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    Chemsheets AS 1066 Halogen Oxidising Power

    Uploaded by

    Ayesha
    The document shows the reactions of chlorine, bromine, and iodine with chloride, bromide, and iodide ions in aqueous and organic solutions. When reacted with the corresponding halide ion, each halogen forms a colored solution - chlorine remains yellow, bromine turns yellow, and iodine turns purple. Chlorine is the strongest oxidizing agent and can oxidize all three halide ions, while bromine can oxidize iodide and iodine can oxidize bromide. The oxidizing power decreases down the halogen group as it becomes harder to gain electrons due to larger atom size and more electron shielding.

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    © All Rights Reserved
    Download as PPT, PDF, TXT or read online from Scribd

    Chemsheets AS 1066 Halogen Oxidising Power

    Uploaded by

    Ayesha
    267 views19 pages
    The document shows the reactions of chlorine, bromine, and iodine with chloride, bromide, and iodide ions in aqueous and organic solutions. When reacted with the corresponding halide ion, each halogen forms a colored solution - chlorine remains yellow, bromine turns yellow, and iodine turns purple. Chlorine is the strongest oxidizing agent and can oxidize all three halide ions, while bromine can oxidize iodide and iodine can oxidize bromide. The oxidizing power decreases down the halogen group as it becomes harder to gain electrons due to larger atom size and more electron shielding.

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    Chemistry

    Original Title

    Chemsheets-AS-1066-Halogen-oxidising-power

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    The document shows the reactions of chlorine, bromine, and iodine with chloride, bromide, and iodide ions in aqueous and organic solutions. When reacted with the corresponding halide ion, each halogen forms a colored solution - chlorine remains yellow, bromine turns yellow, and iodine turns purple. Chlorine is the strongest oxidizing agent and can oxidize all three halide ions, while bromine can oxidize iodide and iodine can oxidize bromide. The oxidizing power decreases down the halogen group as it becomes harder to gain electrons due to larger atom size and more electron shielding.

    Copyright:

    © All Rights Reserved
    Download as PPT, PDF, TXT or read online from Scribd
    Download as ppt, pdf, or txt
    267 views19 pages

    Chemsheets AS 1066 Halogen Oxidising Power

    Uploaded by

    Ayesha
    The document shows the reactions of chlorine, bromine, and iodine with chloride, bromide, and iodide ions in aqueous and organic solutions. When reacted with the corresponding halide ion, each halogen forms a colored solution - chlorine remains yellow, bromine turns yellow, and iodine turns purple. Chlorine is the strongest oxidizing agent and can oxidize all three halide ions, while bromine can oxidize iodide and iodine can oxidize bromide. The oxidizing power decreases down the halogen group as it becomes harder to gain electrons due to larger atom size and more electron shielding.

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    © www.chemsheets.co.

    uk AS 1066 3-July-2015
    © www.chemsheets.co.uk AS 1066 3-July-2015
    Cl2(aq) Br2(aq) I2(aq)

    Cl–(aq)

    Br–(aq)

    I–(aq)

    © www.chemsheets.co.uk AS 1066 3-July-2015


    Cl2(aq) Br2(aq) I2(aq)

    Cl–(aq)
    Stays yellow solution
    (no reaction)

    Br–(aq)

    I–(aq)

    © www.chemsheets.co.uk AS 1066 3-July-2015


    Cl2(aq) Br2(aq) I2(aq)

    Cl–(aq)
    Stays yellow solution Stays brown solution
    (no reaction) (no reaction)

    Br–(aq)

    I–(aq)

    © www.chemsheets.co.uk AS 1066 3-July-2015


    Cl2(aq) Br2(aq) I2(aq)

    Cl–(aq)
    Stays yellow solution Stays brown solution
    (no reaction) (no reaction)

    Yellow solution forms


    (Br2 forms)
    Br–(aq)

    Cl2 + 2 Br-→ 2 Cl- + Br2

    I–(aq)

    © www.chemsheets.co.uk AS 1066 3-July-2015


    Cl2(aq) Br2(aq) I2(aq)

    Cl–(aq)
    Stays yellow solution Stays brown solution
    (no reaction) (no reaction)

    Yellow solution forms


    (Br2 forms) Stays brown solution
    Br–(aq)
    (no reaction)
    Cl2 + 2 Br-→ 2 Cl- + Br2

    I–(aq)

    © www.chemsheets.co.uk AS 1066 3-July-2015


    Cl2(aq) Br2(aq) I2(aq)

    Cl–(aq)
    Stays yellow solution Stays brown solution
    (no reaction) (no reaction)

    Yellow solution forms


    (Br2 forms) Stays brown solution
    Br–(aq)
    (no reaction)
    Cl2 + 2 Br-→ 2 Cl- + Br2

    Brown solution forms


    (I2 forms)
    I–(aq)

    Cl2 + 2 I- → 2 Cl- + I2

    © www.chemsheets.co.uk AS 1066 3-July-2015


    Cl2(aq) Br2(aq) I2(aq)

    Cl–(aq)
    Stays yellow solution Stays brown solution
    (no reaction) (no reaction)

    Yellow solution forms


    (Br2 forms) Stays brown solution
    Br–(aq)
    (no reaction)
    Cl2 + 2 Br-→ 2 Cl- + Br2

    Brown solution forms Brown solution forms


    (I2 forms) (I2 forms)
    I–(aq)

    Cl2 + 2 I- → 2 Cl- + I2 Br2 + 2 I- → 2 Br- + I2

    © www.chemsheets.co.uk AS 1066 3-July-2015


    Oxidising power trend: Cl2 > Br2 > I2

    When a halogen acts as an oxidising agent, it gains


    electrons (taken from the oxidised species).
    X2 + 2 e- → 2 X-
    Cl

    Down the group it becomes harder to


    Br
    gain an electron because:
    atoms are larger & there is more
    I shielding (due to extra electron shell)

    © www.chemsheets.co.uk AS 1066 3-July-2015


    © www.chemsheets.co.uk AS 1066 3-July-2015
    Cl2(aq) Br2(aq) I2(aq)

    Cl–(aq)

    Br–(aq)

    I–(aq)

    © www.chemsheets.co.uk AS 1066 3-July-2015


    Cl2(aq) Br2(aq) I2(aq)

    Cl–(aq)
    Yellow solution
    (organic layer)

    Br–(aq)

    I–(aq)

    © www.chemsheets.co.uk AS 1066 3-July-2015


    Cl2(aq) Br2(aq) I2(aq)

    Cl–(aq)
    Yellow solution Purple solution
    (organic layer) (organic layer)

    Br–(aq)

    I–(aq)

    © www.chemsheets.co.uk AS 1066 3-July-2015


    Cl2(aq) Br2(aq) I2(aq)

    Cl–(aq)
    Yellow solution Purple solution
    (organic layer) (organic layer)

    Yellow solution (organic


    layer) as Br2 forms
    Br–(aq)

    Cl2 + 2 Br-→ 2 Cl- + Br2

    I–(aq)

    © www.chemsheets.co.uk AS 1066 3-July-2015


    Cl2(aq) Br2(aq) I2(aq)

    Cl–(aq)
    Yellow solution Purple solution
    (organic layer) (organic layer)

    Yellow solution (organic


    layer) as Br2 forms Purple solution
    Br–(aq)
    (organic layer)
    Cl2 + 2 Br-→ 2 Cl- + Br2

    I–(aq)

    © www.chemsheets.co.uk AS 1066 3-July-2015


    Cl2(aq) Br2(aq) I2(aq)

    Cl–(aq)
    Yellow solution Purple solution
    (organic layer) (organic layer)

    Yellow solution (organic


    layer) as Br2 forms Purple solution
    Br–(aq)
    (organic layer)
    Cl2 + 2 Br-→ 2 Cl- + Br2

    Purple solution (organic


    layer) as I2 forms
    I–(aq)

    Cl2 + 2 I- → 2 Cl- + I2

    © www.chemsheets.co.uk AS 1066 3-July-2015


    Cl2(aq) Br2(aq) I2(aq)

    Cl–(aq)
    Yellow solution Purple solution
    (organic layer) (organic layer)

    Yellow solution (organic


    layer) as Br2 forms Purple solution
    Br–(aq)
    (organic layer)
    Cl2 + 2 Br-→ 2 Cl- + Br2

    Purple solution (organic Yellow solution (organic


    layer) as I2 forms layer) as Br2 forms
    I–(aq)

    Cl2 + 2 I- → 2 Cl- + I2 Br2 + 2 I- → 2 Br- + I2

    © www.chemsheets.co.uk AS 1066 3-July-2015


    Oxidising power trend: Cl2 > Br2 > I2

    When a halogen acts as an oxidising agent, it gains


    electrons (taken from the oxidised species).
    X2 + 2 e- → 2 X-
    Cl

    Down the group it becomes harder to


    Br
    gain an electron because:
    atoms are larger & there is more
    I shielding (due to extra electron shell)

    © www.chemsheets.co.uk AS 1066 3-July-2015

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