
lies down. If breathing becomes bubbly, have the casualty sit and provide oxygen if available.
Transfer to hospital as soon as possible.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate.
Eye contact: Corneal burns may occur. May cause permanent damage.
Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding
from the mouth or nose.
Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may
cause coughing or wheezing.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

4.3. Indication of any immediate medical attention and special treatment needed

Immediate / special treatment: Eye bathing equipment should be available on the premises.

Section 5: Fire-fighting measures

5.1. Extinguishing media

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool
containers.

[cont...]
SAFETY DATA SHEET
PEROSAN 5
Page: 4

5.2. Special hazards arising from the substance or mixture

Exposure hazards: Corrosive. In combustion emits toxic fumes.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with
skin and eyes.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions: Notify the police and fire brigade immediately. If outside keep bystanders upwind and away
from danger point. Mark out the contaminated area with signs and prevent access to
unauthorised personnel. Do not attempt to take action without suitable protective clothing -
see section 8 of SDS. Turn leaking containers leak-side up to prevent the escape of liquid.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Clean-up should be dealt with only by qualified personnel familiar with the specific substance.
Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal
by an appropriate method.

6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS.

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do
not handle in a confined space. Avoid the formation or spread of mists in the air.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions: Do not store at extreme temperatures. Store in a well ventilated area. Keep container tightly
closed.
Suitable packaging: Must only be kept in original packaging. Polyethylene.

7.3. Specific end use(s)

Section 8: Exposure controls/personal protection

8.1. Control parameters

[cont...]
SAFETY DATA SHEET
PEROSAN 5
Page: 5

Hazardous ingredients:

HYDROGEN PEROXIDE SOLUTION...100%

Workplace exposure limits: Respirable dust

State 8 hour TWA 15 min. STEL 8 hour TWA 15 min. STEL


UK 1.4 mg/m3 2.8 mg/m3 - -

DNEL/PNEC Values

DNEL / PNEC No data available.

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area.


Respiratory protection: Gas/vapour filter, type A: organic vapours (EN141). Self-contained breathing apparatus must
be available in case of emergency.
Hand protection: Gloves (acid resistant).
Eye protection: Tightly fitting safety goggles. Ensure eye bath is to hand.
Skin protection: Acid-resistant protective clothing.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Liquid
Colour: Colourless
Odour: Pungent
Oxidising: Oxidising (by EC criteria)
Solubility in water: Miscible in all proportions
Relative density: 1.12 typical pH: ~2.0

9.2. Other information

Other information: No data available.

Section 10: Stability and reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
Decomposition may occur on exposure to conditions or materials listed below.

[cont...]
SAFETY DATA SHEET
PEROSAN 5
Page: 6

10.4. Conditions to avoid

Conditions to avoid: Direct sunlight. Heat.

10.5. Incompatible materials

Materials to avoid: Bases. Metals. Oxidising agents. Reducing agents. Strong acids. Strong bases. Alkali
metals. Alkali earth metals. Aluminium. Sodium. Potassium. Magnesium. Zinc. Copper.
Nickel. Organic materials. Lead

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

Hazardous ingredients:

HYDROGEN PEROXIDE SOLUTION...100%

ORL MUS LD50 2 gm/kg


ORL RAT LD50 376 mg/kg
SKN RAT LD50 4060 mg/kg

ACETIC ACID...100%

IVN MUS LD50 525 mg/kg


ORL RAT LD50 3310 mg/kg

PERACETIC ACID...100%

IVN MUS LD50 17860 µg/kg


ORL MUS LD50 210 mg/kg
ORL RAT LD50 1540 µl/kg

Relevant hazards for substance:

Hazard Route Basis


Acute toxicity (ac. tox. 4) INH DRM ING Hazardous: calculated
Skin corrosion/irritation DRM Hazardous: calculated
Serious eye damage/irritation OPT Hazardous: calculated
STOT-single exposure INH Hazardous: calculated

Symptoms / routes of exposure

Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate.
Eye contact: Corneal burns may occur. May cause permanent damage.
Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding
from the mouth or nose.
Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may
cause coughing or wheezing. [cont...]
SAFETY DATA SHEET
PEROSAN 5
Page: 7
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

Section 12: Ecological information

12.1. Toxicity

Ecotoxicity values:

Species Test Value Units


Oncorhynchus mykiss NOEC <10 mg/l
Oncorhynchus mykiss 96H LC50 13 mg/l
Daphnia magna 48H NOEC 1 mg/l
Daphnia magna 48H EC50 3.3 mg/l
Pseudomonas aerugino EC100 9.9 mg/l
Selenastrum capricor 120H IC50 0.18 mg/l

12.2. Persistence and degradability

Persistence and degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobility in soil

Mobility: Readily absorbed into soil.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Negligible ecotoxicity.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.
Disposal of packaging: Arrange for collection by specialised disposal company.
NB: The user's attention is drawn to the possible existence of regional or national regulations
regarding disposal.

Section 14: Transport information

14.1. UN number

UN number: UN3149

14.2. UN proper shipping name

Shipping name: HYDROGEN PEROXIDE AND PEROXYACETIC ACID MIXTURE, STABILIZED


(PEROXY ACETIC ACID)

[cont...]
SAFETY DATA SHEET
PEROSAN 5
Page: 8

14.3. Transport hazard class(es)

Transport class: 5.1 (8)

14.4. Packing group

Packing group: II

14.5. Environmental hazards

Environmentally hazardous: No Marine pollutant: No

14.6. Special precautions for user

Special precautions: No special precautions.


Tunnel code: E
Transport category: 2

Section 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.2. Chemical Safety Assessment

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No
453/2010.

Phrases used in s.2 and s.3: EUH071: Corrosive to the respiratory tract.
H226: Flammable liquid and vapour.
H242: Heating may cause a fire.
H271: May cause fire or explosion; strong oxidiser.
H290: May be corrosive to metals.
H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
H400: Very toxic to aquatic life.
H410: Very toxic to aquatic life with long lasting effects.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. This company shall not be held liable for any damage resulting
from handling or from contact with the above product.

[final page]
SAFETY DATA SHEET
TFC 4
Page: 1
Revision date: 01/06/2015
Revision No: 6

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: TFC 4

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: Detergent for professional use.

1.3. Details of the supplier of the safety data sheet

Company name: CCL Pentasol Limited


Hall Wood Avenue
Haydock
St. Helens
WA11 9WA
UK
Tel: +44 (0) 1942 722000
Fax: +44 (0) 1942 722111
Email: info@cclpentasol.co.uk

1.4. Emergency telephone number

Emergency tel: +44 (0) 1942 722000

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: Skin Corr. 1A: H314; Aquatic Acute 1: H400; -: EUH031
Most important adverse effects: Contact with acids liberates toxic gas. Causes severe skin burns and eye damage. Very toxic
to aquatic life.

2.2. Label elements

Label elements:
Hazard statements: EUH031: Contact with acids liberates toxic gas.
H314: Causes severe skin burns and eye damage.
H400: Very toxic to aquatic life.
Signal words: Danger
Hazard pictograms: GHS05: Corrosion
GHS09: Environmental

Precautionary statements: P260: Do not breathe dust/fumes/gas/mist/vapours/spray.

[cont...]
SAFETY DATA SHEET
TFC 4
Page: 2
P321: Specific treatment (see instructions on this label).
P264: Wash with plenty of water and soap thoroughly after handling.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+330+331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+361+353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower.
P304+340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER/doctor/.
P363: Wash contaminated clothing before reuse.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container to hazardous or special waste collection point.

2.3. Other hazards

PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients:

SODIUM HYDROXIDE

EINECS CAS PBT / WEL CLP Classification Percent


215-185-5 1310-73-2 - Skin Corr. 1A: H314 1-10%

SODIUM HYPOCHLORITE SOLUTION CL ACTIVE

231-668-3 7681-52-9 - Skin Corr. 1B: H314; Aquatic Acute 1: 1-10%


H400; -: EUH031

SODIUM XYLENE SULPHONATE

- 1300-72-7 - Eye Irrit. 2: H319 1-10%

N,N-DIMETHYLTETRADECYLAMINE N-OXIDE

- 3332-27-2 - Acute Tox. 4: H302; Skin Irrit. 2: H315; 1-10%


Eye Dam. 1: H318; Aquatic Acute 1:
H400

ALKYL C9-C13 SULPHATE, SODIUM SALT

- 72906-11-7 - Eye Dam. 1: H318; Skin Irrit. 2: H315 1-10%

Section 4: First aid measures

[cont...]
SAFETY DATA SHEET
TFC 4
Page: 3

4.1. Description of first aid measures

Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the
affected skin with running water for 10 minutes or longer if substance is still on skin. Transfer
to hospital if there are burns or symptoms of poisoning.
Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist
examination.
Ingestion: Wash out mouth with water. Do not induce vomiting. Give 1 cup of water to drink every 10
minutes. If unconscious, check for breathing and apply artificial respiration if necessary. If
unconscious and breathing is OK, place in the recovery position. Transfer to hospital as soon
as possible.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. If unconscious
and breathing is OK, place in the recovery position. If conscious, ensure the casualty sits or
lies down. If breathing becomes bubbly, have the casualty sit and provide oxygen if available.
Transfer to hospital as soon as possible.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate.
Eye contact: Corneal burns may occur. May cause permanent damage.
Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding
from the mouth or nose.
Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may
cause coughing or wheezing.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

4.3. Indication of any immediate medical attention and special treatment needed

Immediate / special treatment: Eye bathing equipment should be available on the premises.

Section 5: Fire-fighting measures

5.1. Extinguishing media

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool
containers.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: Corrosive. In combustion emits toxic fumes.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with
skin and eyes.

Section 6: Accidental release measures

[cont...]
SAFETY DATA SHEET
TFC 4
Page: 4

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions: Notify the police and fire brigade immediately. If outside keep bystanders upwind and away
from danger point. Mark out the contaminated area with signs and prevent access to
unauthorised personnel. Do not attempt to take action without suitable protective clothing -
see section 8 of SDS. Turn leaking containers leak-side up to prevent the escape of liquid.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Clean-up should be dealt with only by qualified personnel familiar with the specific substance.
Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal
by an appropriate method.

6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS.

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do
not handle in a confined space. Avoid the formation or spread of mists in the air.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions: Do not store at extreme temperatures. Store in a well ventilated area. Keep container tightly
closed.
Suitable packaging: Must only be kept in original packaging. Polyethylene.

7.3. Specific end use(s)

Section 8: Exposure controls/personal protection

8.1. Control parameters

Hazardous ingredients:

SODIUM HYDROXIDE

Workplace exposure limits: Respirable dust

State 8 hour TWA 15 min. STEL 8 hour TWA 15 min. STEL


UK - 2 mg/m3 - -

DNEL/PNEC Values

DNEL / PNEC No data available.

[cont...]
SAFETY DATA SHEET
TFC 4
Page: 5

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area.


Respiratory protection: Respiratory protection not required. Self-contained breathing apparatus must be available in
case of emergency.
Hand protection: Gloves (alkali-resistant).
Eye protection: Tightly fitting safety goggles. Ensure eye bath is to hand.
Skin protection: Alkali resistant protective clothing.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Liquid
Colour: Yellow-green
Odour: Characteristic odour
Solubility in water: Miscible in all proportions
Viscosity: Non-viscous
Relative density: 1.18 typical pH: >13

9.2. Other information

Other information: No data available.

Section 10: Stability and reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
Decomposition may occur on exposure to conditions or materials listed below.

10.4. Conditions to avoid

Conditions to avoid: Direct sunlight. Heat.

10.5. Incompatible materials

Materials to avoid: Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

[cont...]
SAFETY DATA SHEET
TFC 4
Page: 6

11.1. Information on toxicological effects

Hazardous ingredients:

SODIUM HYDROXIDE

IPR MUS LD50 40 mg/kg


ORL RBT LDLO 500 mg/kg

SODIUM HYPOCHLORITE SOLUTION...100% CL ACTIVE

ORL MUS LD50 5800 mg/kg

SODIUM XYLENE SULPHONATE

DERMAL RBT LD50 2000 mg/kg


ORAL RAT LD50 7200 mg/kg

N,N-DIMETHYLTETRADECYLAMINE N-OXIDE

ORL RAT LD50 1064 mg/kg

Relevant hazards for substance:

Hazard Route Basis


Skin corrosion/irritation DRM Hazardous: calculated
Serious eye damage/irritation OPT Hazardous: calculated

Symptoms / routes of exposure

Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate.
Eye contact: Corneal burns may occur. May cause permanent damage.
Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding
from the mouth or nose.
Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may
cause coughing or wheezing.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

Section 12: Ecological information

12.1. Toxicity

Hazardous ingredients:

SODIUM XYLENE SULPHONATE

ALGAE 96H LC50 230 mg/l


DAPHNIA 48H EC50 1000 mg/l

[cont...]
SAFETY DATA SHEET
TFC 4
Page: 7

FISH 96H LC50 1000 mg/l

N,N-DIMETHYLTETRADECYLAMINE N-OXIDE

ALGAE 72H EC50 0.19 mg/l


BACTERIA 24H EC10 80 mg/l
Daphnia magna 48H IC50 3.1 mg/l
FISH 96H LC50 2.67 mg/l

12.2. Persistence and degradability

Persistence and degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobility in soil

Mobility: Readily absorbed into soil.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Negligible ecotoxicity.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.
Disposal of packaging: Arrange for collection by specialised disposal company.
NB: The user's attention is drawn to the possible existence of regional or national regulations
regarding disposal.

Section 14: Transport information

14.1. UN number

UN number: UN1719

14.2. UN proper shipping name

Shipping name: CAUSTIC ALKALI LIQUID, N.O.S.


(SODIUM HYDROXIDE; SODIUM HYPOCHLORITE SOLUTION)

14.3. Transport hazard class(es)

Transport class: 8

14.4. Packing group

Packing group: III

[cont...]
SAFETY DATA SHEET
TFC 4
Page: 8

14.5. Environmental hazards

Environmentally hazardous: Yes Marine pollutant: No

14.6. Special precautions for user

Special precautions: No special precautions.


Tunnel code: E
Transport category: 3

Section 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.2. Chemical Safety Assessment

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No
453/2010.

Phrases used in s.2 and s.3: EUH031: Contact with acids liberates toxic gas.
H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H315: Causes skin irritation.
H318: Causes serious eye damage.
H319: Causes serious eye irritation.
H400: Very toxic to aquatic life.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. This company shall not be held liable for any damage resulting
from handling or from contact with the above product.

[final page]
SAFETY DATA SHEET
PHOSPHORIC ACID 75% Page 1
Issued: 18/06/2010
Revision No: 3

1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING


Product name: PHOSPHORIC ACID 75%
CAS number: 7664-38-2
EINECS number: 231-633-2
Index number: 015-011-00-6
Use of substance / preparation: Detergent for professional use.
Company name: CCL Pentasol Limited
Hall Wood Avenue
Haydock
St. Helens
WA11 9WA
UK
Tel: +44 (0) 1942 722000
Fax: +44 (0) 1942 722111
2. HAZARDS IDENTIFICATION
Main hazards: Causes burns.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous ingredients: ORTHOPHOSPHORIC ACID 70-90%
EINECS: 231-633-2 CAS: 7664-38-2
[C] R34
4. FIRST AID MEASURES (SYMPTOMS)
Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate.
Eye contact: Corneal burns may occur. May cause permanent damage.
Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding from the mouth or
nose.
Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may cause coughing or
wheezing.
4. FIRST AID MEASURES (ACTION)
Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the affected skin
with running water for 10 minutes or longer if substance is still on skin. Transfer to hospital if there are burns or
symptoms of poisoning.
Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist examination.
Ingestion: Wash out mouth with water. Do not induce vomiting. Give 1 cup of water to drink every 10 minutes. If
unconscious, check for breathing and apply artificial respiration if necessary. If unconscious and breathing is
OK, place in the recovery position. Transfer to hospital as soon as possible.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. If unconscious and breathing is
OK, place in the recovery position. If conscious, ensure the casualty sits or lies down. If breathing becomes
bubbly, have the casualty sit and provide oxygen if available. Transfer to hospital as soon as possible.
5. FIRE-FIGHTING MEASURES
Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.
Exposure hazards: Corrosive. In combustion emits toxic fumes.
Protection of fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Notify the police and fire brigade immediately. If outside keep bystanders upwind and away from danger point.
Mark out the contaminated area with signs and prevent access to unauthorised personnel. Do not attempt to
take action without suitable protective clothing - see section 8 of SDS. Turn leaking containers leak-side up to
prevent the escape of liquid.
Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.
Clean-up procedures: Clean-up should be dealt with only by qualified personnel familiar with the specific substance. Absorb into dry
earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method.
7. HANDLING AND STORAGE
Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do not handle in a
confined space. Avoid the formation or spread of mists in the air.
Storage conditions: Do not store at extreme temperatures. Store in a well ventilated area. Keep container tightly closed.
Suitable packaging: Must only be kept in original packaging. Polyethylene.

[cont...]
Issued: 18/06/2010 SAFETY DATA SHEET
PHOSPHORIC ACID 75% Page 2

8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Hazardous ingredients: ORTHOPHOSPHORIC ACID...100%
WEL (8 hr TWA): 1 mg/m3 WEL (15 min STEL): 2 mg/m3
Engineering measures: Ensure there is sufficient ventilation of the area.
Respiratory protection: Respiratory protection not required. Self-contained breathing apparatus must be available in case of
emergency.
Hand protection: Gloves (acid resistant).
Eye protection: Tightly fitting safety goggles. Ensure eye bath is to hand.
Skin protection: Acid-resistant protective clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
State: Liquid
Colour: Pale yellow
Odour: Odourless
Solubility in water: Miscible in all proportions
Relative density: 1.582 typical
pH: 1
10. STABILITY AND REACTIVITY
Stability: Stable under normal conditions.
Conditions to avoid: Direct sunlight. Heat.
Materials to avoid: Strong bases. Strong reducing agents.
Haz. decomp. products: In combustion emits toxic fumes.
11. TOXICOLOGICAL INFORMATION
Hazardous ingredients: ORTHOPHOSPHORIC ACID...100%
ORL RAT LD50 1530 mg/kg
Routes of exposure: Refer to section 4 of SDS for routes of exposure and corresponding symptoms.
12. ECOLOGICAL INFORMATION
Mobility: Readily absorbed into soil.
Persistence and degradability: Biodegradable.
Bioaccumulative potential: No bioaccumulation potential.
Other adverse effects: Negligible ecotoxicity.
13. DISPOSAL CONSIDERATIONS
Disposal of packaging: Arrange for collection by specialised disposal company.
NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.
14. TRANSPORT INFORMATION

ADR / RID
UN no: 1805 ADR Class: 8
Packing group: III Classification code: C1
Shipping name: PHOSPHORIC ACID, LIQUID
Labelling: 8 Hazard ID no: 80

IMDG / IMO
UN no: 1805 Class: 8
Packing group: III EmS: 8-08
Marine pollutant: NO
Labelling: 8
IATA / ICAO
UN no: 1805 Class: 8
Packing group: III
Packing instructions: 819(P&CA); 821(PAO)
Labelling: 8

[cont...]
Issued: 18/06/2010 SAFETY DATA SHEET
PHOSPHORIC ACID 75% Page 3

15. REGULATORY INFORMATION


Hazard symbols: Corrosive.

Risk phrases: R34: Causes burns.


Safety phrases: S24/25: Avoid contact with skin and eyes.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28: After contact with skin, wash immediately with plenty of water.
S36/37/39: Wear suitable protective clothing, gloves and eye / face protection.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
S60: This material and its container must be disposed of as hazardous waste.
Haz. ingredients (label): ORTHOPHOSPHORIC ACID...100%
Note: The regulatory information given above only indicates the principal regulations specifically applicable to the
product described in the safety data sheet. The user's attention is drawn to the possible existence of additional
provisions which complete these regulations. Refer to all applicable national, international and local regulations
or provisions.
16. OTHER INFORMATION
Other information: This safety data sheet is prepared in accordance with Regulation (EC) No 1907/2006.
Risk phrases used in s.3: R34: Causes burns.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only
as a guide. This company shall not be held liable for any damage resulting from handling or from contact with
the above product.

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SAFETY DATA SHEET
NUTRAPHASE 30
Page: 1
Revision date: 21/09/2015
Revision No: 3

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: NUTRAPHASE 30

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: Detergent for professional use.

1.3. Details of the supplier of the safety data sheet

Company name: CCL Pentasol Limited


Hall Wood Avenue
Haydock
St. Helens
WA11 9WA
UK
Tel: +44 (0) 1942 722000
Fax: +44 (0) 1942 722111
Email: info@cclpentasol.co.uk

1.4. Emergency telephone number

Emergency tel: +44 (0) 1942 722000

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: This product has no classification under CLP.

2.2. Label elements

Label elements: This product has no label elements.

2.3. Other hazards

PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

Non-classified ingredients:

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SAFETY DATA SHEET
NUTRAPHASE 30
Page: 2

CARBAMIDE

EINECS CAS CHIP Classification CLP Classification Percent


200-315-5 57-13-6 - - 10-30%

Section 4: First aid measures

4.1. Description of first aid measures

Skin contact: Wash immediately with plenty of soap and water.


Eye contact: Bathe the eye with running water for 15 minutes.
Ingestion: Wash out mouth with water.
Inhalation: Consult a doctor.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: There may be mild irritation at the site of contact.


Eye contact: There may be irritation and redness.
Ingestion: There may be irritation of the throat.
Inhalation: No symptoms.

4.3. Indication of any immediate medical attention and special treatment needed

Immediate / special treatment: Not applicable.

Section 5: Fire-fighting measures

5.1. Extinguishing media

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool
containers.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: In combustion emits toxic fumes.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with
skin and eyes.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions: Refer to section 8 of SDS for personal protection details. Turn leaking containers leak-side up
to prevent the escape of liquid.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal
by an appropriate method.
[cont...]
SAFETY DATA SHEET
NUTRAPHASE 30
Page: 3

6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS.

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Ensure there is sufficient ventilation of the area.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed.
Suitable packaging: Must only be kept in original packaging. Polyethylene.

7.3. Specific end use(s)

Section 8: Exposure controls/personal protection

8.1. Control parameters

Workplace exposure limits: No data available.

DNEL/PNEC Values

DNEL / PNEC No data available.

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area.


Respiratory protection: Respiratory protection not required. Self-contained breathing apparatus must be available in
case of emergency.
Hand protection: Protective gloves.
Eye protection: Safety glasses. Ensure eye bath is to hand.
Skin protection: Protective clothing.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Liquid
Colour: Colourless
Odour: Odourless
Solubility in water: Miscible in all proportions
Relative density: 1.084 typical pH: 9.0 - 10.0

9.2. Other information

Other information: No data available.

Section 10: Stability and reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

[cont...]
SAFETY DATA SHEET
NUTRAPHASE 30
Page: 4

10.2. Chemical stability

Chemical stability: Stable under normal conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
Decomposition may occur on exposure to conditions or materials listed below.

10.4. Conditions to avoid

Conditions to avoid: Direct sunlight. Heat.

10.5. Incompatible materials

Materials to avoid: Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

Toxicity values: No data available.

Symptoms / routes of exposure

Skin contact: There may be mild irritation at the site of contact.


Eye contact: There may be irritation and redness.
Ingestion: There may be irritation of the throat.
Inhalation: No symptoms.

Section 12: Ecological information

12.1. Toxicity

Ecotoxicity values: No data available.

12.2. Persistence and degradability

Persistence and degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobility in soil

Mobility: Readily absorbed into soil.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Negligible ecotoxicity.

[cont...]
SAFETY DATA SHEET
NUTRAPHASE 30
Page: 5

Section 13: Disposal considerations

13.1. Waste treatment methods

NB: The user's attention is drawn to the possible existence of regional or national regulations
regarding disposal.

Section 14: Transport information

Transport class: This product does not require a classification for transport.

Section 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Specific regulations: Not applicable.

15.2. Chemical Safety Assessment

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No
453/2010.
* indicates text in the SDS which has changed since the last revision.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. This company shall not be held liable for any damage resulting
from handling or from contact with the above product.

[final page]
SAFETY DATA SHEET

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SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE


COMPANY/UNDERTAKING
1.1 Product identifier

Commercial Product Name


AQUAFLOC 240

1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Substance/Mixture
Recommended restrictions on use
-

1.3 Details of the supplier of the safety data sheet


CCL Pentasol Limited
Hall Wood Avenue
Haydock
St. Helens, WA11 9WA
Telephone 01942 722000 Fax 01942 722111

Water Treatment
Unit 1B Millfield Lane
Haydock
St. Helens
WA11 9TW
Telephone 01942 721675

1.4 Emergency telephone number


+44 (0) 1942 722000

SECTION 2: HAZARDS IDENTIFICATION


2.1 Classification of the substance or mixture
Classification according to Regulation (EU) 1272/2008(CLP)
Skin corrosion/irritation; Category 2; Causes skin irritation.
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Irritant; Irritating to skin.

2.2 Label elements


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Labelling (REGULATION (EC) No 1272/2008)


Hazard pictograms :

Signal word : Warning

Hazard statements : H315 Causes skin irritation.

Precautionary statements : Prevention:


P264 W ash hands thoroughly after handling.
P280 Wear protective gloves/ protective clothing.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and
water.
P332 + P313 If skin irritation occurs: Get medical advice/
attention.
P362 Take off contaminated clothing and wash
before reuse.

2.3 Other hazards


Advice; Contaminated surfaces will be extremely slippery.
Potential environmental effects; This substance/mixture contains no components considered to be
either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS


3.2 Mixtures
Chemical nature of the Anionic polyacrylamide in water-in-oil emulsion.
mixture
CAS/EU Chemical name of the substance Concentration Classification according Classification according
number/REACH to Regulation (EU) to EU Directives
Registration 1272/2008(CLP) 67/548/EEC or
Number 1999/45/EC
68439-50-9 Alcohols, C12-14, ethoxylated 0-2% Acute Tox. Category 4,H302 Xn ,R22

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Eye Dam. Category 1,H318 R41


Aquatic Chronic Category
3,H412

68002-97-1 Alcohols, C10-16, ethoxylated 0-2% Acute Tox. Category 4,H302 Xn ,R22
Eye Dam. Category 1,H318 Xi ,R41
Aquatic Chronic Category
3,H412

68551-12-2 Alcohols, C12-16, ethoxylated 0-2% Acute Tox. Category 4,H302 Xn ,R22
Eye Dam. Category 1,H318 Xi ,R41
Aquatic Chronic Category
3,H412

Hydrocarbons, C11-C14, n-alkanes, 0 - 30 % Asp. Tox. Category 1,H304 Xn ,R65, R66


01-2119456620-43 isoalkanes, cyclics, < 2% aromatics

Hydrocarbons, C12-C15, n-alkanes, 0 - 30 % Asp. Tox. Category 1,H304 Xn ,R65, R66


01-2119453414-43 isoalkanes, cyclics, < 2% aromatics

Hydrocarbons, C12-C13, n-alkanes, 0 - 30 % Asp. Tox. Category 1,H304 Xn ,R65, R66


01-2119979538-16 cyclics, < 2% aromatics

1-5% EyeIrrit. Category 2,H319 Xi ,R35


01-2119457026-42 isoalkanes, cyclics, < 0.03%
aromatics

Components listed above that have a zero minimum and a common maximum range are
interchangeably used components based on availability. Only one of these components is contained
in the product up to the maximum amount noted.
Further information
For the full text of the H-Statements mentioned in this Section, see Section 16.
For the full text of the R-phrases mentioned in this Section, see Section 16.

SECTION 4: FIRST AID MEASURES


4.1 Description of first aid measures
Inhalation
Remove to fresh air. If breathing is difficult, give oxygen. If symptoms persist, call a physician.
Skin contact
Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water. Wash
contaminated clothing before reuse. Call a physician if irritation persists.
Eye contact

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Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Ingestion
If swallowed, call a poison control centre or doctor immediately. DO NOT induce vomiting unless directed
to do so by a physician or poison control center. Never give anything by mouth to an unconscious person.

4.2 Most important symptoms and effects, both acute and delayed
Symptoms : No information available.

4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Symptomatic treatment.

SECTION 5: FIREFIGHTING MEASURES


5.1 Extinguishing media
Extinguishing media : Water spray
Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable : High volume water jet
extinguishing media
Water may be ineffective.

5.2 Special hazards arising from the substance or mixture


No information available.

5.3 Advice for firefighters


Wear self-contained breathing apparatus and protective suit.

5.4 Specific methods


Cool containers/tanks with water spray.

SECTION 6: ACCIDENTAL RELEASE MEASURES


6.1 Personal precautions, protective equipment and emergency procedures
Where the exposure level is not known, wear approved, positive pressure, self-contained respirator.
Where the exposure level is known, wear approved respirator suitable for the level of exposure. For
personal protection see section 8. Chemical resistant boots.
6.2 Environmental precautions
Discharge into the environment must be avoided. Prevent product from entering drains.
6.3 Methods and materials for containment and cleaning up

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Sweep up to prevent slipping hazard. Soak up with inert absorbent material (e.g. sand, silica gel, acid
binder, universal binder, sawdust). Shovel into suitable container for disposal. After cleaning, flush away
traces with water. Use detergent if needed.

SECTION 7: HANDLING AND STORAGE


7.1 Precautions for safe handling
Handle in accordance with good industrial hygiene and safety practice. Handle product only in closed
system or provide appropriate exhaust ventilation at machinery.
7.2 Conditions for safe storage, including any incompatibilities
Store at room temperature. To avoid product degradation and equipment corrosion, do not use iron,
copper or aluminium containers or equipment. Flashpoint determination was performed using a Pensky
Martens type closed cup method. The method indicates a flash point greater than 93,3° C (200° F).
Although there was no flashpoint detected below 93,3° C (200° F) some flammable vapours were
evolved during the test as evidenced by the enlargement of the flame. Therefore caution should be
exercised during storage and handling.

Materials to avoid:
Strong oxidizing agents
Storage stability:
Other data Store at room temperature.

7.3 Specific end use(s)

Not listed

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

8.1.1 Limit values in other countries

Finland:
Hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics
HTP (8h) = 500 mg/m³, : Group 1: Aromatics <1%, n-hexane <5%, cyclo/isohexane <25%
Hydrocarbons, C12-C15, n-alkanes, isoalkanes, cyclics, < 2% aromatics
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HTP (8h) = 500 mg/m³, : Group 1: Aromatics <1%, n-hexane <5%, cyclo/isohexane <25%
Hydrocarbons, C13-C15, n-alkanes, isoalkanes, cyclics, < 2% aromatics
HTP (8h) = 500 mg/m³, : Group 1: Aromatics <1%, n-hexane <5%, cyclo/isohexane <25%
Hydrocarbons, C13-C16, n-alkanes, isoalkanes, cyclics, < 0.03% aromatics
HTP (8h) = 500 mg/m³, : Group 1: Aromatics <1%, n-hexane <5%, cyclo/isohexane <25%
Hydrocarbons, C12-C13, isoalkanes, cyclics, < 2% aromatics
HTP (8h) = 500 mg/m³, : Group 1: Aromatics <1%, n-hexane <5%, cyclo/isohexane <25%
Germany:
Hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics
AGW = 600 mg/m³, : C9-C15 Aliphatics
STEL = 1 200 mg/m³, : C9-C15 Aliphatics, 4 times 15 min. per shift
Hydrocarbons, C12-C15, n-alkanes, isoalkanes, cyclics, < 2% aromatics
AGW = 600 mg/m³, : C9-C15 Aliphatics
STEL = 1 200 mg/m³, : C9-C15 Aliphatics, 4 times 15 min. per shift
Hydrocarbons, C13-C15, n-alkanes, isoalkanes, cyclics, < 2% aromatics
AGW = 600 mg/m³, : C9-C15 Aliphatics
STEL = 1 200 mg/m³, : C9-C15 Aliphatics, 4 times 15 min. per shift
Hydrocarbons, C13-C16, n-alkanes, isoalkanes, cyclics, < 0.03% aromatics
AGW = 600 mg/m³, : C9-C15 Aliphatics
STEL = 1 200 mg/m³, : C9-C15 Aliphatics, 4 times 15 min. per shift
Hydrocarbons, C12-C13, isoalkanes, cyclics, < 2% aromatics
AGW = 600 mg/m³, : C9-C15 Aliphatics
STEL = 1 200 mg/m³, : C9-C15 Aliphatics, 4 times 15 min. per shift
Austria:
Hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics
MAK = 200 ml/m³, : Group 1: Aromatics <1%, n-hexane <5%, cyclo/isohexane <25%
STEL = 400 ml/m³, : Group 1: Aromatics <1%, n-hexane <5%, cyclo/isohexane <25%, 4 times 30 min.
per shift
Hydrocarbons, C12-C15, n-alkanes, isoalkanes, cyclics, < 2% aromatics
MAK = 200 ml/m³, : Group 1: Aromatics <1%, n-hexane <5%, cyclo/isohexane <25%
STEL = 400 ml/m³, : Group 1: Aromatics <1%, n-hexane <5%, cyclo/isohexane <25%, 4 times 30 min.
per shift
Hydrocarbons, C13-C15, n-alkanes, isoalkanes, cyclics, < 2% aromatics
MAK = 200 ml/m³, : Group 1: Aromatics <1%, n-hexane <5%, cyclo/isohexane <25%
STEL = 400 ml/m³, : Group 1: Aromatics <1%, n-hexane <5%, cyclo/isohexane <25%, 4 times 30 min.
per shift
Hydrocarbons, C13-C16, n-alkanes, isoalkanes, cyclics, < 0.03% aromatics
MAK = 200 ml/m³, : Group 1: Aromatics <1%, n-hexane <5%, cyclo/isohexane <25%
STEL = 400 ml/m³, : Group 1: Aromatics <1%, n-hexane <5%, cyclo/isohexane <25%, 4 times 30 min.
per shift
Hydrocarbons, C12-C13, isoalkanes, cyclics, < 2% aromatics
MAK = 200 ml/m³, : Group 1: Aromatics <1%, n-hexane <5%, cyclo/isohexane <25%

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STEL = 400 ml/m³, : Group 1: Aromatics <1%, n-hexane <5%, cyclo/isohexane <25%, 4 times 30 min.
per shift
Slovakia:
Acrylamide P/W acrylic acid, ammonium salt
TWA = 5 mg/m³, total compact aerosols

8.2 Exposure controls

8.2.1 Appropriate engineering controls


Dose and handle in closed system if possible. Handle only in a place equipped with local exhaust (or
other appropriate exhaust). Remove and wash contaminated clothing before re-use. Ensure that
eyewash stations and safety showers are close to the workstation location. Wash hands before breaks
and immediately after handling the product.
Ensure adequate ventilation.

8.2.2 Individual protection measures, such as personal protective equipment


Hand protection
Glove material: Nitrile rubber, Permeability tests are not available for this product.Please observe the
instructions regarding permeability and breakthrough time which are provided by the supplier of the
gloves. Also take into consideration the specific local conditions under which the product is used, such as
the danger of cuts, abrasion, and the contact time.

Eye protection
Tightly fitting safety goggles or face-shield.
Skin and body protection
Protective clothing.

Respiratory protection
Use the indicated respiratory protection if the occupational exposure limit is exceeded. (filter ABEK-P3)

8.2.3 Environmental exposure controls


No data available

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES


9.1 Information on basic physical and chemical properties
General Information (appearance, odour)
Physical state liquid, emulsion

Colour grey, to, white

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Odour ammoniacal

Important health safety and environmental information


pH 6-8
(as aqueous solution)
Melting point/range -18 - 0 °C
Boiling point/boiling range 80,6 - 126,7 °C
Flash point > 93 °C (closed cup)

Explosive properties:
Lower explosion limit
No data available
Upper explosion limit
No data available
Vapour pressure
No data available
Relative vapour density
No data available

Density ca. 1,0 g/cm³

Solubility(ies):
Water solubility
completely miscible
Partition coefficient: n-octanol/water
Not applicable
Auto-ignition temperature
No data available
Thermal decomposition
No data available

Viscosity:
Viscosity, kinematic > 22,5 mm²/s ( 40 °C)

Oxidising
The substance or mixture is not classified as oxidizing.

9.2 Other data

Surface tension No data available


Corrosion

SECTION 10: STABILITY AND REACTIVITY


10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
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10.3 Possibility of hazardous reactions


Hazardous reactions : Hazardous polymerisation does not occur.

10.4 Conditions to avoid


Conditions to avoid : No data available

10.5 Incompatible materials


Materials to avoid : Strong oxidizing agents

10.6 Hazardous decomposition products


Hazardous decomposition : Carbon oxides
products Ammonia
Nitrogen oxides (NOx)

Thermal decomposition : Note: No data available

SECTION 11: TOXICOLOGICAL INFORMATION


11.1 Information on toxicological effects
Acute toxicity
LD50/Oral/Rat: > 5 000 mg/kg
Remarks:estimated
LC50/Inhalation/4 h/Rat: > 20,0 mg/l
Remarks: estimated

LD50/Dermal/Rabbit: > 2 000 mg/kg


Remarks: estimated

Distillates (petroleum), hydrotreated light:


LD50/Oral/Rat: > 5 000 mg/kg
LC50/Inhalation/4 h/Rat: > 5,2 mg/l
LD50/Dermal/Rabbit: > 2 000 mg/kg

Irritation and corrosion


Skin:
Remarks: The toxicological data has been taken from products of similar composition.
Irritating to skin.

Eyes:
Remarks: The toxicological data has been taken from products of similar composition.
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No eye irritation

Sensitisation

Based on available data, the classification criteria are not met.

Distillates (petroleum), hydrotreated light:

This substance is not classified as a sensitizer.

Long term toxicity


Repeated dose toxicity

Remarks: No data available

Carcinogenicity

Based on available data, the classification criteria are not met.

Mutagenicity

Based on available data, the classification criteria are not met.

/AMES test:
No data available

Reproductive toxicity

Based on available data, the classification criteria are not met.

Distillates (petroleum), hydrotreated light:

Carcinogenicity

Not classified by IARC or NTP.

Mutagenicity

No known effect.

not mutagenic

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Reproductive toxicity

Did not show teratogenic effects in animal experiments.

SECTION 12: ECOLOGICAL INFORMATION


12.1 Toxicity
Aquatic toxicity
_

This material is not classified as dangerous for the environment. Acute toxicity tests conducted using
environmentally representative water.

LC50/96 h/Pimephales promelas (fathead minnow)/US EPA TSCA Test Guidelines: 21 mg/l
Remarks: Information given is based on data obtained from similar substances.

LC50/96 h/Oncorhynchus mykiss (rainbow trout)/US EPA TSCA Test Guidelines: 70,7 mg/l
Remarks: Information given is based on data obtained from similar substances.

LC50/96 h/Danio rerio (zebra fish)/OECD Test Guideline 203: > 100 mg/l
Remarks: Information given is based on data obtained from similar substances.
EC50/10 d/Corophium volutator (amphipoda)/PARCOM: 857 mg/l
EC50/48 h/Acartia tonsa (copepod)/PARCOM: 7,4 mg/l
EC50/48 h/Daphnia magna (Water flea)/Immobilization/OECD Test Guideline 202: > 100 mg/l
Remarks: Information given is based on data obtained from similar substances.
LC50/48 h/Daphnia magna (Water flea)/US EPA TSCA Test Guidelines: 1,96 mg/l
Remarks: Information given is based on data obtained from similar substances.
IC50/72 h/Skeletonema costatum (diatom)/ISO 10253: ca. 27 mg/l
IC50/72 h/Green algae (Selenastrum capricornutum)/Growth inhibition/OECD Test Guideline 201: > 100
mg/l
Remarks: Information given is based on data obtained from similar substances.

Toxicity to other organisms

No data available

12.2 Persistence and degradability


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Biological degradability:
Modified Sturm Test/OECD Test Guideline 301B:

The polymeric ingredient is not readily biodegradable.

Seawater Shake Flask Method/OECD Test Guideline 306/28 d: 13 %

12.3 Bioaccumulative potential

Because of the high molecular weight of the polymer diffusion through biological membranes is very
small. Bioaccumulation is unlikely.
Partition coefficient: n-octanol/water: Not applicable
12.4.Mobility in soil
Mobility
Water solubility: completely miscible
Surface tension: No data available

12.5. Results of PBT and vPvB assessment


No information available.

12.6 Other adverse effects


No data available
Additional ecological information: Ecotoxicological information provided is based on a structurally or
compositionally similar product.

SECTION 13: DISPOSAL CONSIDERATIONS


13.1 Waste treatment methods
Product Dispose of as special waste in compliance with local and
national regulations.
Contaminated packaging Packages that cannot be cleaned must be disposed of the
same way as the unused product.

SECTION 14: TRANSPORT INFORMATION


14.1 UN number

Land transport
Not classified as dangerous in the meaning of transport regulations.

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Sea transport
Not classified as dangerous in the meaning of transport regulations.

Air transport
Not classified as dangerous in the meaning of transport regulations.
14.6 Special precautions for user

No data available

SECTION 15: REGULATORY INFORMATION


15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Notification status
: All components of this product are included in the United
States TSCA Chemical Inventory or are not required to be
listed on the United States TSCA Chemical Inventory.
: All components of this product are included in the Canada
Domestic Substance List (DSL) or are not required to be listed
on the Canada Domestic Substance List (DSL).
: All components of this product are included in the Australian
Inventory of Chemical Substances (AICS) or are not required
to be listed on the Australian Inventory of Chemical
Substances (AICS).
: All components of this product are included on the Chinese
inventory or are not required to be listed on the Chinese
inventory.
: All components of this product are included in the Korean
(ECL) inventory or are not required to be listed on the Korean
(ECL) inventory.
: All components of this product are included on the Philippine
(PICCS) inventory or are not required to be listed on the
Philippine (PICCS) inventory.
: All components of this product are included on the Japanese
(ENCS) inventory or are not required to be listed on the
Japanese (ENCS) inventory.
:
: All components of this product are included in the European
Inventory of Existing Chemical Substances (EINECS) or are
not required to be listed on EINECS.
: All components of this product are included on the Taiwan
Toxic Chemical Substances Control Act Inventory.

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: This product's New Zealand Inventory of Chemical Substances


(NZIoC) status has NOT been determined.

15.2 Chemical Safety Assessment

A Chemical Safety Assessment is not required for this mixture.

SECTION 16: OTHER INFORMATION


Full text of H-Statements referred to under section 3.
H302 Harmful if swallowed.
H318 Causes serious eye damage.
H412 Harmful to aquatic life with long lasting effects.
H302 Harmful if swallowed.
H318 Causes serious eye damage.
H412 Harmful to aquatic life with long lasting effects.
H302 Harmful if swallowed.
H318 Causes serious eye damage.
H412 Harmful to aquatic life with long lasting effects.
H302 Harmful if swallowed.
H318 Causes serious eye damage.
H412 Harmful to aquatic life with long lasting effects.
H304 May be fatal if swallowed and enters airways.
H304 May be fatal if swallowed and enters airways.
H304 May be fatal if swallowed and enters airways.
H304 May be fatal if swallowed and enters airways.
H304 May be fatal if swallowed and enters airways.
Text of R-phrases mentioned in Section 3
R22 Harmful if swallowed.
R41 Risk of serious damage to eyes.
R22 Harmful if swallowed.
R41 Risk of serious damage to eyes.
R22 Harmful if swallowed.
R41 Risk of serious damage to eyes.
R22 Harmful if swallowed.
R41 Risk of serious damage to eyes.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R65 Harmful: may cause lung damage if swallowed.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
Training advice
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Read the safety data sheet before using the product.


Further information
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as
a guidance for safe handling, use, processing, storage, transportation, disposal and release
and is not to be considered a warranty or quality specification. The information relates only to
the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.
Sources of key data used to compile the Safety Data Sheet
Regulations, databases, literature, own tests.
Additions, Deletions, Revisions
Relevant changes have been marked with vertical lines.

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SAFETY DATA SHEET
HYDROCHLORIC ACID 30% Page 1
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Revision No: 5

1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING

Product name: HYDROCHLORIC ACID 30%


CAS number: 7647-01-0
EINECS number: 231-595-7
Use of substance / preparation: Detergent for professional use.
Company name: CCL Pentasol Limited
Hall Wood Avenue
Haydock
St. Helens
WA11 9WA
UK
Tel: +44 (0) 1942 722000
Fax: +44 (0) 1942 722111
2. HAZARDS IDENTIFICATION

Main hazards: Causes burns. Irritating to respiratory system.


3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous ingredients: HYDROCHLORIC ACID 10-30%


EINECS: 231-595-7
[C] R34; [Xi] R37
4. FIRST AID MEASURES (SYMPTOMS)

Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate.
Eye contact: Corneal burns may occur. May cause permanent damage.
Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding from the mouth or
nose.
Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may cause coughing or
wheezing.
4. FIRST AID MEASURES (ACTION)

Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the affected skin
with running water for 10 minutes or longer if substance is still on skin. Transfer to hospital if there are burns or
symptoms of poisoning.
Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist examination.
Ingestion: Wash out mouth with water. Do not induce vomiting. Give 1 cup of water to drink every 10 minutes. If
unconscious, check for breathing and apply artificial respiration if necessary. If unconscious and breathing is
OK, place in the recovery position. Transfer to hospital as soon as possible.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. If unconscious and breathing is
OK, place in the recovery position. If conscious, ensure the casualty sits or lies down. If breathing becomes
bubbly, have the casualty sit and provide oxygen if available. Transfer to hospital as soon as possible.
5. FIRE-FIGHTING MEASURES

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.
Exposure hazards: Corrosive. In combustion emits toxic fumes.
Protection of fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.
6. ACCIDENTAL RELEASE MEASURES

Personal precautions: Notify the police and fire brigade immediately. If outside keep bystanders upwind and away from danger point.
Mark out the contaminated area with signs and prevent access to unauthorised personnel. Do not attempt to
take action without suitable protective clothing - see section 8 of SDS. Turn leaking containers leak-side up to
prevent the escape of liquid.
Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.
Clean-up procedures: Clean-up should be dealt with only by qualified personnel familiar with the specific substance. Absorb into dry
earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method.
7. HANDLING AND STORAGE

Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do not handle in a
confined space. Avoid the formation or spread of mists in the air.
Storage conditions: Do not store at extreme temperatures. Store in a well ventilated area. Keep container tightly closed.
Suitable packaging: Must only be kept in original packaging. Polyethylene.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Workplace exposure limits


WEL (15 min STEL): 5 ppm (8mg/m3)
Engineering measures: Ensure there is sufficient ventilation of the area.
[cont...]
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HYDROCHLORIC ACID 30% Page 2

Respiratory protection: Gas/vapour filter, type B: inorganic vapours excl. CO (EN141). Self-contained breathing apparatus must be
available in case of emergency.
Hand protection: Gloves (acid resistant).
Eye protection: Tightly fitting safety goggles. Ensure eye bath is to hand.
Skin protection: Acid-resistant protective clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES

State: Liquid
Colour: Pale yellow
Odour: Irritating odour
Solubility in water: Miscible in all proportions
Boiling point/range°C: 108
Vapour pressure: 5-120 mbar 15°C
Relative density: 1.14 typical
pH: <1
10. STABILITY AND REACTIVITY

Stability: Stable under normal conditions.


Conditions to avoid: Direct sunlight. Heat.
Materials to avoid: Metals. Strong oxidising agents. Strong acids. Strong reducing agents. Strong bases.
Haz. decomp. products: In combustion emits toxic fumes.
11. TOXICOLOGICAL INFORMATION

Routes of exposure: Refer to section 4 of SDS for routes of exposure and corresponding symptoms.
12. ECOLOGICAL INFORMATION

Mobility: Readily absorbed into soil.


Persistence and degradability: Biodegradable.
Bioaccumulative potential: No bioaccumulation potential.
Other adverse effects: Negligible ecotoxicity.
13. DISPOSAL CONSIDERATIONS

Disposal of packaging: Arrange for collection by specialised disposal company.


NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.
14. TRANSPORT INFORMATION

ADR / RID

UN no: 1789 ADR Class: 8


Packing group: II Classification code: C1
Shipping name: HYDROCHLORIC ACID
Labelling: 8 Hazard ID no: 80

IMDG / IMO

UN no: 1789 Class: 8


Packing group: II EmS: 8-03
Marine pollutant: NO
Labelling: 8
IATA / ICAO

UN no: 1789 Class: 8


Packing group: II
Packing instructions: 809(P&CA); 813(PAO)
Labelling: 8
15. REGULATORY INFORMATION

Hazard symbols: Corrosive.

[cont...]
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HYDROCHLORIC ACID 30% Page 3

Risk phrases: R34: Causes burns.


R37: Irritating to respiratory system.
Safety phrases: S23: Do not breathe fumes.
S24/25: Avoid contact with skin and eyes.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28: After contact with skin, wash immediately with plenty of water.
S36/37/39: Wear suitable protective clothing, gloves and eye / face protection.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
S60: This material and its container must be disposed of as hazardous waste.
Haz. ingredients (label): HYDROCHLORIC ACID...100%
Note: The regulatory information given above only indicates the principal regulations specifically applicable to the
product described in the safety data sheet. The user's attention is drawn to the possible existence of additional
provisions which complete these regulations. Refer to all applicable national, international and local regulations
or provisions.
16. OTHER INFORMATION

Other information: This safety data sheet is prepared in accordance with Regulation (EC) No 1907/2006.
Risk phrases used in s.3: R34: Causes burns.
R37: Irritating to respiratory system.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only
as a guide. This company shall not be held liable for any damage resulting from handling or from contact with
the above product.

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