M.Sc. Chemistry
M.Sc. Chemistry
M.Sc. Chemistry
in Chemistry
JIS UNIVERSITY,
81, Nilgunj Road, Agarpara,
Kolkata-700109
M.Sc. in Chemistry
FIRST SEMESTER
Course PERIODS
CREDIT
Sl. Code SUBJECT
L T P
No.
THEORY
1 MCH-101 Analytical Chemistry I 3 1 0 4
2 MCH-102 Inorganic Chemistry I 3 1 0 4
3 MCH-103 Organic Chemistry I 3 1 0 4
4 MCH-104 Physical Chemistry I 3 1 0 4
Practical
5 MCH-191 Inorganic Chemistry Lab I 0 0 3 2
6 MCH-192 Organic Chemistry Lab I 0 0 3 2
7 MCH-193 Physical Chemistry Lab I 0 0 3 2
8 MSD-181 Project & Seminar 0 0 0 1
Total 12 4 9 23
M.Sc. in Chemistry
SECOND SEMESTER
Course PERIODS
CREDIT
Sl. Code SUBJECT
L T P
No.
THEORY
1 MCH-201 Analytical Chemistry II 3 1 0 4
2 MCH-202 Inorganic Chemistry II 3 1 0 4
3 MCH-203 Organic Chemistry II 3 1 0 4
4 MCH-204 Physical Chemistry II 3 1 0 4
5 MCS-201 Computer Applications in Physics and Chemistry 2 0 2 3
PRACTICAL
6 MCH-291 Inorganic Chemistry Lab II 0 0 3 2
7 MCH-292 Organic Chemistry Lab II 0 0 3 2
8 MCH-293 Physical Chemistry Lab II 0 0 3 2
9 MSD-281 Project & Seminar 0 0 0 1
10 MSD-282 Skill Development 0 0 0 1
Total 14 4 11 27
M.Sc. in Chemistry
THIRD SEMESTER
Course PERIODS
CREDIT
Sl. Code SUBJECT
L T P
No.
THEORY
1 Principles and Applications of Molecular 3 1 0 4
MCH-301
Spectroscopy
2 MCH-302 Biological Chemistry 3 1 0 4
3 MCH- Special Paper I (Inorganic/Organic/Physical) 3 1 0 4
303/304/305
4 MCH- Special Paper II (Inorganic/Organic/Physical) 3 1 0 4
306/307/308
5 MCH- Elective I 3 0 0 3
309/310
PRACTICAL
6 MCH- Inorganic/Organic/Physical Chemistry Lab III 0 0 9 6
391/392/393
7 MSD-381 Project & Seminar 0 0 0 1
Total 15 4 9 26
M.Sc. in Chemistry
FOURTH SEMESTER
Course PERIODS
CREDIT
Sl. Code SUBJECT
L T P
No.
THEORY
1 MCH-401 Spectroscopy for Structure Elucidation 3 1 0 4
2 MCH-402 Polymer and Materials Chemistry 3 1 0 4
3 MCH- Special Paper III (Inorganic/Organic/Physical) 3 0 0 3
403/404/405
4 MCH- Special Paper IV (Inorganic/Organic/Physical) 3 0 0 3
406/407/408
5 MCH- Elective II 3 0 0 3
409/410
PRACTICAL
6 MCHD-491 PROJECT 0 0 12 8
7 MSD-481 Project & Seminar 0 0 0 1
8 MSD-482 Skill Development 0 0 0 1
Total 15 2 12 27
Specialization Paper I
Specialization Paper II
Elective paper I
MCH-309: Supramolecular Chemistry & Drug Design
MCH-310: Nuclear Chemistry
Semester IV
Specialization Paper IV
Elective paper II
MCH-409: Chemical Applications of Group Theory
MCH-410: Advanced Spectroscopy
Unit-1: Introduction
Scope and objectives, classification of analytical methods, method selection, sample
processing, s teps in a quantitative analysis, quantitative range, data organisation, analytical
validations, limit of detection and quantification, tools of analytical chemistry and good lab
practices.
Unit-2: Separation techniques
Solvent extraction: principle, distribution ratio and partition coefficient, successive extraction
and separation, different methods of extraction systems, Craig extraction and counter current
distribution, problems.
Chromatography: general principle, classification, mathematical relations of capacity, selectivity
factor, distribution constant and retention time, chromatogram, elution in column
chromatography: band broadening and column efficiency, van Deemter equation, column
resolution, numerical problems, gas chromatography, high performance chromatography and
supercritical fluid chromatography: principles, methods, comparison and applications, thin-layer
chromatography, size-exclusion chromatography, ion chromatography and capillary
electrophoresis: principles, methods and applications.
Unit-3: Environmental chemistry
Introduction: environmental segments, atmospheric structure chemistry of lower and upper
atmosphere, radiation balance of earth.
Air pollution: major air pollutant, air quality standards and norms, determination of air
pollutants, Greenhouse effect, mechanistic pathways of smog formation and ozone hole, acid
rain, global warming, technology of air pollution abatement.
Water pollution: classification of water pollutants, characteristics of waste water, water quality
parameters and their measurements, biochemical effects of As, Pb, Cd, Hg and their chemical
speciation, eutrophication, waste water treatment: preliminary, primary, secondary, tertiary
treatment.
Solid waste disposal and management: classification and origin, methods of solid waste disposal,
microbiology involved in solid waste disposal.
Soil pollution: chemical composition of the soil, the exploitation of the mineral resources and
abuse of the earth, soil pollution due to natural and artificial agencies and its effects, remedial
measures to check the pollution.
Energy and Environment: energy sources, renewable and non-renewable, primary and secondary
fossil fuels, their occurrence and estimation.
1. R. L. Pecsok, L. D. Shields, T. Cairns and L.C. Mc William, Modern Methods of Chemical Analysis,
2nd Edition (1976), John Wiley, New York.
2. G. D. Christian, Analytical Chemistry, 5th Edition (1994), John Wiley & Sons, New York.
3. D. A. Skoog, D.M. West, F.J. Holler, S.R. Crouch, Analytical Chemistry - An Introduction, 7th Edition
(2000), Saunders College Publishing, Philadelphia, London.
4. J. H. Kennedy, Analytical Chemistry: Principles, 2nd Edition (1990), Saunders Holt, London.
5. Mani Vasakam, Physico Chemical Examination of Water, Sewage and Industrial effluents, Pragati
Prakashan, 1991
6. F. W. Fifield and W. P. J. Hairens, Environmental Analytical Chemistry, 2nd Edition (2000), Black
Well Science Ltd.
7. Colin Baird, Environmental Chemistry, W. H. Freeman and Company, New York (1995).
8. A. K. De, Environmental Chemistry, 4th Edition (2000), New Age International Private Ltd., New
Delhi.
9. Peter O. Warner, Analysis of Air Pollutants, 1st Edition (1996), John Wiley, New York.
10. S. M. Khopkar, Environmental Pollution Analysis, 1st Edition (1993), Wiley Eastern Ltd., New Delhi.
11. S. K. Banerji, Environmental Chemistry, 1st Edition (1993), Prentice-Hall of India, New Delhi.
Recommended Books
1. F.A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, 6th Edn. (1999), John Wiley & Sons,
New York.
2. J. E. Huheey, E. A. Keiter and R. L. Keiter, Inorganic Chemistry, Principles of structure and reactivity,
Harper Collins 1993.
3. R. S. Drago, Physical Methods in Inorganic Chemistry, International Edn. (1971), Affiliated East-West
Press, New Delhi.
4. Keith F. Purcell and John C. Kotz, Inorganic Chemistry, W. B. Sauders Com. (1987), Hong Kong.
5. K. Veera Reddy, Symmetry and Spectroscopy of Molecules, New Age International Pvt. Ltd., New
Delhi (1999).
6. B.N. Figgis, Introduction to Ligand Fields, Wiley Eastern Ltd. New Delhi (1976).
7. D. J. Newman, Betty, Crystal Field, Science, 2000
8. M. Chanda, Structure and Chemical bond, Tata McGraw Hill Atomic Edition, 2000.
9. D. F. Shriver, P. W. Atkins and C. H. Langford, Inorganic Chemistry, Oxford University Press, 1990.
Unit 2: Aromaticity
Huckel’s rule, concept of aromaticity in benzenoid and nonbenzenoid systems, alternate and non-
alternante hydrocarbons, annulenes, heteroannulenes, fullerenes, anti-aromaticity, pseudo-
aromaticity, homo-aromaticity.
Unit 4: Stereochemistry
Molecular symmetry, chirality, point groups, stereoisomerism, configuration: relative and
absolute, determination of relative configuration: Prelog’s rule, Cram’s rule, and Sharpless rule,
conformation: conformational analysis of acyclic, cyclic, fused, spiro and bridged bicyclo-
systems with typical examples.
Recommended Books
1. Clayden, Greeves, Warren and Wothers, Organic Chemistry, Oxford University Press, 2001.
2. M.B. Smith & Jerry March, March’s Advanced Organic Chemistry, 5th Edition (2001), John Wiley &
Sons, New York.
3. Peter Sykes, A Guide book to Mechanism in Organic Chemistry, 6th Edition (1997), Orient Longman
Ltd., New Delhi.
4. S. M. Mukherjee and S.P. Singh, Reaction Mechanism in Organic Chemistry, Ist Edition (1990),
Macmillan India Ltd., New Delhi.
5. D. Nasipuri, Stereochemistry of Organic Compounds, 2nd Edition (1994), Wiley Eastern Ltd., New
Delhi.
6. E.L. Eliel, S.H. Wilen and L.N. Mander, Stereochemistry of Organic Compounds, Wiley Interscience,
New York (2004).
Unit-1: Thermodynamics
Concise review of thermodynamics, concept of partial molar quantities and their significances,
Nernst heat theorem, consequences of Nernst heat theorem, entropy and third law of
thermodynamics: determination of absolute entropy, concept and significance of residual
entropy.
Thermodynamic probability and entropy, distribution laws: Maxwell-Boltzmann, Bose-Einstein
and Fermi-Dirac, concept of partition function: rotational, translational, vibrational and
electronic partition functions of diatomic molecules, concept of ensembles, relation between
partition functions with various thermodynamic functions, Gibb’s paradox.
Recommended Books
Recommended Books
Recommended Books
1. R. L. Pecsok, L. D. Shields, T. Cairns and L.C. Mc William, Modern Methods of Chemical Analysis,
2 nd Edition (1976), John Wiley, New York.
2. G. D. Christian, Analytical Chemistry, 5th Edition (1994), John Wiley & Sons, New York.
3. D.A. Skoog, Principles of Instrumental Analysis, 5th Edition (1998), Saunders College of Publishing,
Philadelphia, London.
4. D. A. Skoog, D.M. West, F.J. Holler, S.R. Crouch, Analytical Chemistry - An Introduction, 7th
Edition (2000), Saunders College Publishing, Philadelphia, London.
nd
5. J. H. Kennedy, Analytical Chemistry: Principles, 2 Edition (1990), Saunders Holt, London.
6. A. J. Bard, Electroanalytical Chemistry
7. J. W. Robinson, Atomic absorption Spectrometry
8. D. A. Skoog, D.M. West, F.J. Holler, Fundamentals of Analytical Chemistry
9. H. H. Willard, L. L. Meritt, J. A. Dean and F. A. Settle, Instrumental Methods of Analysis
10. H.A. Strobel, Chemical Instrumentation: A Schematic Approach, 2nd Edition (1973)
Recommended Books
Recommended Books
1. Clayden, Greeves, Warren, Organic Chemistry
2. F.A. Carey, R.J. Sundberg, Advanced Organic Chemistry
3. W. Carruthers, I. Coldham, Modern method of Organic Synthesis
4. Michael B. Smith, Jerry March, March's Advanced Organic Chemistry. Reactions, Mechanisms, and
Structure
5. Jie Jack Li , Name Reactions: A Collection of Detailed Reaction Mechanisms
6. Bradford P. Mundy, Michael G. Ellerd, Frank G. Favaloro, Name Reactions and Reagents in Organic
Synthesis
7. I. L. Finar, Organic Chemistry (Volume 1 & 2)
Unit-2: Electrochemistry
Quantitative treatment of Debye-Hückel theory of ion-ion interaction, its applications and
limitations, modification of Debye-Hückel law for finite-sized ions, Debye-Hückel-Onsagar
equation, association of ions: Bjerrum and Fuoss model, electrode kinetics, current-overpotential
relationship, Tafel equation and its importance.
Recommended Books
1. I. N. Levine, Quantum Chemistry, 5th Edition (2000), Pearson Educ., Inc. New Delhi
2. Donald A McQuarrie, Quantum Chemistry, Viva Student Edition, Viva Books, NewDelhi
3. D. J. Grffiths, Introduction to Quantum Mechanics
4. J. L. Powell, B. Crasemann, Quantum Mechanics
5. D. A. McQuarrie, J. D. Simon, Physical Chemistry, A Molecular Approach, (1998), Viva Books, New
Delhi
6. Richard L. Liboff, Introductory Quantum Mechanics
7. R.K. Prasad, Quantum Mechanics
8. Samuel Glasstone, An Introduction To Electrochemistry, Affiliated East-West Press Pvt. Ltd.-New
Delhi (2000)
9. J. O’M. Bockris, A. K. N. Reddy, Modern Electrochemistry, Vol. 2 A & B, 2 nd Edition, Plenum Press,
New York (1998)
Qualitative analysis of mixture of compounds containing six radicals of which two are rare
elements
Titrimetric estimation of mixtures of metal ions by EDTA
Spectroscopic estimation of inorganic complexes
Job’s method of continuous variation
Unit-1: Fundamentals
Interaction of electromagnetic radiation with matter, Einstein coefficient, transition probability,
transition dipole moments and selection rules, intensity of spectral lines, line-widths and line
shapes, Fourier transforms in spectroscopy.
Unit-2: Rotational and Vibrational spectroscopy
Classifications of molecules based on topicity, microwave and vibrational spectroscopy of
diatomic and polyatomic molecules, energy levels, selection rules, isotope effect, non-rigidity on
spectral features, vibration and group frequency, vibration-rotation spectra of diatomic
molecules, origin of P, Q, and R branch, hot bands, applications.
Unit-3: Raman spectroscopy
Raman spectra of diatomic molecules, rotational and rotation- vibrational Raman transitions,
effects of nuclear spin, polarization of Raman lines, applications.
Unit-4: Electronic spectroscopy
Origin, selection rules, spectral features, Franck-Condon principle, dissociation and pre-
dissociation, rotational fine structure, charge transfer spectra, fluorescence and phosphorescence
spectra, applications.
Unit-5: LASER spectroscopy
General features, principles, characteristics of laser, population inversion, basic elements in laser
pulsed, lasers, laser cavity modes, Q-switching, mode locking, harmonic
generation, different lasers: He-Ne, Nd-YAG, titanium-sapphire, dye lasers, semiconductor
lasers, and applications of lasers in spectroscopy.
Unit-6: Photoelectron Spectroscopy
Photoexcitation and photoionization, core level (XPS, ESCA) and valence level (UPS)
photoelectron spectroscopy, XPS and UPS of simple molecules, applications.
Unit-7: Nuclear Magnetic resonance spectroscopy
Basic principles, relaxation times, intensity of NMR signals, electronic shielding, NMR in
liquids: chemical shifts, origin of spin-spin couplings, and qualitative idea about NMR spectra of
AX, AX2, A3X and AB systems.
FT-NMR: Rotating frame of reference, effect of radiofrequency pulses, FID, Multi pulse
operation, measurement of T1 by inversion recovery method, spin echo and measurement of T2.
Unit-3: Bioenergetics
Glycolysis, citric acid cycle, electron transport chain, oxidative phosphorylation, membrane
transport mechanism.
Recommended Books
1. L. Stryer, Biochemistry, 5th edition (2002), Freeman & Co., New York.
2. D. L. Nelson and M. M. Cox, Lehninger, Principles of Biochemistry, 3rd edition (2002) McMillan
North Publication.
3. M. N. Hughes, Inorganic Chemistry of Biological Processes, (1981) John Wiley.
4. M. B. Smith, Organic Synthesis, (1995) McGraw Hill Inc., New York.
5. D. Voet, J. G. Voet, Biochemistry 3rd Edition (2004), Wiley International Publication.
Recommended Books
1. M. N. Hughes, Inorganic Chemistry of Biological Processes, 2nd Ed.(1981), John-Wiley & Sons, New
York.
2. W. Kaim and B. Schwederski, Bioinorganic Chemistry: Inorganic Elements in the Chemistry of Life,
An Introduction and Guide, Wiley, New York (1995).
3. S. J. Lippard and J. M. Berg, Principles of Bioinorganic Chemistry, University Science Books, (1994).
4. I. Bertini, H. B. Grey, S. J. Lippard and J. S. Valentine, Bioinorganic Chemistry, Viva Books Pvt. Ltd.,
New Delhi (1998)
5. F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, 6th Ed. (1999) John Wiley & Sons.
6. J. E. Huheey, Keiter and Keiter, Inorganic Chemistry.
7. R. H. Crabtree, The Organometallic Chemistry of Transition Metals, John Wiley.
8. Ch. Elschenbroich and A. Salzer, Organometallics, VCH.
9. J. P. Collman, L. S. Hegedus, J. R. Norton and R.G. Finke, Principles and Applications of
Organotransition metal Chemistry, Univ. Sci. Books, Mill Valley. California.
Recommended Books
1. Clayden, Greeves, Warren and Wothers, Organic Chemistry, Oxford University Press, 2001.
2. M.B. Smith & Jerry March, March’s Advanced Organic Chemistry, 5th Edition (2001), John Wiley &
Sons, New York.
3. Peter Sykes, A Guide book to Mechanism in Organic Chemistry, 6th Edition (1997), Orient Longman
Ltd., New Delhi.
4. S. M. Mukherjee and S.P. Singh, Reaction Mechanism in Organic Chemistry, Ist Edition (1990),
Macmillan India Ltd., New Delhi.
5. F.A. Carey and R.J. Sundburg,, Advanced Organic Chemistry, Part-A
6. F.A. Carey and R.J. Sundburg, Advanced Organic Chemistry, Part-B
Recommended Books
1. P. W. Atkins and R. S. Friedman, Molecular Quantum Mechanics, 3rd edition (1997), Oxford
University Press. Oxford.
2. I. N. Levine, Quantum Chemistry, 5th edition (2000), Pearson Educ., Inc., New Delhi.
3. D. A. McQuarrie and J. D. Simon, Physical Chemistry: A Molecular Approach, (1998), Viva Books,
New Delhi.
4. A. K. Chandra, Introductory Quantum Chemistry, 4th edition (1994), Tata McGraw Hill, New Delhi.
5. L. Pauling and E. B. Wilson, Introduction to Quantum Mechanics with Applications to Chemistry,
(1935), McGraw Hill, New York.
6. G. C. Schatz and M. A. Ratner, Quantum Mechanics in Chemistry, Dover Publication, Inc, New
York, 2002.
7. Richard L. Liboff, Introductory Quantum Mechanics
8. D. J. Grffiths, Introduction to Quantum Mechanics
9. J. L. Powell, B. Crasemann, Quantum Mechanics
10. R. K. Prasad, Quantum Mechanics
Recommended Books
1. F. A. Cotton and G.Wilkinson, Advanced Inorganic Chemistry, 6th Edn. (1999), John-Wiley &
Sons,New York.
2. James E. Huheey, Inorganic Chemistry, 4th Edn. (1993), Addison Wesley Pub. Co., New York
3. N. N. Greenwood and A. Earnshaw, Chemistry of the Elements, 2nd Edn. (1997), Butterworth
Heinemann, London.
Recommended Books
1. S.M. Mukherjee and S.P. Singh, Pericyclic Reactions &Photochemistry, MacMillan India, New Delhi.
2. I. Fleming, Pericyclic Reactions, Oxford University Press, Oxford (1999).
3.Clayden, Greeves, Warren and Wothers, Organic Chemistry, Oxford University Press, 2001.
4. M.B. Smith & Jerry March, March’s Advanced Organic Chemistry, 5th Edition (2001), John Wiley &
Sons, New York.
5. S. M. Mukherjee and S.P. Singh, Reaction Mechanism in Organic Chemistry, Ist Edition (1990),
Macmillan India Ltd., New Delhi.
6. D. Nasipuri, Stereochemistry of Organic Compounds, 2nd Edition (1994), Wiley Eastern Ltd., New
Delhi.
Recommended Books
1. C. Kittel, Introduction to Solid State Physics, John Wiley & Sons, Inc., New York, Chichester.
2. O. Madelung, Introduction to Solid State Theory
3. A. R. West, Solid State Chemistry and its Applications, (1984) John Wiley and Sons, Singapore.
4. L.V. Azaroff, Introduction to Solids, (1977) Tata McGraw-Hill, New Delhi.
5. A. J. Dekker, Solid State Physics, Prentice Hall
Recommended Books
1. J. M. Lehn, Supramolecular Chemistry- Concepts and Perspectives
2. Schneider, H. J., Yatsimirski, Principles and Methods in Supramolecular Chemistry
3. Advanced Organic Chemistry, Part-A, F.A. Carey and R.J. Sundburg
4. Advanced Organic Chemistry, Part-B, F.A. Carey and R.J. Sundburg
Recommended Books
1. B. Harvey, Introduction to Nuclear Physics and Chemistry, Prentice Hall, New York, 1965.
2. H. J. Arnikar, Essentials of Nuclear Chemistry, 4th Edn Reprint, New Age International (P) Ltd
Publications, New Delhi, 2001.
3. G. R. Choppin and J. Rydberg, Nuclear Chemistry: Theory and Applications, Pergamon, Oxford, 1980.
4. D. D. Sood, A.V. R Reddy and N. Ramamoorty, Fundumentals of Radiochemistry, Yancas, Mumbai,
2004.
Qualitative analysis of liquid sample (color, odour, solubility etc.); Thin Layer
Chromatography (TLC, preparation of TLC plates, analysis), boiling point
determination; functional groups tests, UV-VIS spectral characterizations: (measure max,
and explain), Assign 1H-NMR, 13C-NMR spectra, Identify the liquid substance.
Extraction of Renewable chemicals: Take a particular part of a plant such as fruit, leaf,
bark, heavy wood, etc. Weight it. Extract with a particular solvent. Remove the volatiles.
Purify. Weigh the product. Calculate % yield, Analyze the product by Thin Layer
Chromatography, calculate Rf value. UV-VIS spectral characterizations: measure
max,and explain. Submit the product with proper label.
Quantitative Estimation of: (a) Sugars (Glucose, Cane sugar), (b) Phenol, (c) Aniline, (d)
Nitrogen by Kjldahl method, (e) Saponification and Iodine value.
Recommended Books
1. A.I. Vogel, Qualitative Inorganic Analysis
2. A.I. Vogel, A Textbook of Quantitative Inorganic Analysis, ELBS
3. Ghosal, Mahaparta and Nad, An Advanced Course in Practical chemistry
4. G. N. Mukherjee, Handbook of Practical Chemistry
5. A.I. Vogel, A Textbook of Practical Organic Chemistry
6. A. M. James, F. F. Prichard, Practical Physical Chemistry
7. Shoermaker, Garland, Experimental Physical Chemistry
Recommended Books
1. J. O. Edwards and W. A. Benjamin, Inorganic Reactions Mechanism, INC, New York, 1965.
2. C. H. Langford and H. B. Gray, Ligand Substitution Processes, W. A. Benjamin, New York, 1966.
3. F. Basolo and R. G. Pearson, Mechanism of Inorganic Reactions, 2nd Edn, Wiley, New York, 1967.
4. D. Katakis and G. Gordon, Mechanisms of Inorganic Reactions, John Wiley & Sons, New York, 1987.
5. R. G. Wilkinns, Kinetics and Mechanism of Reactions of Transition Metal Complexes, 2nd Edn, VCH,
Weinheim, 1991.
6. D. M. Roundhill, Photochemistry and Photophysics of Metal Complexes, Plenum Press, New York and
London (1994).
7. G. J. Ferraudi, Elements of Inorganic Photochemistry, John Wiley & Sons (1988).
8. V. Balzani and V. Carassiti, Photochemistry of Coordination Compounds, Academic Press, London
(1970).
9. O. Horvath and K.L. Stevenson, Charge Transfer Photochemistry of Coordination Complexes, VCH
Publishers Inc. (1993)
Recommended Books
1. J. O’M. Bockris and A. K. N. Reddy, Modern Electrochemistry, Vol. 1 & 2A and 2B, (1998) Plenum
Press, New York.
2. A. J. Bard and L. R. Faulkner, Electrochemical Methods: Fundamentals and Applications, 2nd edition,
(2001) John Wiley &Sons, New York.
3. Samuel Glasstone, An Introduction to Electrochemistry: Edition 1st, East-West Press Pvt Ltd New
Delhi, India.
4. S. R. Morrison, Electrochemistry in Semiconductor and Oxidised Metal Electrodes, Plenum Press, New
York, 1980.
5. D. E. Kyriacou and D. A. Jannakoudis, Electrocatalysis for Organic Synthesis, Wiley, New York,
1986.
6. J. Goodisman, Electrochemistry: Theoretical Foundations, Wiley, New York, 1987.
7. J. O’M. Bockris and S. U. M. Khan, Surface Electrochemistry, Plenum Press, New York, 1993.
8. C. M. A. Brett and A. M. O. Brett, Electrochemistry: Principles, Methods and Applications, Oxford
University Press, Oxford, 1993.
9. P. W. Atkins, Physical Chemistry, 5th Edn, Oxford University Press, Oxford, 1994.
10. K. V. Kordesch, Fuel Cells and Their Applications, VCH, Weinheim, 1994.
Unit-1: Magnetochemistry
Types of magnetic materials, magnetic susceptibility and its determination: Gouy, Faraday and
Evans methods, vibrating sample magnetometer, SQUID and NMR methods. Magnetic
anisotropy, diamagnetism in atoms and polyatomic systems, Pascal’s constants, Lande interval
rule, energies of J states, Curie equation, Curies law and Curie-Weiss law, First order and second
order Zeeman effects, temperature independent para magnetism, simplification and application
of Van Vleck susceptibility equation, quenching of magnetic moments of transition metal
compounds in cubic and axially symmetric crystal fields, low spin- high spin crosser, magnetic
behaviour of Lanthanides and Actinides, magnetic exchange interactions, magnetic materials.
Unit-2: Cluster, Cage, Ring of main group transition-metal clusters
Capping rules, metal-ligand complexes vs heteronuclear cluster, isolobal analogs of p-block and
d-block clusters, limitations and exceptions, clusters having interstitial main group elements,
cubane clusters and naked or Zintl clusters, metal-carbonyl clusters, structures, capping and
electron counting, molecular clusters in catalysis, clusters to materials, boron-carbides and
metalborides, illustrative examples from recent literature.
Unit-3: Inorganic Polymers
Classification, types of inorganic polymerization, comparison with organic polymers, Boron-
oxygen and boron-nitrogen polymers, silicones, coordination polymers, sulphur-nitrogen,
sulphur-nitrogen-fluorine compounds, binary and multi-component systems, hemolytic inorganic
systems.
Recommended Books
1. F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, 6th Edn. (1999), John-Wiley & Sons,
New York.
2. N. N. Greenwood and A. Earnshaw, Chemistry of the Elements, 2nd Edn. (1997), Butterworth
Heinemann, London.
3. F. E. Mabbs and D. J. Machin, Magnetism and Transition Metal Complexes, Dover Publications, New
York, 2008.
4.O. Kahn, Molecular Magnetism, VCH, New York, 1993.
5. P. Day and A. E. Underhill (Eds), Metal-organic and Organic Molecular Magnets, RSC, London, 2000.
6. J. S. Miller and M. Drillon (Eds), Magnetism: Molecules to Materials, V; Molecule-based Magnets,
Wiley-VCH, Weinheim, 2005.
7. B. D. Cullity and C. D. Graham, Introduction to Magnetic Materials, 2nd Ed, John Wiley & Sons, New
York, 2011.
8. F. Vogtle, Supramolecular Chemistry: An Introduction, Wiley, Chichester, 1991.20 20
9. V. Balzani and F. Scandola, Supramolecular Photochemistry, Ellis Horwood, Chichester, 1991.
10. J. -M. Lehn, Supramolecular Chemistry: Concepts and Perspectives, VCH, Weinheim, 1995.
11. J. W. Steed and J. L. Atwood, Supramolecular Chemistry, 2nd Ed, John Wiley & Sons.
Unit-1: Fundamentals
Nomenclature of heterocycles: replacement and systematic nomenclature (Hantzsch-Widman
system) for monocyclic, fused and bridged heterocycles; aromatic heterocycles: tautomerism in
heterocyclic systems, reactivity of aromatic heterocycles; non-aromatic heterocycles:
conformation of six-membered heterocycles with reference to molecular geometry, barrier to
ring inversion, pyramidal inversion and 1,3-diaxial interaction, anomeric and related effects,
hydrogen bonding and intermolecular nucleophilic-electrophilic interactions; meso-ionic
systems: general classification, chemistry of some important meso-ionic heterocycles of type A
and B and their applications.
Recommended Books
1. J. A. Joule and K. Mills: Heterocyclic Chemistry (4 th Edition)
2. Clayden, Greeves, Warren and Wothers, Organic Chemistry, Oxford University Press, 2001.
3. M.B. Smith & Jerry March, March’s Advanced Organic Chemistry, 5th Edition (2001), John
Wiley & Sons, New York.
4. Advanced Organic Chemistry, Part-A, F.A. Carey and R.J. Sundburg
5. Advanced Organic Chemistry, Part-B, F.A. Carey and R.J. Sundburg
Recommended Books
1. B. K. Agarwal and M. Eisner, Statistical Mechanics, (1988) Wiley Eastern, New Delhi
2. D. A. McQuarrie, Statistical mechanics, (1976) Harper and Row Publishers, New York
3. E. S. R. Gopal, Statistical Mechanics and Properties of Matter, Ellis Horwood, England, 1974
4. S. K. Ma, Statistical Mechanics, World Sci, Singapore, 1985
5. R. K. Pathria, Statistical Mechanics, Butterworth-Heinemann, 1996
6. B.B. Laud, Statistical Mechanics
Recommended Books
1. F. A. Cotton, Chemical Applications of Group Theory, 3rd Edn. (1999), John Wiley & Sons,
New York.
2. G. L. Miessler and D. A. Tarr, Inorganic Chemistry, 2nd Edn. (1999), Prentice Hall International Inc.,
London.
3. K. Veera Reddy, Symmetry and Spectroscopy of Molecules, New Age International Pvt. Ltd., New
Delhi (1999).
4. A. Vincent, Molecular Symmetry and Group Theory, John Wiley & Sons, New York, 1998.
5. D. M. Bishop, Group Theory and Chemistry, Oxford University Press, 1993.
6. V. Heine, Group Theory in Quantum Mechanics: An Introduction to Its Present Usage, Dover
Publication, New York, 1991.
7. R. McWeeny, Symmetry: An Introduction to Group Theory and Its Applications, Dover Publications,
New York.
Unit-1: Fundamentals
Generation of singlet and triplet states, radiative and non-radiative transitions, fluorescence,
phosphorescence, quantum yield and life-time measurements, fluorescence quenching, resonance
energy transfer, solvation dynamics.
Unit-2: Laser Spectroscopy
Brief review of laser action, application of lasers as excitation source, time resolved fluorimetry,
transient absorption spectroscopy, surface plasmon spectroscopy, multiphoton spectroscopy,
single molecule spectroscopy, fluorescence correlation spectroscopy, upconversion, microscopy
(optical, phase contrast, confocal, FLIM), SERS, and CARS.
Unit-3: Photophysical Processes
Unimolecular processes, delayed fluorescence, kinetics of bimolecular processes: collision
quenching, Stern-Volmer equation, concentration dependence of quenching and excimer
formation, excited state electron transfer processes: exciplex, twisted intramolecular charge
transfer processes, proton couple electron transfer processes, special photochemical reactions,
flash photolysis, laser flash photolysis.
Recommended Books
1. J. M. Hollas, Modern Spectroscopy, Wiley, New York, 1996.
2. D. N. Sathyanarayana, Electronic Absorption Spectroscopy and Related Techniques, University Press,
2001.
3. G. Aruldhas, Molecular Structure and Spectroscopy, 2nd Edn, Prentice-Hall of India, New Delhi, 2007.
4. G. M. Barrow, Introduction to Molecular Spectroscopy, McGraw-Hill International Book Company,
Tokyo, 1982.
5. J. D. Graybeal, Molecular Spectroscopy, McGraw-Hill International Editions, Spectroscopy series,
1998.
6. J. R. Lakowicz, Principles of Fluorescence Spectroscopy
7. R. Schinke, Photodissociation dynamics
8. W. Demtroder, Laser spectroscopy
9. R. D. Levine, Molecular Reaction Dynamics
10. J. I. Steinfeld, J. S. Francisco, W. L. Hase, Chemical Kinetics and Dynamics