WORKSHEET FOR SA-1

1. Brass is (a) Solid solution (b) Liquid solution (c) Gas solution (d) All of these
2. Which of the following 0.1 M aqueous solution is likely to have the highest boiling point? (a) Na2SO4
(b) KCl (c) Glucose (d) Urea
3. 3. 200 mL of water is added to 500 mLof 0.2 M solution. What is the molarity of the diluted solution?
(a) 0.5010 M (b) 0.2897 M (c) 0.7093 M (d) 0.1428 M
4. In which mode of expression, the concentration of solution remains independent of temperature? (a)
Molarity (b) Normality (c) Formality (d) Molality
5.Which one of the following statements is always true about the spontaneous cell reaction in a galvanic
cell? (a) E°cell> 0, ΔG° > 0, Q >Kc (b) E°cell< 0, ΔG° < 0, Q < Kc (c)E°cell>0, ΔG° 0, ΔG° < 0, Q > Kc
6. 5. Among the following cells Leclanché cell (I), Nickel–cadmium cell (II), Lead storage battery (III),
Mercury cell (IV), primary cells are (a) I and II (b) I and III (c) II and III (d) I and IV
7. 13.Which of the following solution has highest equivalent conductance? (a) 0.01 M KCI (b) 0.05 M KCI
(c) 0.02 M KCI (d) 0.005 M KCI
8.In the electrolytic cell, flow of electrons is from (a) cathode to anode in the solution (b) cathode to
anode through external supply (c) cathode to anode through internal supply (d) anode to cathode
through internal supply
9.The increasing order of the crystal field splitting power of some common ligands iS
(a) H2O < OH– < CI– < F– < CN– (b) CN– < H2O < OH– < F– < Cl–
(c) F– < CN– < OH– < CI– < H2O (d) Cl– < F– < OH– < H2O < CN–
10.The position of -Br in the compound in CH3CH = CHC(Br)(CH3)2 can be classified as .......... (a) Allyl (b)
Aryl (c) Vinyl (d) Secondary
11. 23.75% of the first order reaction was completed in 32 min. 50% of the reaction was completed in
(a) 24 min. (b) 8 min. (c) 16 min.
12.General electronic configuration of d-block elements is (a) (n - 1) d1-10 ns1-2 (b) ns2np1-6 (c) (n - 2)
ƒ0-14 (n - 1)1-2 ns2 (d) (n - 1) d1-5 ns1-2
13.he electronic configuration of gadolinium (At. No. 64) is (a) [Xe] 4ƒ8 5d0 6s2 (b) [Xe] 4ƒ7 5d1 6s2 (c)
[Xe] 4ƒ3 5d5 6s2 (d) [Xe] 4ƒ6 5d2 6s2 .
14.Which one of the following is a tridentate ligand? (a) NO2- (b) oxalate ion (c) glycinate ion (d) dien
15. 32.Which one of the following has an optical isomer? (a) [Co(H2O)4(en)]3+ (b) [Zn(en)2] 2+ (c)
[Zn(en)(NH3)2] 2+ (d) [Co(en)3] 3+ (en = ethylenediamine)
16. 36.Alkyl halides are prepared from alcohols by treating with (a) HCl + ZnCl2 (b) Red P + Br2 (c) H2SO4
+ KI (d) All the above
17.The process of converting alkyl halides into alcohols involves...........
(a) addition reaction (b) substitution reaction
(c) dehydrohalogenation reaction (d) rearrangement reaction
18.Monochlorination of toluene in sunlight followed by hydrolysis with aq. NaOH yields, (a) o-Cresol (b)
m-Cresol (c) 2,4-Dihydroxytoluene (d) Benzyl alcohol

2 Marks

1. . Calculate the mass of a non-volatile solute (molar mass 40 g/mol) which should be dissolved in 114 g
octane to reduce its vapour pressure to 80%.
2. . What will be the effect of the followings on rate constant? a. Temperature b. Catalyst c.
Concentration of reactant
3. 4. Name the following: a. A transition metal which does not exhibit variation in oxidation state in its
compounds. b. A compound where the transition metal is in the +7-oxidation state. c. A member of the
lanthanoid series which is well known to exhibit +4 oxidation state. d. Ore used in the preparation of
Potassium dichromate.
4. In what way is the electronic configuration of the transition elements different from that of the non
transition elements?
5. Explain briefly how +2 state becomes more and more stable in the first half of the first row transition
elements with increasing atomic number?
6. Depict the galvanic cell in which the reaction Zn(s)+2Ag+ (aq) →Zn2+(aq)+2Ag(s) takes place. Further
show: (i) Which of the electrode is negatively charged? (ii) The carriers of the current in the cell.
7. How much charge is required for the following reductions: (i) 1 mol of Al3+ to Al? (ii) 1 mol of Cu2+ to
Cu?
8. Square planar complexes with coordination number of four exhibit geometrical isomerism whereas
tetrahedral complexes do not. Why?
9. Calculate the number of unpaired electrons in the following gaseous ions: Mn3+ , Cr3+, V3+ and Ti 3+.
Which one of these is the most stable in aqueous solution?
10. Convert the following: (a) Benzene to m-nitrobenzaldehyde (b) Bromobenzene to benzoic acid
11. Explain why the electrophilic substitution reactions in haloarenes occur slowly and require more
drastic conditions as compared to those in benzene.
12. Write the following conversion (any 2);
a. Aniline to phenyl isocyanide. b. Chlorobenzene to p-nitrophenol
c. Ethyl chloride to propanoic acid d. 2-Bromopropane to 1-bromopropane
13Arrange the following compounds:
a. In order of increasing reactivity towards Lucas’s reagent: 2-butanol, 1-butanol, 2-methyl-2-propanol
b. In order of increasing acidic character Methanol, 1-propanol, 2-propanol
14. Preparation of ethers by acid dehydration of secondary or tertiary alcohols is not a suitable method.
Give reason.
15. Write equations of the following reactions: (i) Friedel-Crafts reaction – alkylation of anisole. (ii)
Nitration of anisole.
16. FeSO4 solution mixed with (NH4)2SO4 solution in 1:1 molar ratio gives the test of Fe2+ ion but
CuSO4 solution mixed with aqueous ammonia in 1:4 molar ratio does not give the test of Cu2+ ion.
Explain why?

3 Marks

1. Indicate the steps in the preparation of: (i) K2Cr2O7 from chromite ore. (ii) KMnO4 from pyrolusite
ore.
2. Compare the chemistry of the actinoids with that of lanthanoids with reference to: (i) electronic
configuration (ii) oxidation states and (iii) chemical reactivity
3. What are alloys? Name an important alloy which contains some of the lanthanoid metals. Mention its
uses.
3. A solution of Ni(NO3 ) 2 is electrolysed between platinum electrodes using a current of 5 amperes for
20 minutes. What mass of Ni is deposited at the cathode?
4. Predict the products of electrolysis in each of the following: (i) An aqueous solution of AgNO3 with
silver electrodes. (ii) An aqueous solution of AgNO3 with platinum electrodes. (iii) A dilute solution of
H2SO4 with platinum electrodes. (iv) An aqueous solution of CuCl2 with platinum electrodes.
5. A solution of glucose in water is labelled as 10% w/w, what would be the molality and mole fraction of
each component in the solution? If the density of solution is 1.2 g mL–1, then what shall be the molarity
of the solution?
6. The vapour pressure of water is 12.3 kPa at 300 K. Calculate vapour pressure of 1 molal solution of a
non-volatile solute in it.
7. State Henry's law correlating the pressure of a gas and its solubility in a Solvent? Explain the reasons
fora. A medical condition known as bends occur during scuba diving b. A medical condition known as
anoxia occur during hill climbing
8. The E° values corresponding to the following two reduction electrode processes are:
(i) Cu+ /Cu = + 0.52 V (ii) Cu2+/Cu+ = + 0.16 V.
Formulate the galvanic cell for their combination. What will be the standard cell potential for it?
Calculate ΔrG° for the cell reaction (F = 96500 C mol–1 )
9. a. Describe the type of hybridisation for the complex ion [Fe(H2O)6] 2+ . b. Write the IUPAC name of
the ionisation isomer of the coordination compound [Co(NH3)5Br]SO4. Give one chemical test to
distinguish between the two compounds.
10. rite down the IUPAC name for each of the following complexes and indicate the oxidation state,
electronic configuration and coordination number. Also give stereochemistry and magnetic moment of
the complex: (i) K[Cr(H2O)2(C2O4)2].3H2O (iii) [CrCl3(py)3] (v) K4[Mn(CN)6] (ii) [Co(NH3)5Cl- ]Cl2 (iv)
Cs[FeCl4]
11. Using IUPAC norms write the systematic names of the following: (i) [Co(NH3)6]Cl3 (iv)
[Co(NH3)4Cl(NO2)]Cl (vii) [Ni(NH3)6]Cl2 (ii) [Pt(NH3)2Cl(NH2CH3)]Cl (v) [Mn(H2O)6] 2+ (viii) [Co(en)3] 3+
(iii) [Ti(H2O)6] 3+ (vi) [NiCl4] 2– (ix) [Ni(CO)4]
12. Explain why
a. The dipole moment of chlorobenzene is lower than that of cyclohexyl chloride?
b. Alkyl halides, though polar, are immiscible with water?
c. Grignard reagents should be prepared under anhydrous conditions? d. Phenols boil at higher
temperature than arenes of comparable molecular masses
13. (1). Aniline dissolved or suspended in cold aqueous mineral acid, is treated with sodium nitrite.
Followed by Mixing the solution of freshly prepared product with cuprous chloride. (2). phenol reacts
with CO2 in the presence of NaOH followed by hydrolysis. (3). phenol reacts with CHCl3 in the presence
of NaOH followed by hydrolysis
14. a. Write the reaction occurring at anode and cathode and the products of electrolysis of aq. KCl. b.
What is the pH of HCl solution when the hydrogen gas electrode shows a potential of -0.59 V at standard
temperature and pressure?
15. Name the reagents used in the following reactions: (i) Oxidation of a primary alcohol to carboxylic
acid. (ii) Oxidation of a primary alcohol to aldehyde. (iii) Bromination of phenol to 2,4,6-tribromophenol.
(iv) Benzyl alcohol to benzoic acid. (v) Dehydration of propan-2-ol to propene. (vi) Butan-2-one to butan-
2-ol
16. If the density of some lake water is 1.25g mL–1 and contains 92 g of Na+ ions per kg of water,
calculate the molality of Na+ ions in the lake.
16. Calculate the depression in the freezing point of water when 10 g of CH3CH2CHClCOOH is added to
250 g of water. Ka = 1.4 × 10–3 , Kf = 1.86 K kg mol–1 .